CN108085118A - A kind of environment-friendly metal processing acid lubricant and technique - Google Patents
A kind of environment-friendly metal processing acid lubricant and technique Download PDFInfo
- Publication number
- CN108085118A CN108085118A CN201711401687.XA CN201711401687A CN108085118A CN 108085118 A CN108085118 A CN 108085118A CN 201711401687 A CN201711401687 A CN 201711401687A CN 108085118 A CN108085118 A CN 108085118A
- Authority
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- Prior art keywords
- acid
- environment
- lubricant
- friendly metal
- metal processing
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- 239000002253 acid Substances 0.000 title claims abstract description 52
- 239000000314 lubricant Substances 0.000 title claims abstract description 49
- 229910052751 metal Inorganic materials 0.000 title claims abstract description 38
- 239000002184 metal Substances 0.000 title claims abstract description 38
- 238000000034 method Methods 0.000 title claims abstract description 36
- 238000012545 processing Methods 0.000 title claims abstract description 27
- NBIIXXVUZAFLBC-UHFFFAOYSA-N Phosphoric acid Chemical compound OP(O)(O)=O NBIIXXVUZAFLBC-UHFFFAOYSA-N 0.000 claims abstract description 32
- 239000013556 antirust agent Substances 0.000 claims abstract description 21
- 229910000147 aluminium phosphate Inorganic materials 0.000 claims abstract description 13
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 13
- 239000004094 surface-active agent Substances 0.000 claims abstract description 7
- 239000002994 raw material Substances 0.000 claims abstract description 6
- 235000011007 phosphoric acid Nutrition 0.000 claims description 15
- 125000001931 aliphatic group Chemical group 0.000 claims description 11
- 238000005555 metalworking Methods 0.000 claims description 10
- 239000003921 oil Substances 0.000 claims description 8
- 235000019198 oils Nutrition 0.000 claims description 8
- 150000003839 salts Chemical class 0.000 claims description 8
- 238000005406 washing Methods 0.000 claims description 7
- VEXZGXHMUGYJMC-UHFFFAOYSA-N Hydrochloric acid Chemical compound Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 claims description 6
- IPCSVZSSVZVIGE-UHFFFAOYSA-N hexadecanoic acid Chemical compound CCCCCCCCCCCCCCCC(O)=O IPCSVZSSVZVIGE-UHFFFAOYSA-N 0.000 claims description 6
- 238000005554 pickling Methods 0.000 claims description 6
- 238000003786 synthesis reaction Methods 0.000 claims description 6
- QDCPNGVVOWVKJG-VAWYXSNFSA-N 2-[(e)-dodec-1-enyl]butanedioic acid Chemical compound CCCCCCCCCC\C=C\C(C(O)=O)CC(O)=O QDCPNGVVOWVKJG-VAWYXSNFSA-N 0.000 claims description 5
- 239000003795 chemical substances by application Substances 0.000 claims description 5
- 238000004140 cleaning Methods 0.000 claims description 5
- 229910000403 monosodium phosphate Inorganic materials 0.000 claims description 5
- 235000019799 monosodium phosphate Nutrition 0.000 claims description 5
- 239000002736 nonionic surfactant Substances 0.000 claims description 5
- AJPJDKMHJJGVTQ-UHFFFAOYSA-M sodium dihydrogen phosphate Chemical compound [Na+].OP(O)([O-])=O AJPJDKMHJJGVTQ-UHFFFAOYSA-M 0.000 claims description 5
- 239000008399 tap water Substances 0.000 claims description 5
- 235000020679 tap water Nutrition 0.000 claims description 5
- WWZKQHOCKIZLMA-UHFFFAOYSA-N octanoic acid Chemical compound CCCCCCCC(O)=O WWZKQHOCKIZLMA-UHFFFAOYSA-N 0.000 claims description 4
- 238000012805 post-processing Methods 0.000 claims description 4
- 239000011684 sodium molybdate Substances 0.000 claims description 4
- 235000015393 sodium molybdate Nutrition 0.000 claims description 4
- TVXXNOYZHKPKGW-UHFFFAOYSA-N sodium molybdate (anhydrous) Chemical compound [Na+].[Na+].[O-][Mo]([O-])(=O)=O TVXXNOYZHKPKGW-UHFFFAOYSA-N 0.000 claims description 4
