CN104263483A - Efficient environment-friendly water-based copper wire-drawing liquor and preparation method thereof - Google Patents
Efficient environment-friendly water-based copper wire-drawing liquor and preparation method thereof Download PDFInfo
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- CN104263483A CN104263483A CN201410454582.0A CN201410454582A CN104263483A CN 104263483 A CN104263483 A CN 104263483A CN 201410454582 A CN201410454582 A CN 201410454582A CN 104263483 A CN104263483 A CN 104263483A
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Abstract
The invention discloses efficient environment-friendly water-based copper wire-drawing liquor. The efficient environment-friendly water-based copper wire-drawing liquor is characterized by being prepared from the following raw materials in parts by weight: 1-2 parts of sodium borate, 2-4 parts of aminosulfonic acid, 2.5-3.5 parts of vinyl carboxylic ester, 5-7 parts of silicon micro powder, 4-5 parts of polyricinoleate, 0.8-1.5 parts of urotropin, 3-5 parts of lithium base grease, 3-4 parts of triethanolamine, 3-5 parts of spindle oil, 3-5 parts of sodium stearate, 2.5-3.5 parts of sodium dioctylsulfosuccinate, 5-7 parts of auxiliaries and 900-950 parts of deionized water. The efficient environment-friendly water-based copper wire-drawing liquor adopts an environment-friendly formula, is efficient and environmentally friendly, and has good wear resistance, dispersion, lubrication and film-forming property due to addition of the auxiliaries; and when the efficient environment-friendly water-based copper wire-drawing liquor and a surfactant constitute a formula, a protective film layer is formed on the surface of the metal to achieve the corrosion inhibition effect. The efficient environment-friendly water-based copper wire-drawing liquor is good in lubricating effect, good in cooling performance, high in heat transfer speed and easy to clean. A copper wire drawn by the efficient environment-friendly water-based copper wire-drawing liquor is bright in surface and not prone to rust.
Description
Technical field
The present invention relates to wire-drawing technology field, particularly a kind of aqueous copper wire drawing liquid and preparation method thereof of high-efficiency environment friendly.
Background technology
Copper cash (silk) is the prevailing transmission wire of power industry conveying electricity, usually obtained by drawing process, wire such as the steel wire larger by diameter passes through mould hole, and drawing under external force makes its reduced cross-sectional area form the wire rod of required diameter.The copper wire pulling process of China's line cable industry, copper material and enameled wire industry, the phenomenon spring such as common exist oxidation stain, blackout, summer are even more serious.Along with popularizing of existing high speed machine, drawing speed greatly improves, and contradiction is more and more outstanding.Lubricant for copper wire drawing has multiple, and use properties differs greatly, and some wire drawing lubricants in use can blackening, smelly.Also have the undesirable conditions such as some copper wire drawing lubricants there will be drawing force increase, frictional force increase, oil temperature rising, oil consumption increase, mould, cone pulley loss is fast, copper powder increases and then cause institute's bracing wire material surface quality to reduce, have a strong impact on the quality of the copper wire wire rod of drawing, therefore in order to improve wire quality, cost-saving, high-efficiency environment friendly, choose reasonable and proper use of copper wire drawing lubricant seem especially important.Copper drawing fluid involved by this project possesses splendid film-forming properties, thermostability, non-corrosibility, cooling performance, greatly reduces the amount of taking away of working fluid, ensure that the clean of copper wire-drawing operation environment, has also greatly saved cost.And the requirement of processing luminance brightness and working accuracy can be met under lower concentration.Meanwhile, the copper drawing fluid that this invention makes does not have irritating smell, safety and environmental protection.
Summary of the invention
Aqueous copper wire drawing liquid that the object of this invention is to provide a kind of high-efficiency environment friendly and preparation method thereof.
In order to realize object of the present invention, the present invention is by following scheme implementation:
An aqueous copper wire drawing liquid for high-efficiency environment friendly, is made up of the raw material of following weight part: Sodium Tetraborate 1-2, thionamic acid 2-4, vinyl carboxylate 2.5-3.5, silicon powder 5-7, ricinolic acid polyester 4-5, urotropine 0.8-1.5, lithium soap grease 3-5, trolamine 3-4, spindle oil 3-5, sodium stearate 3-5, Aerosol OT 2.5-3.5, auxiliary agent 5-7, deionized water 900-950;
Described auxiliary agent is made up of the raw material of following weight part: granular graphite 2-4, nano diatomite 2.5-3.5, bisphenol a dimethacrylate 1-2, sulfuration Oleum Gossypii semen 2-2.5, Lauryl Alcohol ester 2-3, anilinomethyl triethoxysilane 1-1.5, Oleum Bupleuri 1-2, pull open powder 3-4, water 90-94; Preparation method be first by granular graphite, nano diatomite, Oleum Bupleuri, pull open powder and add in the water of half amount, grinding 1-2 hour, then slowly adds all the other remaining components, is slowly heated to 70 DEG C-80 DEG C, stirring reaction 30-50 minute under 300-500 rev/min of condition, is cooled to room temperature and get final product.
