CN103695917B - A kind of Water-emulsion-type antirust liquid and preparation method thereof - Google Patents
A kind of Water-emulsion-type antirust liquid and preparation method thereof Download PDFInfo
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- CN103695917B CN103695917B CN201310617811.1A CN201310617811A CN103695917B CN 103695917 B CN103695917 B CN 103695917B CN 201310617811 A CN201310617811 A CN 201310617811A CN 103695917 B CN103695917 B CN 103695917B
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- water
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- 239000007788 liquid Substances 0.000 title claims abstract description 13
- 238000002360 preparation method Methods 0.000 title claims description 10
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 15
- PHTQWCKDNZKARW-UHFFFAOYSA-N isoamylol Chemical compound CC(C)CCO PHTQWCKDNZKARW-UHFFFAOYSA-N 0.000 claims abstract description 14
- JKNCOURZONDCGV-UHFFFAOYSA-N 2-(dimethylamino)ethyl 2-methylprop-2-enoate Chemical compound CN(C)CCOC(=O)C(C)=C JKNCOURZONDCGV-UHFFFAOYSA-N 0.000 claims abstract description 7
- 239000012752 auxiliary agent Substances 0.000 claims abstract description 7
- -1 hexanediyl ester Chemical class 0.000 claims abstract description 7
- JMMWKPVZQRWMSS-UHFFFAOYSA-N isopropanol acetate Natural products CC(C)OC(C)=O JMMWKPVZQRWMSS-UHFFFAOYSA-N 0.000 claims abstract description 7
- 229940011051 isopropyl acetate Drugs 0.000 claims abstract description 7
- GWYFCOCPABKNJV-UHFFFAOYSA-N isovaleric acid Chemical compound CC(C)CC(O)=O GWYFCOCPABKNJV-UHFFFAOYSA-N 0.000 claims abstract description 7
- 239000002994 raw material Substances 0.000 claims abstract description 7
- BTURAGWYSMTVOW-UHFFFAOYSA-M sodium dodecanoate Chemical compound [Na+].CCCCCCCCCCCC([O-])=O BTURAGWYSMTVOW-UHFFFAOYSA-M 0.000 claims abstract description 7
- 229940082004 sodium laurate Drugs 0.000 claims abstract description 7
- UEUXEKPTXMALOB-UHFFFAOYSA-J tetrasodium;2-[2-[bis(carboxylatomethyl)amino]ethyl-(carboxylatomethyl)amino]acetate Chemical compound [Na+].[Na+].[Na+].[Na+].[O-]C(=O)CN(CC([O-])=O)CCN(CC([O-])=O)CC([O-])=O UEUXEKPTXMALOB-UHFFFAOYSA-J 0.000 claims abstract description 7
- PAWQVTBBRAZDMG-UHFFFAOYSA-N 2-(3-bromo-2-fluorophenyl)acetic acid Chemical compound OC(=O)CC1=CC=CC(Br)=C1F PAWQVTBBRAZDMG-UHFFFAOYSA-N 0.000 claims abstract description 4
- FDLQZKYLHJJBHD-UHFFFAOYSA-N [3-(aminomethyl)phenyl]methanamine Chemical compound NCC1=CC=CC(CN)=C1 FDLQZKYLHJJBHD-UHFFFAOYSA-N 0.000 claims abstract description 4
- 239000005055 methyl trichlorosilane Substances 0.000 claims abstract description 4
- JLUFWMXJHAVVNN-UHFFFAOYSA-N methyltrichlorosilane Chemical compound C[Si](Cl)(Cl)Cl JLUFWMXJHAVVNN-UHFFFAOYSA-N 0.000 claims abstract description 4
- WXMKPNITSTVMEF-UHFFFAOYSA-M sodium benzoate Chemical compound [Na+].[O-]C(=O)C1=CC=CC=C1 WXMKPNITSTVMEF-UHFFFAOYSA-M 0.000 claims abstract description 4
- 235000010234 sodium benzoate Nutrition 0.000 claims abstract description 4
- 239000004299 sodium benzoate Substances 0.000 claims abstract description 4
- ROOXNKNUYICQNP-UHFFFAOYSA-N ammonium persulfate Chemical compound [NH4+].[NH4+].[O-]S(=O)(=O)OOS([O-])(=O)=O ROOXNKNUYICQNP-UHFFFAOYSA-N 0.000 claims description 12
- 238000003756 stirring Methods 0.000 claims description 12
- DNIAPMSPPWPWGF-UHFFFAOYSA-N Propylene glycol Chemical compound CC(O)CO DNIAPMSPPWPWGF-UHFFFAOYSA-N 0.000 claims description 9
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 claims description 6
- YNAVUWVOSKDBBP-UHFFFAOYSA-N Morpholine Chemical compound C1COCCN1 YNAVUWVOSKDBBP-UHFFFAOYSA-N 0.000 claims description 6
- 229910001870 ammonium persulfate Inorganic materials 0.000 claims description 6
