CN105331995B - A kind of environment-friendly type industrial cleaning agent - Google Patents
A kind of environment-friendly type industrial cleaning agent Download PDFInfo
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- CN105331995B CN105331995B CN201510674862.7A CN201510674862A CN105331995B CN 105331995 B CN105331995 B CN 105331995B CN 201510674862 A CN201510674862 A CN 201510674862A CN 105331995 B CN105331995 B CN 105331995B
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- C—CHEMISTRY; METALLURGY
- C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
- C23G—CLEANING OR DE-GREASING OF METALLIC MATERIAL BY CHEMICAL METHODS OTHER THAN ELECTROLYSIS
- C23G1/00—Cleaning or pickling metallic material with solutions or molten salts
- C23G1/24—Cleaning or pickling metallic material with solutions or molten salts with neutral solutions
- C23G1/26—Cleaning or pickling metallic material with solutions or molten salts with neutral solutions using inhibitors
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Abstract
The invention discloses a kind of environment-friendly type industrial cleaning agent, and it includes following components by weight：4~7 parts of fatty alcohol polyoxyethylene ether A, 10~13 parts of AEO B, 5~7 parts of polyoxyethylene polyoxypropylene block polymers, 6~9 parts of cocoanut fatty acid diethanolamides, 5~7 parts of sodium sulfate of polyethenoxy ether of fatty alcohol, 3~5 parts of trihydroxy ethylamine oleate soaps, 12~15 parts of sodium gluconates, 11~14 parts of sodium metasilicate, 5~7 parts of Boratexes, 7~9 parts of sodium molybdates, 17~19 parts of water；The polymer that the AEO A is fatty alcohol, fatty amine obtains with oxirane mixing addition, the wherein quality of fatty alcohol are more than fatty amine；The AEO A is fatty alcohol and oxirane.The cleaning agent has the characteristics that concentration is low, cleaning efficiency is high, bath life is long, especially suitable for being cleaned between the base material part electricity cleaning before copper plating such as steel, aluminium and aluminium alloy, copper and copper alloy or machining sequence.
Description
Technical field
The present invention relates to a kind of environment-friendly type industrial cleaning agent, belong to technical field of surface.
Background technology
Traditional industrial cleaning agent uses to be gathered with sodium hydroxide, tertiary sodium phosphate, sodium carbonate, sodium alkyl benzene sulfonate, alkyl phenol
The Multiple components such as oxygen vinethene, nitrite mixing composition, alkali mist is big in use, and operating environment is poor, and operator is produced
Raw occupational hazards, and the waste liquid and waste water that discharge are harmful to environment, destroy ecology, form serious prestige to the mankind and environmental protection
The side of body.As phosphate makes rivers and lakes nutrient laden, sodium alkyl benzene sulfonate, nitrate all belong to carcinogen, sodium alkyl benzene sulfonate, alkyl
Phenol polyethenoxy ether all in hard-degraded substance, and easily in water environment formed long term accumulation the problems such as.Modern industrial cleaning agent,
More based on surfactant, after discharge opeing processing, the problems such as COD is exceeded is easily produced.The part meeting multipair greatly of existing detergent
Corrosion is produced, so that corrosion of metal, is destroyed.
The content of the invention
For these defects, the present invention is with various new Biodegradable surfactant, harmless antirust agent, without phosphorus
The multiple material mixture such as auxiliary agent forms；Have the characteristics that concentration is low, cleaning efficiency is high, bath life is long.Especially suitable for
To being cleaned between the base material part electricity cleaning before copper plating such as steel, aluminium and aluminium alloy, copper and copper alloy or machining sequence.
The technical scheme is that, there is provided a kind of environment-friendly type industrial cleaning agent, by weight including following components：4~7
Part fatty alcohol polyoxyethylene ether A, 10~13 parts of AEO B, 5~7 parts of PULLRONIC F68 blocks gather
Compound, 6~9 parts of cocoanut fatty acid diethanolamides, 5~7 parts of sodium sulfate of polyethenoxy ether of fatty alcohol, 3~5 parts of triethanolamines
Oleate soap, 12~15 parts of sodium gluconates, 11~14 parts of sodium metasilicate, 5~7 parts of Boratexes, 7~9 parts of sodium molybdates, 17~19 parts
Water；
The polymer that the AEO A is fatty alcohol, fatty amine obtains with oxirane mixing addition,
Wherein the quality of fatty alcohol is more than fatty amine；The AEO B is what fatty alcohol obtained with ethyleneoxide addition
Polymer.
Further, fatty alcohol and fatty amine mass ratio are 8~12:1.
Further, it is composed of the following components：5 parts of fatty alcohol polyoxyethylene ether A, 12 parts of AEO B,
6 parts of PULLRONIC F68 block polymers, 7 parts of cocoanut fatty acid diethanolamides, 6 parts of AEOs
Sodium sulphate, 4 parts of trihydroxy ethylamine oleate soaps, 14 parts of sodium gluconates, 12 parts of sodium metasilicate, 7 parts of Boratexes, 8 parts of sodium molybdates, 19 parts
Water.
