CN106801230A - A kind of galvanized sheet surface cleaning agent and preparation method thereof - Google Patents
A kind of galvanized sheet surface cleaning agent and preparation method thereof Download PDFInfo
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- CN106801230A CN106801230A CN201611259709.9A CN201611259709A CN106801230A CN 106801230 A CN106801230 A CN 106801230A CN 201611259709 A CN201611259709 A CN 201611259709A CN 106801230 A CN106801230 A CN 106801230A
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- cleaning agent
- galvanized sheet
- agent
- sheet surface
- surface cleaning
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- C—CHEMISTRY; METALLURGY
- C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
- C23G—CLEANING OR DE-GREASING OF METALLIC MATERIAL BY CHEMICAL METHODS OTHER THAN ELECTROLYSIS
- C23G1/00—Cleaning or pickling metallic material with solutions or molten salts
- C23G1/14—Cleaning or pickling metallic material with solutions or molten salts with alkaline solutions
- C23G1/19—Iron or steel
-
- C—CHEMISTRY; METALLURGY
- C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
- C23G—CLEANING OR DE-GREASING OF METALLIC MATERIAL BY CHEMICAL METHODS OTHER THAN ELECTROLYSIS
- C23G1/00—Cleaning or pickling metallic material with solutions or molten salts
- C23G1/14—Cleaning or pickling metallic material with solutions or molten salts with alkaline solutions
- C23G1/16—Cleaning or pickling metallic material with solutions or molten salts with alkaline solutions using inhibitors
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- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- General Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Mechanical Engineering (AREA)
- Metallurgy (AREA)
- Organic Chemistry (AREA)
- Cleaning And De-Greasing Of Metallic Materials By Chemical Methods (AREA)
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Abstract
The present invention discloses a kind of galvanized sheet surface cleaning agent, composition of the cleaning agent comprising following weight/mass percentage composition：Cocoamidopropyl betaine 0.1 1%, anion surfactant 1 10%, nonionic surfactant 1 10%, bleeding agent 1 5%, sodium gluconate 1 10%, other are water.Galvanized sheet surface cleaning agent cleansing power of the present invention is stronger, may be such that greasy dirt and particulate matter the cleaning ratio on surface more thoroughly, cleaning rate is corrosion-free to metal surface more than 98%, its rust-preventing characteristic reach 0 grade, good stability, pollution-free, biodegradability it is good.In addition, the present invention discloses a kind of preparation method of galvanized sheet surface cleaning agent, its preparation method is relatively easy, it is not necessary to special process equipment, it is only necessary to completed by being uniformly mixed under raw material normal temperature.
Description
Technical field
The present invention relates to a kind of metal surface cleaning agent, more particularly to a kind of cleaning for being applied to galvanized sheet surface degreasing
Agent.
Background technology
In Treatment of Metal Surface, degreasing is important technical process, and antirust is also the most important thing, metallic article surface
Antirust degreasing degree will directly influence the subsequent treatment quality of product.Antirust degreasing agent is also referred to as cleaning agent, in the market
Cleaning agent be typically all finger aqueous cleaning agent.Water base metal cleaning agent has with water generation oil, save energy, does not endanger operator
Health, reduction pollution, environmental protection, cleaning low cost and other advantages, are widely used in surface degreasing, scale removal before and after intermetallic composite coating
And in the cleaning before finished product assembling or packaging.
Its detergency mechanism is as follows:When water falls on the metal base of machining and metal pipe cap surface, on surface
In the presence of power, You Heshui makes to form an immiscible interface between them, so as to lose to respective internal contraction
Gone wetting action of the water to metal base and metal pipe cap, after adding cleaning agent, surfactant molecule be just attached to oil with
On the immiscible interface of water, so as to reduce the surface tension between oil and the immiscible interface of water.
