CN103351919A - Microemulsion semisynthetic copper wiredrawing liquid composition and preparation method thereof - Google Patents
Microemulsion semisynthetic copper wiredrawing liquid composition and preparation method thereof Download PDFInfo
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- CN103351919A CN103351919A CN2013102435840A CN201310243584A CN103351919A CN 103351919 A CN103351919 A CN 103351919A CN 2013102435840 A CN2013102435840 A CN 2013102435840A CN 201310243584 A CN201310243584 A CN 201310243584A CN 103351919 A CN103351919 A CN 103351919A
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Abstract
The invention provides a microemulsion semisynthetic copper wiredrawing liquid composition and a preparation method thereof. The composition is prepared from the following raw materials by weight parts: 20-25 parts of soybean oil, 1-2 parts of di-t-butyl-p-cresol, 3-4 parts of tri potassium borate, 1-2 parts of benzotriazole, 2-3 parts of sodium butyl naphthalene sulfonate, 2-3 parts of a film forming auxiliary agent, 1-2 parts of alkenyl succinic acid, 3-4 parts of a silane coupling agent KH-5503, and 100-120 parts of water. According to the invention, the soybean oil is used as a lubricating component, thereby being environmental friendly and reducing harm of a wire drawing environment on worker's health; the silane coupling agent KH-5503 is used, thereby improving a film forming effect of the wiredrawing liquid, increasing a wiredrawing speed, facilitating corrosion inhibition components to form films, and prolonging an anti-corrosion time.
Description
Technical field
The present invention relates to copper conductor wire-drawing technology field, is the semi-synthetic copper drawing fluid composition and method of making the same of a kind of micro emulsion.
Background technology
Copper cash (silk) is the main transfer wire that power industry is carried electricity, is usually made by drawing process, is about to the larger wire of diameter such as steel wire by the mould hole, and under external force drawing makes its reduced cross-sectional area form the wire rod of required diameter.
The lubricating oil that adopt as the wire drawing medium more in the existing drawing process, and the conductive line surfaces that drawing goes out is mellow and full, fine and smooth, smooth, bright, no-sundries is detained, and wire broken rate reduces, and quality product improves greatly.But lubricating oil heat radiation is slow, and the damage mould affect quality product, simultaneously easily ignite oil product or oil evaporation is smoldered cause the site environment deterioration of high temperature.
Summary of the invention
The purpose of this invention is to provide the semi-synthetic copper drawing fluid composition and method of making the same of a kind of micro emulsion, have that film forming properties is good, lubricant effect is good, heat transfer rate is fast, characteristics of good cooling results, easy cleaning.
Technical scheme of the present invention is as follows:
The semi-synthetic copper drawing fluid composition of a kind of micro emulsion is characterized in that being made by the raw material of following weight part:
Soybean oil 20-25, ditertbutylparacresol 1-2, three potassium borate 3-4, benzotriazole 1-2, sodium butylnaphthalenesulfonate 2-3, film coalescence aid 2-3, alkenyl succinic acid 1-2, silane resin acceptor kh-550 3-4, water 100-120;
Described film coalescence aid is made by the raw material of following weight part: benzoquinones 0.1-0.2, vinylbenzene 6-8, tertbutyl peroxide 0.1-0.2, itaconic ester 3-4, Silane coupling agent KH550 1-2,1-hydroxyethyl-2-oil-based imidazoline 2-3;
The preparation method is: vinylbenzene is mixed with itaconic ester, stir, add tertbutyl peroxide, benzoquinones, stirring reaction 45-60 minute, then, add 1-hydroxyethyl-2-oil-based imidazoline, stirring reaction, reacts after 30-40 minute by temperature of reaction 70-80 ℃, add Silane coupling agent KH550, stirring reaction 1-2 hour; And get final product.
Three potassium borates, benzotriazole, sodium butylnaphthalenesulfonate are added to the water, are heated to 90-98 ℃, add again silane resin acceptor kh-550, film coalescence aid, stirring reaction 1-2 hour, add again other leftover materials, continued stirring reaction 2-3 hour, and get final product.
The present invention adopts soybean oil to be Lubrication Composition, and is environmentally friendly, reduced the harm of wire drawing environment to workers ' health.Silane resin acceptor kh-550 has increased the film-formation result of wire drawing liquid, has improved drawing speed, is conducive to the inhibition ingredient film forming, has prolonged the time of rust protection.
The present invention has good lubricity, stability in storage, and cost is low, good cooling results, and heat transfer rate is fast, and the temperature increasing degree is little in the use procedure, and is nonflammable, and easy cleaning has guaranteed environment for use safety.The copper wire that adopts this product to draw is linear evenly, and surface-brightening is difficult for corrosion.
Embodiment
The semi-synthetic copper drawing fluid composition of a kind of micro emulsion, made by the raw material (kilogram) of following weight part:
Soybean oil 20, ditertbutylparacresol 2, three potassium borates 3, benzotriazole 2, sodium butylnaphthalenesulfonate 2, film coalescence aid 3, alkenyl succinic acid 1, silane resin acceptor kh-550 4, water 120;
Described film coalescence aid is made by the raw material of following weight part (kilogram): benzoquinones 0.2, vinylbenzene 8, tertbutyl peroxide 0.1, itaconic ester 3, Silane coupling agent KH550 2,1-hydroxyethyl-2-oil-based imidazoline 3;
The preparation method is: vinylbenzene is mixed with itaconic ester, stir, add tertbutyl peroxide, benzoquinones, stirring reaction 45-60 minute, then, add 1-hydroxyethyl-2-oil-based imidazoline, stirring reaction, reacts after 30-40 minute by temperature of reaction 70-80 ℃, add Silane coupling agent KH550, stirring reaction 1-2 hour; And get final product.