- 239000012467 final product Substances 0.000 claims description 6
- GHMLBKRAJCXXBS-UHFFFAOYSA-N resorcinol Chemical compound OC1=CC=CC(O)=C1 GHMLBKRAJCXXBS-UHFFFAOYSA-N 0.000 claims description 6
- PFTAWBLQPZVEMU-DZGCQCFKSA-N (+)-catechin Chemical compound C1([C@H]2OC3=CC(O)=CC(O)=C3C[C@@H]2O)=CC=C(O)C(O)=C1 PFTAWBLQPZVEMU-DZGCQCFKSA-N 0.000 claims description 3
- 239000004115 Sodium Silicate Substances 0.000 claims description 3
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 claims description 3
- ADRVNXBAWSRFAJ-UHFFFAOYSA-N catechin Natural products OC1Cc2cc(O)cc(O)c2OC1c3ccc(O)c(O)c3 ADRVNXBAWSRFAJ-UHFFFAOYSA-N 0.000 claims description 3
- 235000005487 catechin Nutrition 0.000 claims description 3
- 238000006243 chemical reaction Methods 0.000 claims description 3
- 229950001002 cianidanol Drugs 0.000 claims description 3
- 238000010438 heat treatment Methods 0.000 claims description 3
- 239000000463 material Substances 0.000 claims description 3
- 238000002156 mixing Methods 0.000 claims description 3
- 239000000244 polyoxyethylene sorbitan monooleate Substances 0.000 claims description 3
- 235000010482 polyoxyethylene sorbitan monooleate Nutrition 0.000 claims description 3
- 229920000053 polysorbate 80 Polymers 0.000 claims description 3
- NTHWMYGWWRZVTN-UHFFFAOYSA-N sodium silicate Chemical compound [Na+].[Na+].[O-][Si]([O-])=O NTHWMYGWWRZVTN-UHFFFAOYSA-N 0.000 claims description 3
- 229910052911 sodium silicate Inorganic materials 0.000 claims description 3
- OGIDPMRJRNCKJF-UHFFFAOYSA-N titanium oxide Inorganic materials [Ti]=O OGIDPMRJRNCKJF-UHFFFAOYSA-N 0.000 claims description 3
- 239000010409 thin film Substances 0.000 abstract description 6
- 229910052751 metal Inorganic materials 0.000 abstract description 5
- 239000002184 metal Substances 0.000 abstract description 5
- 238000005260 corrosion Methods 0.000 abstract description 3
- 230000007797 corrosion Effects 0.000 abstract description 3
- 239000011347 resin Substances 0.000 abstract description 3
- 229920005989 resin Polymers 0.000 abstract description 3
- 230000003064 anti-oxidating effect Effects 0.000 abstract description 2
- 230000003078 antioxidant effect Effects 0.000 abstract description 2
- 239000013556 antirust agent Substances 0.000 abstract description 2
- 230000000694 effects Effects 0.000 abstract description 2
- 238000002955 isolation Methods 0.000 abstract description 2
- 229920002521 macromolecule Polymers 0.000 abstract description 2
- 230000000116 mitigating effect Effects 0.000 abstract description 2
- 239000003973 paint Substances 0.000 abstract description 2
- JEIPFZHSYJVQDO-UHFFFAOYSA-N iron(III) oxide Inorganic materials O=[Fe]O[Fe]=O JEIPFZHSYJVQDO-UHFFFAOYSA-N 0.000 description 8
- 239000003921 oil Substances 0.000 description 4
- 230000002265 prevention Effects 0.000 description 4
- 230000003449 preventive effect Effects 0.000 description 3
- 238000012360 testing method Methods 0.000 description 3
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 description 2
- 230000007613 environmental effect Effects 0.000 description 2
- 239000010408 film Substances 0.000 description 2
- 230000007774 longterm Effects 0.000 description 2
- LPXPTNMVRIOKMN-UHFFFAOYSA-M sodium nitrite Chemical compound [Na+].[O-]N=O LPXPTNMVRIOKMN-UHFFFAOYSA-M 0.000 description 2
- 229910000831 Steel Inorganic materials 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 230000015556 catabolic process Effects 0.000 description 1
- 238000006731 degradation reaction Methods 0.000 description 1
- 238000002845 discoloration Methods 0.000 description 1
- 238000004090 dissolution Methods 0.000 description 1
