CN103525529A - High-performance environment-friendly water-soluble punching oil - Google Patents
High-performance environment-friendly water-soluble punching oil Download PDFInfo
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- CN103525529A CN103525529A CN201310480155.5A CN201310480155A CN103525529A CN 103525529 A CN103525529 A CN 103525529A CN 201310480155 A CN201310480155 A CN 201310480155A CN 103525529 A CN103525529 A CN 103525529A
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- force feed
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- 238000004080 punching Methods 0.000 title abstract description 4
- 239000003921 oil Substances 0.000 claims abstract description 14
- 235000019198 oils Nutrition 0.000 claims abstract description 14
- 150000001298 alcohols Chemical class 0.000 claims abstract description 7
- 150000001412 amines Chemical class 0.000 claims abstract description 7
- 238000005660 chlorination reaction Methods 0.000 claims abstract description 7
- 239000000314 lubricant Substances 0.000 claims abstract description 7
- 235000015112 vegetable and seed oil Nutrition 0.000 claims abstract description 5
- 239000008158 vegetable oil Substances 0.000 claims abstract description 5
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 5
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 claims description 21
- 239000003795 chemical substances by application Substances 0.000 claims description 13
- 229920002545 silicone oil Polymers 0.000 claims description 13
- SJRJJKPEHAURKC-UHFFFAOYSA-N N-Methylmorpholine Chemical compound CN1CCOCC1 SJRJJKPEHAURKC-UHFFFAOYSA-N 0.000 claims description 9
- 239000002253 acid Substances 0.000 claims description 9
- ATUOYWHBWRKTHZ-UHFFFAOYSA-N Propane Chemical compound CCC ATUOYWHBWRKTHZ-UHFFFAOYSA-N 0.000 claims description 8
- LVTYICIALWPMFW-UHFFFAOYSA-N diisopropanolamine Chemical compound CC(O)CNCC(C)O LVTYICIALWPMFW-UHFFFAOYSA-N 0.000 claims description 8
- 229940043276 diisopropanolamine Drugs 0.000 claims description 8
- ZQPPMHVWECSIRJ-KTKRTIGZSA-N oleic acid Chemical compound CCCCCCCC\C=C/CCCCCCCC(O)=O ZQPPMHVWECSIRJ-KTKRTIGZSA-N 0.000 claims description 8
- RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 claims description 7
- 229920000570 polyether Polymers 0.000 claims description 7
- 235000013311 vegetables Nutrition 0.000 claims description 7
- DNIAPMSPPWPWGF-GSVOUGTGSA-N (R)-(-)-Propylene glycol Chemical compound C[C@@H](O)CO DNIAPMSPPWPWGF-GSVOUGTGSA-N 0.000 claims description 6
- YNAVUWVOSKDBBP-UHFFFAOYSA-N Morpholine Chemical compound C1COCCN1 YNAVUWVOSKDBBP-UHFFFAOYSA-N 0.000 claims description 6
- 239000013543 active substance Substances 0.000 claims description 6
- 239000013530 defoamer Substances 0.000 claims description 6
- 150000002148 esters Chemical class 0.000 claims description 6
- BKIMMITUMNQMOS-UHFFFAOYSA-N nonane Chemical compound CCCCCCCCC BKIMMITUMNQMOS-UHFFFAOYSA-N 0.000 claims description 6
- FBUKVWPVBMHYJY-UHFFFAOYSA-N nonanoic acid Chemical compound CCCCCCCCC(O)=O FBUKVWPVBMHYJY-UHFFFAOYSA-N 0.000 claims description 6
- CXMXRPHRNRROMY-UHFFFAOYSA-N sebacic acid Chemical compound OC(=O)CCCCCCCCC(O)=O CXMXRPHRNRROMY-UHFFFAOYSA-N 0.000 claims description 6
- 238000005987 sulfurization reaction Methods 0.000 claims description 6
- WRIDQFICGBMAFQ-UHFFFAOYSA-N (E)-8-Octadecenoic acid Natural products CCCCCCCCCC=CCCCCCCC(O)=O WRIDQFICGBMAFQ-UHFFFAOYSA-N 0.000 claims description 4
- 229940058020 2-amino-2-methyl-1-propanol Drugs 0.000 claims description 4
- LQJBNNIYVWPHFW-UHFFFAOYSA-N 20:1omega9c fatty acid Natural products CCCCCCCCCCC=CCCCCCCCC(O)=O LQJBNNIYVWPHFW-UHFFFAOYSA-N 0.000 claims description 4
- QSBYPNXLFMSGKH-UHFFFAOYSA-N 9-Heptadecensaeure Natural products CCCCCCCC=CCCCCCCCC(O)=O QSBYPNXLFMSGKH-UHFFFAOYSA-N 0.000 claims description 4
