CN104046455B - A kind of anti-corrosion, scale-inhibiting magnadure wire drawing liquid - Google Patents
A kind of anti-corrosion, scale-inhibiting magnadure wire drawing liquid Download PDFInfo
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- CN104046455B CN104046455B CN201410122607.7A CN201410122607A CN104046455B CN 104046455 B CN104046455 B CN 104046455B CN 201410122607 A CN201410122607 A CN 201410122607A CN 104046455 B CN104046455 B CN 104046455B
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- stir
- wire drawing
- drawing liquid
- sodium
- deionized water
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- 238000005491 wire drawing Methods 0.000 title claims abstract description 34
- 239000007788 liquid Substances 0.000 title claims abstract description 28
- 238000005260 corrosion Methods 0.000 title claims abstract description 11
- 230000002401 inhibitory effect Effects 0.000 title claims abstract description 11
- DOUMFZQKYFQNTF-WUTVXBCWSA-N (R)-rosmarinic acid Chemical compound C([C@H](C(=O)O)OC(=O)\C=C\C=1C=C(O)C(O)=CC=1)C1=CC=C(O)C(O)=C1 DOUMFZQKYFQNTF-WUTVXBCWSA-N 0.000 claims abstract description 18
- 239000008367 deionised water Substances 0.000 claims abstract description 13
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Chemical compound O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 13
- 239000012188 paraffin wax Substances 0.000 claims abstract description 10
- -1 polyoxyethylene Polymers 0.000 claims abstract description 10
- 235000002991 Coptis groenlandica Nutrition 0.000 claims abstract description 9
- 150000004676 glycans Polymers 0.000 claims abstract description 9
- 229920001282 polysaccharide Polymers 0.000 claims abstract description 9
- 239000005017 polysaccharide Substances 0.000 claims abstract description 9
- 150000004804 polysaccharides Polymers 0.000 claims abstract description 9
- MAVFMKWHKMBKDF-UHFFFAOYSA-N 2-amino-2-(hydroxymethyl)propane-1,3-diol;2-ethyl-2-(hydroxymethyl)propane-1,3-diol Chemical compound OCC(N)(CO)CO.CCC(CO)(CO)CO MAVFMKWHKMBKDF-UHFFFAOYSA-N 0.000 claims abstract description 8
- 229940049964 Oleate Drugs 0.000 claims abstract description 8
- ZQPPMHVWECSIRJ-KTKRTIGZSA-M oleate Chemical compound CCCCCCCC\C=C/CCCCCCCC([O-])=O ZQPPMHVWECSIRJ-KTKRTIGZSA-M 0.000 claims abstract description 8
- BMOKHTQIBPRXSL-UHFFFAOYSA-N 2H-benzotriazole;sodium Chemical compound [Na].C1=CC=CC2=NNN=C21 BMOKHTQIBPRXSL-UHFFFAOYSA-N 0.000 claims abstract description 7
- GNSKLFRGEWLPPA-UHFFFAOYSA-M Monopotassium phosphate Chemical compound [K+].OP(O)([O-])=O GNSKLFRGEWLPPA-UHFFFAOYSA-M 0.000 claims abstract description 7
- 229920003171 Poly (ethylene oxide) Polymers 0.000 claims abstract description 7
- 229940005581 Sodium Lactate Drugs 0.000 claims abstract description 7
- NGSFWBMYFKHRBD-UHFFFAOYSA-M Sodium lactate Chemical compound [Na+].CC(O)C([O-])=O NGSFWBMYFKHRBD-UHFFFAOYSA-M 0.000 claims abstract description 7
- 239000003795 chemical substances by application Substances 0.000 claims abstract description 7
- 150000002148 esters Chemical class 0.000 claims abstract description 7
- POULHZVOKOAJMA-UHFFFAOYSA-M laurate Chemical compound CCCCCCCCCCCC([O-])=O POULHZVOKOAJMA-UHFFFAOYSA-M 0.000 claims abstract description 7
- 229940070765 laurate Drugs 0.000 claims abstract description 7
- 229910000402 monopotassium phosphate Inorganic materials 0.000 claims abstract description 7
- 235000019796 monopotassium phosphate Nutrition 0.000 claims abstract description 7
- 239000002994 raw material Substances 0.000 claims abstract description 7
