CN104046454B - A kind of low bubble high-efficient aluminium alloy wire drawing liquid - Google Patents

Abstract

The present invention relates to a kind of wire drawing liquid, be specifically related to a kind of low bubble high-efficient aluminium alloy wire drawing liquid, wire drawing liquid of the present invention is made up of the raw material of following weight part: soybean oil 30-32, epoxy aliphatic acid methyl ester 10-12, neopentyl glycol 8-10, dodecyl benzyl dimethyl ammonium chloride 1-2, alkylphenol polyoxyethylene 4-5, rosemary extract 1-2, linoleic acid dimer 4-5, sulfuration Oleum Gossypii semen 3-5, aluminum stearate 3-4, N.F,USP MANNITOL 1-3, auxiliary agent 4-5, deionized water 800-1000; Wire drawing liquid of the present invention is using aluminum stearate, N.F,USP MANNITOL mixing as defoamer, the composite more traditional defoamer of defoamer of these two kinds of materials is all more superior on cost and use properties, oil based on soybean oil, epoxy aliphatic acid methyl ester mixing again, be equipped with the raw materials such as rosemary extract, linoleic acid dimer, auxiliary agent, wire drawing liquid of the present invention is made to have excellent lubricity, not easy to foaming, emulsion stable performance not easily breakdown of emulsion, environmental protection heatproof, efficient attenuation is high.

Description

A kind of low bubble high-efficient aluminium alloy wire drawing liquid

Technical field

The present invention relates to a kind of wire drawing liquid, be specifically related to a kind of low bubble high-efficient aluminium alloy wire drawing liquid and preparation technology thereof.

Background technology

Drawing process is a kind of metal working process, refer to that metal wire is forced through mould under pressure, the technology working method of the sectional area shape and size required by acquisition, wire drawing liquid is then requisite auxiliary in drawing process, its main effect is at multiple copper wire, draw in the multiple wire rod of aluminium wire, littlely to draw, finely the wire drawing such as to draw, lubricate in bracing wire technological process, have protection wire rod concurrently, mould, reach good wire-drawing effect, the quality of wire drawing liquid directly has influence on wire-drawing effect, the wire drawing liquid of excellent property can well protect mould, reduce wire rod broken end, die wear phenomenon, have concurrently antirust, cooling, the effects such as cleaning, otherwise, then can have a strong impact on wire drawing quality, along with the application of drawing process is extensive gradually, the quality requirements of market to wire drawing liquid is more and more higher, existing wire drawing liquid mainly exists that stability of emulsion difference, corroding metal wire rod, energy consumption are high, the not problem such as easy cleaning, govern wire drawing, drawing quality, be badly in need of improving its composition and engineering, make its more high-efficiency environment friendly.

Summary of the invention

The object of the invention is to, provide a kind of low bubble high-efficient aluminium alloy wire drawing liquid, to control emulsion foam, make wire drawing liquid normally play effect, to achieve these goals, the technical solution used in the present invention is as follows:

A kind of low bubble high-efficient aluminium alloy wire drawing liquid, it is characterized in that, material of the present invention is made up of the raw material of following weight part: soybean oil 30-32, epoxy aliphatic acid methyl ester 10-12, neopentyl glycol 8-10, dodecyl benzyl dimethyl ammonium chloride 1-2, alkylphenol polyoxyethylene 4-5, rosemary extract 1-2, linoleic acid dimer 4-5, sulfuration Oleum Gossypii semen 3-5, aluminum stearate 3-4, N.F,USP MANNITOL 1-3, auxiliary agent 4-5, deionized water 800-1000;