- 239000005642 Oleic acid Substances 0.000 claims description 4
- ZQPPMHVWECSIRJ-UHFFFAOYSA-N Oleic acid Natural products CCCCCCCCC=CCCCCCCCC(O)=O ZQPPMHVWECSIRJ-UHFFFAOYSA-N 0.000 claims description 4
- 239000004721 Polyphenylene oxide Substances 0.000 claims description 4
- UCKMPCXJQFINFW-UHFFFAOYSA-N Sulphide Chemical compound [S-2] UCKMPCXJQFINFW-UHFFFAOYSA-N 0.000 claims description 4
- SLINHMUFWFWBMU-UHFFFAOYSA-N Triisopropanolamine Chemical compound CC(O)CN(CC(C)O)CC(C)O SLINHMUFWFWBMU-UHFFFAOYSA-N 0.000 claims description 4
- CBTVGIZVANVGBH-UHFFFAOYSA-N aminomethyl propanol Chemical compound CC(C)(N)CO CBTVGIZVANVGBH-UHFFFAOYSA-N 0.000 claims description 4
- QRUDEWIWKLJBPS-UHFFFAOYSA-N benzotriazole Chemical compound C1=CC=C2N[N][N]C2=C1 QRUDEWIWKLJBPS-UHFFFAOYSA-N 0.000 claims description 4
- 239000012964 benzotriazole Substances 0.000 claims description 4
- QXJSBBXBKPUZAA-UHFFFAOYSA-N isooleic acid Natural products CCCCCCCC=CCCCCCCCCC(O)=O QXJSBBXBKPUZAA-UHFFFAOYSA-N 0.000 claims description 4
- 229940049964 oleate Drugs 0.000 claims description 4
- -1 pentaerythritol ester Chemical class 0.000 claims description 4
- 239000001294 propane Substances 0.000 claims description 4
- WIHIUTUAHOZVLE-UHFFFAOYSA-N 1,3-diethoxypropan-2-ol Chemical compound CCOCC(O)COCC WIHIUTUAHOZVLE-UHFFFAOYSA-N 0.000 claims description 3
- HXKKHQJGJAFBHI-UHFFFAOYSA-N 1-aminopropan-2-ol Chemical compound CC(O)CN HXKKHQJGJAFBHI-UHFFFAOYSA-N 0.000 claims description 3
- SNTWKPAKVQFCCF-UHFFFAOYSA-N 2,3-dihydro-1h-triazole Chemical compound N1NC=CN1 SNTWKPAKVQFCCF-UHFFFAOYSA-N 0.000 claims description 3
- HZAXFHJVJLSVMW-UHFFFAOYSA-N 2-Aminoethan-1-ol Chemical compound NCCO HZAXFHJVJLSVMW-UHFFFAOYSA-N 0.000 claims description 3
- SFAAOBGYWOUHLU-UHFFFAOYSA-N 2-ethylhexyl hexadecanoate Chemical compound CCCCCCCCCCCCCCCC(=O)OCC(CC)CCCC SFAAOBGYWOUHLU-UHFFFAOYSA-N 0.000 claims description 3
- SAUIGQBKPDQYHL-QXMHVHEDSA-N 6-methylheptyl (z)-octadec-9-enoate Chemical compound CCCCCCCC\C=C/CCCCCCCC(=O)OCCCCCC(C)C SAUIGQBKPDQYHL-QXMHVHEDSA-N 0.000 claims description 3
- XBPCUCUWBYBCDP-UHFFFAOYSA-N Dicyclohexylamine Chemical compound C1CCCCC1NC1CCCCC1 XBPCUCUWBYBCDP-UHFFFAOYSA-N 0.000 claims description 3
- OYHQOLUKZRVURQ-HZJYTTRNSA-N Linoleic acid Chemical compound CCCCC\C=C/C\C=C/CCCCCCCC(O)=O OYHQOLUKZRVURQ-HZJYTTRNSA-N 0.000 claims description 3
- 239000005643 Pelargonic acid Substances 0.000 claims description 3
- GSEJCLTVZPLZKY-UHFFFAOYSA-N Triethanolamine Chemical compound OCCN(CCO)CCO GSEJCLTVZPLZKY-UHFFFAOYSA-N 0.000 claims description 3
- 150000001408 amides Chemical class 0.000 claims description 3
- 229910021529 ammonia Inorganic materials 0.000 claims description 3
- QGZKDVFQNNGYKY-UHFFFAOYSA-N ammonia Natural products N QGZKDVFQNNGYKY-UHFFFAOYSA-N 0.000 claims description 3
- 235000014113 dietary fatty acids Nutrition 0.000 claims description 3
- ZBCBWPMODOFKDW-UHFFFAOYSA-N diethanolamine Chemical compound OCCNCCO ZBCBWPMODOFKDW-UHFFFAOYSA-N 0.000 claims description 3
- 125000004177 diethyl group Chemical group [H]C([H])([H])C([H])([H])* 0.000 claims description 3
- 125000000118 dimethyl group Chemical group [H]C([H])([H])* 0.000 claims description 3
- 239000000194 fatty acid Substances 0.000 claims description 3
- 229930195729 fatty acid Natural products 0.000 claims description 3
- 150000004665 fatty acids Chemical class 0.000 claims description 3
- 229960004232 linoleic acid Drugs 0.000 claims description 3
- 150000002632 lipids Chemical class 0.000 claims description 3
- 150000004702 methyl esters Chemical class 0.000 claims description 3
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 claims description 3
