CN103952221B - A kind of microemulsified wire drawing liquid of not easily analysing oily graining - Google Patents
A kind of microemulsified wire drawing liquid of not easily analysing oily graining Download PDFInfo
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- CN103952221B CN103952221B CN201410122773.7A CN201410122773A CN103952221B CN 103952221 B CN103952221 B CN 103952221B CN 201410122773 A CN201410122773 A CN 201410122773A CN 103952221 B CN103952221 B CN 103952221B
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Abstract
The present invention relates to a kind of wire drawing liquid, be specifically related to a kind of microemulsified wire drawing liquid of not easily analysing oily graining, wire drawing liquid of the present invention is made up of the raw material of following weight part: biofuel 25-28, perfluoro polyether oil 20-22, polyvinyl alcohol 6-8, appropriate youngster oil 2-4, Trisodium Citrate 1-2, Sucrose acetoisobutyrate 2-3, polyhexamethylene guanidine 2-3, sodium lauryl sulphate 8-10, potassium tetraborate 2-3, aluminium oleate 4-6, auxiliary agent 4-5, deionized water 800-1000; Wire drawing liquid of the present invention is oil based on biofuel mixes with perfluoro polyether oil, and with the addition of Sucrose acetoisobutyrate, the density of grease can be regulated, prevent missible oil separation phenomenon, then in conjunction with additives such as aluminium oleate, polyhexamethylene guanidine, potassium tetraborates, it is excellent that these materials cooperation effects make wire drawing liquid of the present invention have good lubricity, efficient attenuation is high, and it is rotten not easily to become sour, emulsion can keep steady state for a long time, analyses oily graining phenomenon and is effectively suppressed.
Description
Technical field
The present invention relates to a kind of wire drawing liquid, be specifically related to a kind of the microemulsified wire drawing liquid and the preparation technology thereof that not easily analyse oily graining.
Background technology
Drawing process is a kind of metal working process, refer to that metal wire is forced through mould under pressure, the technology working method of the sectional area shape and size required by acquisition, wire drawing liquid is then requisite auxiliary in drawing process, its main effect is at multiple copper wire, draw in the multiple wire rod of aluminium wire, littlely to draw, finely the wire drawing such as to draw, lubricate in bracing wire technological process, have protection wire rod concurrently, mould, reach good wire-drawing effect, the quality of wire drawing liquid directly has influence on wire-drawing effect, the wire drawing liquid of excellent property can well protect mould, reduce wire rod broken end, die wear phenomenon, have concurrently antirust, cooling, the effects such as cleaning, otherwise, then can have a strong impact on wire drawing quality, along with the application of drawing process is extensive gradually, the quality requirements of market to wire drawing liquid is more and more higher, existing wire drawing liquid mainly exists that stability of emulsion difference, corroding metal wire rod, energy consumption are high, the not problem such as easy cleaning, govern wire drawing, drawing quality, be badly in need of improving its composition and engineering, make its more high-efficiency environment friendly.
Summary of the invention
The object of the invention is to, provide a kind of microemulsified wire drawing liquid of not easily analysing oily graining, to improve the stability of emulsion, to achieve these goals, the technical solution used in the present invention is as follows:
A kind of microemulsified wire drawing liquid of not easily analysing oily graining, it is characterized in that, material of the present invention is made up of the raw material of following weight part: biofuel 25-28, perfluoro polyether oil 20-22, polyvinyl alcohol 6-8, appropriate youngster oil 2-4, Trisodium Citrate 1-2, Sucrose acetoisobutyrate 2-3, polyhexamethylene guanidine 2-3, sodium lauryl sulphate 8-10, potassium tetraborate 2-3, aluminium oleate 4-6, auxiliary agent 4-5, deionized water 800-1000;
Described auxiliary agent is made up of the raw material of following weight part: epoxy soybean oil 12-15, pyrophyllite 2-3, polyisobutylene succinamide 3-4, tripoly phosphate sodium STPP 0.02-0.05, sodium polyacrylate 0.1-0.2, Silane coupling agent KH550 0.01-0.02, clorafin 421-2, polyglycerol fatty acid ester 1-2, deionized water 12-15, preparation method is: first by pyrophyllite high-temperature calcination 2-3h at 750-800 DEG C, 300 order powders are ground to form after cooling, powder mixes with Silane coupling agent KH550, after ball milling 10-15min, with tripoly phosphate sodium STPP, sodium polyacrylate adds in deionized water together, 20-30min is stirred with the rotating speed of 500-600 rev/min, subsequently spraying dry is carried out to solution, the powder obtained mixes with other leftover materials, be heated to 40-50 DEG C, continue to stir 40-50min, stir end and be cooled to room temperature, obtain slurry.
