CN103695915A - Emulsion-type antirust liquid and preparation method thereof - Google Patents
Emulsion-type antirust liquid and preparation method thereof Download PDFInfo
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- CN103695915A CN103695915A CN201310617645.5A CN201310617645A CN103695915A CN 103695915 A CN103695915 A CN 103695915A CN 201310617645 A CN201310617645 A CN 201310617645A CN 103695915 A CN103695915 A CN 103695915A
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- emulsion
- antirust
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- 239000007788 liquid Substances 0.000 title claims abstract description 21
- 238000002360 preparation method Methods 0.000 title claims abstract description 12
- PEDCQBHIVMGVHV-UHFFFAOYSA-N Glycerine Chemical compound OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 claims abstract description 15
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 12
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 claims abstract description 11
- 239000002480 mineral oil Substances 0.000 claims abstract description 10
- 235000010446 mineral oil Nutrition 0.000 claims abstract description 10
- 239000012752 auxiliary agent Substances 0.000 claims abstract description 7
- 239000002994 raw material Substances 0.000 claims abstract description 7
- QDCPNGVVOWVKJG-VAWYXSNFSA-N 2-[(e)-dodec-1-enyl]butanedioic acid Chemical compound CCCCCCCCCC\C=C\C(C(O)=O)CC(O)=O QDCPNGVVOWVKJG-VAWYXSNFSA-N 0.000 claims abstract description 4
- VVQNEPGJFQJSBK-UHFFFAOYSA-N Methyl methacrylate Chemical compound COC(=O)C(C)=C VVQNEPGJFQJSBK-UHFFFAOYSA-N 0.000 claims abstract description 4
- WXMKPNITSTVMEF-UHFFFAOYSA-M sodium benzoate Chemical compound [Na+].[O-]C(=O)C1=CC=CC=C1 WXMKPNITSTVMEF-UHFFFAOYSA-M 0.000 claims abstract description 4
- 235000010234 sodium benzoate Nutrition 0.000 claims abstract description 4
- 239000004299 sodium benzoate Substances 0.000 claims abstract description 4
- JEIPFZHSYJVQDO-UHFFFAOYSA-N iron(III) oxide Inorganic materials O=[Fe]O[Fe]=O JEIPFZHSYJVQDO-UHFFFAOYSA-N 0.000 claims description 20
- LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical compound OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 claims description 18
- 238000003756 stirring Methods 0.000 claims description 12
- DNIAPMSPPWPWGF-UHFFFAOYSA-N Propylene glycol Chemical compound CC(O)CO DNIAPMSPPWPWGF-UHFFFAOYSA-N 0.000 claims description 9
- RAADJDWNEAXLBL-UHFFFAOYSA-N 1,2-di(nonyl)naphthalene Chemical compound C1=CC=CC2=C(CCCCCCCCC)C(CCCCCCCCC)=CC=C21 RAADJDWNEAXLBL-UHFFFAOYSA-N 0.000 claims description 6
- QTBSBXVTEAMEQO-UHFFFAOYSA-M Acetate Chemical compound CC([O-])=O QTBSBXVTEAMEQO-UHFFFAOYSA-M 0.000 claims description 6
- 239000004160 Ammonium persulphate Substances 0.000 claims description 6
- YNAVUWVOSKDBBP-UHFFFAOYSA-N Morpholine Chemical compound C1COCCN1 YNAVUWVOSKDBBP-UHFFFAOYSA-N 0.000 claims description 6
- ROOXNKNUYICQNP-UHFFFAOYSA-N ammonium persulfate Chemical compound [NH4+].[NH4+].[O-]S(=O)(=O)OOS([O-])(=O)=O ROOXNKNUYICQNP-UHFFFAOYSA-N 0.000 claims description 6
- 235000019395 ammonium persulphate Nutrition 0.000 claims description 6
- 229910052788 barium Inorganic materials 0.000 claims description 6
- DSAJWYNOEDNPEQ-UHFFFAOYSA-N barium atom Chemical compound [Ba] DSAJWYNOEDNPEQ-UHFFFAOYSA-N 0.000 claims description 6