- QYDYPVFESGNLHU-KHPPLWFESA-N methyl oleate Chemical compound CCCCCCCC\C=C/CCCCCCCC(=O)OC QYDYPVFESGNLHU-KHPPLWFESA-N 0.000 claims description 3
- 229920003216 poly(methylphenylsiloxane) Polymers 0.000 claims description 3
- 229920000056 polyoxyethylene ether Polymers 0.000 claims description 3
- 229940051841 polyoxyethylene ether Drugs 0.000 claims description 3
- 235000012424 soybean oil Nutrition 0.000 claims description 3
- 239000003549 soybean oil Substances 0.000 claims description 3
- BDHFUVZGWQCTTF-UHFFFAOYSA-M sulfonate Chemical compound [O-]S(=O)=O BDHFUVZGWQCTTF-UHFFFAOYSA-M 0.000 claims description 3
- 239000003760 tallow Substances 0.000 claims description 3
- 150000003918 triazines Chemical class 0.000 claims description 3
- 229960004418 trolamine Drugs 0.000 claims description 3
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 abstract description 5
- 239000001301 oxygen Substances 0.000 abstract description 5
- 229910052760 oxygen Inorganic materials 0.000 abstract description 5
- 239000000126 substance Substances 0.000 abstract description 3
- 238000010079 rubber tapping Methods 0.000 abstract description 2
- 239000005069 Extreme pressure additive Substances 0.000 abstract 2
- 239000002518 antifoaming agent Substances 0.000 abstract 1
- 150000001732 carboxylic acid derivatives Chemical class 0.000 abstract 1
- 230000001050 lubricating effect Effects 0.000 abstract 1
- 229920000642 polymer Polymers 0.000 abstract 1
- 239000003755 preservative agent Substances 0.000 abstract 1
- 230000002335 preservative effect Effects 0.000 abstract 1
- 239000004094 surface-active agent Substances 0.000 abstract 1
- 238000002360 preparation method Methods 0.000 description 4
- 231100000111 LD50 Toxicity 0.000 description 3
- 239000007788 liquid Substances 0.000 description 3
- 239000002699 waste material Substances 0.000 description 3
- 239000012752 auxiliary agent Substances 0.000 description 2
- 239000012895 dilution Substances 0.000 description 2
- 238000010790 dilution Methods 0.000 description 2
- 238000005516 engineering process Methods 0.000 description 2
- 238000003754 machining Methods 0.000 description 2
- REIUXOLGHVXAEO-UHFFFAOYSA-N pentadecan-1-ol Chemical compound CCCCCCCCCCCCCCCO REIUXOLGHVXAEO-UHFFFAOYSA-N 0.000 description 2
- 239000003208 petroleum Substances 0.000 description 2
- ASFAFOSQXBRFMV-LJQANCHMSA-N 3-n-(2-benzyl-1,3-dihydroxypropan-2-yl)-1-n-[(1r)-1-(4-fluorophenyl)ethyl]-5-[methyl(methylsulfonyl)amino]benzene-1,3-dicarboxamide Chemical compound N([C@H](C)C=1C=CC(F)=CC=1)C(=O)C(C=1)=CC(N(C)S(C)(=O)=O)=CC=1C(=O)NC(CO)(CO)CC1=CC=CC=C1 ASFAFOSQXBRFMV-LJQANCHMSA-N 0.000 description 1
- 229910000838 Al alloy Inorganic materials 0.000 description 1
- 229910001018 Cast iron Inorganic materials 0.000 description 1
- 229920003171 Poly (ethylene oxide) Polymers 0.000 description 1
- XUIMIQQOPSSXEZ-UHFFFAOYSA-N Silicon Chemical compound [Si] XUIMIQQOPSSXEZ-UHFFFAOYSA-N 0.000 description 1
- 229910000831 Steel Inorganic materials 0.000 description 1
- 239000002199 base oil Substances 0.000 description 1
- 239000002131 composite material Substances 0.000 description 1
- 238000005260 corrosion Methods 0.000 description 1
- 230000007797 corrosion Effects 0.000 description 1
- 238000003912 environmental pollution Methods 0.000 description 1
- 231100001261 hazardous Toxicity 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 239000002184 metal Substances 0.000 description 1
- 229910052751 metal Inorganic materials 0.000 description 1
- 239000007769 metal material Substances 0.000 description 1
- 239000002480 mineral oil Substances 0.000 description 1
- 235000010446 mineral oil Nutrition 0.000 description 1
- 238000002156 mixing Methods 0.000 description 1
- 239000000203 mixture Substances 0.000 description 1
