CN103695931B - A kind of Water-soluble metal short-term antirust liquid and preparation method thereof - Google Patents
A kind of Water-soluble metal short-term antirust liquid and preparation method thereof Download PDFInfo
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- CN103695931B CN103695931B CN201310617335.3A CN201310617335A CN103695931B CN 103695931 B CN103695931 B CN 103695931B CN 201310617335 A CN201310617335 A CN 201310617335A CN 103695931 B CN103695931 B CN 103695931B
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- 229910052751 metal Inorganic materials 0.000 title claims abstract description 20
- 239000002184 metal Substances 0.000 title claims abstract description 20
- 239000007788 liquid Substances 0.000 title claims abstract description 13
- 238000002360 preparation method Methods 0.000 title claims description 10
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 15
- NTHWMYGWWRZVTN-UHFFFAOYSA-N sodium silicate Chemical compound [Na+].[Na+].[O-][Si]([O-])=O NTHWMYGWWRZVTN-UHFFFAOYSA-N 0.000 claims abstract description 10
- CIWBSHSKHKDKBQ-JLAZNSOCSA-N Ascorbic acid Chemical compound OC[C@H](O)[C@H]1OC(=O)C(O)=C1O CIWBSHSKHKDKBQ-JLAZNSOCSA-N 0.000 claims abstract description 8
- VKYKSIONXSXAKP-UHFFFAOYSA-N hexamethylenetetramine Chemical compound C1N(C2)CN3CN1CN2C3 VKYKSIONXSXAKP-UHFFFAOYSA-N 0.000 claims abstract description 8
- NLHHRLWOUZZQLW-UHFFFAOYSA-N Acrylonitrile Chemical compound C=CC#N NLHHRLWOUZZQLW-UHFFFAOYSA-N 0.000 claims abstract description 7
- 229910052581 Si3N4 Inorganic materials 0.000 claims abstract description 7
- 239000012752 auxiliary agent Substances 0.000 claims abstract description 7
- 239000003995 emulsifying agent Substances 0.000 claims abstract description 7
- 235000019353 potassium silicate Nutrition 0.000 claims abstract description 7
- 239000002994 raw material Substances 0.000 claims abstract description 7
- HQVNEWCFYHHQES-UHFFFAOYSA-N silicon nitride Chemical compound N12[Si]34N5[Si]62N3[Si]51N64 HQVNEWCFYHHQES-UHFFFAOYSA-N 0.000 claims abstract description 7
- UEUXEKPTXMALOB-UHFFFAOYSA-J tetrasodium;2-[2-[bis(carboxylatomethyl)amino]ethyl-(carboxylatomethyl)amino]acetate Chemical compound [Na+].[Na+].[Na+].[Na+].[O-]C(=O)CN(CC([O-])=O)CCN(CC([O-])=O)CC([O-])=O UEUXEKPTXMALOB-UHFFFAOYSA-J 0.000 claims abstract description 7
- WRIDQFICGBMAFQ-UHFFFAOYSA-N (E)-8-Octadecenoic acid Natural products CCCCCCCCCC=CCCCCCCC(O)=O WRIDQFICGBMAFQ-UHFFFAOYSA-N 0.000 claims abstract description 4
- LQJBNNIYVWPHFW-UHFFFAOYSA-N 20:1omega9c fatty acid Natural products CCCCCCCCCCC=CCCCCCCCC(O)=O LQJBNNIYVWPHFW-UHFFFAOYSA-N 0.000 claims abstract description 4
- QSBYPNXLFMSGKH-UHFFFAOYSA-N 9-Heptadecensaeure Natural products CCCCCCCC=CCCCCCCCC(O)=O QSBYPNXLFMSGKH-UHFFFAOYSA-N 0.000 claims abstract description 4
- 239000004255 Butylated hydroxyanisole Substances 0.000 claims abstract description 4
- ZQPPMHVWECSIRJ-UHFFFAOYSA-N Oleic acid Natural products CCCCCCCCC=CCCCCCCCC(O)=O ZQPPMHVWECSIRJ-UHFFFAOYSA-N 0.000 claims abstract description 4
- 239000005642 Oleic acid Substances 0.000 claims abstract description 4
- 235000010323 ascorbic acid Nutrition 0.000 claims abstract description 4
- 229960005070 ascorbic acid Drugs 0.000 claims abstract description 4
- 239000011668 ascorbic acid Substances 0.000 claims abstract description 4
- 235000019282 butylated hydroxyanisole Nutrition 0.000 claims abstract description 4
- CZBZUDVBLSSABA-UHFFFAOYSA-N butylated hydroxyanisole Chemical compound COC1=CC=C(O)C(C(C)(C)C)=C1.COC1=CC=C(O)C=C1C(C)(C)C CZBZUDVBLSSABA-UHFFFAOYSA-N 0.000 claims abstract description 4
- 229940043253 butylated hydroxyanisole Drugs 0.000 claims abstract description 4
- QXJSBBXBKPUZAA-UHFFFAOYSA-N isooleic acid Natural products CCCCCCCC=CCCCCCCCCC(O)=O QXJSBBXBKPUZAA-UHFFFAOYSA-N 0.000 claims abstract description 4
- 229960004011 methenamine Drugs 0.000 claims abstract description 4
- ZQPPMHVWECSIRJ-KTKRTIGZSA-N oleic acid Chemical compound CCCCCCCC\C=C/CCCCCCCC(O)=O ZQPPMHVWECSIRJ-KTKRTIGZSA-N 0.000 claims abstract description 4