- RTZKZFJDLAIYFH-UHFFFAOYSA-N ether Substances CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 claims description 6
- 235000011187 glycerol Nutrition 0.000 claims description 6
- GHMLBKRAJCXXBS-UHFFFAOYSA-N resorcinol Chemical compound OC1=CC=CC(O)=C1 GHMLBKRAJCXXBS-UHFFFAOYSA-N 0.000 claims description 6
- UEUXEKPTXMALOB-UHFFFAOYSA-J tetrasodium;2-[2-[bis(carboxylatomethyl)amino]ethyl-(carboxylatomethyl)amino]acetate Chemical compound [Na+].[Na+].[Na+].[Na+].[O-]C(=O)CN(CC([O-])=O)CCN(CC([O-])=O)CC([O-])=O UEUXEKPTXMALOB-UHFFFAOYSA-J 0.000 claims description 6
- PFTAWBLQPZVEMU-DZGCQCFKSA-N (+)-catechin Chemical compound C1([C@H]2OC3=CC(O)=CC(O)=C3C[C@@H]2O)=CC=C(O)C(O)=C1 PFTAWBLQPZVEMU-DZGCQCFKSA-N 0.000 claims description 3
- -1 Lauryl Alcohol ester Chemical class 0.000 claims description 3
- OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical group OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 claims description 3
- 235000006040 Prunus persica var persica Nutrition 0.000 claims description 3
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 claims description 3
- ADRVNXBAWSRFAJ-UHFFFAOYSA-N catechin Natural products OC1Cc2cc(O)cc(O)c2OC1c3ccc(O)c(O)c3 ADRVNXBAWSRFAJ-UHFFFAOYSA-N 0.000 claims description 3
- 235000005487 catechin Nutrition 0.000 claims description 3
- 238000006243 chemical reaction Methods 0.000 claims description 3
- 229950001002 cianidanol Drugs 0.000 claims description 3
- 239000000463 material Substances 0.000 claims description 3
- 235000010482 polyoxyethylene sorbitan monooleate Nutrition 0.000 claims description 3
- 239000000244 polyoxyethylene sorbitan monooleate Substances 0.000 claims description 3
- 229920000053 polysorbate 80 Polymers 0.000 claims description 3
- 235000019353 potassium silicate Nutrition 0.000 claims description 3
- NTHWMYGWWRZVTN-UHFFFAOYSA-N sodium silicate Chemical compound [Na+].[Na+].[O-][Si]([O-])=O NTHWMYGWWRZVTN-UHFFFAOYSA-N 0.000 claims description 3
- OGIDPMRJRNCKJF-UHFFFAOYSA-N titanium oxide Inorganic materials [Ti]=O OGIDPMRJRNCKJF-UHFFFAOYSA-N 0.000 claims description 3
- 240000006413 Prunus persica var. persica Species 0.000 claims 1
- 230000000694 effects Effects 0.000 abstract description 3
- 230000007613 environmental effect Effects 0.000 abstract description 3
- 229910052751 metal Inorganic materials 0.000 abstract description 3
- 239000002184 metal Substances 0.000 abstract description 3
- 239000011347 resin Substances 0.000 abstract description 3
- 229920005989 resin Polymers 0.000 abstract description 3
- 238000000034 method Methods 0.000 abstract description 2
- 239000000178 monomer Substances 0.000 abstract description 2
- 239000003960 organic solvent Substances 0.000 abstract description 2
- 230000003647 oxidation Effects 0.000 abstract description 2
- 238000007254 oxidation reaction Methods 0.000 abstract description 2
- SVONRAPFKPVNKG-UHFFFAOYSA-N 2-ethoxyethyl acetate Chemical compound CCOCCOC(C)=O SVONRAPFKPVNKG-UHFFFAOYSA-N 0.000 abstract 1
- LXAHHHIGZXPRKQ-UHFFFAOYSA-N 5-fluoro-2-methylpyridine Chemical compound CC1=CC=C(F)C=N1 LXAHHHIGZXPRKQ-UHFFFAOYSA-N 0.000 abstract 1
- YSIQDTZQRDDQNF-UHFFFAOYSA-L barium(2+);2,3-di(nonyl)naphthalene-1-sulfonate Chemical compound [Ba+2].C1=CC=C2C(S([O-])(=O)=O)=C(CCCCCCCCC)C(CCCCCCCCC)=CC2=C1.C1=CC=C2C(S([O-])(=O)=O)=C(CCCCCCCCC)C(CCCCCCCCC)=CC2=C1 YSIQDTZQRDDQNF-UHFFFAOYSA-L 0.000 abstract 1
