CN103695924B - A kind of five metals salt spray resistance antirust solution and preparation method thereof - Google Patents
A kind of five metals salt spray resistance antirust solution and preparation method thereof Download PDFInfo
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- CN103695924B CN103695924B CN201310617384.7A CN201310617384A CN103695924B CN 103695924 B CN103695924 B CN 103695924B CN 201310617384 A CN201310617384 A CN 201310617384A CN 103695924 B CN103695924 B CN 103695924B
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- salt spray
- spray resistance
- water
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- antirust solution
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- 229910052751 metal Inorganic materials 0.000 title claims abstract description 24
- 239000002184 metal Substances 0.000 title claims abstract description 24
- -1 metals salt Chemical class 0.000 title claims abstract description 16
- 239000007921 spray Substances 0.000 title claims abstract description 15
- 238000002360 preparation method Methods 0.000 title claims description 10
- SOGAXMICEFXMKE-UHFFFAOYSA-N Butylmethacrylate Chemical compound CCCCOC(=O)C(C)=C SOGAXMICEFXMKE-UHFFFAOYSA-N 0.000 claims abstract description 14
- KRKNYBCHXYNGOX-UHFFFAOYSA-N citric acid Chemical compound OC(=O)CC(O)(C(O)=O)CC(O)=O KRKNYBCHXYNGOX-UHFFFAOYSA-N 0.000 claims abstract description 12
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 12
- ZTHYODDOHIVTJV-UHFFFAOYSA-N Propyl gallate Chemical compound CCCOC(=O)C1=CC(O)=C(O)C(O)=C1 ZTHYODDOHIVTJV-UHFFFAOYSA-N 0.000 claims abstract description 8
- 239000012752 auxiliary agent Substances 0.000 claims abstract description 8
- OAYXUHPQHDHDDZ-UHFFFAOYSA-N 2-(2-butoxyethoxy)ethanol Chemical compound CCCCOCCOCCO OAYXUHPQHDHDDZ-UHFFFAOYSA-N 0.000 claims abstract description 7
- 229920000877 Melamine resin Polymers 0.000 claims abstract description 7
- 239000003995 emulsifying agent Substances 0.000 claims abstract description 7
- JDSHMPZPIAZGSV-UHFFFAOYSA-N melamine Chemical compound NC1=NC(N)=NC(N)=N1 JDSHMPZPIAZGSV-UHFFFAOYSA-N 0.000 claims abstract description 7
- 239000002994 raw material Substances 0.000 claims abstract description 7
- UEUXEKPTXMALOB-UHFFFAOYSA-J tetrasodium;2-[2-[bis(carboxylatomethyl)amino]ethyl-(carboxylatomethyl)amino]acetate Chemical compound [Na+].[Na+].[Na+].[Na+].[O-]C(=O)CN(CC([O-])=O)CCN(CC([O-])=O)CC([O-])=O UEUXEKPTXMALOB-UHFFFAOYSA-J 0.000 claims abstract description 7
- RSWGJHLUYNHPMX-UHFFFAOYSA-N Abietic-Saeure Natural products C12CCC(C(C)C)=CC2=CCC2C1(C)CCCC2(C)C(O)=O RSWGJHLUYNHPMX-UHFFFAOYSA-N 0.000 claims abstract description 4
- KHPCPRHQVVSZAH-HUOMCSJISA-N Rosin Natural products O(C/C=C/c1ccccc1)[C@H]1[C@H](O)[C@@H](O)[C@@H](O)[C@@H](CO)O1 KHPCPRHQVVSZAH-HUOMCSJISA-N 0.000 claims abstract description 4
- 150000001412 amines Chemical class 0.000 claims abstract description 4
- 150000002148 esters Chemical class 0.000 claims abstract description 4
- 235000010388 propyl gallate Nutrition 0.000 claims abstract description 4
- WXMKPNITSTVMEF-UHFFFAOYSA-M sodium benzoate Chemical compound [Na+].[O-]C(=O)C1=CC=CC=C1 WXMKPNITSTVMEF-UHFFFAOYSA-M 0.000 claims abstract description 4
- 235000010234 sodium benzoate Nutrition 0.000 claims abstract description 4
- 239000004299 sodium benzoate Substances 0.000 claims abstract description 4
- KHPCPRHQVVSZAH-UHFFFAOYSA-N trans-cinnamyl beta-D-glucopyranoside Natural products OC1C(O)C(O)C(CO)OC1OCC=CC1=CC=CC=C1 KHPCPRHQVVSZAH-UHFFFAOYSA-N 0.000 claims abstract description 4
- ROOXNKNUYICQNP-UHFFFAOYSA-N ammonium persulfate Chemical compound [NH4+].[NH4+].[O-]S(=O)(=O)OOS([O-])(=O)=O ROOXNKNUYICQNP-UHFFFAOYSA-N 0.000 claims description 12