- WRIDQFICGBMAFQ-UHFFFAOYSA-N (E)-8-Octadecenoic acid Natural products CCCCCCCCCC=CCCCCCCC(O)=O WRIDQFICGBMAFQ-UHFFFAOYSA-N 0.000 claims description 3
- LQJBNNIYVWPHFW-UHFFFAOYSA-N 20:1omega9c fatty acid Natural products CCCCCCCCCCC=CCCCCCCCC(O)=O LQJBNNIYVWPHFW-UHFFFAOYSA-N 0.000 claims description 3
- QSBYPNXLFMSGKH-UHFFFAOYSA-N 9-Heptadecensaeure Natural products CCCCCCCC=CCCCCCCCC(O)=O QSBYPNXLFMSGKH-UHFFFAOYSA-N 0.000 claims description 3
- 239000005642 Oleic acid Substances 0.000 claims description 3
- ZQPPMHVWECSIRJ-UHFFFAOYSA-N Oleic acid Natural products CCCCCCCCC=CCCCCCCCC(O)=O ZQPPMHVWECSIRJ-UHFFFAOYSA-N 0.000 claims description 3
- 235000019482 Palm oil Nutrition 0.000 claims description 3
- 235000021314 Palmitic acid Nutrition 0.000 claims description 3
- 235000021355 Stearic acid Nutrition 0.000 claims description 3
- OBETXYAYXDNJHR-UHFFFAOYSA-N alpha-ethylcaproic acid Natural products CCCCC(CC)C(O)=O OBETXYAYXDNJHR-UHFFFAOYSA-N 0.000 claims description 3
- 229910021538 borax Inorganic materials 0.000 claims description 3
- KGBXLFKZBHKPEV-UHFFFAOYSA-N boric acid Chemical compound OB(O)O KGBXLFKZBHKPEV-UHFFFAOYSA-N 0.000 claims description 3
- 239000004327 boric acid Substances 0.000 claims description 3
- 235000010338 boric acid Nutrition 0.000 claims description 3
- 238000005097 cold rolling Methods 0.000 claims description 3
- 235000014113 dietary fatty acids Nutrition 0.000 claims description 3
- 239000000194 fatty acid Substances 0.000 claims description 3
- 229930195729 fatty acid Natural products 0.000 claims description 3
- 150000004665 fatty acids Chemical class 0.000 claims description 3
- QXJSBBXBKPUZAA-UHFFFAOYSA-N isooleic acid Natural products CCCCCCCC=CCCCCCCCCC(O)=O QXJSBBXBKPUZAA-UHFFFAOYSA-N 0.000 claims description 3
- WQEPLUUGTLDZJY-UHFFFAOYSA-N n-Pentadecanoic acid Natural products CCCCCCCCCCCCCCC(O)=O WQEPLUUGTLDZJY-UHFFFAOYSA-N 0.000 claims description 3
- QIQXTHQIDYTFRH-UHFFFAOYSA-N octadecanoic acid Chemical compound CCCCCCCCCCCCCCCCCC(O)=O QIQXTHQIDYTFRH-UHFFFAOYSA-N 0.000 claims description 3
- OQCDKBAXFALNLD-UHFFFAOYSA-N octadecanoic acid Natural products CCCCCCCC(C)CCCCCCCCC(O)=O OQCDKBAXFALNLD-UHFFFAOYSA-N 0.000 claims description 3
- WWZKQHOCKIZLMA-UHFFFAOYSA-M octanoate Chemical compound CCCCCCCC([O-])=O WWZKQHOCKIZLMA-UHFFFAOYSA-M 0.000 claims description 3
- ZQPPMHVWECSIRJ-KTKRTIGZSA-N oleic acid Chemical compound CCCCCCCC\C=C/CCCCCCCC(O)=O ZQPPMHVWECSIRJ-KTKRTIGZSA-N 0.000 claims description 3
- 235000021313 oleic acid Nutrition 0.000 claims description 3
- 239000002540 palm oil Substances 0.000 claims description 3
- 229920000137 polyphosphoric acid Polymers 0.000 claims description 3
- 239000004328 sodium tetraborate Substances 0.000 claims description 3
- 235000010339 sodium tetraborate Nutrition 0.000 claims description 3
- 239000008117 stearic acid Substances 0.000 claims description 3
- RYFMWSXOAZQYPI-UHFFFAOYSA-K trisodium phosphate Chemical compound [Na+].[Na+].[Na+].[O-]P([O-])([O-])=O RYFMWSXOAZQYPI-UHFFFAOYSA-K 0.000 claims description 3
- MFXMOUUKFMDYLM-UHFFFAOYSA-L zinc;dihydrogen phosphate Chemical compound [Zn+2].OP(O)([O-])=O.OP(O)([O-])=O MFXMOUUKFMDYLM-UHFFFAOYSA-L 0.000 claims description 3
- 239000002280 amphoteric surfactant Substances 0.000 claims description 2
- 239000010775 animal oil Substances 0.000 claims description 2
- 235000015112 vegetable and seed oil Nutrition 0.000 claims description 2
- 239000008158 vegetable oil Substances 0.000 claims description 2
- WBYWAXJHAXSJNI-VOTSOKGWSA-M .beta-Phenylacrylic acid Natural products [O-]C(=O)\C=C\C1=CC=CC=C1 WBYWAXJHAXSJNI-VOTSOKGWSA-M 0.000 claims 1
- 239000004215 Carbon black (E152) Substances 0.000 claims 1
- WBYWAXJHAXSJNI-SREVYHEPSA-N Cinnamic acid Chemical compound OC(=O)\C=C/C1=CC=CC=C1 WBYWAXJHAXSJNI-SREVYHEPSA-N 0.000 claims 1
- PEDCQBHIVMGVHV-UHFFFAOYSA-N Glycerine Chemical compound OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 claims 1
