CN103695922A - Low-temperature rust cleaning water-soluble antirust liquor and preparation method thereof - Google Patents
Low-temperature rust cleaning water-soluble antirust liquor and preparation method thereof Download PDFInfo
- Publication number
- CN103695922A CN103695922A CN201310630146.XA CN201310630146A CN103695922A CN 103695922 A CN103695922 A CN 103695922A CN 201310630146 A CN201310630146 A CN 201310630146A CN 103695922 A CN103695922 A CN 103695922A
- Authority
- CN
- China
- Prior art keywords
- parts
- water
- rust cleaning
- cleaning water
- add
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
Landscapes
- Detergent Compositions (AREA)
- Cleaning And De-Greasing Of Metallic Materials By Chemical Methods (AREA)
Abstract
The invention provides a low-temperature rust cleaning water-soluble antirust liquor, which is prepared from the following raw materials in parts by weight: 2-3 parts of polyoxyethylene stearate, 1-2 parts of citric acid, 3-4 parts of zinc dihydrogen phosphate, 2-3 parts of sodium citrate, 1-2 parts of sodium dodecyl benzene sulfonate, 0.5-1.5 parts of urotropin, 1.1-1.7 parts of di-n-octyl-4-isothiazolinone, 10-12 parts of tripropylene glycol diacrylate, 1-2 parts of disodium EDTA (Ethylene Diamine Tetraacetic Acid), 4-5 parts of auxiliaries and 300 parts of water. According to the invention, organic high-molecular polymers and a chelating agent are utilized to quickly form a thin film on the surface of a metal, and as a result, the effects of isolating air and preventing oxidization are achieved; the thin film is easy to clear and can be removed only through water washing; besides, the low-temperature rust cleaning water-soluble antirust liquor can be produced in an ultra-low temperature environment ranging from -15 to -40 DEG C; consequently, the energy source is saved and the environment is protected.
Description
Technical field
The present invention relates to antirust technology field, relate in particular to a kind of low temperature rust cleaning water-soluble anti-rust liquid and preparation method thereof.
Background technology
Metallic surface is antirust is the important topic in industrial production, and traditional rust protection liquid, slushing oil have advantage also to have shortcoming.In common aqueous rust preventive, containing a large amount of Sodium Nitrites, there is carinogenicity, be unfavorable for that environmental protection and the person are healthy, and adopt wetting Agent for Printing Inks to extend the life-span of aqueous rust preventive, bring again the disadvantage of touching with one's hand, being covered with dust, and can not be antirust for a long time; Although it is antirust for a long time that general hard film rust preventive oil is applicable to, film forming is also transparent attractive in appearance, and water white resin kind is less, and unstable also easy oxidation discoloration, also needs organic solvent dissolution, brings inflammable and explosive danger to be also unfavorable for environmental protection and health; General slushing oil is used mineral oil, difficult degradation, and also can bring the problem of oil removing difficulty when antirust for short-term.Therefore, comprehensive study performance is more excellent, and the antirust product being more applicable to for different occasion research is new direction and trend.
Summary of the invention
The object of the present invention is to provide a kind of low temperature rust cleaning water-soluble anti-rust liquid and preparation method thereof, this rust protection liquid has long, low temperature of antirust time can be by the feature of, easy cleaning.
Technical scheme of the present invention is as follows:
A low temperature rust cleaning water-soluble anti-rust liquid, is characterized in that being made by the raw material of following weight part: polyoxyethylene stearic acid ester 2-3, citric acid 1-2, primary zinc phosphate 3-4, Trisodium Citrate 2-3, Sodium dodecylbenzene sulfonate 1-2, urotropine 0.5-1.5, di-n-octyl-4-isothiazolinone 1.1-1.7, tri (propylene glycol) diacrylate 10-12, EDETATE SODIUM 1-2, auxiliary agent 4-5, water 300.Described auxiliary agent is made by the raw material of following weight part: polyoxyethylene sorbitan monooleate 2-3, nano titanium oxide 0.1-0.2, tripoly phosphate sodium STPP 1-2, water glass 1-2, urotropine 1-2, Resorcinol 1-2, borax 3-4, urea 2-3, ammonium persulphate 1-2, peach gum 2-3, water 20-24; Preparation method be ammonium persulphate is water-soluble after, then add other leftover materials, stir 10-15 minute, be heated to 70-80 ℃, stirring reaction 1-2 hour, obtains.