- 239000001540 sodium lactate Substances 0.000 claims abstract description 7
- 235000011088 sodium lactate Nutrition 0.000 claims abstract description 7
- 238000005987 sulfurization reaction Methods 0.000 claims abstract description 7
- 229940043253 Butylated Hydroxyanisole Drugs 0.000 claims abstract description 4
- 239000004255 Butylated hydroxyanisole Substances 0.000 claims abstract description 4
- CZBZUDVBLSSABA-UHFFFAOYSA-N Butylated hydroxyanisole Chemical compound COC1=CC=C(O)C(C(C)(C)C)=C1.COC1=CC=C(O)C=C1C(C)(C)C CZBZUDVBLSSABA-UHFFFAOYSA-N 0.000 claims abstract description 4
- 235000019282 butylated hydroxyanisole Nutrition 0.000 claims abstract description 4
- 238000003756 stirring Methods 0.000 claims description 27
- 239000000463 material Substances 0.000 claims description 14
- 239000000843 powder Substances 0.000 claims description 9
- 244000247747 Coptis groenlandica Species 0.000 claims description 7
- 238000002360 preparation method Methods 0.000 claims description 7
- 239000006087 Silane Coupling Agent Substances 0.000 claims description 6
- NNMHYFLPFNGQFZ-UHFFFAOYSA-M Sodium polyacrylate Chemical compound [Na+].[O-]C(=O)C=C NNMHYFLPFNGQFZ-UHFFFAOYSA-M 0.000 claims description 6
- 238000005516 engineering process Methods 0.000 claims description 6
- 235000021190 leftovers Nutrition 0.000 claims description 6
- 229920001495 poly(sodium acrylate) polymer Polymers 0.000 claims description 6
- 229910052903 pyrophyllite Inorganic materials 0.000 claims description 6
- 239000001488 sodium phosphate Substances 0.000 claims description 6
- 229910000162 sodium phosphate Inorganic materials 0.000 claims description 6
- 239000000243 solution Substances 0.000 claims description 5
- 238000001816 cooling Methods 0.000 claims description 4
- HPSUPGAVFFFPMQ-UHFFFAOYSA-N 1,2,3,4,6,7,10-heptachlorododecane Chemical compound CCC(Cl)CCC(Cl)C(Cl)CC(Cl)C(Cl)C(Cl)CCl HPSUPGAVFFFPMQ-UHFFFAOYSA-N 0.000 claims description 3
- 238000000498 ball milling Methods 0.000 claims description 3
- 235000014113 dietary fatty acids Nutrition 0.000 claims description 3
- 239000006185 dispersion Substances 0.000 claims description 3
- 239000000194 fatty acid Substances 0.000 claims description 3
- 238000003837 high-temperature calcination Methods 0.000 claims description 3
- 238000009413 insulation Methods 0.000 claims description 3
- 239000011259 mixed solution Substances 0.000 claims description 3
- 239000002002 slurry Substances 0.000 claims description 3
- 235000012424 soybean oil Nutrition 0.000 claims description 3
- 239000003549 soybean oil Substances 0.000 claims description 3
- RYFMWSXOAZQYPI-UHFFFAOYSA-K trisodium phosphate Chemical compound [Na+].[Na+].[Na+].[O-]P([O-])([O-])=O RYFMWSXOAZQYPI-UHFFFAOYSA-K 0.000 claims description 3
- 230000000694 effects Effects 0.000 abstract description 8
- 229910052751 metal Inorganic materials 0.000 abstract description 6
- 239000002184 metal Substances 0.000 abstract description 6
- 230000000844 anti-bacterial Effects 0.000 abstract description 4
- 150000002500 ions Chemical class 0.000 abstract description 4
- 230000003647 oxidation Effects 0.000 abstract description 4
- 238000007254 oxidation reaction Methods 0.000 abstract description 4
- 239000003921 oil Substances 0.000 abstract description 3
- 239000002199 base oil Substances 0.000 abstract description 2
- 230000000536 complexating Effects 0.000 abstract description 2
- 230000001050 lubricating Effects 0.000 abstract description 2
- 241000218202 Coptis Species 0.000 abstract 2