The aqueous copper wire drawing liquid of a kind of high-efficiency environment friendly of the present invention, be made up of following concrete steps:
(1) silicon powder, ricinolic acid polyester, sodium stearate are mixed, add appropriate deionized water, be heated to 30 DEG C-35 DEG C, grinding 30-40 minute, obtain mixing A material;
(2) all the other remaining components except auxiliary agent are joined in reactor, be uniformly mixed, be slowly heated to 55 DEG C-65 DEG C, insulation 1-1.5 hour, obtain mixing B material;
(3) slowly joined while stirring in mixing A material by the mixing B of insulation material, add auxiliary agent after fully stirring, 600-800 rev/min of lower stirring reaction 40-60 minute, is cooled to room temperature and get final product.
Excellent effect of the present invention is: the present invention adopts environmental protection formulae, high-efficiency environment friendly, adds auxiliary agent, has good wear-resistant, dispersion, lubrication, film-forming properties, with surfactant formula, forms layer protecting film, play corrosion inhibition in metallic surface; High lubricating effect of the present invention, cooling is good, and heat transfer rate is fast, easy cleaning, the copper wire that product of the present invention draws, surface-brightening, not easily corrosion.
Embodiment
Below by specific examples, the present invention is described in detail.
An aqueous copper wire drawing liquid for high-efficiency environment friendly, is made up of the raw material of following weight part (kilogram): Sodium Tetraborate 1, thionamic acid 2, vinyl carboxylate 2.5, silicon powder 5, ricinolic acid polyester 4, urotropine 0.8, lithium soap grease 3, trolamine 3, spindle oil 3, sodium stearate 3, Aerosol OT 2.5, auxiliary agent 5, deionized water 900;
Described auxiliary agent is made up of the raw material of following weight part (kilogram): granular graphite 2, nano diatomite 2.5, bisphenol a dimethacrylate 1, sulfuration Oleum Gossypii semen 2, Lauryl Alcohol ester 2, anilinomethyl triethoxysilane 1, Oleum Bupleuri 1, pull open powder 3, water 90; Preparation method be first by granular graphite, nano diatomite, Oleum Bupleuri, pull open powder and add in the water of half amount, grinding 1-2 hour, then slowly adds all the other remaining components, is slowly heated to 70 DEG C-80 DEG C, stirring reaction 30-50 minute under 300-500 rev/min of condition, is cooled to room temperature and get final product.
The aqueous copper wire drawing liquid of a kind of high-efficiency environment friendly of the present invention, be made up of following concrete steps:
(1) silicon powder, ricinolic acid polyester, sodium stearate are mixed, add appropriate deionized water, be heated to 30 DEG C-35 DEG C, grinding 30-40 minute, obtain mixing A material;
(2) all the other remaining components except auxiliary agent are joined in reactor, be uniformly mixed, be slowly heated to 55 DEG C-65 DEG C, insulation 1-1.5 hour, obtain mixing B material;
(3) slowly joined while stirring in mixing A material by the mixing B of insulation material, add auxiliary agent after fully stirring, 600-800 rev/min of lower stirring reaction 40-60 minute, is cooled to room temperature and get final product.
Use the present embodiment wire drawing liquid, the highest drawing speed can reach 19m/sec.Concentrate the oil sump drain period to be 3 years, the unit oil sump drain period is 8 months, decreases liquid waste disposal and discharge, protects environment.
Claims (2)
1. the aqueous copper wire drawing liquid of a high-efficiency environment friendly, it is characterized in that, be made up of the raw material of following weight part: Sodium Tetraborate 1-2, thionamic acid 2-4, vinyl carboxylate 2.5-3.5, silicon powder 5-7, ricinolic acid polyester 4-5, urotropine 0.8-1.5, lithium soap grease 3-5, trolamine 3-4, spindle oil 3-5, sodium stearate 3-5, Aerosol OT 2.5-3.5, auxiliary agent 5-7, deionized water 900-950;
Described auxiliary agent is made up of the raw material of following weight part: granular graphite 2-4, nano diatomite 2.5-3.5, bisphenol a dimethacrylate 1-2, sulfuration Oleum Gossypii semen 2-2.5, Lauryl Alcohol ester 2-3, anilinomethyl triethoxysilane 1-1.5, Oleum Bupleuri 1-2, pull open powder 3-4, water 90-94; Preparation method be first by granular graphite, nano diatomite, Oleum Bupleuri, pull open powder and add in the water of half amount, grinding 1-2 hour, then slowly adds all the other remaining components, is slowly heated to 70 DEG C-80 DEG C, stirring reaction 30-50 minute under 300-500 rev/min of condition, is cooled to room temperature and get final product.