- 239000002738 chelating agent Substances 0.000 abstract 1
- 230000003670 easy-to-clean Effects 0.000 abstract 1
- 235000019441 ethanol Nutrition 0.000 abstract 1
- 239000010409 thin film Substances 0.000 abstract 1
- 239000003921 oil Substances 0.000 description 4
- 230000003449 preventive effect Effects 0.000 description 3
- 244000144730 Amygdalus persica Species 0.000 description 2
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 description 2
- 238000005516 engineering process Methods 0.000 description 2
- 229910000831 Steel Inorganic materials 0.000 description 1
- 230000003064 anti-oxidating effect Effects 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 230000015556 catabolic process Effects 0.000 description 1
- 238000004140 cleaning Methods 0.000 description 1
- 238000005260 corrosion Methods 0.000 description 1
- 230000007797 corrosion Effects 0.000 description 1
- 238000006731 degradation reaction Methods 0.000 description 1
- 238000002845 discoloration Methods 0.000 description 1
- 238000004090 dissolution Methods 0.000 description 1
- 239000000428 dust Substances 0.000 description 1
- 239000002360 explosive Substances 0.000 description 1
- 238000007654 immersion Methods 0.000 description 1
- 238000009776 industrial production Methods 0.000 description 1
- 239000000976 ink Substances 0.000 description 1
- 229910052742 iron Inorganic materials 0.000 description 1
- 229920002521 macromolecule Polymers 0.000 description 1
- 239000011159 matrix material Substances 0.000 description 1
- 150000003839 salts Chemical class 0.000 description 1
- 239000003352 sequestering agent Substances 0.000 description 1
- LPXPTNMVRIOKMN-UHFFFAOYSA-M sodium nitrite Chemical class [Na+].[O-]N=O LPXPTNMVRIOKMN-UHFFFAOYSA-M 0.000 description 1
- 235000010288 sodium nitrite Nutrition 0.000 description 1
- 239000002904 solvent Substances 0.000 description 1
- 239000010959 steel Substances 0.000 description 1
- 239000000080 wetting agent Substances 0.000 description 1
Landscapes
- Preventing Corrosion Or Incrustation Of Metals (AREA)
- Lubricants (AREA)
Abstract
The invention discloses an emulsion-type antirust liquid which is prepared from the following raw materials in parts by weight: 10-12 parts of mineral oil, 1-2 parts of OP-10, 20-23 parts of glycerol, 20-24 parts of ethyl alcohol, 1-2 parts of sodium benzoate, 1-2 parts of barium dinonyl naphthalene sulfonate, 3-4 parts of dodecenylsuccinic acid, 4-5 parts of bis-dodecanol ester, 1-2 parts of methyl methacrylate, 3-5 parts of ethylene glycol monoethyl ether acetate, 1-2 parts of EDTA disodium, 4-5 parts of an auxiliary agent, and 300 parts of water. Through use of high-molecular resin monomers and the chelating agent, a thin film can be formed on the surface of a metal, thereby playing roles in isolating air and preventing oxidation; through use of the organic solvent and the mineral oil, the affinity between the antirust liquid and the metal is increased, and the antirust effect is increased; the antirust liquid has strong antirust ability, good solution stability, large treatment capacity, low cost, environmental protection and no pollution; and besides, the antirust liquid is simple in preparation method, does not need to invest a lot of equipment, has simple using method, and is relatively easy to clean and easy to operate.