- 238000000034 method Methods 0.000 description 5
- 238000004140 cleaning Methods 0.000 description 3
- 239000000839 emulsion Substances 0.000 description 3
- RYGMFSIKBFXOCR-UHFFFAOYSA-N copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 description 2
- 229910052802 copper Inorganic materials 0.000 description 2
- 239000010949 copper Substances 0.000 description 2
- 239000000203 mixture Substances 0.000 description 2
- 235000019198 oils Nutrition 0.000 description 2
- 241000894006 Bacteria Species 0.000 description 1
- 239000000654 additive Substances 0.000 description 1
- 230000000996 additive Effects 0.000 description 1
- 230000000240 adjuvant Effects 0.000 description 1
- 239000002671 adjuvant Substances 0.000 description 1
- 239000004411 aluminium Substances 0.000 description 1
- 229910052782 aluminium Inorganic materials 0.000 description 1
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminum Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 1
- 239000003899 bactericide agent Substances 0.000 description 1
- 230000000975 bioactive Effects 0.000 description 1
- 238000009833 condensation Methods 0.000 description 1
- 230000005494 condensation Effects 0.000 description 1
- 238000005265 energy consumption Methods 0.000 description 1
- 238000005555 metalworking Methods 0.000 description 1
- 230000003000 nontoxic Effects 0.000 description 1
- 231100000252 nontoxic Toxicity 0.000 description 1
- 150000007965 phenolic acids Chemical class 0.000 description 1
- 238000001556 precipitation Methods 0.000 description 1
- 238000003672 processing method Methods 0.000 description 1
- 238000004062 sedimentation Methods 0.000 description 1
- 239000000344 soap Substances 0.000 description 1
- PVGBHEUCHKGFQP-UHFFFAOYSA-N sodium;N-[5-amino-2-(4-aminophenyl)sulfonylphenyl]sulfonylacetamide Chemical compound [Na+].CC(=O)NS(=O)(=O)C1=CC(N)=CC=C1S(=O)(=O)C1=CC=C(N)C=C1 PVGBHEUCHKGFQP-UHFFFAOYSA-N 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
Abstract
The present invention relates to a kind of wire drawing liquid, be specifically related to a kind of anti-corrosion, scale-inhibiting magnadure wire drawing liquid, wire drawing liquid of the present invention is made up of the raw material of following weight portion: rilanit special 28-32, benzotriazole sodium 2-3, algal polysaccharides 2-3, trimethylolpropane tris oleate 15-18, butylated hydroxy anisole 4-6, sodium lactate 2-3, coptis extract 1-2, potassium dihydrogen phosphate 1-2, laurate polyoxyethylene ester 6-8, Rosmarinic acid 1-2, sulfuration paraffin 2-3, auxiliary agent 4-5, deionized water 800-1000; The base oil of wire drawing liquid of the present invention has good high temperature lubricating, add algal polysaccharides can effectively slow down Oxidation of Fat and Oils, can also with complexing of metal ion, avoid Integrated Chip on mould, coptis extract, Rosmarinic acid are the bioactivators of two class natural environmental-protectives, have antibacterial anticorrosion, oxidation resistant effect, wire drawing liquid wire-drawing effect of the present invention is good, wire surface no marking, and peace and quiet power is high, mould is difficult for incrustation, under normal temperature, be difficult for putrid and deteriorated, long service life.
Description
Technical field
The present invention relates to a kind of wire drawing liquid, be specifically related to a kind of anti-corrosion, scale-inhibiting magnadure wire drawing liquid and preparation technology thereof.