The hydrophobic group of surfactant molecule stretches to greasy dirt, and affinity interaction is produced with greasy dirt, and greasy dirt is surrounded, and makes
Metal base, the adhesion between metal pipe cap and greasy dirt weaken.Hydrophilic group stretches to water, and immiscible oil is linked with water
Come, the aqueous solution for making metal base, metal pipe cap soon be cleaned agent is soaked.Greasy dirt in the presence of stirring or vibration, very
Easily depart from from metal base and metal pipe cap surface, and be suspended in water.At this moment, water turns into emulsion, and produces bubble
Foam, these foams can discard greasy dirt parcel, reach the purpose except degreasing.
In recent years, the output of China's galvanized sheet is increasing year by year, and also increasing year by year, increasing degree is higher than exit port amount
The increase of output；Deduct after production repeats to count, galvanized sheet consumption figure is about 5,270,000 tons, thus galvanized sheet surface treatment
It is also a critically important part in Treatment of Metal Surface, and during degreasing metal oil removing operation is the weight in whole process
Weight.
In automobile, household electrical appliances, the industry such as both mechanically and electrically, in order to meet product appearance and improve metal service life will
Ask, it is a large amount of to use steel galvanization part or zinc-iron alloy part (abbreviation zinc part).And metallic zinc part is in manufacture, storage and transportation
In, the presence for always having various greasy dirts, these greasy dirts in its surface deposition have impact on the processing characteristics of metal works, or even cause
The failure of application, thus metallic zinc part must carry out degreasing before application, and the various greasy dirts on its surface are sticked to remove.
About 800,000 tons or so of the washing oil of China's consumption every year.On the one hand with the high speed development of China's industry, the energy
Problem becomes increasingly conspicuous, the long-term gasoline for being used for degreasing oil contamination on metal, kerosene, the supply also growing tension of diesel oil, on the other hand exists
When being washed with oil, with inflammable danger, discharge has pollution, and this with other degreasing agents in the urgent need to replacing solvent oils
Degreasing agent alleviate the anxiety of energy supply, and reduce the pollution to degreasing raffinate to environment.
The zinc part degreasing commonly used in current industrial production be with phosphorous alkaline defatting agent, it is higher to metallic matrix product containing alkali
Raw corrosion, makes the performance of metal works change；The chemical substance such as phosphorous can cause the eutrophication of rivers and lakes water.With the country
The fast development of economic technology, the requirement more and more higher to degreasing agent, this is accomplished by further developing efficiently, economical and environmentally friendly
Degreasing agent meets industrial demand.
Aqueous slkali degreasing is also widely used in industrial production, because aqueous slkali, will not burn, required equipment letter
It is single, it is simple to operate and cheap.NaOH, Na are typically contained in aqueous slkali liquid degreasing agent2CO3、NaHCO3、Na3PO4、
Na2HPO4Deng while adding Na5P3O10,Na4P2O7, the intercalating agent such as tetrasodium ethylenediamine tetraacetate, be complexed using these intercalating agents molten
Metal ion of the solution in alkali lye, improves the load oil ability and degreasing effect of alkali lye, while these intercalating agents also have in alkali lye
There are dispersion, emulsification, resistance to hard water and the performance such as prevent metal to be corroded.Phosphate is always that important the helping for synthesizing degreasing agent field is washed
Agent, it can improve the degreasing efficiency of surfactant, dispersion, emulsification, solubilized dirt, and chelant hard calcium, magnesium ion generation are solvable
Property complex compound, prevent soil redeposition, buffering basicity wash function again to improve.Meanwhile, phosphorus is also to cause Water Eutrophication, algae
Class is spread unchecked by phytoplankton, and " red tide " occurs in ocean, one of arch-criminal of rivers and lakes water quality deterioration.As countries in the world limit
Phosphorus, prohibits phosphorus cry and grows to even greater heights, and the requirement that the most of coastal and rivers and lakes regional legislation of China prohibits phosphorus is more and more tighter
Lattice, therefore suddenly wait that developing and develop nontoxic, pollution-free and without phosphorus environment-friendly type new product replaces phosphate.
