CN103952219B - A kind of environmental protection wire drawing liquid of high cleaning performance - Google Patents

A kind of environmental protection wire drawing liquid of high cleaning performance Download PDF

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Publication number
CN103952219B
CN103952219B CN201410122511.0A CN201410122511A CN103952219B CN 103952219 B CN103952219 B CN 103952219B CN 201410122511 A CN201410122511 A CN 201410122511A CN 103952219 B CN103952219 B CN 103952219B
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Prior art keywords
wire drawing
drawing liquid
cleaning performance
sunmorl
acid ester
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CN201410122511.0A
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CN103952219A (en
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鲍征
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ANHUI LEESOV INDUSTRY Co Ltd
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ANHUI LEESOV INDUSTRY Co Ltd
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Abstract

The present invention relates to a kind of wire drawing liquid, be specifically related to a kind of environmental protection wire drawing liquid of high cleaning performance, wire drawing liquid of the present invention is made up of the raw material of following weight part: butter 10-12, trimethylolpropane tris oleic acid ester 28-30, sulfonated castor oil 6-8, myo-Inositol hexaphosphate 2-3, Sulfothiorine 1-2, Sunmorl N 60S 1-3, sodium alkyl benzene sulfonate 2-3, polyvinyl alcohol 10-12, polyoxyethylene polyoxypropylene monobutyl ether 1-2, auxiliary agent 4-5, deionized water 800-1000; Wire drawing liquid of the present invention is grease based on butter, the mixing of trimethylolpropane tris oleic acid ester, there is excellent heat-resistant stable, also with the addition of the additive that Sunmorl N 60S, myo-Inositol hexaphosphate etc. have excellent anticorrosion-antiscaling property especially, especially Sunmorl N 60S, it can with many kinds of metal ions chelating, effective raising cleaning performance, wire drawing liquid prepared by the present invention can prevent wire rod detritus powder from boning on wortle and blocking nib, reduce outage, cleaning performance is good, and wire rod is bright and clean without adhering to.

