CN103952226B - The environment-friendly high-efficiency wire drawing liquid that a kind of viscosity is controlled - Google Patents
The environment-friendly high-efficiency wire drawing liquid that a kind of viscosity is controlled Download PDFInfo
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- CN103952226B CN103952226B CN201410122512.5A CN201410122512A CN103952226B CN 103952226 B CN103952226 B CN 103952226B CN 201410122512 A CN201410122512 A CN 201410122512A CN 103952226 B CN103952226 B CN 103952226B
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Abstract
The present invention relates to a kind of wire drawing liquid, does is be specifically related to the environment-friendly high-efficiency wire drawing liquid that a kind of viscosity is controlled, wire drawing liquid of the present invention made up of the raw material of following weight part: plam oil 20-25, triolein 15-18, Zinic stearas 1-2, oleic acid triethanolamine acid esters 2-3, polyisobutene 1-2, tween 80? 6-8, wilkinite 1-2, polydimethylsiloxane 1-2, auxiliary agent 4-5, deionized water 800-1000; Wire drawing liquid of the present invention realizes the controllable adjustment of wire drawing liquid viscosity by adding the raw material such as polyisobutene, wilkinite, make it in wide temperature range, still can keep suitable viscosity, again in conjunction with other raw material, under wire drawing liquid high temperature prepared by the present invention, lubricity is excellent, and emulsifying property is stable not easy to foaming, can be long time stored, environmental protection low toxicity, wire drawing quality is high, and production energy consumption is low, and wire rod is bright and clean corrosion-resistant.
Description
Technical field
The present invention relates to a kind of wire drawing liquid, be specifically related to the controlled environment-friendly high-efficiency wire drawing liquid of a kind of viscosity and preparation technology thereof.
Background technology
Drawing process is a kind of metal working process, refer to that metal wire is forced through mould under pressure, the technology working method of the sectional area shape and size required by acquisition, wire drawing liquid is then requisite auxiliary in drawing process, its main effect is at multiple copper wire, draw in the multiple wire rod of aluminium wire, littlely to draw, finely the wire drawing such as to draw, lubricate in bracing wire technological process, have protection wire rod concurrently, mould, reach good wire-drawing effect, the quality of wire drawing liquid directly has influence on wire-drawing effect, the wire drawing liquid of excellent property can well protect mould, reduce wire rod broken end, die wear phenomenon, have concurrently antirust, cooling, the effects such as cleaning, otherwise, then can have a strong impact on wire drawing quality, along with the application of drawing process is extensive gradually, the quality requirements of market to wire drawing liquid is more and more higher, existing wire drawing liquid mainly exists that stability of emulsion difference, corroding metal wire rod, energy consumption are high, the not problem such as easy cleaning, govern wire drawing, drawing quality, be badly in need of improving its composition and engineering, make its more high-efficiency environment friendly.
Summary of the invention
The object of the invention is to, provide the environment-friendly high-efficiency wire drawing liquid that a kind of viscosity is controlled, make it stablize in drawing process medium viscosity, improve efficient attenuation, to achieve these goals, the technical solution used in the present invention is as follows:
The environment-friendly high-efficiency wire drawing liquid that a kind of viscosity is controlled, it is characterized in that, material of the present invention is made up of the raw material of following weight part: plam oil 20-25, triolein 15-18, Zinic stearas 1-2, oleic acid triethanolamine acid esters 2-3, polyisobutene 1-2, tween 80 6-8, wilkinite 1-2, polydimethylsiloxane 1-2, auxiliary agent 4-5, deionized water 800-1000;
Described auxiliary agent is made up of the raw material of following weight part: isooctyl oleate 10-12, wilkinite 2-3, stearylamide 4-5, water glass 0.05-0.1, polyoxyethylene 0.1-0.2, Silane coupling agent KH550 0.01-0.02, clorafin 421-2, propylene glycol fatty acid ester 1-2, deionized water 12-15, preparation method is: first by wilkinite high-temperature calcination 2-3h at 600-650 DEG C, 300 order powders are ground to form after cooling, powder mixes with Silane coupling agent KH550, after ball milling 10-15min, with water glass, polyoxyethylene adds in deionized water together, 20-30min is stirred with 500-600 rev/min of rotating speed, subsequently spraying dry is carried out to solution, the powder obtained mixes with other leftover materials, be heated to 40-50 DEG C, continue to stir 40-50min, stir end and be cooled to room temperature, obtain slurry.