- 229930016911 cinnamic acid Natural products 0.000 claims 1
- 235000013985 cinnamic acid Nutrition 0.000 claims 1
- 229930195733 hydrocarbon Natural products 0.000 claims 1
- 125000001183 hydrocarbyl group Chemical class 0.000 claims 1
- WBYWAXJHAXSJNI-UHFFFAOYSA-N methyl p-hydroxycinnamate Natural products OC(=O)C=CC1=CC=CC=C1 WBYWAXJHAXSJNI-UHFFFAOYSA-N 0.000 claims 1
- 239000000470 constituent Substances 0.000 abstract description 6
- 239000000243 solution Substances 0.000 abstract description 5
- 238000005461 lubrication Methods 0.000 abstract description 3
- 239000002351 wastewater Substances 0.000 abstract description 3
- 239000007864 aqueous solution Substances 0.000 abstract description 2
- 230000001804 emulsifying effect Effects 0.000 abstract description 2
- 230000007423 decrease Effects 0.000 abstract 1
- RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 description 4
- 229940051841 polyoxyethylene ether Drugs 0.000 description 4
- 229920000056 polyoxyethylene ether Polymers 0.000 description 4
- 238000006243 chemical reaction Methods 0.000 description 3
- DUIOKRXOKLLURE-UHFFFAOYSA-N 2-octylphenol Chemical compound CCCCCCCCC1=CC=CC=C1O DUIOKRXOKLLURE-UHFFFAOYSA-N 0.000 description 2
- IGFHQQFPSIBGKE-UHFFFAOYSA-N Nonylphenol Natural products CCCCCCCCCC1=CC=C(O)C=C1 IGFHQQFPSIBGKE-UHFFFAOYSA-N 0.000 description 2
- 230000003213 activating effect Effects 0.000 description 2
- 230000003247 decreasing effect Effects 0.000 description 2
- POULHZVOKOAJMA-UHFFFAOYSA-N dodecanoic acid Chemical compound CCCCCCCCCCCC(O)=O POULHZVOKOAJMA-UHFFFAOYSA-N 0.000 description 2
- 230000007613 environmental effect Effects 0.000 description 2
- SNQQPOLDUKLAAF-UHFFFAOYSA-N nonylphenol Chemical compound CCCCCCCCCC1=CC=CC=C1O SNQQPOLDUKLAAF-UHFFFAOYSA-N 0.000 description 2
- 125000005473 octanoic acid group Chemical group 0.000 description 2
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 1
- 239000005639 Lauric acid Substances 0.000 description 1
- 241001465754 Metazoa Species 0.000 description 1
- ZOKXTWBITQBERF-UHFFFAOYSA-N Molybdenum Chemical compound [Mo] ZOKXTWBITQBERF-UHFFFAOYSA-N 0.000 description 1
- 229910019142 PO4 Inorganic materials 0.000 description 1
- 239000004743 Polypropylene Substances 0.000 description 1
- 239000004372 Polyvinyl alcohol Substances 0.000 description 1
- KDYFGRWQOYBRFD-UHFFFAOYSA-N Succinic acid Natural products OC(=O)CCC(O)=O KDYFGRWQOYBRFD-UHFFFAOYSA-N 0.000 description 1
- 150000001408 amides Chemical class 0.000 description 1
- 150000001412 amines Chemical class 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- KDYFGRWQOYBRFD-NUQCWPJISA-N butanedioic acid Chemical compound O[14C](=O)CC[14C](O)=O KDYFGRWQOYBRFD-NUQCWPJISA-N 0.000 description 1
- 239000011248 coating agent Substances 0.000 description 1
- 238000000576 coating method Methods 0.000 description 1
- 239000002131 composite material Substances 0.000 description 1
- 239000012530 fluid Substances 0.000 description 1
- PCHJSUWPFVWCPO-UHFFFAOYSA-N gold Chemical compound [Au] PCHJSUWPFVWCPO-UHFFFAOYSA-N 0.000 description 1
- 239000010931 gold Substances 0.000 description 1
- 229910052737 gold Inorganic materials 0.000 description 1
- JEIPFZHSYJVQDO-UHFFFAOYSA-N iron(III) oxide Inorganic materials O=[Fe]O[Fe]=O JEIPFZHSYJVQDO-UHFFFAOYSA-N 0.000 description 1
- 239000010808 liquid waste Substances 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- XONPDZSGENTBNJ-UHFFFAOYSA-N molecular hydrogen;sodium Chemical compound [Na].[H][H] XONPDZSGENTBNJ-UHFFFAOYSA-N 0.000 description 1
- 229910052750 molybdenum Inorganic materials 0.000 description 1
- 239000011733 molybdenum Substances 0.000 description 1
- NBIIXXVUZAFLBC-UHFFFAOYSA-K phosphate Chemical compound [O-]P([O-])([O-])=O NBIIXXVUZAFLBC-UHFFFAOYSA-K 0.000 description 1
- 239000010452 phosphate Substances 0.000 description 1