- 238000003756 stirring Methods 0.000 claims description 12
- 229910001870 ammonium persulfate Inorganic materials 0.000 claims description 6
- 239000012467 final product Substances 0.000 claims description 6
- 229920002134 Carboxymethyl cellulose Polymers 0.000 claims description 3
- 239000004372 Polyvinyl alcohol Substances 0.000 claims description 3
- 235000006040 Prunus persica var persica Nutrition 0.000 claims description 3
- 239000004115 Sodium Silicate Substances 0.000 claims description 3
- UIIMBOGNXHQVGW-UHFFFAOYSA-M Sodium bicarbonate Chemical compound [Na+].OC([O-])=O UIIMBOGNXHQVGW-UHFFFAOYSA-M 0.000 claims description 3
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 claims description 3
- XSQUKJJJFZCRTK-UHFFFAOYSA-N Urea Chemical compound NC(N)=O XSQUKJJJFZCRTK-UHFFFAOYSA-N 0.000 claims description 3
- 239000004202 carbamide Substances 0.000 claims description 3
- 239000001768 carboxy methyl cellulose Substances 0.000 claims description 3
- 235000010948 carboxy methyl cellulose Nutrition 0.000 claims description 3
- 239000008112 carboxymethyl-cellulose Substances 0.000 claims description 3
- 238000006243 chemical reaction Methods 0.000 claims description 3
- ZBCBWPMODOFKDW-UHFFFAOYSA-N diethanolamine Chemical compound OCCNCCO ZBCBWPMODOFKDW-UHFFFAOYSA-N 0.000 claims description 3
- 229940043237 diethanolamine Drugs 0.000 claims description 3
- 239000000463 material Substances 0.000 claims description 3
- 229920002451 polyvinyl alcohol Polymers 0.000 claims description 3
- 235000019795 sodium metasilicate Nutrition 0.000 claims description 3
- NTHWMYGWWRZVTN-UHFFFAOYSA-N sodium silicate Chemical compound [Na+].[Na+].[O-][Si]([O-])=O NTHWMYGWWRZVTN-UHFFFAOYSA-N 0.000 claims description 3
- 229910052911 sodium silicate Inorganic materials 0.000 claims description 3
- OGIDPMRJRNCKJF-UHFFFAOYSA-N titanium oxide Inorganic materials [Ti]=O OGIDPMRJRNCKJF-UHFFFAOYSA-N 0.000 claims description 3
- 240000006413 Prunus persica var. persica Species 0.000 claims 1
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 abstract description 10
- 229910052742 iron Inorganic materials 0.000 abstract description 5
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 abstract description 4
- 229910052802 copper Inorganic materials 0.000 abstract description 4
- 239000010949 copper Substances 0.000 abstract description 4
- 150000002739 metals Chemical class 0.000 abstract description 4
- 229910001220 stainless steel Inorganic materials 0.000 abstract description 4
- 239000010935 stainless steel Substances 0.000 abstract description 4
- 150000003839 salts Chemical class 0.000 abstract description 3
- 230000003712 anti-aging effect Effects 0.000 abstract description 2
- 238000000280 densification Methods 0.000 abstract description 2
- 230000001681 protective effect Effects 0.000 abstract description 2
- 239000000126 substance Substances 0.000 abstract description 2
- JEIPFZHSYJVQDO-UHFFFAOYSA-N iron(III) oxide Inorganic materials O=[Fe]O[Fe]=O JEIPFZHSYJVQDO-UHFFFAOYSA-N 0.000 description 4
- 239000003921 oil Substances 0.000 description 4
- 230000003449 preventive effect Effects 0.000 description 3
- 244000144730 Amygdalus persica Species 0.000 description 2
- 230000007613 environmental effect Effects 0.000 description 2
- 206010007269 Carcinogenicity Diseases 0.000 description 1
- KEAYESYHFKHZAL-UHFFFAOYSA-N Sodium Chemical compound [Na] KEAYESYHFKHZAL-UHFFFAOYSA-N 0.000 description 1
- 229910000831 Steel Inorganic materials 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 230000007670 carcinogenicity Effects 0.000 description 1
- 231100000260 carcinogenicity Toxicity 0.000 description 1
- 230000015556 catabolic process Effects 0.000 description 1
- 238000004140 cleaning Methods 0.000 description 1