- 239000000428 dust Substances 0.000 description 1
- 239000002360 explosive Substances 0.000 description 1
- 238000007654 immersion Methods 0.000 description 1
- 229910052742 iron Inorganic materials 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 239000011159 matrix material Substances 0.000 description 1
- 239000002480 mineral oil Substances 0.000 description 1
- 235000010446 mineral oil Nutrition 0.000 description 1
- 239000003960 organic solvent Substances 0.000 description 1
- 230000003647 oxidation Effects 0.000 description 1
- 238000007254 oxidation reaction Methods 0.000 description 1
- 239000000047 product Substances 0.000 description 1
- 238000011160 research Methods 0.000 description 1
- 150000003839 salts Chemical class 0.000 description 1
- 235000010288 sodium nitrite Nutrition 0.000 description 1
- 239000010959 steel Substances 0.000 description 1
- 239000000080 wetting agent Substances 0.000 description 1
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- Paints Or Removers (AREA)
Abstract
The invention discloses a kind of Water-emulsion-type antirust liquid, it is made up of the raw material of following weight portion: ammonium nitrate 1-2, sodium benzoate 1-2, m-xylene diamine 1-2,3-methyl-1-butanol 4-5, methyl trichlorosilane 3-5, isopropyl acetate 20-22, sodium laurate 1-2, dimethylaminoethyl methacrylate 10-12,1,6 hexanediyl ester 10-12, EDETATE SODIUM 1-2, auxiliary agent 4-5, water 300.Present invention uses macromolecule resin and chelating agen, can form thin film in metal surface, play isolation air, anti-oxidation effect, and antirust agent difficult drop-off, thin film itself has antioxidative effect, improves corrosion mitigating effect, and thin film easily removes；The present invention is little to metal surface tension, it is easy to application, has the feature of osmosis type, transformant and three kinds of antirusting paints of stable type simultaneously, produces extremely simple.
Description
Technical field
The present invention relates to technical field of rust prevention, particularly relate to a kind of Water-emulsion-type antirust liquid and preparation method thereof.
Background technology
Metal surface is antirust is the important topic in commercial production, and traditional antirust solution, antirust oil have advantage also to have shortcoming.Containing substantial amounts of sodium nitrite in common aqueous rust preventive, there is carcinogenecity, be unfavorable for that environmental protection and the person are healthy, and adopt wetting agent to extend the life-span of aqueous rust preventive, bring again the disadvantage touched with one's hand, be covered with dust, and can not long-term rust prevention；Although general hard film rust preventive oil is suitable for long-term rust prevention, film forming is also transparent attractive in appearance, but water white resin types is less, and instability is easy oxidation discoloration also, in addition it is also necessary to organic solvent dissolution, brings inflammable and explosive danger to be also unfavorable for environmental protection and health；General antirust oil uses mineral oil, difficult degradation, and also brings along the problem that oil removing is difficult during for short-term rust prevention.Therefore, comprehensive study performance is more excellent, and the antirust product being more suitable for for different occasion researchs is new direction and trend.
Summary of the invention
It is an object of the invention to provide a kind of Water-emulsion-type antirust liquid and preparation method thereof, this antirust solution has antirust time length, feature easy and simple to handle.