- 230000001473 noxious effect Effects 0.000 description 1
- QQONPFPTGQHPMA-UHFFFAOYSA-N propylene Natural products CC=C QQONPFPTGQHPMA-UHFFFAOYSA-N 0.000 description 1
- 125000004805 propylene group Chemical group [H]C([H])([H])C([H])([*:1])C([H])([H])[*:2] 0.000 description 1
- 239000002994 raw material Substances 0.000 description 1
- 210000001533 respiratory mucosa Anatomy 0.000 description 1
- 229910052710 silicon Inorganic materials 0.000 description 1
- 239000010703 silicon Substances 0.000 description 1
- 239000000243 solution Substances 0.000 description 1
- 239000010959 steel Substances 0.000 description 1
- 231100000331 toxic Toxicity 0.000 description 1
- 230000002588 toxic effect Effects 0.000 description 1
Abstract
The invention discloses a high-performance environment-friendly water-soluble punching oil which is composed of high-polymer carboxylic acid, organic amine, higher alcohols, a surfactant, vegetable oil or synthetic lubricant, a vulcanizing extreme pressure additive, a chlorination extreme pressure additive, pure water, a defoaming agent and a preservative. The punching oil has superhigh lubricating property; after the product is diluted by 30 times, the tapping torque is less than or equal to 3000 N.cm, the cutter life is long, and the single batch cutter part processing quantity is greater than or equal to 300000. When adopting design formula of excellent-biodegradability vegetable oil (or synthetic fat) and other assistants, after the product is diluted by 30 times, the BOD/COD (biochemical oxygen demand/chemical oxygen demand) is greater than or equal to 0.6.
Description
Technical field
The present invention relates to the high-performance environment protection type water-soluble flush force feed of using in a kind of metal stamping processing.
Background technology
The pure oiliness punching oil that tradition is used (is made base oil with mineral oil, composite extreme pressure agent and the blending of multiple auxiliary agent form, not moisture, can not dilute use), due to its technology and mature preparation process, lubricated, antirust, corrosion resistance is good, the punch machining process of the machining enterprise that is widely used in for a long time the fields such as automobile, motorcycle, engineering machinery to metal materials such as steel, cast iron, aluminium alloys.But also there are some important drawbacks in it.The one, pure Oily preparation consumes bulk petroleum resource, and price is expensive, and use cost is high: the 2nd, there is disaster hidden-trouble, poor stability: and the 3rd, the waste liquid of discharge is difficult for processing, serious environment pollution.Last century the nineties, the developed country such as Japanese, American-European has researched and developed successfully water-soluble flush force feed in succession, compare with pure Oily preparation, significantly reduce petroleum resource consumption, production and use cost are low, there is not disaster hidden-trouble, waste liquid is easily processed, and environmental pollution is little, is subject to market favor, be expected to progressively replace pure Oily preparation, become the main product of future market.Since entering the new millennium, domestic also have some enterprises in succession to succeed in developing water-soluble flush force feed, but all undesirable (subject matter is: lubricity is poor, affects cutter life and workpiece surface quality; Biodegradable performance is poor, and the waste liquid of discharge is difficult for biochemical treatment; In formula, containing hazardous and noxious substances, safety and sanitation are of poor quality), thus its apply (especially high-end market) in market greatly restricted.