Described auxiliary agent is made up of the raw material of following weight part: epoxy soybean oil 12-15, pyrophyllite 2-3, polyisobutylene succinamide 3-4, tripoly phosphate sodium STPP 0.02-0.05, sodium polyacrylate 0.1-0.2, Silane coupling agent KH550 0.01-0.02, clorafin 421-2, polyglycerol fatty acid ester 1-2, deionized water 12-15, preparation method is: first by pyrophyllite high-temperature calcination 2-3h at 750-800 DEG C, 300 order powders are ground to form after cooling, powder mixes with Silane coupling agent KH550, after ball milling 10-15min, with tripoly phosphate sodium STPP, sodium polyacrylate adds in deionized water together, 20-30min is stirred with the rotating speed of 500-600 rev/min, subsequently spraying dry is carried out to solution, the powder obtained mixes with other leftover materials, be heated to 40-50 DEG C, continue to stir 40-50min, stir end and be cooled to room temperature, obtain slurry.

Described one low bubble high-efficient aluminium alloy wire drawing liquid, its preparation technology is:

(1) first deionized water is heated to 50-60 DEG C, adds dodecyl benzyl dimethyl ammonium chloride, N.F,USP MANNITOL, be stirred well to material and dissolve dispersion completely, then add alkylphenol polyoxyethylene, stir 20-30min, mixing solutions insulation is for subsequent use;

(2) soybean oil, epoxy aliphatic acid methyl ester are mixed and heated to 50-60 DEG C, add rosemary extract, linoleic acid dimer, sulfuration Oleum Gossypii semen, aluminum stearate, 20-30min is stirred with the rotating speed of 1200-1500 rev/min, slowly add step (1) gained material on one side subsequently, while continue to stir 40-50min, finally add other leftover materials, stir 20-30min, stirring terminates rear standing 2-3h, gets product.

Wire drawing liquid advantage prepared by the present invention is: in preparation wire drawing liquid process, there is emulsion problem easy to foaming, foam can make wire drawing liquid lubricity decline, heat radiation not easily cools slowly, metal detritus not free settling, directly have influence on efficient attenuation, the present invention is in order to reduce the whipability of wire drawing liquid, with aluminum stearate, N.F,USP MANNITOL mixing is as defoamer, the composite more traditional defoamer of defoamer of these two kinds of materials is all more superior on cost and use properties, again with soybean oil, oil based on epoxy aliphatic acid methyl ester mixing, be equipped with rosemary extract, linoleic acid dimer, the raw materials such as auxiliary agent, wire drawing liquid of the present invention is made to have excellent lubricity, not easy to foaming, emulsion stable performance not easily breakdown of emulsion, environmental protection heatproof, efficient attenuation is high.

Embodiment

Embodiment

The present embodiment wire drawing liquid is made up of the raw material of following weight part (kilogram): soybean oil 32, epoxy aliphatic acid methyl ester 12, neopentyl glycol 10, dodecyl benzyl dimethyl ammonium chloride 2, alkylphenol polyoxyethylene 5, rosemary extract 1, linoleic acid dimer 5, sulfuration Oleum Gossypii semen 5, aluminum stearate 3, N.F,USP MANNITOL 3, auxiliary agent 5, deionized water 1000;

Auxiliary agent is made up of the raw material of following weight part: epoxy soybean oil 12, pyrophyllite 3, polyisobutylene succinamide 4, tripoly phosphate sodium STPP 0.05, sodium polyacrylate 0.1, Silane coupling agent KH550 0.02, clorafin 422, polyglycerol fatty acid ester 2, deionized water 15, preparation method is: first by pyrophyllite high-temperature calcination 3h at 750-800 DEG C, 300 order powders are ground to form after cooling, powder mixes with Silane coupling agent KH550, after ball milling 15min, with tripoly phosphate sodium STPP, sodium polyacrylate adds in deionized water together, 30min is stirred with the rotating speed of 600 revs/min, subsequently spraying dry is carried out to solution, the powder obtained mixes with other leftover materials, be heated to 40-50 DEG C, continue to stir 50min, stir end and be cooled to room temperature, obtain slurry.