2. the aqueous copper wire drawing liquid of a kind of high-efficiency environment friendly according to claim 1, is characterized in that, be made up of following concrete steps:
(1) silicon powder, ricinolic acid polyester, sodium stearate are mixed, add appropriate deionized water, be heated to 30 DEG C-35 DEG C, grinding 30-40 minute, obtain mixing A material;
(2) all the other remaining components except auxiliary agent are joined in reactor, be uniformly mixed, be slowly heated to 55 DEG C-65 DEG C, insulation 1-1.5 hour, obtain mixing B material;
(3) slowly joined while stirring in mixing A material by the mixing B of insulation material, add auxiliary agent after fully stirring, 600-800 rev/min of lower stirring reaction 40-60 minute, is cooled to room temperature and get final product.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
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| CN201410454582.0A CN104263483A (en) | 2014-09-09 | 2014-09-09 | Efficient environment-friendly water-based copper wire-drawing liquor and preparation method thereof |
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| CN201410454582.0A CN104263483A (en) | 2014-09-09 | 2014-09-09 | Efficient environment-friendly water-based copper wire-drawing liquor and preparation method thereof |
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Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN104593125A (en) * | 2015-01-29 | 2015-05-06 | 南京工程学院 | Anti-caking lubricating powder for wire drawing |
| CN104611106A (en) * | 2015-01-10 | 2015-05-13 | 安徽旺达铜业发展有限公司 | Water-based copper wire drawing liquid with excellent lubricity and preparation method of water-based copper wire drawing liquid |
| CN105925357A (en) * | 2016-05-10 | 2016-09-07 | 安徽九华金润铜业有限公司 | Low-density drawing oil used for red copper tube |
| CN108003975A (en) * | 2017-12-11 | 2018-05-08 | 当涂县宏宇金属炉料有限责任公司 | A kind of metal wire rod wire drawing powder |
Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101747987A (en) * | 2009-12-21 | 2010-06-23 | 克拉玛依市金山石油化工有限公司 | Water-based copper and aluminum wiredrawing oil composite and preparation method thereof |
| CN102433211A (en) * | 2011-10-27 | 2012-05-02 | 姜堰市华润化工厂 | Copper drawing water-based cold rolling liquid and preparation method thereof |
| CN103045336A (en) * | 2012-12-31 | 2013-04-17 | 益田润石（北京）化工有限公司 | Micro emulsion semisynthetic copper wire drawing liquid composition |
| CN103614227A (en) * | 2013-10-21 | 2014-03-05 | 全威（铜陵）铜业科技有限公司 | High-grade high-speed copper wire drawing lubricant and preparation method thereof |
-
2014
- 2014-09-09 CN CN201410454582.0A patent/CN104263483A/en active Pending
Patent Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101747987A (en) * | 2009-12-21 | 2010-06-23 | 克拉玛依市金山石油化工有限公司 | Water-based copper and aluminum wiredrawing oil composite and preparation method thereof |
| CN102433211A (en) * | 2011-10-27 | 2012-05-02 | 姜堰市华润化工厂 | Copper drawing water-based cold rolling liquid and preparation method thereof |
| CN103045336A (en) * | 2012-12-31 | 2013-04-17 | 益田润石（北京）化工有限公司 | Micro emulsion semisynthetic copper wire drawing liquid composition |
| CN103614227A (en) * | 2013-10-21 | 2014-03-05 | 全威（铜陵）铜业科技有限公司 | High-grade high-speed copper wire drawing lubricant and preparation method thereof |
Cited By (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN104611106A (en) * | 2015-01-10 | 2015-05-13 | 安徽旺达铜业发展有限公司 | Water-based copper wire drawing liquid with excellent lubricity and preparation method of water-based copper wire drawing liquid |
| CN104593125A (en) * | 2015-01-29 | 2015-05-06 | 南京工程学院 | Anti-caking lubricating powder for wire drawing |
| CN104593125B (en) * | 2015-01-29 | 2017-07-11 | 南京工程学院 | A kind of agglomeration resistance wire-drawing lubrication powder |
| CN105925357A (en) * | 2016-05-10 | 2016-09-07 | 安徽九华金润铜业有限公司 | Low-density drawing oil used for red copper tube |
| CN108003975A (en) * | 2017-12-11 | 2018-05-08 | 当涂县宏宇金属炉料有限责任公司 | A kind of metal wire rod wire drawing powder |
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