CN105331995A - Environment-friendly industrial cleaning agent - Google Patents
Environment-friendly industrial cleaning agent Download PDFInfo
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- CN105331995A CN105331995A CN201510674862.7A CN201510674862A CN105331995A CN 105331995 A CN105331995 A CN 105331995A CN 201510674862 A CN201510674862 A CN 201510674862A CN 105331995 A CN105331995 A CN 105331995A
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- fatty alcohol
- polyoxyethylene ether
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- alcohol
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- C—CHEMISTRY; METALLURGY
- C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
- C23G—CLEANING OR DE-GREASING OF METALLIC MATERIAL BY CHEMICAL METHODS OTHER THAN ELECTROLYSIS
- C23G1/00—Cleaning or pickling metallic material with solutions or molten salts
- C23G1/24—Cleaning or pickling metallic material with solutions or molten salts with neutral solutions
- C23G1/26—Cleaning or pickling metallic material with solutions or molten salts with neutral solutions using inhibitors
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- Chemical Kinetics & Catalysis (AREA)
- General Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Mechanical Engineering (AREA)
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Abstract
The invention discloses an environment-friendly industrial cleaning agent which comprises, by weight, 4-7 parts of fatty alcohol-polyoxyethylene ether A, 10-13 parts of fatty alcohol-polyoxyethylene ether B, 5-7 parts of polyoxyethylene-polypropylene oxide block polymer, 6-9 parts of coconut oil fatty acid diethanol amide, 5-7 parts of fatty alcohol-polyoxyethylene ether sodium sulfate, 3-5 parts of triethanolamine oleic soap, 12-15 parts of sodium gluconate, 11-14 parts of sodium silicate, 5-7 parts of sodium borate, 7-9 parts of sodium molybdate and 17-19 parts of water. The fatty alcohol-polyoxyethylene ether A is a polymer obtained by mixing and addition of fatty alcohol, fatty amine and ethylene oxide, wherein the mass of fatty alcohol is larger than that of fatty amine. The fatty alcohol-polyoxyethylene ether A is fatty alcohol and ethylene oxide. The cleaning agent has the beneficial effects of being low in use concentration, high in cleaning efficiency, long in solution service life and the like and is particularly suitable for cleaning before electroplating of steel, aluminum, aluminum alloy, copper, copper alloy and other base material parts or cleaning between machining processes.
Description
Technical field
The present invention relates to a kind of environment-friendly type industrial cleaning agent, belong to technical field of surface.
Background technology
Traditional industrial cleaning agent adopts with Multiple components mixing compositions such as sodium hydroxide, tertiary sodium phosphate, sodium carbonate, sodium alkyl benzene sulfonate, alkylphenol polyoxyethylene, nitrite; in use alkali mist is large; operating environment is poor; occupational hazards is produced to operator; and discharge waste liquid and waste water to bad environmental, destroy ecological, the mankind and environment protection are constituted a serious threat.As phosphoric acid salt makes rivers and lakes nutrient laden, sodium alkyl benzene sulfonate, nitrate all belong to carcinogenic substance, and sodium alkyl benzene sulfonate, alkylphenol polyoxyethylene all in hard-degraded substance, and easily form the problems such as long term accumulation in water surrounding.Modern industrial cleaning agent is main mainly with tensio-active agent, after discharge opeing process, easily produces the problems such as COD exceeds standard.The large multipair part of existing washing composition can produce corrosion, thus makes corrosion of metal, is destroyed.
Summary of the invention
For these defects, the present invention forms with multiple material mixtures such as various new biodegradation type tensio-active agent, harmless rust-preventive agent, phosphorus-free adjuvants; There is the features such as working concentration is low, cleaning efficiency is high, bath life is long.Be specially adapted to clean between the base material part electricity cleaning before copper platings such as iron and steel, Al and Alalloy, Copper and its alloy or machining sequence.