Technical scheme is as follows:
A kind of Water-emulsion-type antirust liquid, it is characterized in that being made up of the raw material of following weight portion: ammonium nitrate 1-2, sodium benzoate 1-2, m-xylene diamine 1-2,3-methyl-1-butanol 4-5, methyl trichlorosilane 3-5, isopropyl acetate 20-22, sodium laurate 1-2, dimethylaminoethyl methacrylate 10-12,1,6 hexanediyl ester 10-12, EDETATE SODIUM 1-2, auxiliary agent 4-5, water 300.Described auxiliary agent is made up of the raw material of following weight portion: polyoxyethylene sorbitan monooleate 2-3, nano titanium oxide 0.1-0.2, catechin 1-2, ethanol 10-12, sodium silicate 3-4, resorcinol 1-2, propylene glycol 3-4, morpholine 1-2, Resina persicae 2-3, Ammonium persulfate. 1-2, water 20-24；Preparation method is after dissolving ammonium persulfate into water, adds other leftover materials, stirs 10-15 minute, heats to 70-80 DEG C, stirring reaction 1-2 hour, to obtain final product.
The preparation method of described Water-emulsion-type antirust liquid, it is characterised in that comprise the following steps: by water, sodium laurate mixing, heating is to 40-50 DEG C；Add 3-methyl-1-butanol, isopropyl acetate, dimethylaminoethyl methacrylate, 1,6 hexanediyl ester, EDETATE SODIUM, continue to be heated to 85-90 DEG C, stir 10-15 minute；Add other residual componentss, continue stirring 15-20 minute, to obtain final product.
Beneficial effects of the present invention
Present invention uses macromolecule resin and chelating agen, can form thin film in metal surface, play isolation air, anti-oxidation effect, and antirust agent difficult drop-off, thin film itself has antioxidative effect, improves corrosion mitigating effect, and thin film easily removes；The present invention is little to metal surface tension, it is easy to application, has the feature of osmosis type, transformant and three kinds of antirusting paints of stable type simultaneously, produces extremely simple.
Detailed description of the inventionClearly
A kind of Water-emulsion-type antirust liquid, it is made up of the raw material of following weight portion (kilogram): ammonium nitrate 1.5, sodium benzoate 1.5, m-xylene diamine 1.5,3-methyl-1-butanol 4.5, methyl trichlorosilane 4, isopropyl acetate 21, sodium laurate 1.5, dimethylaminoethyl methacrylate 11,1,6 hexanediyl ester 11, EDETATE SODIUM 1.5, auxiliary agent 4.5, water 300.Described auxiliary agent is made up of the raw material of following weight portion (kilogram): polyoxyethylene sorbitan monooleate 2, nano titanium oxide 0.1, catechin 1, ethanol 10, sodium silicate 3, resorcinol 1, propylene glycol 3, morpholine 2, Resina persicae 2, Ammonium persulfate. 1, water 20；Preparation method is after dissolving ammonium persulfate into water, adds other leftover materials, stirs 10-15 minute, heats to 70-80 DEG C, stirring reaction 1-2 hour, to obtain final product.
The preparation method of described Water-emulsion-type antirust liquid, comprises the following steps: by water, sodium laurate mixing, heating is to 45 DEG C；Add 3-methyl-1-butanol, isopropyl acetate, dimethylaminoethyl methacrylate, 1,6 hexanediyl ester, EDETATE SODIUM, continue to be heated to 88 DEG C, stir 14 minutes；Add other residual componentss, continue stirring 18 minutes, to obtain final product.
The Water-emulsion-type antirust liquid that this embodiment obtains detects by national standard, and damp heat test * (1) is qualified；Salt water immersion test * (1): qualified；Corrosion testing * (2): qualified；Rust removability (secondary) < 6.Prepared Water-emulsion-type antirust liquid is brushed that be newly processed into and do not have the steel matrix surface of greasy dirt, within 20 days disposed within, to have no obvious iron mold.