The preparation method of described low temperature rust cleaning water-soluble anti-rust liquid, is characterized in that comprising the following steps: heat water to 40-50 ℃, add polyoxyethylene stearic acid ester, Sodium dodecylbenzene sulfonate; Continue to be heated to 85-90 ℃, add tri (propylene glycol) diacrylate, EDETATE SODIUM, Trisodium Citrate, stir 10-15 minute; Add other remaining components, continue to stir 10-15 minute, obtain.
Beneficial effect of the present invention
The present invention uses organic high molecular polymer and sequestrant, can be in metallic surface quick film, play isolated air, anti-oxidation effect, film easy-clear, washing is fallen; The present invention can produce under-15 degree-40 degree ultra-low temperature surroundings, save energy, and environmental protection.
Embodiment
A low temperature rust cleaning low temperature rust cleaning water-soluble anti-rust liquid, by following weight part (kilogram) raw material make: polyoxyethylene stearic acid ester 2.5, citric acid 1.5, primary zinc phosphate 3.5, Trisodium Citrate 2.5, Sodium dodecylbenzene sulfonate 1.5, urotropine 1.1, di-n-octyl-4-isothiazolinone 1.4, tri (propylene glycol) diacrylate 11, EDETATE SODIUM 1.5, auxiliary agent 4.5, water 300.Described auxiliary agent by following weight part (kilogram) raw material make: polyoxyethylene sorbitan monooleate 3, nano titanium oxide 0.1, tripoly phosphate sodium STPP 1, water glass 2, urotropine 2, Resorcinol 1, borax 3, urea 3, ammonium persulphate 1, peach gum 2, water 20; Preparation method be ammonium persulphate is water-soluble after, then add other leftover materials, stir 10-15 minute, be heated to 70-80 ℃, stirring reaction 1-2 hour, obtains.
The preparation method of described low temperature rust cleaning water-soluble anti-rust liquid, comprises the following steps: heat water to 45 ℃, add polyoxyethylene stearic acid ester, Sodium dodecylbenzene sulfonate; Continue to be heated to 88 ℃, add tri (propylene glycol) diacrylate, EDETATE SODIUM, Trisodium Citrate, stir 13 minutes; Add other remaining components, continue to stir 14 minutes, obtain.
The low temperature rust cleaning water-soluble anti-rust liquid that this embodiment obtains detects by national standard, and humid heat test * (1) is qualified; Salt water immersion test * (1): qualified; Corrosion test * (2): qualified; Rust removability (inferior) < 6.Prepared low temperature rust cleaning water-soluble anti-rust liquid is brushed on the steel matrix surface of being newly processed into and there is no greasy dirt, be placed in and within indoor 20 days, have no obvious iron mold.
Claims (2)
1. a low temperature rust cleaning water-soluble anti-rust liquid, is characterized in that being made by the raw material of following weight part: polyoxyethylene stearic acid ester 2-3, citric acid 1-2, primary zinc phosphate 3-4, Trisodium Citrate 2-3, Sodium dodecylbenzene sulfonate 1-2, urotropine 0.5-1.5, di-n-octyl-4-isothiazolinone 1.1-1.7, tri (propylene glycol) diacrylate 10-12, EDETATE SODIUM 1-2, auxiliary agent 4-5, water 300; Described auxiliary agent is made by the raw material of following weight part: polyoxyethylene sorbitan monooleate 2-3, nano titanium oxide 0.1-0.2, tripoly phosphate sodium STPP 1-2, water glass 1-2, urotropine 1-2, Resorcinol 1-2, borax 3-4, urea 2-3, ammonium persulphate 1-2, peach gum 2-3, water 20-24; Preparation method be ammonium persulphate is water-soluble after, then add other leftover materials, stir 10-15 minute, be heated to 70-80 ℃, stirring reaction 1-2 hour, obtains.
