CN103695940B - A kind of Water-soluble antioxidant derusting rust-proofing liquid and preparation method thereof - Google Patents
A kind of Water-soluble antioxidant derusting rust-proofing liquid and preparation method thereof Download PDFInfo
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- CN103695940B CN103695940B CN201310617602.7A CN201310617602A CN103695940B CN 103695940 B CN103695940 B CN 103695940B CN 201310617602 A CN201310617602 A CN 201310617602A CN 103695940 B CN103695940 B CN 103695940B
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- water
- antirust
- soluble antioxidant
- derusting
- preparation
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- 239000003963 antioxidant agent Substances 0.000 title claims abstract description 12
- 230000003078 antioxidant effect Effects 0.000 title claims abstract description 12
- 239000007788 liquid Substances 0.000 title claims abstract description 12
- 238000002360 preparation method Methods 0.000 title claims description 9
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 14
- VEXZGXHMUGYJMC-UHFFFAOYSA-N Hydrochloric acid Chemical compound Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 claims abstract description 12
- 239000004115 Sodium Silicate Substances 0.000 claims abstract description 9
- NTHWMYGWWRZVTN-UHFFFAOYSA-N sodium silicate Chemical compound [Na+].[Na+].[O-][Si]([O-])=O NTHWMYGWWRZVTN-UHFFFAOYSA-N 0.000 claims abstract description 9
- 229910052911 sodium silicate Inorganic materials 0.000 claims abstract description 9
- NIXOWILDQLNWCW-UHFFFAOYSA-M Acrylate Chemical compound [O-]C(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-M 0.000 claims abstract description 8
- 229920001451 polypropylene glycol Polymers 0.000 claims abstract description 8
- 239000012752 auxiliary agent Substances 0.000 claims abstract description 7
- 239000002994 raw material Substances 0.000 claims abstract description 7
- KEAYESYHFKHZAL-UHFFFAOYSA-N Sodium Chemical compound [Na] KEAYESYHFKHZAL-UHFFFAOYSA-N 0.000 claims abstract description 6
- ZFSLODLOARCGLH-UHFFFAOYSA-N isocyanuric acid Chemical compound OC1=NC(O)=NC(O)=N1 ZFSLODLOARCGLH-UHFFFAOYSA-N 0.000 claims abstract description 6
- UEUXEKPTXMALOB-UHFFFAOYSA-J tetrasodium;2-[2-[bis(carboxylatomethyl)amino]ethyl-(carboxylatomethyl)amino]acetate Chemical compound [Na+].[Na+].[Na+].[Na+].[O-]C(=O)CN(CC([O-])=O)CCN(CC([O-])=O)CC([O-])=O UEUXEKPTXMALOB-UHFFFAOYSA-J 0.000 claims abstract description 6
- QDCPNGVVOWVKJG-VAWYXSNFSA-N 2-[(e)-dodec-1-enyl]butanedioic acid Chemical compound CCCCCCCCCC\C=C\C(C(O)=O)CC(O)=O QDCPNGVVOWVKJG-VAWYXSNFSA-N 0.000 claims abstract description 4
- ROOXNKNUYICQNP-UHFFFAOYSA-N ammonium persulfate Chemical compound [NH4+].[NH4+].[O-]S(=O)(=O)OOS([O-])(=O)=O ROOXNKNUYICQNP-UHFFFAOYSA-N 0.000 claims description 12
- 235000006708 antioxidants Nutrition 0.000 claims description 10
- 238000003756 stirring Methods 0.000 claims description 10
- DNIAPMSPPWPWGF-UHFFFAOYSA-N Propylene glycol Chemical compound CC(O)CO DNIAPMSPPWPWGF-UHFFFAOYSA-N 0.000 claims description 9
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 claims description 6
- YNAVUWVOSKDBBP-UHFFFAOYSA-N Morpholine Chemical compound C1COCCN1 YNAVUWVOSKDBBP-UHFFFAOYSA-N 0.000 claims description 6
- 229910001870 ammonium persulfate Inorganic materials 0.000 claims description 6
- GHMLBKRAJCXXBS-UHFFFAOYSA-N resorcinol Chemical compound OC1=CC=CC(O)=C1 GHMLBKRAJCXXBS-UHFFFAOYSA-N 0.000 claims description 6
- 239000012467 final product Substances 0.000 claims description 5
- PFTAWBLQPZVEMU-DZGCQCFKSA-N (+)-catechin Chemical compound C1([C@H]2OC3=CC(O)=CC(O)=C3C[C@@H]2O)=CC=C(O)C(O)=C1 PFTAWBLQPZVEMU-DZGCQCFKSA-N 0.000 claims description 3
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 claims description 3
- ADRVNXBAWSRFAJ-UHFFFAOYSA-N catechin Natural products OC1Cc2cc(O)cc(O)c2OC1c3ccc(O)c(O)c3 ADRVNXBAWSRFAJ-UHFFFAOYSA-N 0.000 claims description 3
- 235000005487 catechin Nutrition 0.000 claims description 3