Summary of the invention
The object of the present invention is to provide that a kind of lubricity is strong, the high-performance environment protection type water-soluble flush force feed to human and environment safety.
Technical solution of the present invention is:
A water-soluble flush force feed, is characterized in that: the one-tenth by following weight percent is grouped into:
Polymeric carboxylic 3 ~ 10%
Organic amine 5 ~ 20%
Higher alcohols 1 ~ 10%
Tensio-active agent 1 ~ 20%
Vegetables oil or synthetic lubricant 10 ~ 30%
Sulfurized extreme pressure agent 10 ~ 30%
Chlorination extreme pressure agent 5 ~ 15%
Pure water 5 ~ 25%
Defoamer 0 ~ 0.5%
Sanitas or sterilant 0 ~ 5%.
Described polymeric carboxylic is sad, pelargonic acid, sebacic acid, hexanodioic acid, nonane diacid, bay diacid, C
8~ C
18one or more in lipid acid, oleic acid, linolic acid, triazines multi-carboxylic acid compounds.
Described organic amine is one or more in Monoethanolamine MEA BASF, diethanolamine, trolamine, monoisopropanolamine, diisopropanolamine (DIPA), tri-isopropanolamine, morpholine, dicyclohexyl amine, N-methylmorpholine, 2-amino-2-methyl-1-propanol, diethylin ethanol.
Described higher alcohols is C
8~ C
10straight chain alcohol, C
12~ C
13straight chain alcohol or isomery alcohol, C
14~ C
15straight chain alcohol or one or more in isomery alcohol.
Described tensio-active agent is one or more in fatty alcohol-polyoxyethylene ether (5～12), aliphatic alcohol polyethenoxy polyethenoxy ether, alkylol amide, aliphatic alcohol polyethenoxy ester (5～12), sulfonate.
Described vegetables oil or synthetic lubricant are one or more in sirasimeyu, soybean oil, plam oil, Oleum Cocois, suet, tricarboxymethyl propane oleate, pentaerythritol ester, isooctyl oleate, Witconol 2301, hexanodioic acid dibutyl ester, Wickenol 155.
Described sulfurized extreme pressure agent is one or more in olefine sulfide, sulfuration methyl esters, sulfuration tallow fatty acid, vulcanized vegetable oil.
Described chlorination extreme pressure agent is clorafin.
Described defoamer is one or more in dimethyl silicone oil, diethyl silicone oil, methyl phenyl silicone oil, ammonia alkyl silicone oil, polyether silicone oil, polyethers.
Described sanitas is benzotriazole, methyl benzotriazazole, 1H-1,2, one or more in 4-triazole.
The present invention has superpower lubricity; During 30 times of uses of product dilution, its tapping moment of torsion≤3000N.cm, cutter life is long, single batch of tool sharpening part amount >=300000.Select the vegetables oil that biodegradable performance is good (or synthetic fat) and other auxiliary agent component designs, during 30 times of uses of product dilution, its BOD(biological oxygen demand (BOD))/COD(chemical oxygen demand) >=0.6.Select that environmentally safe and HUMAN HEALTH is harmless, the alternative raw material component design of excellent property, the biological Lethal Dose 50 LD50>=5000mg/kg of product, toxic limit medium dose LC50>=5000mg/m
3, respiratory mucosa stimulates≤1 grade.
Below in conjunction with embodiment, the invention will be further described.
Embodiment
Embodiment 1:
A water-soluble flush force feed, is mixed by the composition of following weight percent:
Month silicon diacid 5%
Oleic acid 5%
2-amino-2-methyl-1-propanol 11%
Diisopropanolamine (DIPA) 3%
Tri-isopropanolamine 3%
Alkylol amide 4%
Polyoxyethylene poly-oxygen propylene aether 2%
Pure water 13.4%
Pentadecanol 2%
Tricarboxymethyl propane oleate 10%
Plam oil 10%
Polyether silicone oil 0.5%
Benzotriazole 0.1%
Clorafin 5%
Olefine sulfide 26%.