When degreasing is carried out using aqueous slkali, the concentration of aqueous slkali is too low or too high all by influence degreasing efficiency, and such alkali is dense
Degree must be controlled in optimal concentration range, and otherwise some metals can be corroded in the solution, and metal base is corroded
The performance and finishing operations of whole metal works are influenceed afterwards, it is also possible to cause the failure of finishing operations, therefore, be according to difference
Metal material strictly control the concentration of aqueous slkali and the pH value of solution, but be difficult to effectively be controlled in industrialized production,
And the discharge of alkali wasteliquid has a certain impact to environment.
The performance and quality of electronic product can be influenceed during due to aqueous degreaser, is mainly made in high-precision electronic product
With organic solvent, some can be made to be difficult to be dissolved in the oil emulsion and saponified oil of alkali can be dissolved in wherein well.But advising greatly
Harm in the industrial production of mould due to organic solvent to human body is big, and environmental pollution is serious, and trichloroethanes etc. damages the ozone layer
Material oneself through being prohibited from using；And greasy dirt can not be removed thoroughly, because the molten traditional work when attachment on the metal surface
Mainly oil wash and alkali cleaning are used in industry production.Oil wash method solution grease organic solvent volatilization after, because greasy dirt can not
Vapor away, one layer of thin greasy dirt developing rapidly with industrialized production, various and greasy dirt the composition of the species of greasy dirt will be left
Also become increasingly complex.Various bonding forms of industrial greasy dirt and degreasing object, form chemistry, the water base degreasing of good physical properties and take off
Fat agent is particularly important.The application field of degreasing agent expands day by day, and the kind of degreasing agent is also increasing, reduces cost of material, adopts
With the surfactant of excellent special efficacy, strengthen one that various effective ingredient composition researchs have become degreasing metal surface field
Important research direction.
The content of the invention
There is provided that a kind of cleaning efficiency is high, biological drop it is an object of the invention to overcome above-mentioned the deficiencies in the prior art part
The solution good galvanized sheet surface cleaning agent of performance.
To achieve the above object, the technical scheme taken of the present invention is：A kind of galvanized sheet surface cleaning agent, comprising following matter
Measure the composition of percentage composition：Cocoamidopropyl betaine 0.1-1%, anion surfactant 1-10%, non-ionic surface
Activating agent 1-10%, bleeding agent 1-5%, sodium gluconate 1-10%, other are deionized water.
Influences of the various auxiliary agents to degreasing rate of present inventor's comprehensive analysis, the present invention has been obtained by orthogonal experiment
The galvanized sheet surface cleaning agent, and technique for applying to degreasing agent studies.
Used as the preferred embodiment of galvanized sheet surface cleaning agent of the present invention, the anion surfactant is alkane
Base benzene sulfonic acid sodium salt；Preferably, the anion surfactant is neopelex.
Used as the preferred embodiment of galvanized sheet surface cleaning agent of the present invention, the nonionic surfactant is different
Tridecyl alcohol APEO or AEO.
Used as the preferred embodiment of galvanized sheet surface cleaning agent of the present invention, the bleeding agent is Polyoxyethylene fatty
Alcohol ether or isooctanol polyethoxylate sulfuric ester.
Galvanized sheet surface cleaning agent of the present invention is strong using the special quaternary ammonium salt group of Cocoamidopropyl betaine
Inhale electrical, meanwhile, the hydrophilic radical-COO positioned at carbochain end is coordinated under alkalescence condition-, with the stronger of reduction surface tension
Effect, thus show more excellent cleansing power.Simultaneously because the amide group of Cocoamidopropyl betaine, increased the moon
The compatibility and dissolubility of ionic surface active agent such as sodium alkyl benzene sulfonate and nonionic surfactant such as polyethenoxy ether class
Can, make cleansing power more excellent, product is more stable, gentle.
Used as the preferred embodiment of galvanized sheet surface cleaning agent of the present invention, the cleaning agent includes following quality hundred
Divide the composition of content：Cocoamidopropyl betaine 0.2-0.8%, anion surfactant 5-10%, non-ionic surface are lived
Property agent 0.1-5%, bleeding agent 2-5%, sodium gluconate 2-10%, other are water.