- -1 polypropylene Polymers 0.000 description 1
- 229920001155 polypropylene Polymers 0.000 description 1
- 229920002451 polyvinyl alcohol Polymers 0.000 description 1
- 238000002360 preparation method Methods 0.000 description 1
- 239000011734 sodium Substances 0.000 description 1
- 229910052708 sodium Inorganic materials 0.000 description 1
- 235000015424 sodium Nutrition 0.000 description 1
- 230000006641 stabilisation Effects 0.000 description 1
- 238000011105 stabilization Methods 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 230000001988 toxicity Effects 0.000 description 1
- 231100000419 toxicity Toxicity 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M173/00—Lubricating compositions containing more than 10% water
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M173/00—Lubricating compositions containing more than 10% water
- C10M173/02—Lubricating compositions containing more than 10% water not containing mineral or fatty oils
-
- C—CHEMISTRY; METALLURGY
- C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
- C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
- C23C22/00—Chemical surface treatment of metallic material by reaction of the surface with a reactive liquid, leaving reaction products of surface material in the coating, e.g. conversion coatings, passivation of metals
- C23C22/05—Chemical surface treatment of metallic material by reaction of the surface with a reactive liquid, leaving reaction products of surface material in the coating, e.g. conversion coatings, passivation of metals using aqueous solutions
- C23C22/06—Chemical surface treatment of metallic material by reaction of the surface with a reactive liquid, leaving reaction products of surface material in the coating, e.g. conversion coatings, passivation of metals using aqueous solutions using aqueous acidic solutions with pH less than 6
- C23C22/07—Chemical surface treatment of metallic material by reaction of the surface with a reactive liquid, leaving reaction products of surface material in the coating, e.g. conversion coatings, passivation of metals using aqueous solutions using aqueous acidic solutions with pH less than 6 containing phosphates
-
- C—CHEMISTRY; METALLURGY
- C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
- C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
- C23C22/00—Chemical surface treatment of metallic material by reaction of the surface with a reactive liquid, leaving reaction products of surface material in the coating, e.g. conversion coatings, passivation of metals
- C23C22/05—Chemical surface treatment of metallic material by reaction of the surface with a reactive liquid, leaving reaction products of surface material in the coating, e.g. conversion coatings, passivation of metals using aqueous solutions
- C23C22/06—Chemical surface treatment of metallic material by reaction of the surface with a reactive liquid, leaving reaction products of surface material in the coating, e.g. conversion coatings, passivation of metals using aqueous solutions using aqueous acidic solutions with pH less than 6
- C23C22/40—Chemical surface treatment of metallic material by reaction of the surface with a reactive liquid, leaving reaction products of surface material in the coating, e.g. conversion coatings, passivation of metals using aqueous solutions using aqueous acidic solutions with pH less than 6 containing molybdates, tungstates or vanadates
- C23C22/42—Chemical surface treatment of metallic material by reaction of the surface with a reactive liquid, leaving reaction products of surface material in the coating, e.g. conversion coatings, passivation of metals using aqueous solutions using aqueous acidic solutions with pH less than 6 containing molybdates, tungstates or vanadates containing also phosphates