Embodiment 2:
A water-soluble flush force feed, is grouped into by the one-tenth of following weight percent:
Polymeric carboxylic 3 ~ 10%(example 3%, 7%, 10%)
Organic amine 5 ~ 20%(example 5%, 13%, 20%)
Higher alcohols 1 ~ 10%(example 1%, 5%, 10%)
Tensio-active agent 1 ~ 20%(example 1%, 10%, 20%)
Vegetables oil or synthetic lubricant 10 ~ 30%(example 10%, 20%, 30%)
Sulfurized extreme pressure agent 10 ~ 30%(example 10%, 20%, 30%)
Chlorination extreme pressure agent 5 ~ 15%(example 5%, 10%, 15%)
Pure water 5 ~ 25%(example 5%, 15%, 25%)
Defoamer 0 ~ 0.5%(example 0.1%, 0.3%, 0.5%)
Sanitas or sterilant 0 ~ 5%(example 1%, 3%, 5%).
Described polymeric carboxylic is sad, pelargonic acid, sebacic acid, hexanodioic acid, nonane diacid, bay diacid, C
8~ C
18one or more in lipid acid, oleic acid, linolic acid, triazines multi-carboxylic acid compounds.
Described organic amine is one or more in Monoethanolamine MEA BASF, diethanolamine, trolamine, monoisopropanolamine, diisopropanolamine (DIPA), tri-isopropanolamine, morpholine, dicyclohexyl amine, N-methylmorpholine, 2-amino-2-methyl-1-propanol, diethylin ethanol.
Described higher alcohols is C
8~ C
10straight chain alcohol, C
12~ C
13straight chain alcohol or isomery alcohol, C
14~ C
15straight chain alcohol or one or more in isomery alcohol.
Described tensio-active agent is one or more in fatty alcohol-polyoxyethylene ether (5～12), aliphatic alcohol polyethenoxy polyethenoxy ether, alkylol amide, aliphatic alcohol polyethenoxy ester (5～12), sulfonate.
Described vegetables oil or synthetic lubricant are one or more in sirasimeyu, soybean oil, plam oil, Oleum Cocois, suet, tricarboxymethyl propane oleate, pentaerythritol ester, isooctyl oleate, Witconol 2301, hexanodioic acid dibutyl ester, Wickenol 155.
Described sulfurized extreme pressure agent is one or more in olefine sulfide, sulfuration methyl esters, sulfuration tallow fatty acid, vulcanized vegetable oil.
Described chlorination extreme pressure agent is clorafin.
Described defoamer is one or more in dimethyl silicone oil, diethyl silicone oil, methyl phenyl silicone oil, ammonia alkyl silicone oil, polyether silicone oil, polyethers.
Described sanitas is benzotriazole, methyl benzotriazazole, 1H-1,2, one or more in 4-triazole.
Claims (10)
1. a high-performance environment protection type water-soluble flush force feed, is characterized in that: the one-tenth by following weight percent is grouped into:
Polymeric carboxylic 3 ~ 10%
Organic amine 5 ~ 20%
Higher alcohols 1 ~ 10%
Tensio-active agent 1 ~ 20%
Vegetables oil or synthetic lubricant 10 ~ 30%
Sulfurized extreme pressure agent 10 ~ 30%
Chlorination extreme pressure agent 5 ~ 15%
Pure water 5 ~ 25%
Defoamer 0 ~ 0.5%
Sanitas or sterilant 0 ~ 5%.
2. high-performance environment protection type water-soluble flush force feed according to claim 1, is characterized in that: described polymeric carboxylic is sad, pelargonic acid, sebacic acid, hexanodioic acid, nonane diacid, bay diacid, C
8~ C
18one or more in lipid acid, oleic acid, linolic acid, triazines multi-carboxylic acid compounds.
3. high-performance environment protection type water-soluble flush force feed according to claim 1 and 2, is characterized in that: described organic amine is one or more in Monoethanolamine MEA BASF, diethanolamine, trolamine, monoisopropanolamine, diisopropanolamine (DIPA), tri-isopropanolamine, morpholine, dicyclohexyl amine, N-methylmorpholine, 2-amino-2-methyl-1-propanol, diethylin ethanol.