Used as the preferred embodiment of galvanized sheet surface cleaning agent of the present invention, the cleaning agent includes following quality hundred
Divide the composition of content：Cocoamidopropyl betaine 0.3-0.5%, anion surfactant 4-8%, non-ionic surface active
Agent 0.5-2%, bleeding agent 2-4%, sodium gluconate 3-8%, other are water.
As the preferred embodiment of galvanized sheet surface cleaning agent of the present invention, the cleaning agent also comprising sodium carbonate or
NaOH；In the cleaning agent, the weight/mass percentage composition of sodium carbonate or NaOH is 1-30%.
As the preferred embodiment of galvanized sheet surface cleaning agent of the present invention, the cleaning agent also comprising isopropanol or
Ethylene glycol monobutyl ether；In the cleaning agent, the weight/mass percentage composition of isopropanol or ethylene glycol monobutyl ether is 1-5%.
Used as the preferred embodiment of galvanized sheet surface cleaning agent of the present invention, the cleaning agent also includes wetting agent；
In the cleaning agent, the weight/mass percentage composition of wetting agent is 1-5%.After adding wetting agent, the cleaning performance to cleaning agent is improved
Significantly.
Used as the preferred embodiment of galvanized sheet surface cleaning agent of the present invention, the wetting agent is silicate.Add
After silicate, the wetability of surface cleaning agent is significantly improved.
In addition, the present invention discloses a kind of preparation method of the galvanized sheet surface cleaning agent, it is comprised the following steps：First will
The sodium carbonate of solid-state, sodium alkyl benzene sulfonate, sodium gluconate, corrosion inhibiter these four compositions are added in deionized water in sequence,
Stirring and dissolving is until all dissolvings, are then placed in sequentially adding the Cocoamidopropyl betaine of liquid, anion surface active
Agent, nonionic surfactant, bleeding agent, are stirred continuously, and it is foamed, and after stirring 10min, liquid uniformly mixes, foam
Disappear, obtain final product galvanized sheet surface cleaning agent of the present invention.
The beneficial effect of galvanized sheet surface cleaning agent of the present invention is：Cleaning agent cleansing power is stronger, and scavenging period is short,
Manpower and the energy are greatly saved, improving operating efficiency, oil stain, particulate matter to zinc-plated plate surface etc. has efficient cleaning
Effect, may be such that greasy dirt and particulate matter the cleaning ratio on surface more thoroughly；Cleaning way either soaks or sprays 5-8min i.e.
Can, can carry out film conversion processing after drying；Galvanized sheet surface cleaning agent pH value of the present invention is typically presented alkalescent, for machine
The rate of corrosion of tool equipment is relatively low, using comparatively safe reliability, can reduce the amortization charge of equipment, reduces the corruption to metal etc.
Erosion.The preparation method of galvanized sheet surface cleaning agent of the present invention is simple and convenient, and production technology is relatively easy, it is not necessary to special technique
Equipment, it is only necessary to completed by being uniformly mixed under raw material normal temperature.
Specific embodiment
For the object, technical solutions and advantages of the present invention are better described, below in conjunction with specific embodiment to the present invention
It is described further.
Embodiment 1
A kind of embodiment of galvanized sheet surface cleaning agent of the present invention, cleaning agent described in the present embodiment includes following quality percentage
The composition of content：Cocoamidopropyl betaine 0.2%, anion surfactant：Sodium alkyl benzene sulfonate 9%, nonionic table
Face activating agent：Isotrideyl alcohol APEO 1%, bleeding agent：Polyoxyethylene aliphatic alcohol ether 2%, sodium gluconate 5%,
Sodium carbonate 20%, remaining is deionized water.
Uniform stirring after above-mentioned each composition is mixed, stands for a moment, and liquid is presented colorless and transparent, as present invention plating
Zine plate surface cleaning agent.