Background technology
Drawing process is a kind of metal working process, refer to that metal wire rod passes through mould under pressure by force, obtain the technology processing method of desired sectional area shape and size, wire drawing liquid is requisite adjuvant in drawing process, its main effect is at multiple copper wire, in the multiple wire rod of aluminium wire, draw, little drawing, finely the wire drawing such as draw, lubricate in bracing wire technical process, have protection wire rod concurrently, mould, reach good wire-drawing effect, the quality of wire drawing liquid directly has influence on wire-drawing effect, the wire drawing liquid of function admirable can well be protected mould, reduce wire rod broken end, die wear phenomenon, have concurrently antirust, cooling, the effects such as cleaning, otherwise, can have a strong impact on wire drawing quality, along with the application of drawing process is extensive gradually, market is more and more higher to the quality demand of wire drawing liquid, existing wire drawing liquid mainly exists that stability of emulsion is poor, corroding metal wire rod, energy consumption are high, the problem such as easy cleaning not, restricting wire drawing, drawing quality, be badly in need of improving its composition and engineering, make its more high-efficiency environment friendly.
Summary of the invention
The object of the invention is to, a kind of anti-corrosion, scale-inhibiting magnadure wire drawing liquid is provided, to achieve these goals, the technical solution used in the present invention is as follows:
A kind of anti-corrosion, scale-inhibiting magnadure wire drawing liquid, it is characterized in that, material of the present invention is made up of the raw material of following weight portion: rilanit special 28-32, benzotriazole sodium 2-3, algal polysaccharides 2-3, trimethylolpropane tris oleate 15-18, butylated hydroxy anisole 4-6, sodium lactate 2-3, coptis extract 1-2, potassium dihydrogen phosphate 1-2, laurate polyoxyethylene ester 6-8, Rosmarinic acid 1-2, sulfuration paraffin 2-3, auxiliary agent 4-5, deionized water 800-1000;
Described auxiliary agent is made up of the raw material of following weight portion: epoxidized soybean oil 12-15, pyrophyllite 2-3, polyisobutenyl succimide 3-4, sodium phosphate trimer 0.02-0.05, Sodium Polyacrylate 0.1-0.2, Silane coupling agent KH550 0.01-0.02, chlorinated paraffin wax 421-2, polyglyceryl fatty acid ester 1-2, deionized water 12-15, preparation method is: first by pyrophyllite high-temperature calcination 2-3h at 750-800 DEG C, after cooling, grind to form 300 order powders, powder mixes with Silane coupling agent KH550, after ball milling 10-15min, with sodium phosphate trimer, Sodium Polyacrylate adds in deionized water together, stir 20-30min with the rotating speed of 500-600 rev/min, subsequently solution is sprayed dry, the powder obtaining mixes with other leftover materials, be heated to 40-50 DEG C, continue to stir 40-50min, stir and finish to be cooled to room temperature, obtain slurry.
Described a kind of anti-corrosion, scale-inhibiting magnadure wire drawing liquid, its preparation technology is:
(1) first deionized water is heated to 50-60 DEG C, add algal polysaccharides, potassium dihydrogen phosphate, Rosmarinic acid, be stirred well to material and dissolve dispersion completely, then add sodium lactate, laurate polyoxyethylene ester, continue to stir 20-30min, the mixed solution obtaining insulation is for subsequent use;
(2) rilanit special, trimethylolpropane tris oleate are mixed and heated to 50-60 DEG C, add benzotriazole sodium, coptis extract, sulfuration paraffin, stir 20-30min with the rotating speed of 1200-1500 rev/min, continue subsequently to stir on one side, slowly add step (1) gained material on one side, stir 40-50min, finally add other leftover materials, stir 20-30min, stir and finish rear standing 2-3h, get product.