- NVIFVTYDZMXWGX-UHFFFAOYSA-N sodium metaborate Chemical compound [Na+].[O-]B=O NVIFVTYDZMXWGX-UHFFFAOYSA-N 0.000 claims abstract description 4
- ROOXNKNUYICQNP-UHFFFAOYSA-N ammonium persulfate Chemical compound [NH4+].[NH4+].[O-]S(=O)(=O)OOS([O-])(=O)=O ROOXNKNUYICQNP-UHFFFAOYSA-N 0.000 claims description 12
- 238000003756 stirring Methods 0.000 claims description 12
- UIIMBOGNXHQVGW-UHFFFAOYSA-M Sodium bicarbonate Chemical compound [Na+].OC([O-])=O UIIMBOGNXHQVGW-UHFFFAOYSA-M 0.000 claims description 6
- XSQUKJJJFZCRTK-UHFFFAOYSA-N Urea Chemical compound NC(N)=O XSQUKJJJFZCRTK-UHFFFAOYSA-N 0.000 claims description 6
- 229910001870 ammonium persulfate Inorganic materials 0.000 claims description 6
- 239000012467 final product Substances 0.000 claims description 6
- 229920002134 Carboxymethyl cellulose Polymers 0.000 claims description 3
- 239000004372 Polyvinyl alcohol Substances 0.000 claims description 3
- 239000004115 Sodium Silicate Substances 0.000 claims description 3
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 claims description 3
- 239000004202 carbamide Substances 0.000 claims description 3
- 235000013877 carbamide Nutrition 0.000 claims description 3
- 239000001768 carboxy methyl cellulose Substances 0.000 claims description 3
- 235000010948 carboxy methyl cellulose Nutrition 0.000 claims description 3
- 239000008112 carboxymethyl-cellulose Substances 0.000 claims description 3
- 238000006243 chemical reaction Methods 0.000 claims description 3
- ZBCBWPMODOFKDW-UHFFFAOYSA-N diethanolamine Chemical compound OCCNCCO ZBCBWPMODOFKDW-UHFFFAOYSA-N 0.000 claims description 3
- 239000000463 material Substances 0.000 claims description 3
- 238000002156 mixing Methods 0.000 claims description 3
- 239000000244 polyoxyethylene sorbitan monooleate Substances 0.000 claims description 3
- 235000010482 polyoxyethylene sorbitan monooleate Nutrition 0.000 claims description 3
- 229920000053 polysorbate 80 Polymers 0.000 claims description 3
- 229920002451 polyvinyl alcohol Polymers 0.000 claims description 3
- 229910000030 sodium bicarbonate Inorganic materials 0.000 claims description 3
- 235000017557 sodium bicarbonate Nutrition 0.000 claims description 3
- 229910052911 sodium silicate Inorganic materials 0.000 claims description 3
- OGIDPMRJRNCKJF-UHFFFAOYSA-N titanium oxide Inorganic materials [Ti]=O OGIDPMRJRNCKJF-UHFFFAOYSA-N 0.000 claims description 3
- JEIPFZHSYJVQDO-UHFFFAOYSA-N iron(III) oxide Inorganic materials O=[Fe]O[Fe]=O JEIPFZHSYJVQDO-UHFFFAOYSA-N 0.000 abstract description 10
- 230000002265 prevention Effects 0.000 abstract description 6
- 230000003064 anti-oxidating effect Effects 0.000 abstract description 4
- 238000005260 corrosion Methods 0.000 abstract description 4
- 230000007797 corrosion Effects 0.000 abstract description 4
- 239000010409 thin film Substances 0.000 abstract description 4
- 230000000116 mitigating effect Effects 0.000 abstract description 3
- 230000000694 effects Effects 0.000 abstract description 2
- 230000002045 lasting effect Effects 0.000 abstract description 2
- 150000002739 metals Chemical class 0.000 abstract description 2
- 230000001681 protective effect Effects 0.000 abstract description 2
- 238000005406 washing Methods 0.000 abstract description 2
- 238000003466 welding Methods 0.000 abstract description 2
- 239000003921 oil Substances 0.000 description 4
- 230000003449 preventive effect Effects 0.000 description 3
- 238000012360 testing method Methods 0.000 description 3
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 description 2
- 230000007613 environmental effect Effects 0.000 description 2
- 239000010408 film Substances 0.000 description 2
- 230000007774 longterm Effects 0.000 description 2
- LPXPTNMVRIOKMN-UHFFFAOYSA-M sodium nitrite Chemical compound [Na+].[O-]N=O LPXPTNMVRIOKMN-UHFFFAOYSA-M 0.000 description 2
- 229910000831 Steel Inorganic materials 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 230000015556 catabolic process Effects 0.000 description 1