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2201/00—Inorganic compounds or elements as ingredients in lubricant compositions
- C10M2201/085—Phosphorus oxides, acids or salts
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
- C10N2010/00—Metal present as such or in compounds
- C10N2010/02—Groups 1 or 11
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
- C10N2010/00—Metal present as such or in compounds
- C10N2010/04—Groups 2 or 12
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
- C10N2030/00—Specified physical or chemical properties which is improved by the additive characterising the lubricating composition, e.g. multifunctional additives
- C10N2030/06—Oiliness; Film-strength; Anti-wear; Resistance to extreme pressure
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
- C10N2040/00—Specified use or application for which the lubricating composition is intended
- C10N2040/20—Metal working
- C10N2040/24—Metal working without essential removal of material, e.g. forming, gorging, drawing, pressing, stamping, rolling or extruding; Punching metal
Landscapes
- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- General Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Mechanical Engineering (AREA)
- Metallurgy (AREA)
- Lubricants (AREA)
Abstract
It is processed the invention discloses a kind of environment-friendly metal and uses acid lubricant, include the raw material of following weight percent：Free phosphoric acid 3 10%, surfactant 10 30%, antirust agent 20 35%, organic lubricant 30 60%, water surplus.The present invention uses a kind of aqueous solution for not only having contained acid phosphating solution, but also can be by organic lubricant emulsifying soln into the constituent of a stable system；Phosphatization and lubrication are combined, to reduce operational sequence, reduce the usage amount of water, while decreases the discharge of waste water, reduces the pollution to environment, there is Social benefit and economic benefit；The present invention can avoid metal from processing surface being caused to form striped, prevent the damage of the mold in drawing process, reduce the friction between metal, while also improve the finish of product.
Description
Technical field
The present invention relates to a kind of technical field of lubricant preparation, are specifically a kind of acid lubricant of environment-friendly metal processing
And technique.
Background technology
, it is necessary to various lubricants in process of metal working（Oil）It is lubricated.Some metal working lubricants
（Oil）It easily damages to human body, environment etc., process-intensive adds the production cost of user.Therefore " environmental protection is green for exploitation
Non-ferrous metal lubricant " has critically important meaning." environment-friendly and green metal working lubricant " refers to have to human body and environment
Good metal working fluid, it is harmless in use, environmentally safe or low stain.
The present invention has also taken into full account intermetallic composite coating while the performance and cost of metal working lubricant is taken into full account
Lubricant is harmless in use, environmentally safe, and convenient for liquid waste processing, reduces technique process.By original
The technique of the pickling-washing-phosphatization-washing-lubrication-post processing come is changed to pickling-washing-lubrication-aftertreatment technology.Reduce
The usage amount of water, while the discharge of waste water is decreased, the pollution to environment is reduced, there is Social benefit and economic benefit.
The content of the invention
It is processed it is an object of the invention to provide a kind of environment-friendly metal and uses acid lubricant and technique, to solve the above-mentioned back of the body
The problem of being proposed in scape technology.