Technical scheme of the present invention is, a kind of environment-friendly type industrial cleaning agent is provided, comprises following component by weight: 4 ~ 7 parts of poly alkyl alcohol oxidative ethane ether A, 10 ~ 13 parts of fatty alcohol-polyoxyethylene ether B, 5 ~ 7 parts of PULLRONIC F68 block polymers, 6 ~ 9 parts of cocoanut fatty acid diethanolamides, 5 ~ 7 parts of polyoxyethylenated alcohol sodium sulfate, 3 ~ 5 parts of trihydroxy ethylamine oleate soaps, 12 ~ 15 parts of Sunmorl N 60Ss, 11 ~ 14 parts of water glass, 5 ~ 7 parts of Sodium Tetraboratees, 7 ~ 9 parts of Sodium orthomolybdates, 17 ~ 19 parts of water;
The polymkeric substance that described fatty alcohol-polyoxyethylene ether A is fatty alcohol, aliphatic amide obtains with oxyethane mixing addition, wherein the quality of fatty alcohol is greater than aliphatic amide; Described fatty alcohol-polyoxyethylene ether B is the polymkeric substance that fatty alcohol and ethyleneoxide addition obtain.
Further, fatty alcohol and aliphatic amide mass ratio are 8 ~ 12:1.
Further, composed of the following components: 5 parts of poly alkyl alcohol oxidative ethane ether A, 12 parts of fatty alcohol-polyoxyethylene ether B, 6 parts of PULLRONIC F68 block polymers, 7 parts of cocoanut fatty acid diethanolamides, 6 parts of polyoxyethylenated alcohol sodium sulfate, 4 parts of trihydroxy ethylamine oleate soaps, 14 parts of Sunmorl N 60Ss, 12 parts of water glass, 7 parts of Sodium Tetraboratees, 8 parts of Sodium orthomolybdates, 19 parts of water.
In fatty alcohol-polyoxyethylene ether A, because aliphatic amide uses fatty alcohol less relatively, we still draw fat polyoxyethylenated alcohol class, adding a small amount of aliphatic amide mainly in order to improve the performance such as antirust, acidproof, sterilization, dirt-proof deposition of clean-out system, not having influence on again the cleaning performance of clean-out system simultaneously.Fatty alcohol-polyoxyethylene ether B has good emulsifying, washing, the effect such as wetting; These two kinds of fatty alcohol-polyoxyethylene ether cooperatively interact, and cleaning performance and antirust ability are significantly improved; Polyoxyethylene, oxygen oxypropylene block ether have low bubble, high detersive power effect, have froth breaking effect at environment-protecting industrial clean-out system; Fatty acid distribution of coconut oil diglycollic amide has the effects such as high infiltration, washing, wetting, dispersion; Polyoxyethylenated alcohol sodium sulfate has good foaming, decontamination, resistance to hard water effect; Other constituent materials has the effects such as good antirust, resistance to hard water.Mark Huaihe River according to QB2117 " universal metal aqueous cleaning agent ", measure to obtain washing power >=99% of this clean-out system, its rust-preventing characteristic >=24h.
The invention has the beneficial effects as follows:
(1) in fatty alcohol-polyoxyethylene ether a small amount of aliphatic amide add the performance such as antirust, acidproof, sterilization, dirt-proof deposition that improve clean-out system, do not have influence on again the cleaning performance of clean-out system simultaneously.
(2) owing to adopting the multiple auxiliary agent such as inorganic industrial water glass, Sodium Tetraborate to replace phosphoric acid salt to make auxiliary agent, eliminate the generation nutrition problem of phosphoric acid salt discharge to water surrounding, and improve cleaning effect.
(3) tensio-active agent that this environmental protection universal type industrial clean-out system adopts is all readily biodegradable type, and tool, from degradation function, realizes innoxious, solves COD excessive problem, eliminates discharge long term accumulation problem in the environment.
(4) what the inhibition component in this environmental protection universal type industrial clean-out system adopted is all nontoxic silicate, borate etc., eliminates and adopts nitrite to the harm of human and environment.
Embodiment
Embodiment 1
The present embodiment provides a kind of environment-friendly type industrial detergent, by weight, mixed by following component and form: 7g fatty alcohol-polyoxyethylene ether A, 12g fatty alcohol-polyoxyethylene ether B, 6g PULLRONIC F68 block polymer, 7g fatty acid distribution of coconut oil diglycollic amide, 6g polyoxyethylenated alcohol sodium sulfate, 4g trihydroxy ethylamine oleate soap, 14g Sunmorl N 60S, 12g water glass, 7g Sodium Tetraborate, 8g Sodium orthomolybdate, 18g water; Wherein fatty alcohol-polyoxyethylene ether A be fatty alcohol, the polymkeric substance that obtains with oxyethane mixing addition of aliphatic amide, the fatty alcohol that addition reaction is used and aliphatic amide mass ratio are 8:1.
As follows by the effect of this clean-out system cleaning components: washing power >=99.2%; Rust-preventing characteristic >=28h.