- 238000005260 corrosion Methods 0.000 description 1
- 230000007797 corrosion Effects 0.000 description 1
- 238000006731 degradation reaction Methods 0.000 description 1
- 238000002845 discoloration Methods 0.000 description 1
- 238000004090 dissolution Methods 0.000 description 1
- 239000000428 dust Substances 0.000 description 1
- 239000002360 explosive Substances 0.000 description 1
- 238000007654 immersion Methods 0.000 description 1
- 238000009776 industrial production Methods 0.000 description 1
- 239000011159 matrix material Substances 0.000 description 1
- 239000002480 mineral oil Substances 0.000 description 1
- 235000010446 mineral oil Nutrition 0.000 description 1
- 239000003960 organic solvent Substances 0.000 description 1
- 230000003647 oxidation Effects 0.000 description 1
- 238000007254 oxidation reaction Methods 0.000 description 1
- 239000000047 product Substances 0.000 description 1
- 229920005989 resin Polymers 0.000 description 1
- 239000011347 resin Substances 0.000 description 1
- 239000010959 steel Substances 0.000 description 1
Landscapes
- Preventing Corrosion Or Incrustation Of Metals (AREA)
- Chemical Treatment Of Metals (AREA)
Abstract
The invention discloses a kind of five metals salt spray resistance antirust solution, made by the raw material of following weight portion: Emulsifier EL-60 2-3, Sodium Benzoate 1-2, diethylene glycol butyl ether 12-14,6-hexanediyl ester 8-10, n-propyl gallate 2-4, citric acid 3-5, rosin amine 1-2, melamine 6-8, butyl methacrylate 6-8, EDETATE SODIUM 1-2, auxiliary agent 4-5, water 300. Five metals antirust solution salt spray resistance ability of the present invention is strong, can be at copper, and iron, the protective film that the metal surfaces such as stainless steel form one deck densification, prevents external substance corroding metal effectively, does not affect conduction and freezes, and diaphragm easily cleans. Between workpiece and workpiece, can not paste and connect together, the anti-variable color of anti-finger line ﹑ and anti-aging capability are strong, and the operation of normal temperature stoste, saves the energy. The present invention be applicable to the metals such as copper, iron, stainless steel and plated metal surface antirust.
Description
Technical field
The present invention relates to antirust technology field, relate in particular to a kind of five metals salt spray resistance antirust solution and preparation method thereof.
Background technology
Metal surface is antirust is the important topic in industrial production, and traditional antirust solution, antirust oil has advantage also to have shortcoming. In common aqueous rust preventive, containing a large amount of natrium nitrosums, there is carcinogenicity, be unfavorable for environmental protection and person health, and adopt NMF to extend the life-span of aqueous rust preventive, bring again the disadvantage of touching with one's hand, being covered with dust, and can not be antirust for a long time; Although it is antirust for a long time that general hard film rust preventive oil is applicable to, film forming is also transparent attractive in appearance, and water white resin kind is less, and unstable also easy oxidation discoloration, also needs organic solvent dissolution, brings inflammable and explosive danger to be also unfavorable for environmental protection and health; General antirust oil uses mineral oil, difficult degradation, and also can bring the problem of oil removing difficulty when antirust for short-term. Therefore, comprehensive study performance is more excellent, and the antirust product being more applicable to for different occasion research is new direction and trend.