- 238000006243 chemical reaction Methods 0.000 claims description 3
- 229950001002 cianidanol Drugs 0.000 claims description 3
- 239000000463 material Substances 0.000 claims description 3
- 239000000244 polyoxyethylene sorbitan monooleate Substances 0.000 claims description 3
- 235000010482 polyoxyethylene sorbitan monooleate Nutrition 0.000 claims description 3
- 229920000053 polysorbate 80 Polymers 0.000 claims description 3
- OGIDPMRJRNCKJF-UHFFFAOYSA-N titanium oxide Inorganic materials [Ti]=O OGIDPMRJRNCKJF-UHFFFAOYSA-N 0.000 claims description 3
- 229910052751 metal Inorganic materials 0.000 abstract description 5
- 239000002184 metal Substances 0.000 abstract description 5
- 230000003064 anti-oxidating effect Effects 0.000 abstract description 4
- 230000007774 longterm Effects 0.000 abstract description 4
- 239000013556 antirust agent Substances 0.000 abstract description 2
- 230000002301 combined effect Effects 0.000 abstract description 2
- 230000000694 effects Effects 0.000 abstract description 2
- 238000002955 isolation Methods 0.000 abstract description 2
- 239000000178 monomer Substances 0.000 abstract description 2
- 229920000642 polymer Polymers 0.000 abstract description 2
- 239000000126 substance Substances 0.000 abstract description 2
- 239000010409 thin film Substances 0.000 abstract description 2
- 238000005406 washing Methods 0.000 abstract description 2
- JEIPFZHSYJVQDO-UHFFFAOYSA-N iron(III) oxide Inorganic materials O=[Fe]O[Fe]=O JEIPFZHSYJVQDO-UHFFFAOYSA-N 0.000 description 9
- 239000003921 oil Substances 0.000 description 6
- 230000002265 prevention Effects 0.000 description 4
- 230000003449 preventive effect Effects 0.000 description 3
- 238000012360 testing method Methods 0.000 description 3
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 description 2
- OFOBLEOULBTSOW-UHFFFAOYSA-N Propanedioic acid Natural products OC(=O)CC(O)=O OFOBLEOULBTSOW-UHFFFAOYSA-N 0.000 description 2
- 238000004140 cleaning Methods 0.000 description 2
- 230000007613 environmental effect Effects 0.000 description 2
- 239000010408 film Substances 0.000 description 2
- 238000010438 heat treatment Methods 0.000 description 2
- VZCYOOQTPOCHFL-UPHRSURJSA-N maleic acid Chemical compound OC(=O)\C=C/C(O)=O VZCYOOQTPOCHFL-UPHRSURJSA-N 0.000 description 2
- 239000011976 maleic acid Substances 0.000 description 2
- 238000002156 mixing Methods 0.000 description 2
- LPXPTNMVRIOKMN-UHFFFAOYSA-M sodium nitrite Chemical compound [Na+].[O-]N=O LPXPTNMVRIOKMN-UHFFFAOYSA-M 0.000 description 2
- VZCYOOQTPOCHFL-UHFFFAOYSA-N trans-butenedioic acid Natural products OC(=O)C=CC(O)=O VZCYOOQTPOCHFL-UHFFFAOYSA-N 0.000 description 2
- 229910000831 Steel Inorganic materials 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 230000015556 catabolic process Effects 0.000 description 1
- 238000005260 corrosion Methods 0.000 description 1
- 230000007797 corrosion Effects 0.000 description 1
- 238000006731 degradation reaction Methods 0.000 description 1
- 238000002845 discoloration Methods 0.000 description 1
- 238000004090 dissolution Methods 0.000 description 1
- 239000000428 dust Substances 0.000 description 1
- 239000002360 explosive Substances 0.000 description 1
- 238000007654 immersion Methods 0.000 description 1
- 229910052742 iron Inorganic materials 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 239000011159 matrix material Substances 0.000 description 1
- 239000002480 mineral oil Substances 0.000 description 1
- 235000010446 mineral oil Nutrition 0.000 description 1
- 239000003960 organic solvent Substances 0.000 description 1
- 230000003647 oxidation Effects 0.000 description 1
- 238000007254 oxidation reaction Methods 0.000 description 1
- 239000000047 product Substances 0.000 description 1
- 238000011160 research Methods 0.000 description 1
- 239000011347 resin Substances 0.000 description 1
- 229920005989 resin Polymers 0.000 description 1
- 150000003839 salts Chemical class 0.000 description 1