Embodiment 2
The present embodiment provides a kind of environment-friendly type industrial detergent, by weight, mixed by following component and form: 5g fatty alcohol-polyoxyethylene ether A, 12g fatty alcohol-polyoxyethylene ether B, 6g PULLRONIC F68 block polymer, 7g fatty acid distribution of coconut oil diglycollic amide, 6g polyoxyethylenated alcohol sodium sulfate, 4g trihydroxy ethylamine oleate soap, 14g Sunmorl N 60S, 12g water glass, 7g Sodium Tetraborate, 8g Sodium orthomolybdate, 19g water; Wherein fatty alcohol-polyoxyethylene ether A be fatty alcohol, the polymkeric substance that obtains with oxyethane mixing addition of aliphatic amide, the fatty alcohol that addition reaction is used and aliphatic amide mass ratio are 10:1.
As follows by the effect of this clean-out system cleaning components: washing power >=99.5%; Rust-preventing characteristic >=34h.
Embodiment 3
The present embodiment provides a kind of environment-friendly type industrial detergent, by weight, mixed by following component and form: 6g fatty alcohol-polyoxyethylene ether A, 11g fatty alcohol-polyoxyethylene ether B, 6g PULLRONIC F68 block polymer, 7g fatty acid distribution of coconut oil diglycollic amide, 6g polyoxyethylenated alcohol sodium sulfate, 4g trihydroxy ethylamine oleate soap, 14g Sunmorl N 60S, 12g water glass, 7g Sodium Tetraborate, 8g Sodium orthomolybdate, 18g water; Wherein fatty alcohol-polyoxyethylene ether A be fatty alcohol, the polymkeric substance that obtains with oxyethane mixing addition of aliphatic amide, the fatty alcohol that addition reaction is used and aliphatic amide mass ratio are 10:1.
As follows by the effect of this clean-out system cleaning components: washing power >=99.2%; Rust-preventing characteristic >=27h.
Embodiment 4
The present embodiment provides a kind of environment-friendly type industrial detergent, by weight, mixed by following component and form: 6g fatty alcohol-polyoxyethylene ether A, 12g fatty alcohol-polyoxyethylene ether B, 7g PULLRONIC F68 block polymer, 7g fatty acid distribution of coconut oil diglycollic amide, 6g polyoxyethylenated alcohol sodium sulfate, 4g trihydroxy ethylamine oleate soap, 14g Sunmorl N 60S, 12g water glass, 6g Sodium Tetraborate, 8g Sodium orthomolybdate, 17g water; Wherein fatty alcohol-polyoxyethylene ether A be fatty alcohol, the polymkeric substance that obtains with oxyethane mixing addition of aliphatic amide, the fatty alcohol that addition reaction is used and aliphatic amide mass ratio are 20:1.
As follows by the effect of this clean-out system cleaning components: washing power >=99.2%; Rust-preventing characteristic >=24h.
Claims (3)
1. an environment-friendly type industrial cleaning agent, is characterized in that, comprises following component by weight:
4 ~ 7 parts of poly alkyl alcohol oxidative ethane ether A,
10 ~ 13 parts of fatty alcohol-polyoxyethylene ether B,
5 ~ 7 parts of PULLRONIC F68 block polymers,
6 ~ 9 parts of cocoanut fatty acid diethanolamides,
5 ~ 7 parts of polyoxyethylenated alcohol sodium sulfate,
3 ~ 5 parts of trihydroxy ethylamine oleate soaps,
12 ~ 15 parts of Sunmorl N 60Ss,
11 ~ 14 parts of water glass,
5 ~ 7 parts of Sodium Tetraboratees,
7 ~ 9 parts of Sodium orthomolybdates,
17 ~ 19 parts of water;
The polymkeric substance that described fatty alcohol-polyoxyethylene ether A is fatty alcohol, aliphatic amide obtains with oxyethane mixing addition, wherein the quality of fatty alcohol is greater than aliphatic amide;
Described fatty alcohol-polyoxyethylene ether B is the polymkeric substance that fatty alcohol and ethyleneoxide addition obtain.
2. industrial cleaning agent as claimed in claim 1, it is characterized in that, fatty alcohol and aliphatic amide mass ratio are 8 ~ 12:1.