Summary of the invention
The object of the present invention is to provide a kind of five metals salt spray resistance antirust solution and preparation method thereof, this antirust solution has the feature of anti-salt fog, easy and simple to handle, easy cleaning.
Technical scheme of the present invention is as follows:
A kind of five metals salt spray resistance antirust solution, it is characterized in that being made by the raw material of following weight portion: Emulsifier EL-60 2-3, Sodium Benzoate 1-2, diethylene glycol butyl ether 12-14,1,6-hexanediyl ester 8-10, n-propyl gallate 2-4, citric acid 3-5, rosin amine 1-2, melamine 6-8, butyl methacrylate 6-8, EDETATE SODIUM 1-2, auxiliary agent 4-5, water 300. Described auxiliary agent is made up of the raw material of following weight portion: Tween-81 2-3, nano titanium oxide 0.1-0.2, sodium acid carbonate 1-2, diethanol amine 2-3, carboxymethyl cellulose 2-3, polyvinyl alcohol 1-2, peach gum 1-2, sodium metasilicate 1-2, urea 3-4, ammonium persulfate 1-2, water 20-24; Preparation method be ammonium persulfate is water-soluble after, then add other leftover materials, stir 10-15 minute, be heated to 70-80 DEG C, stirring reaction 1-2 hour, to obtain final product.
The preparation method of described five metals salt spray resistance antirust solution, is characterized in that comprising the following steps: water, Emulsifier EL-60 are mixed, be heated to 40-50 DEG C; Add diethylene glycol butyl ether, 1,6-hexanediyl ester, melamine, EDETATE SODIUM, butyl methacrylate, continue to be heated to 85-90 DEG C, stirs 10-15 minute; Add other residual components, continue to stir 15-20 minute, to obtain final product.
Beneficial effect of the present invention
Five metals antirust solution salt spray resistance ability of the present invention is strong, can be at copper, and iron, the protective film that the metal surfaces such as stainless steel form one deck densification, prevents external substance corroding metal effectively, does not affect conduction and freezes, and diaphragm easily cleans. Between workpiece and workpiece, can not paste and connect together, the anti-variable color of anti-finger line ﹑ and anti-aging capability are strong, and the operation of normal temperature stoste, saves the energy. The present invention be applicable to the metals such as copper, iron, stainless steel and plated metal surface antirust.
Detailed description of the invention
A kind of five metals salt spray resistance antirust solution, by following weight portion (kilogram) raw material make: Emulsifier EL-60 2.5, Sodium Benzoate 1.5, diethylene glycol butyl ether 13,1,6-hexanediyl ester 9, n-propyl gallate 3, citric acid 4, rosin amine 1.5, melamine 7, butyl methacrylate 7, EDETATE SODIUM 1.5, auxiliary agent 4.5, water 300. Described auxiliary agent by following weight portion (kilogram) raw material make: Tween-81 2, nano titanium oxide 0.1, sodium acid carbonate 2, diethanol amine 2, carboxymethyl cellulose 3, polyvinyl alcohol 2, peach gum 1, sodium metasilicate 2, urea 3, ammonium persulfate 1, water 20; Preparation method be ammonium persulfate is water-soluble after, then add other leftover materials, stir 10-15 minute, be heated to 70-80 DEG C, stirring reaction 1-2 hour, to obtain final product.
The preparation method of described five metals salt spray resistance antirust solution, comprises the following steps: water, Emulsifier EL-60 are mixed, be heated to 45 DEG C; Add diethylene glycol butyl ether, 1,6-hexanediyl ester, melamine, EDETATE SODIUM, butyl methacrylate, continue to be heated to 88 DEG C, stirs 14 minutes; Add other residual components, continue to stir 17 minutes, to obtain final product.