Described a kind of microemulsified wire drawing liquid of not easily analysing oily graining, its preparation technology is:
(1) first deionized water is heated to 50-60 DEG C, add polyvinyl alcohol, Trisodium Citrate, potassium tetraborate, be stirred well to compound and dissolve completely, then add polyhexamethylene guanidine, sodium lauryl sulphate, be stirred to mixture and dissolve dispersion completely, mixing solutions insulation is for subsequent use;
(2) biofuel, perfluoro polyether oil are mixed and heated to 40-50 DEG C, add appropriate youngster oil, Sucrose acetoisobutyrate, aluminium oleate, 20-30min is stirred with the rotating speed of 1200-1500 rev/min, slowly add step (1) gained material on one side subsequently, while continue to stir 40-50min, finally add other remaining component, continue to stir 20-30min, stirring terminates rear standing 2-3h, gets product.
Wire drawing liquid advantage prepared by the present invention is: traditional wire drawing liquid is along with the impact of duration of service and external environment, emulsion can lose steady state gradually, occur analysing oily graining, the phenomenons such as retrogradation, cause lubricity degradation, finally have to change emulsion in advance, the present invention is in order to improve the work-ing life of wire drawing liquid, reduce and analyse oily graining phenomenon, first oil based on biofuel mixes with perfluoro polyether oil, base oil is made to show good temperature resistant capability, in use procedure, temperature influence is little, and Sucrose acetoisobutyrate is with the addition of in base oil, it is a kind of stablizer of excellent property, the density of grease can be regulated, effectively prevent missible oil separation phenomenon, in addition, also containing aluminium oleate in formula, polyhexamethylene guanidine, the additives such as potassium tetraborate, it is excellent that the synergy of these materials makes wire drawing liquid of the present invention have lubricity, efficient attenuation is high, and it is rotten not easily to become sour, emulsion can keep steady state for a long time, analyse oily graining phenomenon to be effectively suppressed.
Embodiment
Embodiment
The present embodiment wire drawing liquid is made up of the raw material of following weight part (kilogram): biofuel 28, perfluoro polyether oil 22, polyvinyl alcohol 6, appropriate youngster's oil 4, Trisodium Citrate 2, Sucrose acetoisobutyrate 2, polyhexamethylene guanidine 3, sodium lauryl sulphate 10, potassium tetraborate 2, aluminium oleate 6, auxiliary agent 5, deionized water 1000;
Auxiliary agent is made up of the raw material of following weight part: epoxy soybean oil 12, pyrophyllite 3, polyisobutylene succinamide 4, tripoly phosphate sodium STPP 0.05, sodium polyacrylate 0.1, Silane coupling agent KH550 0.02, clorafin 422, polyglycerol fatty acid ester 2, deionized water 15, preparation method is: first by pyrophyllite high-temperature calcination 3h at 750-800 DEG C, 300 order powders are ground to form after cooling, powder mixes with Silane coupling agent KH550, after ball milling 15min, with tripoly phosphate sodium STPP, sodium polyacrylate adds in deionized water together, 30min is stirred with the rotating speed of 600 revs/min, subsequently spraying dry is carried out to solution, the powder obtained mixes with other leftover materials, be heated to 40-50 DEG C, continue to stir 50min, stir end and be cooled to room temperature, obtain slurry.
Described a kind of microemulsified wire drawing liquid of not easily analysing oily graining, its preparation technology is:
(1) first deionized water is heated to 50-60 DEG C, add polyvinyl alcohol, Trisodium Citrate, potassium tetraborate, be stirred well to compound and dissolve completely, then add polyhexamethylene guanidine, sodium lauryl sulphate, be stirred to mixture and dissolve dispersion completely, mixing solutions insulation is for subsequent use;
(2) biofuel, perfluoro polyether oil are mixed and heated to 40-50 DEG C, add appropriate youngster oil, Sucrose acetoisobutyrate, aluminium oleate, 20min is stirred with the rotating speed of 1500 revs/min, slowly add step (1) gained material on one side subsequently, while continue to stir 50min, finally add other remaining component, continue to stir 30min, stirring terminates rear standing 3h, gets product.