3. industrial cleaning agent as claimed in claim 1 or 2, is characterized in that, composed of the following components:
5 parts of poly alkyl alcohol oxidative ethane ether A,
12 parts of fatty alcohol-polyoxyethylene ether B,
6 parts of PULLRONIC F68 block polymers,
7 parts of cocoanut fatty acid diethanolamides,
6 parts of polyoxyethylenated alcohol sodium sulfate,
4 parts of trihydroxy ethylamine oleate soaps,
14 parts of Sunmorl N 60Ss,
12 parts of water glass,
7 parts of Sodium Tetraboratees,
8 parts of Sodium orthomolybdates,
19 parts of water.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
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| CN201510674862.7A CN105331995B (en) | 2015-10-19 | 2015-10-19 | A kind of environment-friendly type industrial cleaning agent |
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| CN201510674862.7A CN105331995B (en) | 2015-10-19 | 2015-10-19 | A kind of environment-friendly type industrial cleaning agent |
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| CN105331995A true CN105331995A (en) | 2016-02-17 |
| CN105331995B CN105331995B (en) | 2018-03-16 |
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Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN106521530A (en) * | 2016-12-07 | 2017-03-22 | 江西瑞思博化工有限公司 | Efficient wax solvent of metal workpiece and preparation method thereof |
| CN108395943A (en) * | 2018-05-25 | 2018-08-14 | 上海巨石化工有限公司 | A kind of multifunctional efficient aqueous cleaning agent and preparation method thereof |
| CN112522723A (en) * | 2020-11-20 | 2021-03-19 | 天津迪亚赫斯科技有限公司 | Water-soluble precision cleaning solution and preparation method thereof |
| CN114621826A (en) * | 2022-03-30 | 2022-06-14 | 苏州科锐德节能环境科技有限公司 | Environment-friendly oil-separating type battery shell heavy oil stain cleaning agent |
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| CN101565831A (en) * | 2009-04-30 | 2009-10-28 | 深圳市科玺化工有限公司 | Cyclic renewable water-based cleaning agent and cyclic renewing technology |
| CN103014730A (en) * | 2013-01-18 | 2013-04-03 | 华东理工大学 | Environment-friendly low-temperature efficient metal cleaner |
| CN104130873A (en) * | 2014-07-18 | 2014-11-05 | 青岛蓬勃石油技术服务有限公司 | Corrosion-resistant cleaning agent special for crude oil storage tank and preparation method thereof |
| CN104830583A (en) * | 2015-04-08 | 2015-08-12 | 湖州南浔宏亮纺织有限公司 | Novel cleaning agent for fur-containing textile and preparation method thereof |
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2015
- 2015-10-19 CN CN201510674862.7A patent/CN105331995B/en active Active
Patent Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
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| CN101565831A (en) * | 2009-04-30 | 2009-10-28 | 深圳市科玺化工有限公司 | Cyclic renewable water-based cleaning agent and cyclic renewing technology |
| CN103014730A (en) * | 2013-01-18 | 2013-04-03 | 华东理工大学 | Environment-friendly low-temperature efficient metal cleaner |
| CN104130873A (en) * | 2014-07-18 | 2014-11-05 | 青岛蓬勃石油技术服务有限公司 | Corrosion-resistant cleaning agent special for crude oil storage tank and preparation method thereof |
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| Publication number | Priority date | Publication date | Assignee | Title |
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| CN106521530A (en) * | 2016-12-07 | 2017-03-22 | 江西瑞思博化工有限公司 | Efficient wax solvent of metal workpiece and preparation method thereof |
| CN106521530B (en) * | 2016-12-07 | 2019-05-03 | 江西瑞思博化工有限公司 | Efficient Wax removal water of metal works and preparation method thereof |
| CN108395943A (en) * | 2018-05-25 | 2018-08-14 | 上海巨石化工有限公司 | A kind of multifunctional efficient aqueous cleaning agent and preparation method thereof |
| CN108395943B (en) * | 2018-05-25 | 2020-04-03 | 上海巨石化工有限公司 | Multifunctional efficient water-based cleaning agent and preparation method thereof |
| CN112522723A (en) * | 2020-11-20 | 2021-03-19 | 天津迪亚赫斯科技有限公司 | Water-soluble precision cleaning solution and preparation method thereof |
| CN114621826A (en) * | 2022-03-30 | 2022-06-14 | 苏州科锐德节能环境科技有限公司 | Environment-friendly oil-separating type battery shell heavy oil stain cleaning agent |
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| CN105331995B (en) | 2018-03-16 |
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