The cleaning agent be in colourless transparent and homogeneous shape, pH value substantially 9.8, smell is than thin, density 1.08g/mL.
Embodiment 2
A kind of embodiment of galvanized sheet surface cleaning agent of the present invention, cleaning agent described in the present embodiment includes following quality percentage
The composition of content：Cocoamidopropyl betaine 0.1%, anion surfactant：Sodium alkyl benzene sulfonate:Detergent alkylate sulphur
Sour sodium 5%, nonionic surfactant：AEO 0.1%, bleeding agent：Isooctanol polyethoxylate sulfuric ester
1%, sodium gluconate 1%, isopropanol 2%, remaining is deionized water.
Uniform stirring after above-mentioned each composition is mixed, stands for a moment, and liquid is presented colorless and transparent, as present invention plating
Zine plate surface cleaning agent.
The cleaning agent be in colourless transparent and homogeneous shape, pH value substantially 8.5, smell is than thin, density 1.01g/mL.
Embodiment 3
A kind of embodiment of galvanized sheet surface cleaning agent of the present invention, cleaning agent described in the present embodiment includes following quality percentage
The composition of content：Cocoamidopropyl betaine 0.3%, anion surfactant：Sodium alkyl benzene sulfonate 10%, nonionic table
Face activating agent：Isotrideyl alcohol APEO 0.5%, bleeding agent：Isooctanol polyethoxylate sulfuric ester 4%, glucose
Sour sodium 2%, sodium carbonate 1%, isopropanol 5%, sodium metasilicate 2%, remaining is deionized water.
Uniform stirring after above-mentioned each composition is mixed, stands for a moment, and liquid is presented colorless and transparent, as present invention plating
Zine plate surface cleaning agent.
The cleaning agent be in colourless transparent and homogeneous shape, pH value substantially 8.5, smell is than thin, density 1.04g/mL.
Embodiment 4
A kind of embodiment of galvanized sheet surface cleaning agent of the present invention, cleaning agent described in the present embodiment includes following quality percentage
The composition of content：Cocoamidopropyl betaine 0.5%, anion surfactant：Sodium alkyl benzene sulfonate 4%, nonionic table
Face activating agent：Isotrideyl alcohol APEO 2%, bleeding agent：Isooctanol polyethoxylate sulfuric ester 2%, gluconic acid
Sodium 10%, NaOH 30%, ethylene glycol monobutyl ether 5%, sodium metasilicate 5%, remaining is deionized water.
Uniform stirring after above-mentioned each composition is mixed, stands for a moment, and liquid is presented colorless and transparent, as present invention plating
Zine plate surface cleaning agent.
The cleaning agent be in colourless transparent and homogeneous shape, pH value substantially 8.6, smell is than thin, density 1.05g/mL.
Embodiment 5
A kind of embodiment of galvanized sheet surface cleaning agent of the present invention, cleaning agent described in the present embodiment includes following quality percentage
The composition of content：Cocoamidopropyl betaine 0.8%, anion surfactant：Sodium alkyl benzene sulfonate 8%, nonionic table
Face activating agent：Natural fatty alcohol APEO 5%, bleeding agent：Polyoxyethylene aliphatic alcohol ether 5%, sodium gluconate 3%, hydrogen
Sodium oxide molybdena 1%, isopropanol 1%, sodium metasilicate 3%, remaining is deionized water.
Uniform stirring after above-mentioned each composition is mixed, stands for a moment, and liquid is presented colorless and transparent, as present invention plating
Zine plate surface cleaning agent.
The cleaning agent be in colourless transparent and homogeneous shape, pH value substantially 8.6, smell is than thin, density 1.03g/mL.
Embodiment 6
A kind of embodiment of galvanized sheet surface cleaning agent of the present invention, cleaning agent described in the present embodiment includes following quality percentage
The composition of content：Cocoamidopropyl betaine 1%, anion surfactant：Sodium alkyl benzene sulfonate 1%, non-ionic surface
Activating agent：Natural fatty alcohol APEO 10%, bleeding agent：Polyoxyethylene aliphatic alcohol ether 3%, sodium gluconate 8%, carbonic acid
Sodium 30%, ethylene glycol monobutyl ether 1%, sodium metasilicate 1%, remaining is deionized water.
