CN102286302A - Water-soluble cutting fluid - Google Patents
Water-soluble cutting fluid Download PDFInfo
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- CN102286302A CN102286302A CN2010102041718A CN201010204171A CN102286302A CN 102286302 A CN102286302 A CN 102286302A CN 2010102041718 A CN2010102041718 A CN 2010102041718A CN 201010204171 A CN201010204171 A CN 201010204171A CN 102286302 A CN102286302 A CN 102286302A
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- water
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- metalworking liquid
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Abstract
The invention discloses a water-soluble cutting fluid, which is composed of base oil or an oily agent, an anionic surfactant, a nonionic surfactant, an antirust agent, an extreme-pressure additive, a coupling agent, a copper alloy corrosion inhibitor, an anticorrosive agent, a defoaming agent, an aluminum alloy corrosion inhibitor and a stabilizer of the aluminum alloy corrosion inhibitor. The water-soluble cutting fluid can be repeatedly used for long time, is free of nitrites, phenols and other toxic and harmful substances, and is beneficial to environment and health.
Description
Technical field:
The present invention relates to a kind of metal cutting working fluid.
Background technology:
Owing to reasons such as its prescriptions, there is undesirable part in existing metal cutting working fluid at aspects such as oilness, rust-preventing characteristic, cooling, antifoam performances.
Goal of the invention:
The object of the present invention is to provide a kind of water-soluble metalworking liquid of good combination property.
Technical solution of the present invention is:
A kind of water-soluble metalworking liquid, its feature: form by following composition by weight:
Base oil or oiliness improver 45～55%
Anion surfactant 10～20%
Nonionogenic tenside 0.5～2.0%
Rust-preventive agent 5～15%
Extreme-pressure additive 5～10%
Couplant 5～10%
Copper alloy inhibiter 0.2～1.0%
Anticorrosive agent 1～2%
Defoamer 0.2～0.5%
Aluminium alloy inhibiter 0.2～1.0%
The stablizer 0.5～3.0% of aluminium alloy inhibiter.
Base oil or oiliness improver are mineral oil, poly-alpha olefins, dibasic ester class (example: the polyoxyethylene polyoxypropylene ester of linoleic acid dimer, the glycol ester of linoleic acid dimer), pentaerythritol esters (example: tetramethylolmethane four oleic acid esters, pentaerythritol tetrastearate), vegetables oil or department of botany's oleic acid ester (example: Methyl palmitoleinate, oleic acid methyl esters).
Anion surfactant is one or more (1 weight parts) and Monoethanolamine MEA BASF, diethanolamine, trolamine, a Yi Bingchunan, diisopropanolamine (DIPA), 2-amino-2-methyl-1-propanol, the morpholine in oleic acid, ricinolic acid, dimeracid, appropriate youngster's oleic acid, the isomery stearic acid, the mixture or the petroleum sodium sulfonate of one or more (1.5～2.5 weight parts) in the N-methylmorpholine.
Nonionogenic tenside is polyoxyethylene carboxylate or aliphatic acid polyethenoxy ether.
Rust-preventive agent is one or more (1 weight parts) and Monoethanolamine MEA BASF, diethanolamine, trolamine, a Yi Bingchunan, diisopropanolamine (DIPA), 2-amino-2-methyl-1-propanol, the morpholine in boric acid, p-tert-butyl benzoic acid, p-nitrobenzoic acid, triazines multi-carboxylic acid compounds, the ε-different nonanoyl amino acid derivative, the mixture of one or more (1～2 weight parts) in the N-methylmorpholine.
Extreme-pressure additive is sulfuration grease (example: sulfuration lard, sulfuration vulcanized vegetable oil), alkyl polysulfide (example: two nonyl polythiaethers, two dodecyl polythiaether) or Polymer Synthesizing ester.
Couplant is Virahol, propylene glycol or isomery stearyl alcohol.
The copper alloy inhibiter is 124 Triazole, tetrahydroglyoxaline, thiadiazoles polysulfide or methyl benzotriazole.
Sanitas is hexahydrotriazine or isothiazolinone; Defoamer is a silicone emulsion.