- 235000010288 sodium nitrite Nutrition 0.000 description 1
- 239000010959 steel Substances 0.000 description 1
- 239000000080 wetting agent Substances 0.000 description 1
Landscapes
- Preventing Corrosion Or Incrustation Of Metals (AREA)
- Anti-Oxidant Or Stabilizer Compositions (AREA)
Abstract
The invention discloses a kind of Water-soluble antioxidant derusting rust-proofing liquid, be made up of the raw material of following weight portion: BTA 1-2, dodecenylsuccinic acid 1-2, natrium malicum 3-4, oleum lini 6-8, hydrochloric acid 2-3, polypropylene glycol acrylate 4-5, paregal O 1-2, sodium silicate 6-9, cyanurate three-glycidyl ester 1-2, EDETATE SODIUM 1-2, auxiliary agent 4-5, water 300.By the present invention in that with high molecular polymer monomer and chelating agen combined effect, thin film can be formed in metal surface, play isolation air, stick antirust agent, anti-oxidation effect；By using natrium malicum, oleum lini, not only completely cut off air, and antioxidation；By using hydrochloric acid, can quick derusting；Antirust solution easy-clear of the present invention, namely washing is fallen；Harmful substance is few, it is prevented that metal variable color, it is adaptable to metallic article, machine components shot and long term antirust.
Description
Technical field
The present invention relates to technical field of rust prevention, particularly relate to a kind of Water-soluble antioxidant derusting rust-proofing liquid and preparation method thereof.
Background technology
Metal surface is antirust is the important topic in commercial production, and traditional antirust solution, antirust oil have advantage also to have shortcoming.Containing substantial amounts of sodium nitrite in common aqueous rust preventive, there is carcinogenecity, be unfavorable for that environmental protection and the person are healthy, and adopt wetting agent to extend the life-span of aqueous rust preventive, bring again the disadvantage touched with one's hand, be covered with dust, and can not long-term rust prevention；Although general hard film rust preventive oil is suitable for long-term rust prevention, film forming is also transparent attractive in appearance, but water white resin types is less, and instability is easy oxidation discoloration also, in addition it is also necessary to organic solvent dissolution, brings inflammable and explosive danger to be also unfavorable for environmental protection and health；General antirust oil uses mineral oil, difficult degradation, and also brings along the problem that oil removing is difficult during for short-term rust prevention.Therefore, comprehensive study performance is more excellent, and the antirust product being more suitable for for different occasion researchs is new direction and trend.
Summary of the invention
It is an object of the invention to provide a kind of Water-soluble antioxidant derusting rust-proofing liquid and preparation method thereof, this antirust solution has the feature of rust cleaning, antirust, easy cleaning.
Technical scheme is as follows:
A kind of Water-soluble antioxidant derusting rust-proofing liquid, it is characterised in that be made up of the raw material of following weight portion: BTA 1-2, dodecenylsuccinic acid 1-2, natrium malicum 3-4, oleum lini 6-8, hydrochloric acid 2-3, polypropylene glycol acrylate 4-5, paregal O 1-2, sodium silicate 6-9, cyanurate three-glycidyl ester 1-2, EDETATE SODIUM 1-2, auxiliary agent 4-5, water 300.Described auxiliary agent is made up of the raw material of following weight portion: polyoxyethylene sorbitan monooleate 2-3, nano titanium oxide 0.1-0.2, catechin 1-2, ethanol 10-12, sodium silicate 3-4, resorcinol 1-2, propylene glycol 3-4, morpholine 1-2, Resina persicae 2-3, Ammonium persulfate. 1-2, water 20-24；Preparation method is after dissolving ammonium persulfate into water, adds other leftover materials, stirs 10-15 minute, heats to 70-80 DEG C, stirring reaction 1-2 hour, to obtain final product.