4. high-performance environment protection type water-soluble flush force feed according to claim 1 and 2, is characterized in that: described higher alcohols is C
8~ C
10straight chain alcohol, C
12~ C
13straight chain alcohol or isomery alcohol, C
14~ C
15straight chain alcohol or one or more in isomery alcohol.
5. high-performance environment protection type water-soluble flush force feed according to claim 1 and 2, is characterized in that: described tensio-active agent is one or more in fatty alcohol-polyoxyethylene ether (5～12), aliphatic alcohol polyethenoxy polyethenoxy ether, alkylol amide, aliphatic alcohol polyethenoxy ester (5～12), sulfonate.
6. high-performance environment protection type water-soluble flush force feed according to claim 1 and 2, is characterized in that: described vegetables oil or synthetic lubricant are one or more in sirasimeyu, soybean oil, plam oil, Oleum Cocois, suet, tricarboxymethyl propane oleate, pentaerythritol ester, isooctyl oleate, Witconol 2301, hexanodioic acid dibutyl ester, Wickenol 155.
7. high-performance environment protection type water-soluble flush force feed according to claim 1 and 2, is characterized in that: described sulfurized extreme pressure agent is one or more in olefine sulfide, sulfuration methyl esters, sulfuration tallow fatty acid, vulcanized vegetable oil.
8. high-performance environment protection type water-soluble flush force feed according to claim 1 and 2, is characterized in that: described chlorination extreme pressure agent is clorafin.
9. high-performance environment protection type water-soluble flush force feed according to claim 1 and 2, is characterized in that: described defoamer is one or more in dimethyl silicone oil, diethyl silicone oil, methyl phenyl silicone oil, ammonia alkyl silicone oil, polyether silicone oil, polyethers.
10. high-performance environment protection type water-soluble flush force feed according to claim 1 and 2, is characterized in that: described sanitas is benzotriazole, methyl benzotriazazole, 1H-1,2, one or more in 4-triazole.
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| CN201310480155.5A CN103525529B (en) | 2013-10-15 | 2013-10-15 | High-performance environment-friendly water-soluble punching oil |
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|---|---|---|---|
| CN201310480155.5A CN103525529B (en) | 2013-10-15 | 2013-10-15 | High-performance environment-friendly water-soluble punching oil |
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| CN103525529B CN103525529B (en) | 2014-12-24 |
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Cited By (15)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN104694234A (en) * | 2015-03-18 | 2015-06-10 | 启东尤希路化学工业有限公司 | High-performance environmentally-friendly medium- and long-period antirust punching oil |
| CN104830409A (en) * | 2015-04-01 | 2015-08-12 | 瑞虹电子（昆山）有限公司 | Connection elastic plate stamping lubricating oil and preparation method thereof |
| CN104928000A (en) * | 2015-07-03 | 2015-09-23 | 上海尤希路化学工业有限公司 | Multipurpose carbon-deposition-free environmental-friendly water soluble drawing lubricant |
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| CN109797035A (en) * | 2019-02-19 | 2019-05-24 | 华彦汽车零部件(江苏)有限公司 | A kind of high-performance punching press oil formula |
| CN110951532A (en) * | 2019-12-23 | 2020-04-03 | 苏州铱诺化学材料有限公司 | Water-based stamping oil for aluminum fins and preparation method thereof |
| CN110951532B (en) * | 2019-12-23 | 2022-03-11 | 苏州铱诺化学材料有限公司 | Water-based stamping oil for aluminum fins and preparation method thereof |
| CN111763559A (en) * | 2020-07-30 | 2020-10-13 | 东莞市鹏润压铸材料科技有限公司 | Environment-friendly water-based plunger punch lubricating liquid |
| CN112080334A (en) * | 2020-09-22 | 2020-12-15 | 湖北诚祥科技有限公司 | Novel water-soluble punching oil |
| CN112080334B (en) * | 2020-09-22 | 2023-01-06 | 湖北诚祥科技有限公司 | Novel water-soluble punching oil |
| CN115521825A (en) * | 2022-11-07 | 2022-12-27 | 季华实验室 | Water-based punching liquid and preparation method and application thereof |
| CN115521825B (en) * | 2022-11-07 | 2023-11-21 | 季华实验室 | Water-based stamping liquid and preparation method and application thereof |
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