Description
Technical field
The present invention relates to antirust technology field, relate in particular to a kind of emulsion-type rust protection liquid and preparation method thereof.
Background technology
Metallic surface is antirust is the important topic in industrial production, and traditional rust protection liquid, slushing oil have advantage also to have shortcoming.In common aqueous rust preventive, containing a large amount of Sodium Nitrites, there is carinogenicity, be unfavorable for that environmental protection and the person are healthy, and adopt wetting Agent for Printing Inks to extend the life-span of aqueous rust preventive, bring again the disadvantage of touching with one's hand, being covered with dust, and can not be antirust for a long time; Although it is antirust for a long time that general hard film rust preventive oil is applicable to, film forming is also transparent attractive in appearance, and water white resin kind is less, and unstable also easy oxidation discoloration, also needs organic solvent dissolution, brings inflammable and explosive danger to be also unfavorable for environmental protection and health; General slushing oil is used mineral oil, difficult degradation, and also can bring the problem of oil removing difficulty when antirust for short-term.Therefore, comprehensive study performance is more excellent, and the antirust product being more applicable to for different occasion research is new direction and trend.
Summary of the invention
The object of the present invention is to provide a kind of emulsion-type rust protection liquid and preparation method thereof, this rust protection liquid has long, easy and simple to handle feature of antirust time.
Technical scheme of the present invention is as follows:
An emulsion-type rust protection liquid, is characterized in that being made by the raw material of following weight part: mineral oil 10-12, OP-10 1-2, glycerine 20-23, alcohol 20-24, Sodium Benzoate 1-2, dinonyl naphthalene sulfonate barium 1-2, dodecenylsuccinic acid 3-4, two Lauryl Alcohol ester 4-5, methyl methacrylate 1-2, ethylene glycol ether acetate 3-5, EDETATE SODIUM 1-2, auxiliary agent 4-5, water 300.Described auxiliary agent is made by the raw material of following weight part: polyoxyethylene sorbitan monooleate 2-3, nano titanium oxide 0.1-0.2, catechin 1-2, ethanol 10-12, water glass 3-4, Resorcinol 1-2, propylene glycol 3-4, morpholine 1-2, peach gum 2-3, ammonium persulphate 1-2, water 20-24; Preparation method be ammonium persulphate is water-soluble after, then add other leftover materials, stir 10-15 minute, be heated to 70-80 ℃, stirring reaction 1-2 hour, obtains.
The preparation method of described emulsion-type rust protection liquid, is characterized in that comprising the following steps: water, OP-10, dinonyl naphthalene sulfonate barium, glycerine are mixed, be heated to 40-50 ℃; Add mineral oil, alcohol, methyl methacrylate, ethylene glycol ether acetate, EDETATE SODIUM, continue to be heated to 85-90 ℃, stir 10-15 minute; Add other remaining components, continue to stir 15-20 minute, obtain.
Beneficial effect of the present invention
The present invention uses macromolecule resin monomer, sequestrant, can form film in metallic surface, plays isolated air, anti-oxidation effect; By using machine solvent, mineral oil to increase the avidity between rust protection liquid and metal, increased rust-proof effect; Rust protection liquid of the present invention, antirust ability is strong, and stability of solution is good, and processing capacity is large, and cost is low and environment friendly and pollution-free, and the preparation method of this rust protection liquid is simple and easy simultaneously, and without a large amount of equipment investments, using method is simple, compared with easy cleaning, easy to operate.