2. the preparation method of low temperature rust cleaning water-soluble anti-rust liquid according to claim 1, is characterized in that comprising the following steps: heat water to 40-50 ℃, add polyoxyethylene stearic acid ester, Sodium dodecylbenzene sulfonate; Continue to be heated to 85-90 ℃, add tri (propylene glycol) diacrylate, EDETATE SODIUM, Trisodium Citrate, stir 10-15 minute; Add other remaining components, continue to stir 10-15 minute, obtain.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201310630146.XA CN103695922A (en) | 2013-11-29 | 2013-11-29 | Low-temperature rust cleaning water-soluble antirust liquor and preparation method thereof |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201310630146.XA CN103695922A (en) | 2013-11-29 | 2013-11-29 | Low-temperature rust cleaning water-soluble antirust liquor and preparation method thereof |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN103695922A true CN103695922A (en) | 2014-04-02 |
Family
ID=50357580
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201310630146.XA Pending CN103695922A (en) | 2013-11-29 | 2013-11-29 | Low-temperature rust cleaning water-soluble antirust liquor and preparation method thereof |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN103695922A (en) |
Cited By (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN103882449A (en) * | 2014-02-25 | 2014-06-25 | 安徽拓普森电池有限责任公司 | Low-temperature rust removal water-soluble antirust fluid and preparation method thereof |
| CN105039993A (en) * | 2015-07-21 | 2015-11-11 | 安徽江威精密制造有限公司 | Copper piece antirust agent and preparation method and application thereof |
| CN105907308A (en) * | 2016-06-23 | 2016-08-31 | 苏州洪河金属制品有限公司 | Long-acting water-based metal rust preventing agent |
| CN106521521A (en) * | 2016-12-29 | 2017-03-22 | 柳州市凯夕贸易有限公司 | Dust remover for copper product and preparation method therefor |
| CN112301350A (en) * | 2019-07-25 | 2021-02-02 | 杭州悦山科技有限公司 | Environment-friendly universal rust remover |
Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1386907A (en) * | 2001-05-18 | 2002-12-25 | 天津市宇泰化工高科技有限公司 | Liquid for removing oil and rust from metal and its preparing process |
| JP2003105572A (en) * | 2001-09-28 | 2003-04-09 | Masanao Uchiyama | Rust preventive or rust removing agent or cleaning water using electrolytic cathodic water |
| CN101220479A (en) * | 2007-12-05 | 2008-07-16 | 南宝树脂（中国）有限公司 | Rust-proof rust-cleaning film forming material and preparation thereof |
| CN101660149A (en) * | 2008-08-28 | 2010-03-03 | 北京玉佳明三态离子科学研究院有限公司 | Steel ultra-low temperature multifunctional derusting phosphatization antirust solution |
-
2013
- 2013-11-29 CN CN201310630146.XA patent/CN103695922A/en active Pending
Patent Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1386907A (en) * | 2001-05-18 | 2002-12-25 | 天津市宇泰化工高科技有限公司 | Liquid for removing oil and rust from metal and its preparing process |
| JP2003105572A (en) * | 2001-09-28 | 2003-04-09 | Masanao Uchiyama | Rust preventive or rust removing agent or cleaning water using electrolytic cathodic water |
| CN101220479A (en) * | 2007-12-05 | 2008-07-16 | 南宝树脂（中国）有限公司 | Rust-proof rust-cleaning film forming material and preparation thereof |
| CN101660149A (en) * | 2008-08-28 | 2010-03-03 | 北京玉佳明三态离子科学研究院有限公司 | Steel ultra-low temperature multifunctional derusting phosphatization antirust solution |
Cited By (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN103882449A (en) * | 2014-02-25 | 2014-06-25 | 安徽拓普森电池有限责任公司 | Low-temperature rust removal water-soluble antirust fluid and preparation method thereof |