The aluminium alloy inhibiter is one or more in Starso, sodium orthosilicate, tetraethoxysilane, the methyltrimethoxy silane; The stablizer of aluminium alloy inhibiter is one or more in γ-An Bingjisanyiyangjiguiwan, N-β-(aminoethyl)-γ-An Bingjisanjiayangjiguiwan, γ-methacryloxypropyl trimethoxy silane, γ-glycidoxypropyltrimewasxysilane, N-β-(aminoethyl)-γ-aminopropyl methyl dimethoxysilane.
Highly versatile of the present invention is suitable for multiple metal, particularly is used in the processing aluminium alloy part, and aluminium alloy is had splendid anti-corrosion effects, can effectively prevent the variable color of responsive aluminium alloy; Have excellent lubricating property and guarantee the work-ing life of working accuracy and cutter; Have excellent rustless property and guarantee that the machine tool of workpiece and costliness is not by corrosion; Have outstanding anti-corrupt ability and outstanding anti-hard water ability, can recycle for a long time; Do not contain hazardous and noxious substances such as nitrite, phenols, to environment and healthy and beneficial; Have good liquid waste disposal performance, can handle by commonly industrial wastewater.
The invention will be further described below in conjunction with embodiment.
Embodiment 1:
A kind of water-soluble metalworking liquid, form by following composition by weight mixing:
Base oil or oiliness improver 45%
Anion surfactant 20%
Nonionogenic tenside 1.2%
Rust-preventive agent 10%
Extreme-pressure additive 9.8%
Couplant 9.8%
Copper alloy inhibiter 1.0%
Anticorrosive agent 1.5%
Defoamer 0.2%
Aluminium alloy inhibiter 1.0%
The stablizer 0.5% of aluminium alloy inhibiter.
Base oil or oiliness improver are the polyoxyethylene polyoxypropylene esters (or mineral oil, poly-alpha olefins, the glycol ester of linoleic acid dimer, tetramethylolmethane four oleic acid esters, pentaerythritol tetrastearate, vegetables oil, Methyl palmitoleinate, oleic acid methyl esters) of linoleic acid dimer.
Anion surfactant is an oleic acid (or ricinolic acid, dimeracid, appropriate youngster's oleic acid, isomery stearic acid 1 weight part) and the mixture (anion surfactant also can adopt petroleum sodium sulfonate) of Monoethanolamine MEA BASF (or diethanolamine, trolamine, a Yi Bingchunan, diisopropanolamine (DIPA), 2-amino-2-methyl-1-propanol, morpholine, N-methylmorpholine) 1.5～2.5 weight parts (example 1.5,2,2.5 weight parts).
Nonionogenic tenside is polyoxyethylene carboxylate (or aliphatic acid polyethenoxy ether).
Rust-preventive agent is the mixture of boric acid (or p-tert-butyl benzoic acid, p-nitrobenzoic acid, triazines multi-carboxylic acid compounds, ε-different nonanoyl amino acid derivative) 1 weight part and Monoethanolamine MEA BASF (or in diethanolamine, trolamine, a Yi Bingchunan, diisopropanolamine (DIPA), 2-amino-2-methyl-1-propanol, morpholine, N-methylmorpholine) 1～2 weight part.
Extreme-pressure additive is a sulfuration lard (or vulcanized vegetable oil, two nonyl polythiaether, two dodecyl polythiaether, Polymer Synthesizing ester).
Couplant is Virahol (or propylene glycol, isomery stearyl alcohol).
The copper alloy inhibiter is 124 Triazole (or tetrahydroglyoxaline, thiadiazoles polysulfide, methyl benzotriazole).
Sanitas is hexahydrotriazine (or isothiazolinone); Defoamer is a silicone emulsion.
The aluminium alloy inhibiter is tetraethoxysilane (or Starso, sodium orthosilicate, methyltrimethoxy silane); The stablizer of aluminium alloy inhibiter is γ-An Bingjisanyiyangjiguiwan (or N-β-(aminoethyl)-γ-An Bingjisanjiayangjiguiwan, γ-methacryloxypropyl trimethoxy silane, γ-glycidoxypropyltrimewasxysilane, N-β-(aminoethyl)-γ-aminopropyl methyl dimethoxysilane).