Embodiment
An emulsion-type rust protection liquid, by following weight part (kilogram) raw material make: mineral oil 11, OP-10 1.5, glycerine 22, alcohol 22, Sodium Benzoate 1.5, dinonyl naphthalene sulfonate barium 1.5, dodecenylsuccinic acid 3.5, two Lauryl Alcohol ester 4.5, methyl methacrylate 1.5, ethylene glycol ether acetate 4, EDETATE SODIUM 1.5, auxiliary agent 4.5, water 300.Described auxiliary agent by following weight part (kilogram) raw material make: polyoxyethylene sorbitan monooleate 2, nano titanium oxide 0.1, catechin 1, ethanol 10, water glass 3, Resorcinol 1, propylene glycol 3, morpholine 2, peach gum 2, ammonium persulphate 1, water 20; Preparation method be ammonium persulphate is water-soluble after, then add other leftover materials, stir 10-15 minute, be heated to 70-80 ℃, stirring reaction 1-2 hour, obtains.
The preparation method of described emulsion-type rust protection liquid, comprises the following steps: water, OP-10, dinonyl naphthalene sulfonate barium, glycerine are mixed, be heated to 46 ℃; Add mineral oil, alcohol, methyl methacrylate, ethylene glycol ether acetate, EDETATE SODIUM, continue to be heated to 88 ℃, stir 14 minutes; Add other remaining components, continue to stir 18 minutes, obtain.
The emulsion-type rust protection liquid that this embodiment obtains detects by national standard, and humid heat test * (1) is qualified; Salt water immersion test * (1): qualified; Corrosion test * (2): qualified; Rust removability (inferior) < 6.Prepared emulsion-type rust protection liquid is brushed on the steel matrix surface of being newly processed into and there is no greasy dirt, be placed in and within indoor 20 days, have no obvious iron mold.
Claims (2)
1. an emulsion-type rust protection liquid, is characterized in that being made by the raw material of following weight part: mineral oil 10-12, OP-10 1-2, glycerine 20-23, alcohol 20-24, Sodium Benzoate 1-2, dinonyl naphthalene sulfonate barium 1-2, dodecenylsuccinic acid 3-4, two Lauryl Alcohol ester 4-5, methyl methacrylate 1-2, ethylene glycol ether acetate 3-5, EDETATE SODIUM 1-2, auxiliary agent 4-5, water 300; Described auxiliary agent is made by the raw material of following weight part: polyoxyethylene sorbitan monooleate 2-3, nano titanium oxide 0.1-0.2, catechin 1-2, ethanol 10-12, water glass 3-4, Resorcinol 1-2, propylene glycol 3-4, morpholine 1-2, peach gum 2-3, ammonium persulphate 1-2, water 20-24; Preparation method be ammonium persulphate is water-soluble after, then add other leftover materials, stir 10-15 minute, be heated to 70-80 ℃, stirring reaction 1-2 hour, obtains.
2. the preparation method of emulsion-type rust protection liquid according to claim 1, is characterized in that comprising the following steps: water, OP-10, dinonyl naphthalene sulfonate barium, glycerine are mixed, be heated to 40-50 ℃; Add mineral oil, alcohol, methyl methacrylate, ethylene glycol ether acetate, EDETATE SODIUM, continue to be heated to 85-90 ℃, stir 10-15 minute; Add other remaining components, continue to stir 15-20 minute, obtain.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201310617645.5A CN103695915B (en) | 2013-11-29 | 2013-11-29 | A kind of emulsion-type antirust solution and preparation method thereof |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201310617645.5A CN103695915B (en) | 2013-11-29 | 2013-11-29 | A kind of emulsion-type antirust solution and preparation method thereof |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN103695915A true CN103695915A (en) | 2014-04-02 |
| CN103695915B CN103695915B (en) | 2016-05-04 |
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Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201310617645.5A Active CN103695915B (en) | 2013-11-29 | 2013-11-29 | A kind of emulsion-type antirust solution and preparation method thereof |