Wire drawing liquid of the present invention can store more than at least 15 months at normal temperatures, and change more than liquid cycle stretch-out to 10 month, not easily break during wire drawing, the bright and clean no marking of wire surface, cone pulley cabling is unobstructed, and its concrete test performance index is as follows:
| Project | Index |
| Kinematic viscosity (50 DEG C) | ≤100mm 2/s |
| Condensation point | ≤-5℃ |
| PH value | 8.2 |
| Emulsion corrosion (55 ± 2) DEG C, full leaching copper sheet 1h | Qualified |
| Emulsion stability (15-35 DEG C) 1h | Without layering, without precipitation, separate out without soap, oil |
| Defoaming (55 ± 2 DEG C, 5min) | ≤4mL |
Claims (1)
1. not easily analyse the microemulsified wire drawing liquid of oily graining for one kind, it is characterized in that, this wire drawing liquid is made up of the raw material of following weight part: biofuel 25-28, perfluoro polyether oil 20-22, polyvinyl alcohol 6-8, Yatall MA 2-4, Trisodium Citrate 1-2, Sucrose acetoisobutyrate 2-3, polyhexamethylene guanidine 2-3, sodium lauryl sulphate 8-10, potassium tetraborate 2-3, aluminium oleate 4-6, auxiliary agent 4-5, deionized water 800-1000, described auxiliary agent is made up of the raw material of following weight part: epoxy soybean oil 12-15, pyrophyllite 2-3, polyisobutylene succinamide 3-4, tripoly phosphate sodium STPP 0.02-0.05, sodium polyacrylate 0.1-0.2, Silane coupling agent KH550 0.01-0.02, chlorinated paraffin-42 1-2, polyglycerol fatty acid ester 1-2, deionized water 12-15, the preparation method of described auxiliary agent is: first by pyrophyllite high-temperature calcination 2-3h at 750-800 DEG C, 300 order powders are ground to form after cooling, powder mixes with Silane coupling agent KH550, after ball milling 10-15min, with tripoly phosphate sodium STPP, sodium polyacrylate adds in deionized water together, 20-30min is stirred with the rotating speed of 500-600 rev/min, subsequently spraying dry is carried out to solution, the powder obtained mixes with other leftover materials, be heated to 40-50 DEG C, continue to stir 40-50min, stir end and be cooled to room temperature, obtain slurry, described a kind of preparation technology not easily analysing the microemulsified wire drawing liquid of oily graining is as follows:
(1) first deionized water is heated to 50-60 DEG C, add polyvinyl alcohol, Trisodium Citrate, potassium tetraborate, be stirred well to compound and dissolve completely, then add polyhexamethylene guanidine, sodium lauryl sulphate, be stirred to mixture and dissolve dispersion completely, mixing solutions insulation is for subsequent use;
(2) biofuel, perfluoro polyether oil are mixed and heated to 40-50 DEG C, add Yatall MA, Sucrose acetoisobutyrate, aluminium oleate, 20-30min is stirred with the rotating speed of 1200-1500 rev/min, slowly add step (1) gained material on one side subsequently, while continue to stir 40-50min, finally add other remaining component, continue to stir 20-30min, stirring terminates rear standing 2-3h, gets product.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201410122773.7A CN103952221B (en) | 2014-03-28 | 2014-03-28 | A kind of microemulsified wire drawing liquid of not easily analysing oily graining |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201410122773.7A CN103952221B (en) | 2014-03-28 | 2014-03-28 | A kind of microemulsified wire drawing liquid of not easily analysing oily graining |
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| Publication Number | Publication Date |
|---|---|
| CN103952221A CN103952221A (en) | 2014-07-30 |
| CN103952221B true CN103952221B (en) | 2016-01-27 |
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Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101386804A (en) * | 2008-10-11 | 2009-03-18 | 佛山市威奇电工材料有限公司 | Drawing oil special for aluminum wire and production process thereof |
| CN103289806A (en) * | 2013-07-02 | 2013-09-11 | 江苏省海安石油化工厂 | Scratch-proof wire drawing oil |
| CN103614204A (en) * | 2013-10-21 | 2014-03-05 | 全威（铜陵）铜业科技有限公司 | Metal drawing oil and preparation method thereof |
| CN103614222A (en) * | 2013-10-21 | 2014-03-05 | 全威（铜陵）铜业科技有限公司 | Copper drawing oil and preparation method thereof |
-
2014
- 2014-03-28 CN CN201410122773.7A patent/CN103952221B/en active Active
Patent Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101386804A (en) * | 2008-10-11 | 2009-03-18 | 佛山市威奇电工材料有限公司 | Drawing oil special for aluminum wire and production process thereof |
| CN103289806A (en) * | 2013-07-02 | 2013-09-11 | 江苏省海安石油化工厂 | Scratch-proof wire drawing oil |
| CN103614204A (en) * | 2013-10-21 | 2014-03-05 | 全威（铜陵）铜业科技有限公司 | Metal drawing oil and preparation method thereof |
| CN103614222A (en) * | 2013-10-21 | 2014-03-05 | 全威（铜陵）铜业科技有限公司 | Copper drawing oil and preparation method thereof |
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| Publication number | Publication date |
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| CN103952221A (en) | 2014-07-30 |
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Effective date of registration: 20210525 Address after: No.18-91, Gongye Road, South Taihu high tech Industrial Park, Wuxing District, Huzhou City, Zhejiang Province Patentee after: Zhejiang julibao Textile Technology Co., Ltd Address before: 242800 Matang Industrial Park, Dingqiao Town, Qingyang County, Chizhou City, Anhui Province Patentee before: ANHUI WEIMIN MAGNETIC TECHNOLOGY Co.,Ltd. |