Description

A kind of environmental protection wire drawing liquid of high cleaning performance
Technical field
The present invention relates to a kind of wire drawing liquid, be specifically related to a kind of environmental protection wire drawing liquid and preparation technology thereof of high cleaning performance.
Background technology
Drawing process is a kind of metal working process, refer to that metal wire is forced through mould under pressure, the technology working method of the sectional area shape and size required by acquisition, wire drawing liquid is then requisite auxiliary in drawing process, its main effect is at multiple copper wire, draw in the multiple wire rod of aluminium wire, littlely to draw, finely the wire drawing such as to draw, lubricate in bracing wire technological process, have protection wire rod concurrently, mould, reach good wire-drawing effect, the quality of wire drawing liquid directly has influence on wire-drawing effect, the wire drawing liquid of excellent property can well protect mould, reduce wire rod broken end, die wear phenomenon, have concurrently antirust, cooling, the effects such as cleaning, otherwise, then can have a strong impact on wire drawing quality, along with the application of drawing process is extensive gradually, the quality requirements of market to wire drawing liquid is more and more higher, existing wire drawing liquid mainly exists that stability of emulsion difference, corroding metal wire rod, energy consumption are high, the not problem such as easy cleaning, govern wire drawing, drawing quality, be badly in need of improving its composition and engineering, make its more high-efficiency environment friendly.
Summary of the invention
The object of the invention is to, provide a kind of environmental protection wire drawing liquid of high cleaning performance, to improve efficient attenuation, reduce outage, to achieve these goals, the technical solution used in the present invention is as follows:
A kind of environmental protection wire drawing liquid of high cleaning performance, it is characterized in that, material of the present invention is made up of the raw material of following weight part: butter 10-12, trimethylolpropane tris oleic acid ester 28-30, sulfonated castor oil 6-8, myo-Inositol hexaphosphate 2-3, Sulfothiorine 1-2, Sunmorl N 60S 1-3, sodium alkyl benzene sulfonate 2-3, polyvinyl alcohol 10-12, polyoxyethylene polyoxypropylene monobutyl ether 1-2, auxiliary agent 4-5, deionized water 800-1000;
Described auxiliary agent is made up of the raw material of following weight part: isooctyl oleate 10-12, wilkinite 2-3, stearylamide 4-5, water glass 0.05-0.1, polyoxyethylene 0.1-0.2, Silane coupling agent KH550 0.01-0.02, clorafin 421-2, propylene glycol fatty acid ester 1-2, deionized water 12-15, preparation method is: first by wilkinite high-temperature calcination 2-3h at 600-650 DEG C, 300 order powders are ground to form after cooling, powder mixes with Silane coupling agent KH550, after ball milling 10-15min, with water glass, polyoxyethylene adds in deionized water together, 20-30min is stirred with 500-600 rev/min of rotating speed, subsequently spraying dry is carried out to solution, the powder obtained mixes with other leftover materials, be heated to 40-50 DEG C, continue to stir 40-50min, stir end and be cooled to room temperature, obtain slurry.
The environmental protection wire drawing liquid of described a kind of high cleaning performance, its preparation technology is:
(1) first deionized water is heated to 50-60 DEG C, add sodium alkyl benzene sulfonate, polyvinyl alcohol, be stirred well to it and dissolve dispersion completely, then add myo-Inositol hexaphosphate, Sulfothiorine, Sunmorl N 60S, continue to be stirred to mixture to dissolve completely, mixing solutions insulation is for subsequent use;
(2) butter, trimethylolpropane tris oleic acid ester, sulfonated castor oil are mixed and heated to 50-60 DEG C, and stir with the rotating speed of 1200-1500 rev/min, slowly add step (1) gained material and other remaining component, after stirring 40-50min, standing 2-3h gets product simultaneously.
Wire drawing liquid advantage prepared by the present invention is: grease based on butter, the mixing of trimethylolpropane tris oleic acid ester, there is excellent heat-resistant stable, lubricity is excellent, and environmental protection low toxicity is easily degraded, and decreases the harm to environment and human body in use procedure; In addition, in order to improve the cleaning performance of wire drawing liquid of the present invention, the additive that Sunmorl N 60S, myo-Inositol hexaphosphate etc. have excellent anticorrosion-antiscaling property is with the addition of in formula, especially Sunmorl N 60S, it can also with many kinds of metal ions chelating, it is the metal cleaner of environment-friendly high-efficiency, wire drawing liquid prepared by the present invention in actual use lubricity is excellent, can effectively prevent wire rod detritus powder from boning on wortle and blocking nib, wire drawing outage is low, not easy to foaming, cleaning performance is good, and wire rod is bright and clean without adhering to.
Embodiment
Embodiment
The present embodiment wire drawing liquid is made up of the raw material of following weight part (kilogram): butter 12, trimethylolpropane tris oleic acid ester 30, sulfonated castor oil 6, myo-Inositol hexaphosphate 3, Sulfothiorine 2, Sunmorl N 60S 2, sodium alkyl benzene sulfonate 2, polyvinyl alcohol 12, polyoxyethylene polyoxypropylene monobutyl ether 2, auxiliary agent 5, deionized water 1000;
Auxiliary agent is made up of the raw material of following weight part: isooctyl oleate 12, wilkinite 3, stearylamide 5, water glass 0.1, polyoxyethylene 0.1, Silane coupling agent KH550 0.02, clorafin 421, propylene glycol fatty acid ester 2, deionized water 15, preparation method is: first by wilkinite high-temperature calcination 3h at 600-650 DEG C, 300 order powders are ground to form after cooling, powder mixes with Silane coupling agent KH550, after ball milling 15min, with water glass, polyoxyethylene adds in deionized water together, 25min is stirred with 600 revs/min of rotating speeds, subsequently spraying dry is carried out to solution, the powder obtained mixes with other leftover materials, be heated to 50 DEG C, continue to stir 50min, stir end and be cooled to room temperature, obtain slurry.
The environmental protection wire drawing liquid of described a kind of high cleaning performance, its preparation technology is:
(1) first deionized water is heated to 50-60 DEG C, add sodium alkyl benzene sulfonate, polyvinyl alcohol, be stirred well to it and dissolve dispersion completely, then add myo-Inositol hexaphosphate, Sulfothiorine, Sunmorl N 60S, continue to be stirred to mixture to dissolve completely, mixing solutions insulation is for subsequent use;
(2) butter, trimethylolpropane tris oleic acid ester, sulfonated castor oil are mixed and heated to 50-60 DEG C, and stir with the rotating speed of 1500 revs/min, slowly add step (1) gained material and other remaining component, after stirring 50min, standing 3h gets product simultaneously.
Wire drawing liquid of the present invention can store more than at least 15 months at normal temperatures, and change more than liquid cycle stretch-out to 10 month, not easily break during wire drawing, the bright and clean no marking of wire surface, cone pulley cabling is unobstructed, and its concrete test performance index is as follows:
Project Index
Kinematic viscosity (50 DEG C) ≤100mm 2/s
Condensation point ≤-5℃
PH value 8.1
Emulsion corrosion (55 ± 2) DEG C, full leaching copper sheet 1h Qualified
Emulsion stability (15-35 DEG C) 1h Without layering, without precipitation, separate out without soap, oil
Defoaming (55 ± 2 DEG C, 5min) ≤2mL