To achieve the above object, the present invention provides following technical solution：
A kind of acid lubricant of environment-friendly metal processing includes the raw material of following weight percent：Free phosphoric acid 3-10%, table
Face activating agent 10-30%, antirust agent 20-35%, organic lubricant 30-60%, water surplus.
As further embodiment of the present invention：The organic lubricant uses oiliness improver.
As further embodiment of the present invention：The oiliness improver for hydrocarbon-type oil, aliphatic acid, natural animal oil, vegetable oil or
The derivative of above-mentioned object.
As further embodiment of the present invention：The aliphatic acid is lauric acid, cocinic acid, stearic acid, palmitic acid, oleic acid
Or palm oil fatty acid.
As further embodiment of the present invention：The antirust agent uses inorganic salts antirust agent or organic synthesis antirust agent.
As further embodiment of the present invention：The inorganic salts antirust agent includes sodium molybdate and boric acid, borax, phosphoric acid
One or more in sodium dihydrogen and tertiary sodium phosphate.
As further embodiment of the present invention：The organic synthesis antirust agent is octanoic acid, dodecenylsuccinic acid, caprylate
One or both of with dodecenylsuccinic acid salt.
As further embodiment of the present invention：The nonionic surfactant is using aliphatic acid polyethenoxy ether, nonyl
Phenol polyethenoxy ether or octyl phenol polyoxyethylene ether.
As further embodiment of the present invention：The free phosphoric acid from orthophosphoric acid, polyphosphoric acids, zinc dihydrogen phosphate and
One or more in sodium dihydrogen phosphate.
A kind of metal working process processed using environment-friendly metal with acid lubricant, is comprised the following steps：（1）Using
Hydrochloric acid carries out technique acid cleaning process, pickling concentration 15-20%, time 35-45 minute；（2）Washing process is carried out using tap water,
Washing 2-3 minutes；（3）At 65-70 DEG C, immerse in the acid lubricant of the environment-friendly metal processing 10-15 minutes；（4）Afterwards
Processing：Cold-drawn process, cold rolling process.
Compared with prior art, the beneficial effects of the invention are as follows：
The present invention uses a kind of aqueous solution for not only having contained acid phosphating solution, but also can be steady into one by organic lubricant emulsifying soln
The constituent of fixed system；Phosphatization and lubrication are combined, to reduce operational sequence, reduce the usage amount of water, simultaneously
The discharge of waste water is decreased, reduces the pollution to environment, there is Social benefit and economic benefit；The present invention can avoid metal from existing
Surface is caused to form striped during processing, prevents the damage of the mold in drawing process, the friction between metal is reduced, while also carries
The high finish of product.
Specific embodiment
The technical solution of this patent is described in more detail With reference to embodiment.
Embodiment 1
A kind of acid lubricant of environment-friendly metal processing includes the raw material of following weight percent：Free phosphoric acid 3%, surface are lived
Property agent 10%, antirust agent 20%, organic lubricant 60%, water surplus.
Embodiment 2
A kind of acid lubricant of environment-friendly metal processing includes the raw material of following weight percent：Free phosphoric acid 10%, surface
Activating agent 20%, antirust agent 35%, organic lubricant 30%, water surplus.
Embodiment 3
A kind of acid lubricant of environment-friendly metal processing includes the raw material of following weight percent：Free phosphoric acid 5%, surface are lived
Property agent 30%, antirust agent 22%, organic lubricant 32%, water surplus.
Embodiment 4
The organic lubricant uses oiliness improver.Preferably, the oiliness improver is hydrocarbon-type oil, aliphatic acid, natural animal are oily, plant
The derivative of oily or above-mentioned object.Preferably, the organic lubricant is oil, aliphatic acid or oil base amine.The oil viscosity should
For 2.4-15 ° of Engler viscosity（At 50 degree）.The aliphatic acid is the aliphatic acid of C12-C18.Preferably, the aliphatic acid is bay
Acid, cocinic acid, stearic acid, palmitic acid, oleic acid or palm oil fatty acid.