Embodiment 2:
A kind of water-soluble metalworking liquid, form by following composition by weight mixing:
Base oil or oiliness improver 51.5%
Anion surfactant 16.2%
Nonionogenic tenside 2%
Rust-preventive agent 5%
Extreme-pressure additive 10%
Couplant 10%
Copper alloy inhibiter 0.6%
Anticorrosive agent 2%
Defoamer 0.5%
Aluminium alloy inhibiter 0.7%
The stablizer 1.5% of aluminium alloy inhibiter.
All the other are all with embodiment 1.
Embodiment 3: a kind of water-soluble metalworking liquid, form by following composition by weight mixing:
Base oil or oiliness improver 55%
Anion surfactant 10%
Nonionogenic tenside 0.5%
Rust-preventive agent 15%
Extreme-pressure additive 8%
Couplant 7.5%
Copper alloy inhibiter 0.2%
Anticorrosive agent 1%
Defoamer 0.3%
Aluminium alloy inhibiter 0.2%
The stablizer 3% of aluminium alloy inhibiter.
All the other are all with embodiment 1.
Embodiment 4:
A kind of water-soluble metalworking liquid, form by following composition by weight mixing:
Base oil or oiliness improver 54.8%
Anion surfactant 18%
Nonionogenic tenside 1%
Rust-preventive agent 12%
Extreme-pressure additive 5%
Couplant 5%
Copper alloy inhibiter 0.7%
Anticorrosive agent 1.6%
Defoamer 0.4%
Aluminium alloy inhibiter 0.5%
The stablizer 1% of aluminium alloy inhibiter.
All the other are all with embodiment 1.
Claims (7)
1. water-soluble metalworking liquid is characterized in that: be made up of following composition by weight:
Base oil or oiliness improver 45～55%
Anion surfactant 10～20%
Nonionogenic tenside 0.5～2.0%
Rust-preventive agent 5～15%
Extreme-pressure additive 5～10%
Couplant 5～10%
Copper alloy inhibiter 0.2～1.0%
Anticorrosive agent 1～2%
Defoamer 0.2～0.5%
Aluminium alloy inhibiter 0.2～1.0%
The stablizer 0.5～3.0% of aluminium alloy inhibiter.
2. water-soluble metalworking liquid according to claim 1 is characterized in that: base oil or oiliness improver are mineral oil, poly-alpha olefins, dibasic ester class, pentaerythritol esters, vegetables oil or department of botany's oleic acid ester.
3. water-soluble metalworking liquid according to claim 1 and 2 is characterized in that: anion surfactant is one or more and Monoethanolamine MEA BASF, diethanolamine, trolamine, a Yi Bingchunan, diisopropanolamine (DIPA), 2-amino-2-methyl-1-propanol, the morpholine in oleic acid, ricinolic acid, dimeracid, appropriate youngster's oleic acid, the isomery stearic acid, one or more mixture or the petroleum sodium sulfonate in the N-methylmorpholine.
4. water-soluble metalworking liquid according to claim 1 and 2 is characterized in that: nonionogenic tenside is polyoxyethylene carboxylate or aliphatic acid polyethenoxy ether.
5. water-soluble metalworking liquid according to claim 1 and 2 is characterized in that: rust-preventive agent is one or more and Monoethanolamine MEA BASF, diethanolamine, trolamine, a Yi Bingchunan, diisopropanolamine (DIPA), 2-amino-2-methyl-1-propanol, the morpholine in boric acid, p-tert-butyl benzoic acid, p-nitrobenzoic acid, triazines multi-carboxylic acid compounds, the ε-different nonanoyl amino acid derivative, one or more the mixture in the N-methylmorpholine.
6. water-soluble metalworking liquid according to claim 1 and 2 is characterized in that: extreme-pressure additive is sulfuration grease, alkyl polysulfide or a Polymer Synthesizing ester.