Claims (2)
1. a Water-emulsion-type antirust liquid, it is characterized in that being made up of the raw material of following weight portion: ammonium nitrate 1-2, sodium benzoate 1-2, m-xylene diamine 1-2,3-methyl-1-butanol 4-5, methyl trichlorosilane 3-5, isopropyl acetate 20-22, sodium laurate 1-2, dimethylaminoethyl methacrylate 10-12,1,6 hexanediyl ester 10-12, EDETATE SODIUM 1-2, auxiliary agent 4-5, water 300；Described auxiliary agent is made up of the raw material of following weight portion: polyoxyethylene sorbitan monooleate 2-3, nano titanium oxide 0.1-0.2, catechin 1-2, ethanol 10-12, sodium silicate 3-4, resorcinol 1-2, propylene glycol 3-4, morpholine 1-2, Resina persicae 2-3, Ammonium persulfate. 1-2, water 20-24；Preparation method is after dissolving ammonium persulfate into water, adds other leftover materials, stirs 10-15 minute, heats to 70-80 DEG C, stirring reaction 1-2 hour, to obtain final product.
2. the preparation method of Water-emulsion-type antirust liquid according to claim 1, it is characterised in that comprise the following steps: by water, sodium laurate mixing, heating is to 40-50 DEG C；Add 3-methyl-1-butanol, isopropyl acetate, dimethylaminoethyl methacrylate, 1,6 hexanediyl ester, EDETATE SODIUM, continue to be heated to 85-90 DEG C, stir 10-15 minute；Add other residual componentss, continue stirring 15-20 minute, to obtain final product.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201310617811.1A CN103695917B (en) | 2013-11-29 | 2013-11-29 | A kind of Water-emulsion-type antirust liquid and preparation method thereof |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201310617811.1A CN103695917B (en) | 2013-11-29 | 2013-11-29 | A kind of Water-emulsion-type antirust liquid and preparation method thereof |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN103695917A CN103695917A (en) | 2014-04-02 |
| CN103695917B true CN103695917B (en) | 2016-06-29 |
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| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201310617811.1A Active CN103695917B (en) | 2013-11-29 | 2013-11-29 | A kind of Water-emulsion-type antirust liquid and preparation method thereof |
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Families Citing this family (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN107573989A (en) * | 2017-08-12 | 2018-01-12 | 安徽英科成流体科技有限公司 | A kind of valve derusting lubricant |
Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO2005047402A1 (en) * | 2003-11-10 | 2005-05-26 | Trigenex Technologies, Inc. | Method of corrosion prevention and anticorrosion material |
| CN101608310A (en) * | 2008-06-16 | 2009-12-23 | 南京科润工业介质有限公司 | Long-acting emulsion-type antirust fluid |
| CN101660161A (en) * | 2008-08-28 | 2010-03-03 | 北京玉佳明三态离子科学研究院有限公司 | Formulation and manufacturing method for high-performance metal-cutting-cooling antirust fluid |
| CN102676277A (en) * | 2011-09-06 | 2012-09-19 | 安徽江南机械有限责任公司 | Water soluble antirusting fluid, and preparation method and using method thereof |
-
2013
- 2013-11-29 CN CN201310617811.1A patent/CN103695917B/en active Active
Patent Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO2005047402A1 (en) * | 2003-11-10 | 2005-05-26 | Trigenex Technologies, Inc. | Method of corrosion prevention and anticorrosion material |
| CN101608310A (en) * | 2008-06-16 | 2009-12-23 | 南京科润工业介质有限公司 | Long-acting emulsion-type antirust fluid |
| CN101660161A (en) * | 2008-08-28 | 2010-03-03 | 北京玉佳明三态离子科学研究院有限公司 | Formulation and manufacturing method for high-performance metal-cutting-cooling antirust fluid |
| CN102676277A (en) * | 2011-09-06 | 2012-09-19 | 安徽江南机械有限责任公司 | Water soluble antirusting fluid, and preparation method and using method thereof |
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| CN103695917A (en) | 2014-04-02 |
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Effective date of registration: 20240522 Address after: No. 98 Qicang Road, Mingguang City, Chuzhou City, Anhui Province, 239000 Patentee after: Mingguang Jiuzhi Intellectual Property Management Co.,Ltd. Country or region after: China Address before: 239400 No. 72, Liuwan Road, Mingguang Industrial Park, Chuzhou City, Anhui Province Patentee before: MINGGUANG CITY LIUXIANG PUMP INDUSTRY Co.,Ltd. Country or region before: China |