Described one low bubble high-efficient aluminium alloy wire drawing liquid, its preparation technology is:

(1) first deionized water is heated to 50-60 DEG C, adds dodecyl benzyl dimethyl ammonium chloride, N.F,USP MANNITOL, be stirred well to material and dissolve dispersion completely, then add alkylphenol polyoxyethylene, stir 20-30min, mixing solutions insulation is for subsequent use;

(2) soybean oil, epoxy aliphatic acid methyl ester are mixed and heated to 50-60 DEG C, add rosemary extract, linoleic acid dimer, sulfuration Oleum Gossypii semen, aluminum stearate, 20min is stirred with the rotating speed of 1500 revs/min, slowly add step (1) gained material on one side subsequently, while continue to stir 50min, finally add other leftover materials, stir 30min, stirring terminates rear standing 3h, gets product.

Wire drawing liquid of the present invention can store more than at least 16 months at normal temperatures, and change more than liquid cycle stretch-out to 10 month, not easily break during wire drawing, the bright and clean no marking of wire surface, cone pulley cabling is unobstructed, and its concrete test performance index is as follows:

Project	Index
		Kinematic viscosity (50 DEG C)	≤100mm 2/s
Condensation point	≤-5℃
		PH value	8.0
Emulsion corrosion (55 ± 2) DEG C, full leaching copper sheet 1h	Qualified
		Emulsion stability (15-35 DEG C) 1h	Without layering, without precipitation, separate out without soap, oil
Defoaming (55 ± 2 DEG C, 5min)	≤2mL

Claims (2)

1. one kind low bubble high-efficient aluminium alloy wire drawing liquid, it is characterized in that, this wire drawing liquid is made up of the raw material of following weight part: soybean oil 30-32, epoxy aliphatic acid methyl ester 10-12, neopentyl glycol 8-10, dodecyl benzyl dimethyl ammonium chloride 1-2, alkylphenol polyoxyethylene 4-5, rosemary extract 1-2, linoleic acid dimer 4-5, sulfuration Oleum Gossypii semen 3-5, aluminum stearate 3-4, N.F,USP MANNITOL 1-3, auxiliary agent 4-5, deionized water 800-1000;

Described auxiliary agent is made up of the raw material of following weight part: epoxy soybean oil 12-15, pyrophyllite 2-3, polyisobutylene succinamide 3-4, tripoly phosphate sodium STPP 0.02-0.05, sodium polyacrylate 0.1-0.2, Silane coupling agent KH550 0.01-0.02, clorafin 421-2, polyglycerol fatty acid ester 1-2, deionized water 12-15, preparation method is: first by pyrophyllite high-temperature calcination 2-3h at 750-800 DEG C, 300 order powders are ground to form after cooling, powder mixes with Silane coupling agent KH550, after ball milling 10-15min, with tripoly phosphate sodium STPP, sodium polyacrylate adds in deionized water together, 20-30min is stirred with the rotating speed of 500-600 rev/min, subsequently spraying dry is carried out to solution, the powder obtained mixes with other leftover materials, be heated to 40-50 DEG C, continue to stir 40-50min, stir end and be cooled to room temperature, obtain slurry.

2. a kind of low bubble high-efficient aluminium alloy wire drawing liquid as claimed in claim 1, its preparation technology is as follows:

(1) first deionized water is heated to 50-60 DEG C, adds dodecyl benzyl dimethyl ammonium chloride, N.F,USP MANNITOL, be stirred well to material and dissolve dispersion completely, then add alkylphenol polyoxyethylene, stir 20-30min, mixing solutions insulation is for subsequent use;

(2) soybean oil, epoxy aliphatic acid methyl ester are mixed and heated to 50-60 DEG C, add rosemary extract, linoleic acid dimer, sulfuration Oleum Gossypii semen, aluminum stearate, 20-30min is stirred with the rotating speed of 1200-1500 rev/min, slowly add step (1) gained material on one side subsequently, while continue to stir 40-50min, finally add other leftover materials, stir 20-30min, stirring terminates rear standing 2-3h, gets product.