7. water-soluble metalworking liquid according to claim 1 and 2 is characterized in that: couplant is Virahol, propylene glycol or isomery stearyl alcohol.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN2010102041718A CN102286302A (en) | 2010-06-17 | 2010-06-17 | Water-soluble cutting fluid |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN2010102041718A CN102286302A (en) | 2010-06-17 | 2010-06-17 | Water-soluble cutting fluid |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN102286302A true CN102286302A (en) | 2011-12-21 |
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| Application Number | Title | Priority Date | Filing Date |
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| CN2010102041718A Pending CN102286302A (en) | 2010-06-17 | 2010-06-17 | Water-soluble cutting fluid |
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| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN103146464A (en) * | 2013-01-15 | 2013-06-12 | 陕西航空电气有限责任公司 | Cutting fluid for machining inner hole of range gear cylinder |
| CN103361164A (en) * | 2013-08-02 | 2013-10-23 | 鲁南煤化工研究院 | Environmental-friendly water-based cutting fluid |
| CN103468382A (en) * | 2013-08-30 | 2013-12-25 | 广州机械科学研究院有限公司 | Boron-free chlorine-free formaldehyde-free microemulsified cutting fluid and application thereof |
| CN103627490A (en) * | 2013-11-18 | 2014-03-12 | 青岛广联达精密机械有限公司 | Improved high-permeability cutting fluid |
| CN103725392A (en) * | 2013-12-06 | 2014-04-16 | 当涂县金龙机械厂 | Environment-friendly microemulsification cutting fluid and preparation method thereof |
| CN104004578A (en) * | 2014-04-25 | 2014-08-27 | 天长市润达金属防锈助剂有限公司 | Special cutting fluid for aluminum alloys |
| CN104109578A (en) * | 2014-06-25 | 2014-10-22 | 安徽豪鼎金属制品有限公司 | Eco-friendly aqueous metal cutting fluid and preparation method thereof |
| CN104194884A (en) * | 2014-08-13 | 2014-12-10 | 铜陵日科电子有限责任公司 | Composite nano transformer oil comprising chlorinated paraffin with excellent insulative and flame retardant performances and preparation method of composite nano transformer oil |
| CN104345583A (en) * | 2013-08-02 | 2015-02-11 | 安集微电子科技(上海)有限公司 | Cleaning solution for removing light resistance residue |
| CN104450129A (en) * | 2014-12-30 | 2015-03-25 | 马艳荣 | Water-based cutting fluid and preparation method thereof |
| CN104450128A (en) * | 2014-12-30 | 2015-03-25 | 马艳荣 | Settleable water-based grinding fluid and preparation method thereof |
| CN104450145A (en) * | 2014-12-30 | 2015-03-25 | 马艳荣 | Water-based cutting fluid and preparation method thereof |
| CN104531322A (en) * | 2014-12-30 | 2015-04-22 | 马艳荣 | Settleable water-based cutting solution and preparation method thereof |
| CN105296076A (en) * | 2015-09-01 | 2016-02-03 | 当涂县维思共创工业产品设计有限公司 | High-stability molybdenum disulfide lubricant for production of aluminum profiles |
| CN105368552A (en) * | 2015-11-30 | 2016-03-02 | 陕西航空电气有限责任公司 | Cutting oil for precisely processing big and small internal holes of range shift air cylinder body |
| CN105670738A (en) * | 2016-03-11 | 2016-06-15 | 东莞市纳晟润滑油科技有限公司 | Rust-proof emulsified type metal cutting fluid |
| CN105733790A (en) * | 2016-03-11 | 2016-07-06 | 东莞市纳晟润滑油科技有限公司 | Total-synthesis special aluminum alloy cutting fluid |
| CN105754698A (en) * | 2016-03-11 | 2016-07-13 | 东莞市纳晟润滑油科技有限公司 | Water-soluble magnesium alloy machining fluid |
| CN108070431A (en) * | 2016-11-14 | 2018-05-25 | 镇江市润州金山金属粉末厂 | A kind of magnesium alloy water-soluble metalworking liquid |
| CN111979034A (en) * | 2020-09-16 | 2020-11-24 | 江苏赢新润滑科技有限公司 | Environment-friendly aluminum alloy hub machining liquid |