- 239000011248 coating agent Substances 0.000 description 1
- 238000000576 coating method Methods 0.000 description 1
- 239000002131 composite material Substances 0.000 description 1
- 238000006731 degradation reaction Methods 0.000 description 1
- 238000002845 discoloration Methods 0.000 description 1
- 239000000428 dust Substances 0.000 description 1
- 239000002360 explosive Substances 0.000 description 1
- 238000007654 immersion Methods 0.000 description 1
- 229910052742 iron Inorganic materials 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 239000011159 matrix material Substances 0.000 description 1
- 239000002480 mineral oil Substances 0.000 description 1
- 235000010446 mineral oil Nutrition 0.000 description 1
- 239000003960 organic solvent Substances 0.000 description 1
- 230000003647 oxidation Effects 0.000 description 1
- 238000007254 oxidation reaction Methods 0.000 description 1
- 239000000047 product Substances 0.000 description 1
- 238000011160 research Methods 0.000 description 1
- 239000011347 resin Substances 0.000 description 1
- 229920005989 resin Polymers 0.000 description 1
- 150000003839 salts Chemical class 0.000 description 1
- 235000010288 sodium nitrite Nutrition 0.000 description 1
- 239000010959 steel Substances 0.000 description 1
- 239000000080 wetting agent Substances 0.000 description 1
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- Paints Or Removers (AREA)
- Preventing Corrosion Or Incrustation Of Metals (AREA)
- Application Of Or Painting With Fluid Materials (AREA)
Abstract
The invention discloses a kind of Water-soluble metal short-term antirust liquid, be prepared by the raw materials in: APG 2-3, emulsifier op-10 1-2, sodium metaborate 2-3, ascorbic acid 1-2, Butylated hydroxyanisole 2-3, hexamethylenamine 0.5-1.5, three oleic acid Adeps Bovis seu Bubali diamidogen 1.1-1.7, silicon nitride 0.5-1, acrylonitrile 10-12, waterglass 5-7, EDETATE SODIUM 1-2, auxiliary agent 4-5, water 300.Antirust solution of the present invention can form thin film in metal surface, completely cuts off air, anti-oxidation, thin film easy-clear, and washing is i.e. fallen；Antioxidation of the present invention, corrosion mitigating effect are good, form protective oxide layer in metal surface, and rust-proof effect is lasting；The present invention is applicable to the short-term rust prevention of the metallic article such as five metals, auto parts, does not affect the performances such as welding.
Description
Technical field
The present invention relates to technical field of rust prevention, particularly relate to a kind of Water-soluble metal short-term antirust liquid and preparation method thereof.
Background technology
Metal surface is antirust is the important topic in commercial production, and traditional antirust solution, antirust oil have advantage also to have shortcoming.Containing substantial amounts of sodium nitrite in common aqueous rust preventive, there is carcinogenecity, be unfavorable for that environmental protection and the person are healthy, and use wetting agent to extend the life-span of aqueous rust preventive, bring again the disadvantage touched with one's hand, be covered with dust, and can not long-term rust prevention；Although general hard film rust preventive oil is suitable for long-term rust prevention, film forming is the most transparent attractive in appearance, but water white resin types is less, instability also easy oxidation discoloration, in addition it is also necessary to organic solvent dissolves, and brings inflammable and explosive danger to be also unfavorable for environmental protection and health；General antirust oil uses mineral oil, difficult degradation, and also brings along the problem that oil removing is difficult when short-term rust prevention.Therefore, comprehensive study performance is more excellent, and the antirust product being more suitable for for different occasion researchs is new direction and trend.