In AEO A, because fatty amine is relative less with fatty alcohol, we still draw fat alcohol polyoxy
Ethene ethers, add a small amount of fatty amine primarily to improving the performances such as the antirust of cleaning agent, acidproof, sterilization, antifouling dirt deposition, together
When do not interfere with the cleaning performance of cleaning agent again.AEO B has the effect such as good emulsification, washing, wetting；
Both AEOs cooperate so that cleaning performance and antirust ability significantly improve；Polyoxyethylene, oxygen oxygen third
Alkene block ether has low bubble, the effect of high detergency, has defoaming effect in environment-protecting industrial cleaning agent；Fatty acid distribution of coconut oil diethanol acyl
Amine has the effect such as high infiltration, washing, wetting, scattered；Sodium sulfate of polyethenoxy ether of fatty alcohol has good foaming, gone
Dirty, resistance to hard water effect；Other component materials have the effect such as good antirust, resistance to hard water.According to QB2117《Universal metal is water base
Cleaning agent》Huaihe River is marked, determines washing power >=99% for obtaining the cleaning agent, its rust-preventing characteristic >=24h.
The beneficial effects of the invention are as follows：
（1）The addition of a small amount of fatty amine improves the antirust of cleaning agent, acidproof, sterilization, anti-in AEO
The performances such as dirt deposition, while the cleaning performance of cleaning agent is not interfered with again.
（2）Due to making auxiliary agent instead of phosphate using a variety of auxiliary agents such as inorganic industrial sodium metasilicate, Boratexes, phosphoric acid is eliminated
Generation nutrition problem of the salt emission to water environment, and improve cleaning effect.
（3）The surfactant that this environmentally friendly universal type industrial cleaning agent uses all is easily biological-degradable type, is had from degraded work(
Can, realize innoxious, solve COD excessive problems, eliminate emission long term accumulation problem in the environment.
（4）What inhibition component in this environmentally friendly universal type industrial cleaning agent used is all nontoxic silicate, borate etc.,
Eliminate and use harm of the nitrite to human and environment.
Embodiment
Embodiment 1
The present embodiment provides a kind of environment-friendly type industrial detergent, by weight, is formed by following components is well mixed：7g fat
Fat alcohol APEO A, 12g AEO B, 6g PULLRONIC F68 block polymer, 7g cocounut oil
Fatty diglycollic amide, 6g sodium sulfate of polyethenoxy ether of fatty alcohol, 4g trihydroxy ethylamine oleate soaps, 14g sodium gluconates, 12g
Sodium metasilicate, 7g Boratexes, 8g sodium molybdates, 18g water；Wherein AEO A is fatty alcohol, fatty amine and epoxy second
The polymer that alkane mixing addition obtains, fatty alcohol and fatty amine mass ratio used in addition reaction are 8:1.
The effect that part is cleaned with the cleaning agent is as follows：Washing power >=99.2%；Rust-preventing characteristic >=28h.
Embodiment 2
The present embodiment provides a kind of environment-friendly type industrial detergent, by weight, is formed by following components is well mixed：5g fat
Fat alcohol APEO A, 12g AEO B, 6g PULLRONIC F68 block polymer, 7g cocounut oil
Fatty diglycollic amide, 6g sodium sulfate of polyethenoxy ether of fatty alcohol, 4g trihydroxy ethylamine oleate soaps, 14g sodium gluconates, 12g
Sodium metasilicate, 7g Boratexes, 8g sodium molybdates, 19g water；Wherein AEO A is fatty alcohol, fatty amine and epoxy second
The polymer that alkane mixing addition obtains, fatty alcohol and fatty amine mass ratio used in addition reaction are 10:1.
The effect that part is cleaned with the cleaning agent is as follows：Washing power >=99.5%；Rust-preventing characteristic >=34h.
Embodiment 3
The present embodiment provides a kind of environment-friendly type industrial detergent, by weight, is formed by following components is well mixed：6g fat
Fat alcohol APEO A, 11g AEO B, 6g PULLRONIC F68 block polymer, 7g cocounut oil
Fatty diglycollic amide, 6g sodium sulfate of polyethenoxy ether of fatty alcohol, 4g trihydroxy ethylamine oleate soaps, 14g sodium gluconates, 12g
Sodium metasilicate, 7g Boratexes, 8g sodium molybdates, 18g water；Wherein AEO A is fatty alcohol, fatty amine and epoxy second
The polymer that alkane mixing addition obtains, fatty alcohol and fatty amine mass ratio used in addition reaction are 10:1.
The effect that part is cleaned with the cleaning agent is as follows：Washing power >=99.2%；Rust-preventing characteristic >=27h.
Embodiment 4
The present embodiment provides a kind of environment-friendly type industrial detergent, by weight, is formed by following components is well mixed：6g fat
Fat alcohol APEO A, 12g AEO B, 7g PULLRONIC F68 block polymer, 7g cocounut oil
Fatty diglycollic amide, 6g sodium sulfate of polyethenoxy ether of fatty alcohol, 4g trihydroxy ethylamine oleate soaps, 14g sodium gluconates, 12g
Sodium metasilicate, 6g Boratexes, 8g sodium molybdates, 17g water；Wherein AEO A is fatty alcohol, fatty amine and epoxy second
The polymer that alkane mixing addition obtains, fatty alcohol and fatty amine mass ratio used in addition reaction are 20:1.