Country Status (1)
| Country | Link |
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| CN (1) | CN103695915B (en) |
Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN106381201A (en) * | 2016-08-17 | 2017-02-08 | 安徽红桥金属制造有限公司 | Multifunctional composite rust-preventative oil used for alloy castings |
| CN110106012A (en) * | 2019-06-13 | 2019-08-09 | 莱州市恒力达化工有限公司 | A kind of long-acting water-based antirust agent |
| CN114438500A (en) * | 2021-12-24 | 2022-05-06 | 苏州市浒墅关化工添加剂有限公司 | Environment-friendly emulsified antirust liquid and preparation method thereof |
| CN115261866A (en) * | 2022-08-02 | 2022-11-01 | 黄山学院 | Long-acting thick-film water-based antirust agent and preparation method thereof |
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| Publication number | Priority date | Publication date | Assignee | Title |
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| GB2005300A (en) * | 1977-10-03 | 1979-04-19 | Exxon Research Engineering Co | Metalworking lubricant |
| CN101608310A (en) * | 2008-06-16 | 2009-12-23 | 南京科润工业介质有限公司 | Long-acting emulsion-type antirust fluid |
| CN102924991A (en) * | 2012-10-12 | 2013-02-13 | 天津大学 | Application of rust-preventative oil in enhancing corrosion resistance of carbon steel material |
| CN103147079A (en) * | 2013-02-04 | 2013-06-12 | 安徽省繁昌县皖南阀门铸造有限公司 | Metal rust-preventative oil containing terpene resin T-120 |
| CN103243326A (en) * | 2012-02-08 | 2013-08-14 | 骆伟伟 | Method for preparing dodecenylsuccinic acid oil soluble corrosion inhibitor |
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2013
- 2013-11-29 CN CN201310617645.5A patent/CN103695915B/en active Active
Patent Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| GB2005300A (en) * | 1977-10-03 | 1979-04-19 | Exxon Research Engineering Co | Metalworking lubricant |
| CN101608310A (en) * | 2008-06-16 | 2009-12-23 | 南京科润工业介质有限公司 | Long-acting emulsion-type antirust fluid |
| CN103243326A (en) * | 2012-02-08 | 2013-08-14 | 骆伟伟 | Method for preparing dodecenylsuccinic acid oil soluble corrosion inhibitor |
| CN102924991A (en) * | 2012-10-12 | 2013-02-13 | 天津大学 | Application of rust-preventative oil in enhancing corrosion resistance of carbon steel material |
| CN103147079A (en) * | 2013-02-04 | 2013-06-12 | 安徽省繁昌县皖南阀门铸造有限公司 | Metal rust-preventative oil containing terpene resin T-120 |
Cited By (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN106381201A (en) * | 2016-08-17 | 2017-02-08 | 安徽红桥金属制造有限公司 | Multifunctional composite rust-preventative oil used for alloy castings |
| CN110106012A (en) * | 2019-06-13 | 2019-08-09 | 莱州市恒力达化工有限公司 | A kind of long-acting water-based antirust agent |
| CN114438500A (en) * | 2021-12-24 | 2022-05-06 | 苏州市浒墅关化工添加剂有限公司 | Environment-friendly emulsified antirust liquid and preparation method thereof |
| CN115261866A (en) * | 2022-08-02 | 2022-11-01 | 黄山学院 | Long-acting thick-film water-based antirust agent and preparation method thereof |
| CN115261866B (en) * | 2022-08-02 | 2023-12-19 | 黄山学院 | Long-acting thick film water-based antirust agent and preparation method thereof |
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| Publication number | Publication date |
|---|---|
| CN103695915B (en) | 2016-05-04 |
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Effective date of registration: 20240522 Address after: No. 98 Qicang Road, Mingguang City, Chuzhou City, Anhui Province, 239000 Patentee after: Mingguang Jiuzhi Intellectual Property Management Co.,Ltd. Country or region after: China Address before: 239400 No. 72, Liuwan Road, Mingguang Industrial Park, Chuzhou City, Anhui Province Patentee before: MINGGUANG CITY LIUXIANG PUMP INDUSTRY Co.,Ltd. Country or region before: China |