The preparation method of described Water-soluble antioxidant derusting rust-proofing liquid, it is characterised in that comprise the following steps: by water, paregal O, mixing, heating is to 40-50 DEG C；Add Petiolus Trachycarpi oil, polypropylene glycol acrylate, maleic acid, polypropylene glycol acrylate, cyanurate three-glycidyl ester, sodium silicate, EDETATE SODIUM, continue to be heated to 85-90 DEG C, stir 10-15 minute；Add other residual componentss, continue stirring 15-20 minute, to obtain final product.
Beneficial effects of the present invention
By the present invention in that with high molecular polymer monomer and chelating agen combined effect, thin film can be formed in metal surface, play isolation air, stick antirust agent, anti-oxidation effect；By using natrium malicum, oleum lini, not only completely cut off air, and antioxidation；By using hydrochloric acid, can quick derusting；Antirust solution easy-clear of the present invention, namely washing is fallen；Harmful substance is few, it is prevented that metal variable color, it is adaptable to metallic article, machine components shot and long term antirust.
Detailed description of the invention
A kind of Water-soluble antioxidant derusting rust-proofing liquid, is made up of the raw material of following weight portion (kilogram): BTA 1.5, dodecenylsuccinic acid 1.5, natrium malicum 3.5, oleum lini 7, hydrochloric acid 2.5, polypropylene glycol acrylate 4.5, paregal O 1.5, sodium silicate 8, cyanurate three-glycidyl ester 1.5, EDETATE SODIUM 1.5, auxiliary agent 4.5, water 300.Described auxiliary agent is made up of the raw material of following weight portion (kilogram): polyoxyethylene sorbitan monooleate 2, nano titanium oxide 0.1, catechin 1, ethanol 10, sodium silicate 3, resorcinol 1, propylene glycol 3, morpholine 2, Resina persicae 2, Ammonium persulfate. 1, water 20；Preparation method is after dissolving ammonium persulfate into water, adds other leftover materials, stirs 10-15 minute, heats to 70-80 DEG C, stirring reaction 1-2 hour, to obtain final product.
The preparation method of described Water-soluble antioxidant derusting rust-proofing liquid, comprises the following steps: by water, paregal O, mixing, heating is to 45 DEG C；Add Petiolus Trachycarpi oil, polypropylene glycol acrylate, maleic acid, polypropylene glycol acrylate, cyanurate three-glycidyl ester, sodium silicate, EDETATE SODIUM, continue to be heated to 88 DEG C, stir 13 minutes；Add other residual componentss, continue stirring 18 minutes, to obtain final product.
The Water-soluble antioxidant derusting rust-proofing liquid that this embodiment obtains detects by national standard, and damp heat test * (1) is qualified；Salt water immersion test * (1): qualified；Corrosion testing * (2): qualified；Rust removability (secondary) < 6.Prepared Water-soluble antioxidant derusting rust-proofing liquid is brushed that be newly processed into and do not have the steel matrix surface of greasy dirt, within 20 days disposed within, to have no obvious iron mold.
