CN103709811B - A kind of inter-process water-based anti-rusting liquid and preparation method thereof - Google Patents
A kind of inter-process water-based anti-rusting liquid and preparation method thereof Download PDFInfo
- Publication number
- CN103709811B CN103709811B CN201310614645.XA CN201310614645A CN103709811B CN 103709811 B CN103709811 B CN 103709811B CN 201310614645 A CN201310614645 A CN 201310614645A CN 103709811 B CN103709811 B CN 103709811B
- Authority
- CN
- China
- Prior art keywords
- water
- propylene glycol
- inter
- based anti
- process water
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Active
Links
Landscapes
- Preventing Corrosion Or Incrustation Of Metals (AREA)
Abstract
A kind of inter-process water-based anti-rusting liquid, is prepared by the raw materials in: glycerol 10 12, BTA 23, sodium silicate 23, hexamethylenetetramine 12, styrylphenol polyoxyethylene ether 12, Polyethylene Glycol 12, propylene glycol 23, tri (propylene glycol) diacrylate 10 12, phenyl glycidyl ether 12, EDETATE SODIUM 12, deionization auxiliary agent 45, water 300.The present invention uses high molecular polymer monomer, chelating agen jointly to act on, and can form thin film in metal surface, play isolation air, anti-oxidation effect；The present invention has antirust, the corrosion inhibition of excellence, and rust-proof life is long, reaches as high as 12 months；Simple to operate, easily remove, wash, subsequent handling will not be had a negative impact；It is applicable to various metal material course of processing rust prevention during manufacture；Safety is good, without carcinogen such as sodium nitrite, nontoxic.
Description
Technical field
The present invention relates to technical field of rust prevention, particularly relate to a kind of inter-process water-based anti-rusting liquid and preparation method thereof.
Background technology
Metal surface is antirust is the important topic in commercial production, and traditional antirust solution, antirust oil have advantage also to have shortcoming.Containing substantial amounts of sodium nitrite in common aqueous rust preventive, there is carcinogenecity, be unfavorable for that environmental protection and the person are healthy, and use wetting agent to extend the life-span of aqueous rust preventive, bring again the disadvantage touched with one's hand, be covered with dust, and can not long-term rust prevention；Although general hard film rust preventive oil is suitable for long-term rust prevention, film forming is the most transparent attractive in appearance, but water white resin types is less, instability also easy oxidation discoloration, in addition it is also necessary to organic solvent dissolves, and brings inflammable and explosive danger to be also unfavorable for environmental protection and health；General antirust oil uses mineral oil, difficult degradation, and also brings along the problem that oil removing is difficult when short-term rust prevention.Therefore, comprehensive study performance is more excellent, and the antirust product being more suitable for for different occasion researchs is new direction and trend.
Summary of the invention
It is an object of the invention to provide a kind of inter-process water-based anti-rusting liquid and preparation method thereof, this antirust solution has rust-proof life length, easy and simple to handle, the feature of easy cleaning.
Technical scheme is as follows:
A kind of inter-process water-based anti-rusting liquid, it is characterised in that be prepared by the raw materials in: glycerol 10-12, BTA 2-3, sodium silicate 2-3, hexamethylenetetramine 1-2, styrylphenol polyoxyethylene ether 1-2, Polyethylene Glycol 1-2, propylene glycol 2-3, tri (propylene glycol) diacrylate 10-12, phenyl glycidyl ether 1-2, EDETATE SODIUM 1-2, deionization auxiliary agent 4-5, water 300.Described auxiliary agent is prepared by the raw materials in: alkylphenol polyoxyethylene 4-5, nano titanium oxide 0.1-0.2, catechol 1-2, morpholine 2-3, arabic gum 2-3, sodium silicate 1-2, carbamide 3-4, Ammonium persulfate. 1-2, water 20-24；Preparation method be dissolve ammonium persulfate into water after, add other leftover materials, stir 10-15 minute, be heated to 70-80 DEG C, stirring reaction 1-2 hour, to obtain final product.
The preparation method of described inter-process water-based anti-rusting liquid, it is characterised in that comprise the following steps: heat water to 40-50 DEG C, adds styrylphenol polyoxyethylene ether, phenyl glycidyl ether；Continue to be heated to 85-90 DEG C, add glycerol, Polyethylene Glycol, propylene glycol, tri (propylene glycol) diacrylate, phenyl glycidyl ether, stir 10-15 minute；Add other residual componentss, continue stirring 17-24 minute, to obtain final product.
Beneficial effects of the present invention
The present invention uses high molecular polymer monomer, chelating agen jointly to act on, and can form thin film in metal surface, play isolation air, anti-oxidation effect；The present invention has antirust, the corrosion inhibition of excellence, and rust-proof life is long, reaches as high as 12 months；Simple to operate, easily remove, wash, subsequent handling will not be had a negative impact；It is applicable to various metal material course of processing rust prevention during manufacture；Safety is good, without carcinogen such as sodium nitrite, nontoxic.