Embodiment 5
The antirust agent uses inorganic salts antirust agent or organic synthesis antirust agent.Preferably, the inorganic salts antirust agent includes molybdenum
One or more in sour sodium and boric acid, borax, sodium dihydrogen phosphate and tertiary sodium phosphate.Sodium molybdate can be formed in metal surface
FeMoO4-Fe2O3 passivating films are antirust agent of good performance, and almost without toxicity and to environmental hazard.Above-mentioned substance
It is compounded with sodium molybdate, the rustless property of single dose can be improved.Preferably, the organic synthesis antirust agent is octanoic acid, laurylene
One or both of base succinic acid, caprylate and dodecenylsuccinic acid salt, are compounded with arbitrary proportion.
Embodiment 6
The main function of surfactant is that several constituents in lubricant are emulsified into a stable system.Preferably,
Surfactant can use nonionic surfactant or amphoteric surfactant.Aliphatic acid can be used in nonionic surfactant
Polyoxyethylene ether, nonylphenol polyoxyethylene ether or octyl phenol polyoxyethylene ether.Preferably, surfactant can also use polypropylene
Amide or polyvinyl alcohol are compounded with nonionic surfactant, to increase the stability of solution.
Embodiment 7
Free phosphoric acid is to ensure being normally carried out for phosphating reaction in system；Free phosphoric acid can come from orthophosphoric acid, polyphosphoric acids,
One or more in zinc dihydrogen phosphate and sodium dihydrogen phosphate.Free phosphoric acid is to ensure fully must for metal surface phosphating reaction
Want condition.There is free phosphoric acid, metal surface could form one layer of phosphate film, carry lubricant, form final profit
Slip layer film can avoid metal from processing surface being caused to form striped, prevent the damage of the mold in drawing process, reduce gold
Friction between category improves the finish of product.
Embodiment 8
A kind of metal working process processed using the environment-friendly metal with acid lubricant, is comprised the following steps：（1）Pickling：
Technique acid cleaning process, pickling concentration 15%, 35 minutes time are carried out using hydrochloric acid；（2）Washing：Washing work is carried out using tap water
Skill is washed 2 minutes；（3）Lubrication：At 65 DEG C, immerse in the acid lubricant of the environment-friendly metal processing 10 minutes；（4）Afterwards
Processing：Cold-drawn process, cold rolling process.
Embodiment 9
A kind of metal working process processed using the environment-friendly metal with acid lubricant, is comprised the following steps：（1）Using salt
Acid carries out technique acid cleaning process, pickling concentration 20%, 45 minutes time；（2）Washing process is carried out using tap water, washes 3 points
Clock；（3）At 70 DEG C, immerse in the acid lubricant of the environment-friendly metal processing 15 minutes；（4）Post processing：It is cold-drawn process, cold
Roll process.
Embodiment 10
A kind of metal working process processed using the environment-friendly metal with acid lubricant, is comprised the following steps：（1）Using salt
Acid carries out technique acid cleaning process, pickling concentration 18%, 40 minutes time；（2）Washing process is carried out using tap water, washes 2.5 points
Clock；（3）At 68 DEG C, immerse in the acid lubricant of the environment-friendly metal processing 12 minutes；（4）Post processing：It is cold-drawn process, cold
Roll process.
The present invention operation principle be：Water can be catalyzed and promote the phosphating reaction of metal surface, be fully must in system
Condition is wanted, water will excessively influence the stability of the compositional system, if constituent becomes unstable and have to be separated into showing for two-phase
As it is necessary to adjust the content of water by other components in this constituent, being allowed to normal；When water is higher, then constituent is forced
In must include suitable surfactant, to ensure to form the stabilization of objects system.
The better embodiment of this patent is explained in detail above, but this patent is not limited to above-mentioned embodiment party
Formula, can also be on the premise of this patent objective not be departed from the knowledge that one skilled in the relevant art possesses
Various changes can be made.
Claims (10)
1. the acid lubricant of a kind of environment-friendly metal processing, which is characterized in that include the raw material of following weight percent：It is free
Phosphoric acid 3-10%, surfactant 10-30%, antirust agent 20-35%, organic lubricant 30-60%, water surplus.
2. the acid lubricant of environment-friendly metal processing according to claim 1, which is characterized in that the organic lubricant
Using oiliness improver.
3. the acid lubricant of environment-friendly metal processing according to claim 2, which is characterized in that the oiliness improver is hydrocarbon
Class oil, aliphatic acid, natural animal oil, the derivative of vegetable oil or above-mentioned object.