The environment-friendly high-efficiency wire drawing liquid that described a kind of viscosity is controlled, its preparation technology is:
(1) first deionized water is heated to 50-60 DEG C, adds tween 80, be stirred well to it and dissolve completely, add wilkinite more subsequently, be stirred to it and be uniformly dispersed completely, solution insulation is for subsequent use;
(2) by plam oil, triolein mixing, be heated to 50-60 DEG C, add polyisobutene, 20-30min is stirred with the rotating speed of 1200-1500 rev/min, add Zinic stearas, oleic acid triethanolamine acid esters subsequently again, continue to stir 25-30min, finally add step (1) gained material and other remaining component, leave standstill 2-3h after stirring 40-50min, get product.
The wire drawing liquid advantage that the present invention prepares is: because drawing process range of temperature is large, the viscosity of wire drawing liquid can change along with the change of temperature, and when temperature is low, viscosity increases, and cause the easy twisted wire of cone pulley, cleaning is poor, and lubricity reduces, when temperature is too high, viscosity reduces, wire drawing liquid and metallic surface not easily film forming, lubricity also decreases, cause wire rod outlet temperature high, affect mold use life-span and quality product, therefore suitable viscosity is kept to be the key keeping oilness and play abrasion resistance, wire drawing liquid of the present invention is oil based on plam oil and triolein mixing, with the addition of polyisobutene simultaneously, the raw materials such as wilkinite, can effectively regulate wire drawing liquid viscosity, make it in wide temperature range, still can keep suitable viscosity, thus ensure that wire drawing quality, again in conjunction with other raw material, wire drawing liquid emulsifying property prepared by the present invention is stablized, not easy to foaming, can be long time stored, under high temperature, lubricity is excellent, wire drawing quality is high, wire rod is bright and clean corrosion-resistant.
Embodiment
Embodiment
The present embodiment wire drawing liquid is made up of the raw material of following weight part (kilogram): plam oil 25, triolein 15, Zinic stearas 2, oleic acid triethanolamine acid esters 3, polyisobutene 1, tween 80 8, wilkinite 2, polydimethylsiloxane 1, auxiliary agent 5, deionized water 1000;
Auxiliary agent is made up of the raw material of following weight part: isooctyl oleate 12, wilkinite 3, stearylamide 5, water glass 0.1, polyoxyethylene 0.1, Silane coupling agent KH550 0.02, clorafin 421, propylene glycol fatty acid ester 2, deionized water 15, preparation method is: first by wilkinite high-temperature calcination 3h at 600-650 DEG C, 300 order powders are ground to form after cooling, powder mixes with Silane coupling agent KH550, after ball milling 15min, with water glass, polyoxyethylene adds in deionized water together, 25min is stirred with 600 revs/min of rotating speeds, subsequently spraying dry is carried out to solution, the powder obtained mixes with other leftover materials, be heated to 50 DEG C, continue to stir 50min, stir end and be cooled to room temperature, obtain slurry.
The environment-friendly high-efficiency wire drawing liquid that described a kind of viscosity is controlled, its preparation technology is:
(1) first deionized water is heated to 50-60 DEG C, adds tween 80, be stirred well to it and dissolve completely, add wilkinite more subsequently, be stirred to it and be uniformly dispersed completely, solution insulation is for subsequent use;
(2) by plam oil, triolein mixing, be heated to 50-60 DEG C, add polyisobutene, 30min is stirred with the rotating speed of 1500 revs/min, add Zinic stearas, oleic acid triethanolamine acid esters subsequently again, continue to stir 30min, finally add step (1) gained material and other remaining component, leave standstill 3h after stirring 40min, get product.