Detailed description of the invention
A kind of inter-process water-based anti-rusting liquid, is made up of the raw material of following weight portion (kilogram): glycerol 11, BTA 2.5, sodium silicate 2.5, hexamethylenetetramine 1.5, styrylphenol polyoxyethylene ether 1.5, Polyethylene Glycol 1.5, propylene glycol 2.5, tri (propylene glycol) diacrylate 11, phenyl glycidyl ether 1.5, EDETATE SODIUM 1.5, deionization auxiliary agent 4.5, water 300.Described auxiliary agent is made up of the raw material of following weight portion (kilogram): alkylphenol polyoxyethylene 5, nano titanium oxide 0.1, catechol 1, morpholine 2, arabic gum 2, sodium silicate 1, carbamide 3, Ammonium persulfate. 1, water 20；Preparation method be dissolve ammonium persulfate into water after, add other leftover materials, stir 10-15 minute, be heated to 70-80 DEG C, stirring reaction 1-2 hour, to obtain final product.
The preparation method of described inter-process water-based anti-rusting liquid, comprises the following steps: heat water to 45 DEG C, adds styrylphenol polyoxyethylene ether, phenyl glycidyl ether；Continue to be heated to 87 DEG C, add glycerol, Polyethylene Glycol, propylene glycol, tri (propylene glycol) diacrylate, phenyl glycidyl ether, stir 13 minutes；Add other residual componentss, continue stirring 22 minutes, to obtain final product.
The inter-process water-based anti-rusting liquid that this embodiment obtains is detected by national standard, and damp heat test * (1) is qualified；Salt water immersion test * (1): qualified；Corrosion testing * (2): qualified；Rust removability (secondary) ＜ 6.Prepared inter-process water-based anti-rusting liquid is brushed that be newly processed into and do not have the steel matrix surface of greasy dirt, within 20 days disposed within, to have no obvious iron mold.
Claims (1)
1. an inter-process water-based anti-rusting liquid, it is characterised in that be prepared by the raw materials in: glycerol 10-12, BTA 2-3, sodium silicate 2-3, hexamethylenetetramine 1-2, styrylphenol polyoxyethylene ether 1-2, Polyethylene Glycol 1-2, propylene glycol 2-3, tri (propylene glycol) diacrylate 10-12, phenyl glycidyl ether 1-2, EDETATE SODIUM 1-2, deionization auxiliary agent 4-5, water 300；Described auxiliary agent is prepared by the raw materials in: alkylphenol polyoxyethylene 4-5, nano titanium oxide 0.1-0.2, catechol 1-2, morpholine 2-3, arabic gum 2-3, sodium silicate 1-2, carbamide 3-4, Ammonium persulfate. 1-2, water 20-24；Preparation method be dissolve ammonium persulfate into water after, add other leftover materials, stir 10-15 minute, be heated to 70-80 DEG C, stirring reaction 1-2 hour, to obtain final product；
The preparation method of described inter-process water-based anti-rusting liquid comprises the following steps: heat water to 40-50 DEG C, adds styrylphenol polyoxyethylene ether, phenyl glycidyl ether；Continue to be heated to 85-90 DEG C, add glycerol, Polyethylene Glycol, propylene glycol, tri (propylene glycol) diacrylate, phenyl glycidyl ether, stir 10-15 minute；Add other residual componentss, continue stirring 17-24 minute, to obtain final product.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201310614645.XA CN103709811B (en) | 2013-11-28 | 2013-11-28 | A kind of inter-process water-based anti-rusting liquid and preparation method thereof |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201310614645.XA CN103709811B (en) | 2013-11-28 | 2013-11-28 | A kind of inter-process water-based anti-rusting liquid and preparation method thereof |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN103709811A CN103709811A (en) | 2014-04-09 |
| CN103709811B true CN103709811B (en) | 2016-08-17 |
Family
ID=50403183
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201310614645.XA Active CN103709811B (en) | 2013-11-28 | 2013-11-28 | A kind of inter-process water-based anti-rusting liquid and preparation method thereof |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN103709811B (en) |
Families Citing this family (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN109097784A (en) * | 2017-06-21 | 2018-12-28 | 伊犁优创锅炉制造有限公司 | A kind of steel derusting antirust solution and preparation method thereof |
| CN108817376A (en) * | 2018-06-02 | 2018-11-16 | 南通盛州电子科技有限公司 | A kind of electrically conductive graphite copper facing not method for oxidation |
Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101407916A (en) * | 2008-11-13 | 2009-04-15 | 常熟华冶薄板有限公司 | Low-alkali non-phosphate degreasing agent |
| CN102051611A (en) * | 2010-12-31 | 2011-05-11 | 大连工业大学 | Metal surface treating agent |