Wire drawing liquid advantage prepared by the present invention is: mix as base oil using rilanit special, trimethylolpropane tris oleate, there is good high temperature lubricating, algal polysaccharides is that a class has bioactive material, can effectively slow down Oxidation of Fat and Oils, can also with complexing of metal ion, metal ion in can enrichment solution, thus metal ion sedimentation accelerated, avoid Integrated Chip on mould; Reach scale inhibition effect; In the coptis extract adding, contain the antibacterial substance of multiple high-efficiency broad spectrum, can slow down the corruption of bacterium to wire drawing liquid, it is a kind of bactericide of inexpensive efficient Nantural non-toxic, in addition Rosmarinic acid is also the natural multi-functional phenolic acid class of a class, there is antibacterial oxidation resistant effect, again in conjunction with other class additive, make wire drawing liquid of the present invention there is good greasy property, anti-extreme pressure is wear-resisting, the wire surface no marking obtaining, and peace and quiet power is high, and mould is difficult for incrustation, wire drawing liquid is difficult for putrid and deteriorated at normal temperatures, and extended service life.
Detailed description of the invention
Embodiment
The present embodiment wire drawing liquid by following weight portion (kilogram) raw material make: rilanit special 32, benzotriazole sodium 3, algal polysaccharides 2, trimethylolpropane tris oleate 18, butylated hydroxy anisole 6, sodium lactate 3, coptis extract 1, potassium dihydrogen phosphate 2, laurate polyoxyethylene ester 8, Rosmarinic acid 2, sulfuration paraffin 3, auxiliary agent 5, deionized water 1000;
Auxiliary agent is made up of the raw material of following weight portion: epoxidized soybean oil 12, pyrophyllite 3, polyisobutenyl succimide 4, sodium phosphate trimer 0.05, Sodium Polyacrylate 0.1, Silane coupling agent KH550 0.02, chlorinated paraffin wax 422, polyglyceryl fatty acid ester 2, deionized water 15, preparation method is: first by pyrophyllite high-temperature calcination 3h at 750-800 DEG C, after cooling, grind to form 300 order powders, powder mixes with Silane coupling agent KH550, after ball milling 15min, with sodium phosphate trimer, Sodium Polyacrylate adds in deionized water together, stir 30min with the rotating speeds of 600 revs/min, subsequently solution is sprayed dry, the powder obtaining mixes with other leftover materials, be heated to 40-50 DEG C, continue to stir 50min, stir and finish to be cooled to room temperature, obtain slurry.
Described a kind of anti-corrosion, scale-inhibiting magnadure wire drawing liquid, its preparation technology is:
(1) first deionized water is heated to 50-60 DEG C, add algal polysaccharides, potassium dihydrogen phosphate, Rosmarinic acid, be stirred well to material and dissolve dispersion completely, then add sodium lactate, laurate polyoxyethylene ester, continue to stir 30min, the mixed solution obtaining insulation is for subsequent use;
(2) rilanit special, trimethylolpropane tris oleate are mixed and heated to 50-60 DEG C, add benzotriazole sodium, coptis extract, sulfuration paraffin, stir 30min with the rotating speeds of 1500 revs/min, continue subsequently to stir on one side, slowly add step (1) gained material on one side, stir 50min, finally add other leftover materials, stir 200min, stir and finish rear standing 3h, get product.