Summary of the invention
It is an object of the invention to provide a kind of Water-soluble metal short-term antirust liquid and preparation method thereof, this antirust solution has the advantages that corrosion mitigating effect is good, do not affect intermetallic composite coating performance.
Technical scheme is as follows:
A kind of Water-soluble metal short-term antirust liquid, it is characterised in that be prepared by the raw materials in: APG 2-3, emulsifier op-10 1-2, sodium metaborate 2-3, ascorbic acid 1-2, Butylated hydroxyanisole 2-3, hexamethylenamine 0.5-1.5, three oleic acid Adeps Bovis seu Bubali diamidogen 1.1-1.7, silicon nitride 0.5-1, acrylonitrile 10-12, waterglass 5-7, EDETATE SODIUM 1-2, auxiliary agent 4-5, water 300.Described auxiliary agent is prepared by the raw materials in: polyoxyethylene sorbitan monooleate 2-3, nano titanium oxide 0.1-0.2, sodium bicarbonate 1-2, diethanolamine 2-3, carboxymethyl cellulose 2-3, polyvinyl alcohol 1-2, Resina persicae 1-2, sodium silicate 1-2, carbamide 3-4, Ammonium persulfate. 1-2, water 20-24；Preparation method be dissolve ammonium persulfate into water after, add other leftover materials, stir 10-15 minute, be heated to 70-80 DEG C, stirring reaction 1-2 hour, to obtain final product.
The preparation method of described Water-soluble metal short-term antirust liquid, it is characterised in that comprise the following steps: by water, APG, emulsifier op-10 mixing, be heated to 40-50 DEG C；Add silicon nitride, acrylonitrile, waterglass, EDETATE SODIUM, continue to be heated to 85-90 DEG C, stir 10-15 minute；Add other residual componentss, continue stirring 15-20 minute, to obtain final product.
Beneficial effects of the present invention
Antirust solution of the present invention can form thin film in metal surface, completely cuts off air, anti-oxidation, thin film easy-clear, and washing is i.e. fallen；Antioxidation of the present invention, corrosion mitigating effect are good, form protective oxide layer in metal surface, and rust-proof effect is lasting；The present invention is applicable to the short-term rust prevention of the metallic article such as five metals, auto parts, does not affect the performances such as welding.
Detailed description of the invention
A kind of Water-soluble metal short-term antirust liquid, is made up of the raw material of following weight portion (kilogram): APG 2.5, emulsifier op-10 1.5, sodium metaborate 2.5, ascorbic acid 1.5, Butylated hydroxyanisole 2.5, hexamethylenamine 1, three oleic acid Adeps Bovis seu Bubali diamidogen 1.2, silicon nitride 0.8, acrylonitrile 11, waterglass 6, EDETATE SODIUM 1.5, auxiliary agent 4.5, water 300.Described auxiliary agent is made up of the raw material of following weight portion (kilogram): polyoxyethylene sorbitan monooleate 2, nano titanium oxide 0.1, sodium bicarbonate 2, diethanolamine 2, carboxymethyl cellulose 3, polyvinyl alcohol 2, Resina persicae 1, sodium silicate 2, carbamide 3, Ammonium persulfate. 1, water 20；Preparation method be dissolve ammonium persulfate into water after, add other leftover materials, stir 10-15 minute, be heated to 70-80 DEG C, stirring reaction 1-2 hour, to obtain final product.
The preparation method of described Water-soluble metal short-term antirust liquid, comprises the following steps: by water, APG, emulsifier op-10 mixing, be heated to 45 DEG C；Add silicon nitride, acrylonitrile, waterglass, EDETATE SODIUM, continue to be heated to 88 DEG C, stir 13 minutes；Add other residual componentss, continue stirring 18 minutes, to obtain final product.
The Water-soluble metal short-term antirust liquid that this embodiment obtains is detected by national standard, and damp heat test * (1) is qualified；Salt water immersion test * (1): qualified；Corrosion testing * (2): qualified；Rust removability (secondary) ＜ 6.Prepared Water-soluble metal short-term antirust liquid is brushed that be newly processed into and do not have the steel matrix surface of greasy dirt, within 20 days disposed within, to have no obvious iron mold.