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2010
- 2010-06-17 CN CN2010102041718A patent/CN102286302A/en active Pending
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| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN103146464A (en) * | 2013-01-15 | 2013-06-12 | 陕西航空电气有限责任公司 | Cutting fluid for machining inner hole of range gear cylinder |
| CN104345583A (en) * | 2013-08-02 | 2015-02-11 | 安集微电子科技(上海)有限公司 | Cleaning solution for removing light resistance residue |
| CN103361164A (en) * | 2013-08-02 | 2013-10-23 | 鲁南煤化工研究院 | Environmental-friendly water-based cutting fluid |
| CN104345583B (en) * | 2013-08-02 | 2020-07-03 | 安集微电子科技（上海）股份有限公司 | Cleaning solution for removing photoresist residues |
| CN103468382A (en) * | 2013-08-30 | 2013-12-25 | 广州机械科学研究院有限公司 | Boron-free chlorine-free formaldehyde-free microemulsified cutting fluid and application thereof |
| CN103468382B (en) * | 2013-08-30 | 2015-07-08 | 广州机械科学研究院有限公司 | Boron-free chlorine-free formaldehyde-free microemulsified cutting fluid and application thereof |
| CN103627490A (en) * | 2013-11-18 | 2014-03-12 | 青岛广联达精密机械有限公司 | Improved high-permeability cutting fluid |
| CN103627490B (en) * | 2013-11-18 | 2016-04-13 | 青岛祥嘉知识产权服务有限公司 | A kind of hypertonicity cutting fluid of improvement |
| CN103725392B (en) * | 2013-12-06 | 2016-03-23 | 当涂县金龙机械厂 | A kind of environmental protection micro-emulsion cutting fluid and preparation method thereof |
| CN103725392A (en) * | 2013-12-06 | 2014-04-16 | 当涂县金龙机械厂 | Environment-friendly microemulsification cutting fluid and preparation method thereof |
| CN104004578A (en) * | 2014-04-25 | 2014-08-27 | 天长市润达金属防锈助剂有限公司 | Special cutting fluid for aluminum alloys |
| CN104109578A (en) * | 2014-06-25 | 2014-10-22 | 安徽豪鼎金属制品有限公司 | Eco-friendly aqueous metal cutting fluid and preparation method thereof |
| CN104194884A (en) * | 2014-08-13 | 2014-12-10 | 铜陵日科电子有限责任公司 | Composite nano transformer oil comprising chlorinated paraffin with excellent insulative and flame retardant performances and preparation method of composite nano transformer oil |
| CN104531322A (en) * | 2014-12-30 | 2015-04-22 | 马艳荣 | Settleable water-based cutting solution and preparation method thereof |
| CN104450145A (en) * | 2014-12-30 | 2015-03-25 | 马艳荣 | Water-based cutting fluid and preparation method thereof |
| CN104450128A (en) * | 2014-12-30 | 2015-03-25 | 马艳荣 | Settleable water-based grinding fluid and preparation method thereof |
| CN104450129A (en) * | 2014-12-30 | 2015-03-25 | 马艳荣 | Water-based cutting fluid and preparation method thereof |
| CN105296076A (en) * | 2015-09-01 | 2016-02-03 | 当涂县维思共创工业产品设计有限公司 | High-stability molybdenum disulfide lubricant for production of aluminum profiles |
| CN105368552A (en) * | 2015-11-30 | 2016-03-02 | 陕西航空电气有限责任公司 | Cutting oil for precisely processing big and small internal holes of range shift air cylinder body |
| CN105670738A (en) * | 2016-03-11 | 2016-06-15 | 东莞市纳晟润滑油科技有限公司 | Rust-proof emulsified type metal cutting fluid |
| CN105733790A (en) * | 2016-03-11 | 2016-07-06 | 东莞市纳晟润滑油科技有限公司 | Total-synthesis special aluminum alloy cutting fluid |
| CN105754698A (en) * | 2016-03-11 | 2016-07-13 | 东莞市纳晟润滑油科技有限公司 | Water-soluble magnesium alloy machining fluid |
| CN108070431A (en) * | 2016-11-14 | 2018-05-25 | 镇江市润州金山金属粉末厂 | A kind of magnesium alloy water-soluble metalworking liquid |
| CN111979034A (en) * | 2020-09-16 | 2020-11-24 | 江苏赢新润滑科技有限公司 | Environment-friendly aluminum alloy hub machining liquid |
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Application publication date: 20111221 |