Wire drawing liquid of the present invention can be stored more than at least 18 months at normal temperatures, more than changing liquid cycle stretch-out to 10 month, is difficult for broken string when wire drawing, the bright and clean no marking of wire surface, and cone pulley cabling is unobstructed, and its concrete test performance index is as follows:
| Project | Index |
| Kinematic viscosity (50 DEG C) | ≤100mm2/s |
| Condensation point | ≤-5℃ |
| PH value | 8.7 |
| Emulsion corrosion (55 ± 2) DEG C, soaks copper sheet 1h entirely | Qualified |
| Emulsion stability (15-35 DEG C) 1h | Without layering, without precipitation, separate out without soap, oil |
| Defoaming (55 ± 2 DEG C, 5min) | ≤2mL |
Claims (2)
1. an anti-corrosion, scale-inhibiting magnadure wire drawing liquid, it is characterized in that, this wire drawing liquid is made up of the raw material of following weight portion: rilanit special 28-32, benzotriazole sodium 2-3, algal polysaccharides 2-3, trimethylolpropane tris oleate 15-18, butylated hydroxy anisole 4-6, sodium lactate 2-3, coptis extract 1-2, potassium dihydrogen phosphate 1-2, laurate polyoxyethylene ester 6-8, Rosmarinic acid 1-2, sulfuration paraffin 2-3, auxiliary agent 4-5, deionized water 800-1000;
Described auxiliary agent is made up of the raw material of following weight portion: epoxidized soybean oil 12-15, pyrophyllite 2-3, polyisobutenyl succimide 3-4, sodium phosphate trimer 0.02-0.05, Sodium Polyacrylate 0.1-0.2, Silane coupling agent KH550 0.01-0.02, chlorinated paraffin wax 421-2, polyglyceryl fatty acid ester 1-2, deionized water 12-15, preparation method is: first by pyrophyllite high-temperature calcination 2-3h at 750-800 DEG C, after cooling, grind to form 300 order powders, powder mixes with Silane coupling agent KH550, after ball milling 10-15min, with sodium phosphate trimer, Sodium Polyacrylate adds in deionized water together, stir 20-30min with the rotating speed of 500-600 rev/min, subsequently solution is sprayed dry, the powder obtaining mixes with other leftover materials, be heated to 40-50 DEG C, continue to stir 40-50min, stir and finish to be cooled to room temperature, obtain slurry.
2. a kind of anti-corrosion, scale-inhibiting magnadure wire drawing liquid as claimed in claim 1, its preparation technology is as follows:
(1) first deionized water is heated to 50-60 DEG C, add algal polysaccharides, potassium dihydrogen phosphate, Rosmarinic acid, be stirred well to material and dissolve dispersion completely, then add sodium lactate, laurate polyoxyethylene ester, continue to stir 20-30min, the mixed solution obtaining insulation is for subsequent use;
(2) rilanit special, trimethylolpropane tris oleate are mixed and heated to 50-60 DEG C, add benzotriazole sodium, coptis extract, sulfuration paraffin, stir 20-30min with the rotating speed of 1200-1500 rev/min, continue subsequently to stir on one side, slowly add step (1) gained material on one side, stir 40-50min, finally add other leftover materials, stir 20-30min, stir and finish rear standing 2-3h, get product.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201410122607.7A CN104046455B (en) | 2014-03-28 | 2014-03-28 | A kind of anti-corrosion, scale-inhibiting magnadure wire drawing liquid |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201410122607.7A CN104046455B (en) | 2014-03-28 | 2014-03-28 | A kind of anti-corrosion, scale-inhibiting magnadure wire drawing liquid |
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| Publication Number | Publication Date |
|---|---|
| CN104046455A CN104046455A (en) | 2014-09-17 |
| CN104046455B true CN104046455B (en) | 2016-05-18 |
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| CN201410122607.7A Active CN104046455B (en) | 2014-03-28 | 2014-03-28 | A kind of anti-corrosion, scale-inhibiting magnadure wire drawing liquid |
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| Publication number | Priority date | Publication date | Assignee | Title |
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| CN104528960B (en) * | 2014-12-24 | 2016-07-06 | 安徽协诚实业股份有限公司 | A kind of high efficiency corrosion inhibiting scale retardant |
| CN105001966B (en) * | 2015-06-24 | 2017-09-08 | 安阳师范学院 | A kind of aluminium and aluminum alloy cutting fluid |
Citations (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102925266A (en) * | 2012-11-13 | 2013-02-13 | 南宁飞日润滑科技有限公司 | Multipurpose aluminum-magnesium drawing oil and production method thereof |
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- 2014-03-28 CN CN201410122607.7A patent/CN104046455B/en active Active
Patent Citations (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102925266A (en) * | 2012-11-13 | 2013-02-13 | 南宁飞日润滑科技有限公司 | Multipurpose aluminum-magnesium drawing oil and production method thereof |
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