Wire drawing liquid of the present invention can store more than at least 1 year at normal temperatures, and change more than liquid cycle stretch-out to 10 month, not easily break during wire drawing, wire surface is bright and clean without dirt, and cone pulley cabling is unobstructed, and its concrete test performance index is as follows:
| Project | Index |
| Kinematic viscosity (50 DEG C) | ≤80mm 2/s |
| Condensation point | ≤-5℃ |
| PH value | 8.0 |
| Emulsion corrosion (55 ± 2) DEG C, full leaching copper sheet 1h | Qualified |
| Emulsion stability (15-35 DEG C) 1h | Without layering, without precipitation, separate out without soap, oil |
| Defoaming (55 ± 2 DEG C, 5min) | ≤2mL |
Claims (2)
1. the environment-friendly high-efficiency wire drawing liquid that a viscosity is controlled, it is characterized in that, this wire drawing liquid is made up of the raw material of following weight part: plam oil 20-25, triolein 15-18, Zinic stearas 1-2, triethanolamine oleate ester 2-3, polyisobutene 1-2, tween 80 6-8, wilkinite 1-2, polydimethylsiloxane 1-2, auxiliary agent 4-5, deionized water 800-1000, described auxiliary agent is made up of the raw material of following weight part: isooctyl oleate 10-12, wilkinite 2-3, stearylamide 4-5, water glass 0.05-0.1, polyoxyethylene 0.1-0.2, Silane coupling agent KH550 0.01-0.02, clorafin 421-2, propylene glycol fatty acid ester 1-2, deionized water 12-15, preparation method is: first by wilkinite high-temperature calcination 2-3h at 600-650 DEG C, 300 order powders are ground to form after cooling, powder mixes with Silane coupling agent KH550, after ball milling 10-15min, with water glass, polyoxyethylene adds in deionized water together, 20-30min is stirred with 500-600 rev/min of rotating speed, subsequently spraying dry is carried out to solution, the powder obtained mixes with other leftover materials, be heated to 40-50 DEG C, continue to stir 40-50min, stir end and be cooled to room temperature, obtain slurry.
2. the environment-friendly high-efficiency wire drawing liquid that a kind of viscosity as claimed in claim 1 is controlled, its preparation technology is as follows: deionized water is first heated to 50-60 DEG C by (1), adds tween 80, be stirred well to it to dissolve completely, add wilkinite more subsequently, be stirred to it and be uniformly dispersed completely, solution insulation is for subsequent use; (2) by plam oil, triolein mixing, be heated to 50-60 DEG C, add polyisobutene, 20-30min is stirred with the rotating speed of 1200-1500 rev/min, add Zinic stearas, triethanolamine oleate ester subsequently again, continue to stir 25-30min, finally add step (1) gained material and other remaining component, leave standstill 2-3h after stirring 40-50min, get product.
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| Application Number | Priority Date | Filing Date | Title |
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| CN201410122512.5A CN103952226B (en) | 2014-03-28 | 2014-03-28 | The environment-friendly high-efficiency wire drawing liquid that a kind of viscosity is controlled |
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| CN201410122512.5A CN103952226B (en) | 2014-03-28 | 2014-03-28 | The environment-friendly high-efficiency wire drawing liquid that a kind of viscosity is controlled |
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| CN103952226B true CN103952226B (en) | 2016-03-02 |
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| CN104289541A (en) * | 2014-10-30 | 2015-01-21 | 苏州广型模具有限公司 | Wire-drawing die lubricant |
Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101983232A (en) * | 2008-01-30 | 2011-03-02 | 凯密特尔有限责任公司 | Method for coating metal surfaces with a phosphate layer and then with a polymer lubricant layer |
| CN103614223A (en) * | 2013-10-21 | 2014-03-05 | 全威（铜陵）铜业科技有限公司 | Anti-wear drawing fluid and preparation method thereof |
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Patent Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101983232A (en) * | 2008-01-30 | 2011-03-02 | 凯密特尔有限责任公司 | Method for coating metal surfaces with a phosphate layer and then with a polymer lubricant layer |
| CN103614223A (en) * | 2013-10-21 | 2014-03-05 | 全威（铜陵）铜业科技有限公司 | Anti-wear drawing fluid and preparation method thereof |
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