Claims (2)
1. a Water-soluble metal short-term antirust liquid, it is characterised in that be prepared by the raw materials in: APG 2-3, emulsifier op-10 1-2, sodium metaborate 2-3, ascorbic acid 1-2, Butylated hydroxyanisole 2-3, hexamethylenamine 0.5-1.5, three oleic acid Adeps Bovis seu Bubali diamidogen 1.1-1.7, silicon nitride 0.5-1, acrylonitrile 10-12, waterglass 5-7, EDETATE SODIUM 1-2, auxiliary agent 4-5, water 300；Described auxiliary agent is prepared by the raw materials in: polyoxyethylene sorbitan monooleate 2-3, nano titanium oxide 0.1-0.2, sodium bicarbonate 1-2, diethanolamine 2-3, carboxymethyl cellulose 2-3, polyvinyl alcohol 1-2, Resina persicae 1-2, sodium silicate 1-2, carbamide 3-4, Ammonium persulfate. 1-2, water 20-24；Preparation method be dissolve ammonium persulfate into water after, add other leftover materials, stir 10-15 minute, be heated to 70-80 DEG C, stirring reaction 1-2 hour, to obtain final product.
The preparation method of Water-soluble metal short-term antirust liquid the most according to claim 1, it is characterised in that comprise the following steps: by water, APG, emulsifier op-10 mixing, be heated to 40-50 DEG C；Add silicon nitride, acrylonitrile, waterglass, EDETATE SODIUM, continue to be heated to 85-90 DEG C, stir 10-15 minute；Add other residual componentss, continue stirring 15-20 minute, to obtain final product.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201310617335.3A CN103695931B (en) | 2013-11-29 | 2013-11-29 | A kind of Water-soluble metal short-term antirust liquid and preparation method thereof |
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| Application Number | Priority Date | Filing Date | Title |
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| CN201310617335.3A CN103695931B (en) | 2013-11-29 | 2013-11-29 | A kind of Water-soluble metal short-term antirust liquid and preparation method thereof |
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| Publication Number | Publication Date |
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| CN103695931A CN103695931A (en) | 2014-04-02 |
| CN103695931B true CN103695931B (en) | 2016-08-24 |
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Families Citing this family (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN105463472A (en) * | 2015-12-08 | 2016-04-06 | 彭国泉 | Water-soluble antirust agent |
| CN106282986A (en) * | 2016-08-25 | 2017-01-04 | 常熟市梅李合金材料有限公司 | Heating nickel chromium triangle flat filament |
| CN114854257A (en) * | 2022-05-09 | 2022-08-05 | 杭州金固环保设备科技有限公司 | High-temperature-resistant antirust agent and preparation method thereof |
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| JPH01279917A (en) * | 1988-02-12 | 1989-11-10 | Exxon Res & Eng Co | Quaternary salt of quinoline oligomer as metal surface protective substance |
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| CN1434705A (en) * | 1999-12-16 | 2003-08-06 | 德马全兹股份有限公司 | Use of hydroxide-releasing agents as skin permeation enhancers |
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| EP2219600A1 (en) * | 2007-11-19 | 2010-08-25 | Stiefel Laboratories, Inc. | Topical cosmetic skin lightening compositions and methods of use thereof |
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| JPH01279917A (en) * | 1988-02-12 | 1989-11-10 | Exxon Res & Eng Co | Quaternary salt of quinoline oligomer as metal surface protective substance |
| CN1059171A (en) * | 1990-08-11 | 1992-03-04 | 彭忆祖 | The protectant manufacture method of a kind of chromium-plated part |
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Address after: 239400 No. 72, Liuwan Road, Mingguang Industrial Park, Chuzhou City, Anhui Province Patentee after: Anhui Liuxiang Special Ship Co.,Ltd. Address before: 239400 No. 72, Liuwan Road, Mingguang Industrial Park, Chuzhou City, Anhui Province Patentee before: MINGGUANG CITY LIUXIANG PUMP INDUSTRY Co.,Ltd. |
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Application publication date: 20140402 Assignee: Mingguang Runjia Pump Ship Technology Co.,Ltd. Assignor: Anhui Liuxiang Special Ship Co.,Ltd. Contract record no.: X2024980000261 Denomination of invention: A water-soluble metal short-term rust inhibitor and its preparation method Granted publication date: 20160824 License type: Exclusive License Record date: 20240111 |
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Effective date of registration: 20240523 Address after: No. 98 Qicang Road, Mingguang City, Chuzhou City, Anhui Province, 239000 Patentee after: Mingguang Jiuzhi Intellectual Property Management Co.,Ltd. Country or region after: China Address before: 239400 No. 72, Liuwan Road, Mingguang Industrial Park, Chuzhou City, Anhui Province Patentee before: Anhui Liuxiang Special Ship Co.,Ltd. Country or region before: China |