Claims (1)
1. a Water-soluble antioxidant derusting rust-proofing liquid, it is characterised in that be made up of the raw material of following weight portion: BTA 1-2, dodecenylsuccinic acid 1-2, natrium malicum 3-4, oleum lini 6-8, hydrochloric acid 2-3, polypropylene glycol acrylate 4-5, paregal O 1-2, sodium silicate 6-9, cyanurate three-glycidyl ester 1-2, EDETATE SODIUM 1-2, auxiliary agent 4-5, water 300；Described auxiliary agent is made up of the raw material of following weight portion: polyoxyethylene sorbitan monooleate 2-3, nano titanium oxide 0.1-0.2, catechin 1-2, ethanol 10-12, sodium silicate 3-4, resorcinol 1-2, propylene glycol 3-4, morpholine 1-2, Resina persicae 2-3, Ammonium persulfate. 1-2, water 20-24；Preparation method is after dissolving ammonium persulfate into water, adds other leftover materials, stirs 10-15 minute, heats to 70-80 DEG C, stirring reaction 1-2 hour, to obtain final product.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201310617602.7A CN103695940B (en) | 2013-11-29 | 2013-11-29 | A kind of Water-soluble antioxidant derusting rust-proofing liquid and preparation method thereof |
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| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201310617602.7A CN103695940B (en) | 2013-11-29 | 2013-11-29 | A kind of Water-soluble antioxidant derusting rust-proofing liquid and preparation method thereof |
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| Publication Number | Publication Date |
|---|---|
| CN103695940A CN103695940A (en) | 2014-04-02 |
| CN103695940B true CN103695940B (en) | 2016-06-29 |
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Families Citing this family (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN104131287A (en) * | 2014-07-01 | 2014-11-05 | 蚌埠天光传感器有限公司 | Antirust chemically mechanical polishing solution and preparation method thereof |
| RU2581347C1 (en) * | 2014-12-05 | 2016-04-20 | Федеральное государственное бюджетное образовательное учреждение высшего профессионального образования "Московский государственный машиностроительный университет (МАМИ)" | Method of removing scale-corrosion sediments from metal surfaces of carbon non-alloyed steels |
| CN106048588A (en) * | 2016-05-26 | 2016-10-26 | 安徽开林新材料股份有限公司 | Water-based antirust agent for surface of 09CuPTi steel and processing technique thereof |
| CN106637272A (en) * | 2017-01-04 | 2017-05-10 | 邯郸学院 | Silverware brightening emulsion and preparation method thereof |
Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| EP0972854A2 (en) * | 1998-07-15 | 2000-01-19 | Andritz-Patentverwaltungs-Gesellschaft m.b.H. | Process for pickling stainless steel |
| JP2004175839A (en) * | 2002-11-25 | 2004-06-24 | Toppan Printing Co Ltd | Etchant for metallic material and etching method |
| WO2009032460A1 (en) * | 2007-08-02 | 2009-03-12 | Advanced Technology Materials, Inc. | Non-fluoride containing composition for the removal of residue from a microelectronic device |
| CN103215594A (en) * | 2013-02-04 | 2013-07-24 | 安徽省繁昌县皖南阀门铸造有限公司 | Metal rust-preventive oil comprising coconut oil fatty acid diethanolamide |
-
2013
- 2013-11-29 CN CN201310617602.7A patent/CN103695940B/en active Active
Patent Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| EP0972854A2 (en) * | 1998-07-15 | 2000-01-19 | Andritz-Patentverwaltungs-Gesellschaft m.b.H. | Process for pickling stainless steel |
| JP2004175839A (en) * | 2002-11-25 | 2004-06-24 | Toppan Printing Co Ltd | Etchant for metallic material and etching method |
| WO2009032460A1 (en) * | 2007-08-02 | 2009-03-12 | Advanced Technology Materials, Inc. | Non-fluoride containing composition for the removal of residue from a microelectronic device |
| CN103215594A (en) * | 2013-02-04 | 2013-07-24 | 安徽省繁昌县皖南阀门铸造有限公司 | Metal rust-preventive oil comprising coconut oil fatty acid diethanolamide |
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| CN103695940A (en) | 2014-04-02 |
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Denomination of invention: Water-soluble antioxidant derusting antirust liquid and preparation method thereof Effective date of registration: 20171024 Granted publication date: 20160629 Pledgee: Anhui Mingguang rural commercial bank Limited by Share Ltd. East Ming sub branch Pledgor: MINGGUANG CITY LIUXIANG PUMP INDUSTRY Co.,Ltd. Registration number: 2017340000306 |
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Address after: 239400 No. 72, Liuwan Road, Mingguang Industrial Park, Chuzhou City, Anhui Province Patentee after: Anhui Liuxiang Special Ship Co.,Ltd. Country or region after: China Address before: 239400 No. 72, Liuwan Road, Mingguang Industrial Park, Chuzhou City, Anhui Province Patentee before: MINGGUANG CITY LIUXIANG PUMP INDUSTRY Co.,Ltd. Country or region before: China |