The effect that part is cleaned with the cleaning agent is as follows：Washing power >=99.2%；Rust-preventing characteristic >=24h.
Claims (3)
1. a kind of environment-friendly type industrial cleaning agent, it is characterised in that by weight including following components：
4~7 parts of fatty alcohol polyoxyethylene ether A,
10~13 parts of AEO B,
5~7 parts of PULLRONIC F68 block polymers,
6~9 parts of cocoanut fatty acid diethanolamides,
5~7 parts of sodium sulfate of polyethenoxy ether of fatty alcohol,
3~5 parts of trihydroxy ethylamine oleate soaps,
12~15 parts of sodium gluconates,
11~14 parts of sodium metasilicate,
5~7 parts of Boratexes,
7~9 parts of sodium molybdates,
17~19 parts of water；
The polymer that the AEO A is fatty alcohol, fatty amine obtains with oxirane mixing addition, wherein
The quality of fatty alcohol is more than fatty amine；
The AEO B is the polymer that fatty alcohol obtains with ethyleneoxide addition.
2. industrial cleaning agent as claimed in claim 1, it is characterised in that fatty alcohol is 8~12 with fatty amine mass ratio:1.
3. industrial cleaning agent as claimed in claim 1 or 2, it is characterised in that composed of the following components：
5 parts of fatty alcohol polyoxyethylene ether A,
12 parts of AEO B,
6 parts of PULLRONIC F68 block polymers,
7 parts of cocoanut fatty acid diethanolamides,
6 parts of sodium sulfate of polyethenoxy ether of fatty alcohol,
4 parts of trihydroxy ethylamine oleate soaps,
14 parts of sodium gluconates,
12 parts of sodium metasilicate,
7 parts of Boratexes,
8 parts of sodium molybdates,
19 parts of water.
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| Application Number | Priority Date | Filing Date | Title |
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| CN201510674862.7A CN105331995B (en) | 2015-10-19 | 2015-10-19 | A kind of environment-friendly type industrial cleaning agent |
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| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201510674862.7A CN105331995B (en) | 2015-10-19 | 2015-10-19 | A kind of environment-friendly type industrial cleaning agent |
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| Publication Number | Publication Date |
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| CN105331995A CN105331995A (en) | 2016-02-17 |
| CN105331995B true CN105331995B (en) | 2018-03-16 |
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Families Citing this family (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN106521530B (en) * | 2016-12-07 | 2019-05-03 | 江西瑞思博化工有限公司 | Efficient Wax removal water of metal works and preparation method thereof |
| CN108395943B (en) * | 2018-05-25 | 2020-04-03 | 上海巨石化工有限公司 | Multifunctional efficient water-based cleaning agent and preparation method thereof |
| CN112522723A (en) * | 2020-11-20 | 2021-03-19 | 天津迪亚赫斯科技有限公司 | Water-soluble precision cleaning solution and preparation method thereof |
| CN114621826A (en) * | 2022-03-30 | 2022-06-14 | 苏州科锐德节能环境科技有限公司 | Environment-friendly oil-separating type battery shell heavy oil stain cleaning agent |
Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101565831A (en) * | 2009-04-30 | 2009-10-28 | 深圳市科玺化工有限公司 | Cyclic renewable water-based cleaning agent and cyclic renewing technology |
| CN103014730A (en) * | 2013-01-18 | 2013-04-03 | 华东理工大学 | Environment-friendly low-temperature efficient metal cleaner |
| CN104130873A (en) * | 2014-07-18 | 2014-11-05 | 青岛蓬勃石油技术服务有限公司 | Corrosion-resistant cleaning agent special for crude oil storage tank and preparation method thereof |
| CN104830583A (en) * | 2015-04-08 | 2015-08-12 | 湖州南浔宏亮纺织有限公司 | Novel cleaning agent for fur-containing textile and preparation method thereof |
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- 2015-10-19 CN CN201510674862.7A patent/CN105331995B/en active Active
Patent Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101565831A (en) * | 2009-04-30 | 2009-10-28 | 深圳市科玺化工有限公司 | Cyclic renewable water-based cleaning agent and cyclic renewing technology |
| CN103014730A (en) * | 2013-01-18 | 2013-04-03 | 华东理工大学 | Environment-friendly low-temperature efficient metal cleaner |
| CN104130873A (en) * | 2014-07-18 | 2014-11-05 | 青岛蓬勃石油技术服务有限公司 | Corrosion-resistant cleaning agent special for crude oil storage tank and preparation method thereof |
| CN104830583A (en) * | 2015-04-08 | 2015-08-12 | 湖州南浔宏亮纺织有限公司 | Novel cleaning agent for fur-containing textile and preparation method thereof |
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| CN105331995A (en) | 2016-02-17 |
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