4. the acid lubricant of environment-friendly metal processing according to claim 3, which is characterized in that the aliphatic acid is the moon
Cinnamic acid, cocinic acid, stearic acid, palmitic acid, oleic acid or palm oil fatty acid.
5. the acid lubricant of environment-friendly metal processing according to claim 1, which is characterized in that the antirust agent uses
Inorganic salts antirust agent or organic synthesis antirust agent.
6. the acid lubricant of environment-friendly metal processing according to claim 5, which is characterized in that the inorganic salts antirust
Agent includes the one or more in sodium molybdate and boric acid, borax, sodium dihydrogen phosphate and tertiary sodium phosphate.
7. the acid lubricant of environment-friendly metal processing according to claim 5, which is characterized in that the organic synthesis is prevented
Agent of becoming rusty is one or both of octanoic acid, dodecenylsuccinic acid, caprylate and dodecenylsuccinic acid salt.
8. the acid lubricant of environment-friendly metal processing according to claim 1, which is characterized in that the surfactant
With nonionic surfactant or amphoteric surfactant.
9. the acid lubricant of environment-friendly metal processing according to claim 1, which is characterized in that the free phosphoric acid
One or more in orthophosphoric acid, polyphosphoric acids, zinc dihydrogen phosphate and sodium dihydrogen phosphate.
10. a kind of metal working process of any acid lubricants of environment-friendly metal processing of usage right requirement 1-9,
It is characterised in that it includes following steps：（1）Technique acid cleaning process, pickling concentration 15-20%, time 35-45 are carried out using hydrochloric acid
Minute；（2）Washing process is carried out using tap water, is washed 2-3 minutes；（3）At 65-70 DEG C, immerse the environment-friendly metal and add
Work is with 10-15 minutes in acid lubricant；（4）Post processing：Cold-drawn process, cold rolling process.
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| CN109251783A (en) * | 2018-08-17 | 2019-01-22 | 宁波市铭宏国光化工有限公司 | A kind of Metalworking fluid |
| CN109513767A (en) * | 2018-11-27 | 2019-03-26 | 宁波市铭宏国光化工有限公司 | A kind of metal wire rod drawing process and wire-drawing equipment |
| CN109628200A (en) * | 2018-12-10 | 2019-04-16 | 江苏恒丰新材料制造有限公司 | A kind of high-strength steel environment-friendly type ROLLING OIL and preparation method thereof |
| CN109679706A (en) * | 2018-12-29 | 2019-04-26 | 南京派诺金属表面处理技术有限公司 | The preparation method of reactive drawing oil |
| CN111909766A (en) * | 2020-07-15 | 2020-11-10 | 浙江机电职业技术学院 | High-fluidity lubricant for metal drawing and application thereof |
| CN112940836A (en) * | 2021-02-09 | 2021-06-11 | 鞍钢股份有限公司 | High-dispersity nano molybdenum disulfide water-based rolling liquid and preparation method thereof |
| CN115651742A (en) * | 2022-10-25 | 2023-01-31 | 常州大学 | Phosphating reaction type diamond wire drawing oil and preparation method and application thereof |
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| CN109513767A (en) * | 2018-11-27 | 2019-03-26 | 宁波市铭宏国光化工有限公司 | A kind of metal wire rod drawing process and wire-drawing equipment |
| CN109628200A (en) * | 2018-12-10 | 2019-04-16 | 江苏恒丰新材料制造有限公司 | A kind of high-strength steel environment-friendly type ROLLING OIL and preparation method thereof |
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| CN111909766B (en) * | 2020-07-15 | 2022-03-15 | 浙江机电职业技术学院 | High-fluidity lubricant for metal drawing and application thereof |
| CN112940836A (en) * | 2021-02-09 | 2021-06-11 | 鞍钢股份有限公司 | High-dispersity nano molybdenum disulfide water-based rolling liquid and preparation method thereof |
| CN115651742A (en) * | 2022-10-25 | 2023-01-31 | 常州大学 | Phosphating reaction type diamond wire drawing oil and preparation method and application thereof |
| CN115651742B (en) * | 2022-10-25 | 2023-11-14 | 常州大学 | Phosphating reaction type diamond wire drawing oil and preparation method and application thereof |
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