| CN105039993A (en) * | 2015-07-21 | 2015-11-11 | 安徽江威精密制造有限公司 | Copper piece antirust agent and preparation method and application thereof |
| CN105907308A (en) * | 2016-06-23 | 2016-08-31 | 苏州洪河金属制品有限公司 | Long-acting water-based metal rust preventing agent |
| CN106521521A (en) * | 2016-12-29 | 2017-03-22 | 柳州市凯夕贸易有限公司 | Dust remover for copper product and preparation method therefor |
| CN112301350A (en) * | 2019-07-25 | 2021-02-02 | 杭州悦山科技有限公司 | Environment-friendly universal rust remover |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN103882451B (en) | A kind of water base normal temperature rust-removing and antirusting agent and preparation method thereof | |
| CN103695922A (en) | Low-temperature rust cleaning water-soluble antirust liquor and preparation method thereof | |
| CN103882439B (en) | A kind of water-soluble metal degreasing derusting rust-proofing liquid and preparation method thereof | |
| CN103882450B (en) | A kind of water base rust-removing and antirusting agent and preparation method thereof | |
| CN103695920A (en) | Water-based metal rustproof liquid and preparation method thereof | |
| CN103695140A (en) | Water-soluble cutting antirust liquid and preparation method thereof | |
| CN103695948A (en) | Cast iron derusting antirust liquid and preparation method thereof | |
| CN103695940A (en) | Water-soluble antioxidant derusting antirust liquid and preparation method thereof | |
| CN103695919B (en) | A kind of metal parts antirust liquid for inner chamber and preparation method thereof | |
| CN103882434A (en) | Pollution-free inter-process antirust liquid and preparation method thereof | |
| CN103695915B (en) | A kind of emulsion-type antirust solution and preparation method thereof | |
| CN103695934A (en) | Emulsion-type derusting antirust liquid and preparation method thereof | |
| CN103710118B (en) | A kind of water base cutting cooling antirust liquid and preparation method thereof | |
| CN103614714A (en) | Rust removing and preventing liquid for steel and preparation method thereof | |
| CN103710709A (en) | Water-based emulsion-type antirust liquid and preparation method thereof | |
| CN103695925A (en) | Water-soluble conversion-type antirust liquid and preparation method thereof | |
| CN103695913A (en) | Water-soluble ferrous metal antirust liquid and preparation method thereof | |
| CN103695931A (en) | Water-soluble metal short-term antirust liquid and preparation method thereof | |
| CN103882445B (en) | One can coating derusting rust-proofing liquid and preparation method thereof | |
| CN103709811B (en) | A kind of inter-process water-based anti-rusting liquid and preparation method thereof | |
| CN103695141B (en) | A kind of environment protection metal cutting cooling antirust liquid and preparation method thereof | |
| CN103695921B (en) | A kind of derusting rust-proofing liquid containing alkyd resins and preparation method thereof | |
| CN103695936A (en) | Water-based inter-process environment-friendly antirust liquid and preparation method thereof | |
| CN103882449A (en) | Low-temperature rust removal water-soluble antirust fluid and preparation method thereof | |
| CN103695932A (en) | Water-soluble metal anticorrosion antirust liquid and preparation method thereof |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| C06 | Publication | ||
| PB01 | Publication | ||
| C10 | Entry into substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| RJ01 | Rejection of invention patent application after publication | ||
| RJ01 | Rejection of invention patent application after publication |
Application publication date: 20140402 |