The five metals salt spray resistance antirust solution that this embodiment obtains detects by national standard, and damp heat test * (1) is qualified; Salt water immersion test * (1): qualified; Corrosion test * (2): qualified; Rust removability (inferior) < 6. Prepared five metals salt spray resistance antirust solution is brushed on the steel matrix surface of being newly processed into and there is no greasy dirt, be placed in and within indoor 20 days, have no obvious iron mold.
Claims (2)
1. a five metals salt spray resistance antirust solution, it is characterized in that being made by the raw material of following weight portion: Emulsifier EL-60 2-3, Sodium Benzoate 1-2, diethylene glycol butyl ether 12-14,1,6-hexanediyl ester 8-10, n-propyl gallate 2-4, citric acid 3-5, rosin amine 1-2, melamine 6-8, butyl methacrylate 6-8, EDETATE SODIUM 1-2, auxiliary agent 4-5, water 300; Described auxiliary agent is made up of the raw material of following weight portion: Tween-81 2-3, nano titanium oxide 0.1-0.2, sodium acid carbonate 1-2, diethanol amine 2-3, carboxymethyl cellulose 2-3, polyvinyl alcohol 1-2, peach gum 1-2, sodium metasilicate 1-2, urea 3-4, ammonium persulfate 1-2, water 20-24; The preparation method of auxiliary agent be ammonium persulfate is water-soluble after, then add other leftover materials, stir 10-15 minute, be heated to 70-80 DEG C, stirring reaction 1-2 hour, to obtain final product.
2. the preparation method of five metals salt spray resistance antirust solution according to claim 1, is characterized in that comprising the following steps: water, Emulsifier EL-60 are mixed, be heated to 40-50 DEG C; Add diethylene glycol butyl ether,, 1,6-hexanediyl ester, melamine, EDETATE SODIUM, butyl methacrylate, continue to be heated to 85-90 DEG C, stir 10-15 minute; Add other residual components, continue to stir 15-20 minute, to obtain final product.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201310617384.7A CN103695924B (en) | 2013-11-29 | 2013-11-29 | A kind of five metals salt spray resistance antirust solution and preparation method thereof |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201310617384.7A CN103695924B (en) | 2013-11-29 | 2013-11-29 | A kind of five metals salt spray resistance antirust solution and preparation method thereof |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN103695924A CN103695924A (en) | 2014-04-02 |
| CN103695924B true CN103695924B (en) | 2016-05-04 |
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| Application Number | Title | Priority Date | Filing Date |
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| CN201310617384.7A Active CN103695924B (en) | 2013-11-29 | 2013-11-29 | A kind of five metals salt spray resistance antirust solution and preparation method thereof |
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Families Citing this family (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN110172554B (en) * | 2019-06-27 | 2021-04-02 | 江苏鑫露化工新材料有限公司 | High-temperature-resistant ferrous metal antioxidant and preparation method thereof |
Family Cites Families (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| GB795819A (en) * | 1955-03-25 | 1958-05-28 | Monsanto Chemicals | Improvements relating to corrosion-preventive compositions |
| GB1455250A (en) * | 1972-12-13 | 1976-11-10 | Century Oils Ltd | Corrosion inhibitng preparations |
| CN102230180B (en) * | 2011-04-10 | 2012-11-07 | 李舰 | Antirust compound glycerin and its preparation method |
| CN103215598A (en) * | 2013-02-04 | 2013-07-24 | 安徽省繁昌县皖南阀门铸造有限公司 | Metal rust-preventive oil comprising hydroxyethyl methacrylate |
| CN103215595B (en) * | 2013-02-04 | 2016-03-02 | 安徽省繁昌县皖南阀门铸造有限公司 | A kind of rust-proof oil containing sorbitan monooleate |
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Effective date of registration: 20240521 Address after: No. 98 Qicang Road, Mingguang City, Chuzhou City, Anhui Province, 239000 Patentee after: Mingguang Jiuzhi Intellectual Property Management Co.,Ltd. Country or region after: China Address before: 239400 No. 72, Liuwan Road, Mingguang Industrial Park, Chuzhou City, Anhui Province Patentee before: MINGGUANG CITY LIUXIANG PUMP INDUSTRY Co.,Ltd. Country or region before: China |