Uniform stirring after above-mentioned each composition is mixed, stands for a moment, and liquid is presented colorless and transparent, as present invention plating
Zine plate surface cleaning agent.
The cleaning agent be in colourless transparent and homogeneous shape, pH value substantially 8.6, smell is than thin, density 1.05g/mL.
The cleaning efficiency evaluation test of the galvanized sheet surface cleaning agent of the present invention of embodiment 7
Standard galvanized sheet is cleaned using galvanized sheet surface cleaning agent described in embodiment 1~4.In the lab, using leaching
Bubble method, takes the cleaning agent of 2mL, and temperature is taken out, using water curtain method (according to JB/T under room temperature condition, to soak 4-8 minutes
4323.2-1999 chapter 6 specifies to determine) carry out the evaluation of cleaning efficiency.
Test result is as shown in table 1：
The galvanized sheet surface cleaning agent of the embodiment 1~4 of table 1 cleans the cleaning efficiency of standard galvanized sheet
As can be seen here, the cleaning efficiency of galvanized sheet surface cleaning agent of the present invention is high, and the pollutant component such as not phosphorous, nontoxic
Property, biodegradable rate is up to more than 95%, and, good stability corrosion-free to metal surface.
It is last to should be noted that the above embodiments are merely illustrative of the technical solutions of the present invention rather than the present invention is protected
The limitation of scope is protected, although being explained in detail to the present invention with reference to preferred embodiment, one of ordinary skill in the art should
Understand, technical scheme can be modified or equivalent, without deviating from the essence of technical solution of the present invention
And scope.
Claims (10)
1. a kind of galvanized sheet surface cleaning agent, it is characterised in that composition of the cleaning agent comprising following weight/mass percentage composition：Coconut palm
Oleamide CAB 0.1-1%, anion surfactant 1-10%, nonionic surfactant 1-10%, bleeding agent
1-5%, sodium gluconate 1-10%, other are water.
2. galvanized sheet surface cleaning agent as claimed in claim 1, it is characterised in that the anion surfactant is alkylbenzene
Sodium sulfonate；Preferably, the anion surfactant is neopelex.
3. galvanized sheet surface cleaning agent as claimed in claim 1, it is characterised in that the nonionic surfactant is different 13
Alkyl alcohol ethoxylates or AEO.
4. galvanized sheet surface cleaning agent as claimed in claim 1, it is characterised in that the bleeding agent is AEO
Or isooctanol polyethoxylate sulfuric ester.
5. galvanized sheet surface cleaning agent as claimed in claim 1, it is characterised in that the cleaning agent contains comprising following quality percentage
The composition of amount：Cocoamidopropyl betaine 0.2-0.8%, anion surfactant 5-10%, nonionic surfactant
0.1-5%, bleeding agent 2-5%, sodium gluconate 2-10%, other are water.
6. galvanized sheet surface cleaning agent as claimed in claim 1, it is characterised in that the cleaning agent contains comprising following quality percentage
The composition of amount：Cocoamidopropyl betaine 0.3-0.5%, anion surfactant 4-8%, nonionic surfactant
0.5-2%, bleeding agent 2-4%, sodium gluconate 3-8%, other are water.
7. the galvanized sheet surface cleaning agent as described in claim 1~6, it is characterised in that the cleaning agent also comprising sodium carbonate or
NaOH；In the cleaning agent, the weight/mass percentage composition of sodium carbonate or NaOH is 1-30%.
8. the galvanized sheet surface cleaning agent as described in claim 1~6, it is characterised in that the cleaning agent also comprising isopropanol or
Ethylene glycol monobutyl ether；In the cleaning agent, the weight/mass percentage composition of isopropanol or ethylene glycol monobutyl ether is 1-5%.