| CN102952425A (en) * | 2012-11-19 | 2013-03-06 | 南京信息工程大学 | Water-based printing ink cleaning agent and preparation method thereof |
-
2013
- 2013-11-28 CN CN201310614645.XA patent/CN103709811B/en active Active
Patent Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101407916A (en) * | 2008-11-13 | 2009-04-15 | 常熟华冶薄板有限公司 | Low-alkali non-phosphate degreasing agent |
| CN102051611A (en) * | 2010-12-31 | 2011-05-11 | 大连工业大学 | Metal surface treating agent |
| CN102952425A (en) * | 2012-11-19 | 2013-03-06 | 南京信息工程大学 | Water-based printing ink cleaning agent and preparation method thereof |
Also Published As
| Publication number | Publication date |
|---|---|
| CN103709811A (en) | 2014-04-09 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN103882451B (en) | A kind of water base normal temperature rust-removing and antirusting agent and preparation method thereof | |
| CN103882439B (en) | A kind of water-soluble metal degreasing derusting rust-proofing liquid and preparation method thereof | |
| CN103695940B (en) | A kind of Water-soluble antioxidant derusting rust-proofing liquid and preparation method thereof | |
| CN103695920A (en) | Water-based metal rustproof liquid and preparation method thereof | |
| CN103695922A (en) | Low-temperature rust cleaning water-soluble antirust liquor and preparation method thereof | |
| CN103882450B (en) | A kind of water base rust-removing and antirusting agent and preparation method thereof | |
| CN103709811B (en) | A kind of inter-process water-based anti-rusting liquid and preparation method thereof | |
| CN103695140A (en) | Water-soluble cutting antirust liquid and preparation method thereof | |
| CN103710118B (en) | A kind of water base cutting cooling antirust liquid and preparation method thereof | |
| CN103695915B (en) | A kind of emulsion-type antirust solution and preparation method thereof | |
| CN103882434A (en) | Pollution-free inter-process antirust liquid and preparation method thereof | |
| CN103695948A (en) | Cast iron derusting antirust liquid and preparation method thereof | |
| CN103882445B (en) | One can coating derusting rust-proofing liquid and preparation method thereof | |
| CN103695931B (en) | A kind of Water-soluble metal short-term antirust liquid and preparation method thereof | |
| CN103695913A (en) | Water-soluble ferrous metal antirust liquid and preparation method thereof | |
| CN103695916B (en) | A kind of antifouling antirust solution of water solublity and preparation method thereof | |
| CN103695936A (en) | Water-based inter-process environment-friendly antirust liquid and preparation method thereof | |
| CN103710707B (en) | A kind of amino resins water-soluble anti-rust liquid and preparation method thereof | |
| CN103642288B (en) | A kind of Environment-friendlywater-soluble water-soluble rust protection liquid and preparation method thereof | |
| CN103614727B (en) | A kind of water-base metal surface antirust solution and preparation method thereof | |
| CN103642287B (en) | A kind of Water-soluble antirust liquid and preparation method thereof | |
| CN103695921B (en) | A kind of derusting rust-proofing liquid containing alkyd resins and preparation method thereof | |
| CN103695917B (en) | A kind of Water-emulsion-type antirust liquid and preparation method thereof | |
| CN103695141B (en) | A kind of environment protection metal cutting cooling antirust liquid and preparation method thereof | |
| CN103695930B (en) | A kind of water base copper antirust solution and preparation method thereof |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| C06 | Publication | ||
| PB01 | Publication | ||
| C10 | Entry into substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| C14 | Grant of patent or utility model | ||
| GR01 | Patent grant | ||
| TR01 | Transfer of patent right | ||
| TR01 | Transfer of patent right |
Effective date of registration: 20190409 Address after: 037010 No. 14 Heng'an Street, Hudong, Datong Development Zone, Shanxi Province Patentee after: Datong Yinglai Shell lubricants limited liability company Address before: 237000 Intersection of Xingxing Road and Yongtai Road in Pingqiao Industrial Park, Yuan District, Luan City, Anhui Province Patentee before: ANHUI SUKEDA VEHICLE CO., LTD. |
|
| CP01 | Change in the name or title of a patent holder | ||
| CP01 | Change in the name or title of a patent holder |
Address after: 037010 No. 14 Heng'an Street, Hudong, Datong Development Zone, Shanxi Province Patentee after: Shanxi yinglaike Technology Co., Ltd Address before: 037010 No. 14 Heng'an Street, Hudong, Datong Development Zone, Shanxi Province Patentee before: Datong Yinglai Shell lubricants LLC |