Preparation wire drawing liquid: three potassium borates, benzotriazole, sodium butylnaphthalenesulfonate are added to the water, are heated to 90-98 ℃, add again silane resin acceptor kh-550, film coalescence aid, stirring reaction 1-2 hour, add again other leftover materials, continued stirring reaction 2-3 hour, and get final product.
Use wire drawing liquid of the present invention, the highest drawing speed can reach 16m/sec.The copper wire rust prevention during manufacture time of producing is more than 5 days; Concentrating the oil sump drain period is 3 years, and the unit oil sump drain period is 8 months, has reduced liquid waste disposal and discharging, has protected environment.
Claims (2)
1. semi-synthetic copper drawing fluid composition of micro emulsion is characterized in that being made by the raw material of following weight part:
Soybean oil 20-25, ditertbutylparacresol 1-2, three potassium borate 3-4, benzotriazole 1-2, sodium butylnaphthalenesulfonate 2-3, film coalescence aid 2-3, alkenyl succinic acid 1-2, silane resin acceptor kh-550 3-4, water 100-120;
Described film coalescence aid is made by the raw material of following weight part: benzoquinones 0.1-0.2, vinylbenzene 6-8, tertbutyl peroxide 0.1-0.2, itaconic ester 3-4, Silane coupling agent KH550 1-2,1-hydroxyethyl-2-oil-based imidazoline 2-3;
The preparation method is: vinylbenzene is mixed with itaconic ester, stir, add tertbutyl peroxide, benzoquinones, stirring reaction 45-60 minute, then, add 1-hydroxyethyl-2-oil-based imidazoline, stirring reaction, reacts after 30-40 minute by temperature of reaction 70-80 ℃, add Silane coupling agent KH550, stirring reaction 1-2 hour; And get final product.
2. the preparation method of the semi-synthetic copper drawing fluid composition of micro emulsion according to claim 1, it is characterized in that may further comprise the steps: three potassium borates, benzotriazole, sodium butylnaphthalenesulfonate are added to the water, be heated to 90-98 ℃, add again silane resin acceptor kh-550, film coalescence aid, stirring reaction 1-2 hour, add again other leftover materials, continued stirring reaction 2-3 hour, and get final product.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN2013102435840A CN103351919A (en) | 2013-06-19 | 2013-06-19 | Microemulsion semisynthetic copper wiredrawing liquid composition and preparation method thereof |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN2013102435840A CN103351919A (en) | 2013-06-19 | 2013-06-19 | Microemulsion semisynthetic copper wiredrawing liquid composition and preparation method thereof |
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| CN103351919A true CN103351919A (en) | 2013-10-16 |
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| CN2013102435840A Pending CN103351919A (en) | 2013-06-19 | 2013-06-19 | Microemulsion semisynthetic copper wiredrawing liquid composition and preparation method thereof |
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Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101205499A (en) * | 2007-11-28 | 2008-06-25 | 周贤言 | Aluminum-magnesium alloy wiredrawing lubricant |
| CN101724464A (en) * | 2009-12-29 | 2010-06-09 | 南京石油化工股份有限公司 | Preparation method of oil soluble hydrogenation corrosion inhibitor for hydrogenation and reforming device |
| CN101747987A (en) * | 2009-12-21 | 2010-06-23 | 克拉玛依市金山石油化工有限公司 | Water-based copper and aluminum wiredrawing oil composite and preparation method thereof |
| CN102361908A (en) * | 2009-03-25 | 2012-02-22 | 帝斯曼知识产权资产管理有限公司 | Process for preparing unsaturated polyester |
| CN102618372A (en) * | 2012-02-28 | 2012-08-01 | 上海尤希路化学工业有限公司 | High performance biodegradation type metal machining protection liquid |
-
2013
- 2013-06-19 CN CN2013102435840A patent/CN103351919A/en active Pending
Patent Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101205499A (en) * | 2007-11-28 | 2008-06-25 | 周贤言 | Aluminum-magnesium alloy wiredrawing lubricant |
| CN102361908A (en) * | 2009-03-25 | 2012-02-22 | 帝斯曼知识产权资产管理有限公司 | Process for preparing unsaturated polyester |
| CN101747987A (en) * | 2009-12-21 | 2010-06-23 | 克拉玛依市金山石油化工有限公司 | Water-based copper and aluminum wiredrawing oil composite and preparation method thereof |
| CN101724464A (en) * | 2009-12-29 | 2010-06-09 | 南京石油化工股份有限公司 | Preparation method of oil soluble hydrogenation corrosion inhibitor for hydrogenation and reforming device |
| CN102618372A (en) * | 2012-02-28 | 2012-08-01 | 上海尤希路化学工业有限公司 | High performance biodegradation type metal machining protection liquid |
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Application publication date: 20131016 |
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