9. the galvanized sheet surface cleaning agent as described in claim 1~6, it is characterised in that the cleaning agent also includes wetting agent；Institute
State in cleaning agent, the weight/mass percentage composition of wetting agent is 1-5%.
10. galvanized sheet surface cleaning agent as claimed in claim 9, it is characterised in that the wetting agent is silicate.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201611259709.9A CN106801230A (en) | 2016-12-30 | 2016-12-30 | A kind of galvanized sheet surface cleaning agent and preparation method thereof |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201611259709.9A CN106801230A (en) | 2016-12-30 | 2016-12-30 | A kind of galvanized sheet surface cleaning agent and preparation method thereof |
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| CN106801230A true CN106801230A (en) | 2017-06-06 |
Family
ID=58984230
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| Application Number | Title | Priority Date | Filing Date |
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| CN201611259709.9A Pending CN106801230A (en) | 2016-12-30 | 2016-12-30 | A kind of galvanized sheet surface cleaning agent and preparation method thereof |
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Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN107419283A (en) * | 2017-08-14 | 2017-12-01 | 上海倍宁汽车零部件有限公司 | A kind of utral degreaser and its preparation method and application |
| CN107488862A (en) * | 2017-08-29 | 2017-12-19 | 天津普罗米新材料有限公司 | A kind of zinc-plated punching press shell scavenger specially |
| CN114836764A (en) * | 2022-05-19 | 2022-08-02 | 宁波市旭一新材料有限公司 | Environment-friendly phosphorus-free water-based low-foam metal cleaning agent and preparation method thereof |
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| JPS6411985A (en) * | 1987-07-04 | 1989-01-17 | Nisshin Steel Co Ltd | Method for removing oxide film from galvanized steel sheet |
| CN102296004A (en) * | 2011-07-26 | 2011-12-28 | 山东丽波日化股份有限公司 | Paste washing agent for cleaning hard surfaces in kitchen and preparation method thereof |
| CN104803888A (en) * | 2015-04-23 | 2015-07-29 | 中国日用化学工业研究院 | Isomeric alcohol derivative sulphate and preparation method thereof |
| CN105969550A (en) * | 2016-06-29 | 2016-09-28 | 苏州禾川化学技术服务有限公司 | Washing tablet |
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|---|---|---|---|---|
| JPS6411985A (en) * | 1987-07-04 | 1989-01-17 | Nisshin Steel Co Ltd | Method for removing oxide film from galvanized steel sheet |
| CN102296004A (en) * | 2011-07-26 | 2011-12-28 | 山东丽波日化股份有限公司 | Paste washing agent for cleaning hard surfaces in kitchen and preparation method thereof |
| CN104803888A (en) * | 2015-04-23 | 2015-07-29 | 中国日用化学工业研究院 | Isomeric alcohol derivative sulphate and preparation method thereof |
| CN105969550A (en) * | 2016-06-29 | 2016-09-28 | 苏州禾川化学技术服务有限公司 | Washing tablet |
Cited By (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN107419283A (en) * | 2017-08-14 | 2017-12-01 | 上海倍宁汽车零部件有限公司 | A kind of utral degreaser and its preparation method and application |
| CN107419283B (en) * | 2017-08-14 | 2019-01-01 | 上海倍宁汽车零部件有限公司 | A kind of utral degreaser and its preparation method and application |
| CN107488862A (en) * | 2017-08-29 | 2017-12-19 | 天津普罗米新材料有限公司 | A kind of zinc-plated punching press shell scavenger specially |
| CN114836764A (en) * | 2022-05-19 | 2022-08-02 | 宁波市旭一新材料有限公司 | Environment-friendly phosphorus-free water-based low-foam metal cleaning agent and preparation method thereof |
| CN114836764B (en) * | 2022-05-19 | 2023-11-24 | 宁波市旭一新材料有限公司 | Environment-friendly phosphorus-free water-based low-foam metal cleaning agent and preparation method thereof |
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Application publication date: 20170606 |