Claims (2)

1. the environmental protection wire drawing liquid of a high cleaning performance, it is characterized in that, this wire drawing liquid is made up of the raw material of following weight part: butter 10-12, trimethylolpropane tris oleic acid ester 28-30, sulfonated castor oil 6-8, myo-Inositol hexaphosphate 2-3, Sulfothiorine 1-2, Sunmorl N 60S 1-3, sodium alkyl benzene sulfonate 2-3, polyvinyl alcohol 10-12, polyoxyethylene polyoxypropylene monobutyl ether 1-2, auxiliary agent 4-5, deionized water 800-1000;
Described auxiliary agent is made up of the raw material of following weight part: isooctyl oleate 10-12, wilkinite 2-3, stearylamide 4-5, water glass 0.05-0.1, polyoxyethylene 0.1-0.2, Silane coupling agent KH550 0.01-0.02, clorafin 421-2, propylene glycol fatty acid ester 1-2, deionized water 12-15, preparation method is: first by wilkinite high-temperature calcination 2-3h at 600-650 DEG C, 300 order powders are ground to form after cooling, powder mixes with Silane coupling agent KH550, after ball milling 10-15min, with water glass, polyoxyethylene adds in deionized water together, 20-30min is stirred with 500-600 rev/min of rotating speed, subsequently spraying dry is carried out to solution, the powder obtained mixes with other leftover materials, be heated to 40-50 DEG C, continue to stir 40-50min, stir end and be cooled to room temperature, obtain slurry.
2. the environmental protection wire drawing liquid of a kind of high cleaning performance as claimed in claim 1, its preparation technology is as follows:
(1) first deionized water is heated to 50-60 DEG C, add sodium alkyl benzene sulfonate, polyvinyl alcohol, be stirred well to it and dissolve dispersion completely, then add myo-Inositol hexaphosphate, Sulfothiorine, Sunmorl N 60S, continue to be stirred to mixture to dissolve completely, mixing solutions insulation is for subsequent use;
(2) butter, trimethylolpropane tris oleic acid ester, sulfonated castor oil are mixed and heated to 50-60 DEG C, and stir with the rotating speed of 1200-1500 rev/min, slowly add step (1) gained material and other remaining component, after stirring 40-50min, standing 2-3h gets product simultaneously.
CN201410122511.0A 2014-03-28 2014-03-28 A kind of environmental protection wire drawing liquid of high cleaning performance Active CN103952219B (en)

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Publication number Priority date Publication date Assignee Title
CN104531372A (en) * 2014-12-22 2015-04-22 珠海市澜诺新材料科技有限公司 Anhydrous vehicle-cleaning composition and preparation method thereof
CN111979031A (en) * 2020-09-17 2020-11-24 苏州英忆新材料有限公司 Water-based environment-friendly titanium alloy wire drawing lubricating liquid and preparation method thereof

Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1746281A (en) * 2004-09-06 2006-03-15 大连广汇化学有限公司 Environmental-protective water-base synthesized cutting fluid
CN103614200A (en) * 2013-10-21 2014-03-05 全威(铜陵)铜业科技有限公司 Copper wire high-speed drawing fluid and preparation method thereof

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Publication number Priority date Publication date Assignee Title
JP6085559B2 (en) * 2011-07-11 2017-02-22 共栄社化学株式会社 Lubricant for belt-shaped dry drawing and method for producing the same

Patent Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1746281A (en) * 2004-09-06 2006-03-15 大连广汇化学有限公司 Environmental-protective water-base synthesized cutting fluid
CN103614200A (en) * 2013-10-21 2014-03-05 全威(铜陵)铜业科技有限公司 Copper wire high-speed drawing fluid and preparation method thereof

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