CN105733765A - Environment-friendly cleaning-free antirust punching oil - Google Patents
Environment-friendly cleaning-free antirust punching oil Download PDFInfo
- Publication number
- CN105733765A CN105733765A CN201610051063.9A CN201610051063A CN105733765A CN 105733765 A CN105733765 A CN 105733765A CN 201610051063 A CN201610051063 A CN 201610051063A CN 105733765 A CN105733765 A CN 105733765A
- Authority
- CN
- China
- Prior art keywords
- oil
- parts
- antirust
- moistening
- extreme pressure
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M169/00—Lubricating compositions characterised by containing as components a mixture of at least two types of ingredient selected from base-materials, thickeners or additives, covered by the preceding groups, each of these compounds being essential
- C10M169/04—Mixtures of base-materials and additives
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M105/00—Lubricating compositions characterised by the base-material being a non-macromolecular organic compound
- C10M105/02—Well-defined hydrocarbons
- C10M105/04—Well-defined hydrocarbons aliphatic
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M129/00—Lubricating compositions characterised by the additive being an organic non-macromolecular compound containing oxygen
- C10M129/02—Lubricating compositions characterised by the additive being an organic non-macromolecular compound containing oxygen having a carbon chain of less than 30 atoms
- C10M129/68—Esters
- C10M129/74—Esters of polyhydroxy compounds
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M133/00—Lubricating compositions characterised by the additive being an organic non-macromolecular compound containing nitrogen
- C10M133/02—Lubricating compositions characterised by the additive being an organic non-macromolecular compound containing nitrogen having a carbon chain of less than 30 atoms
- C10M133/38—Heterocyclic nitrogen compounds
- C10M133/44—Five-membered ring containing nitrogen and carbon only
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M145/00—Lubricating compositions characterised by the additive being a macromolecular compound containing oxygen
- C10M145/18—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
- C10M145/22—Polyesters
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2203/00—Organic non-macromolecular hydrocarbon compounds and hydrocarbon fractions as ingredients in lubricant compositions
- C10M2203/02—Well-defined aliphatic compounds
- C10M2203/0206—Well-defined aliphatic compounds used as base material
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2207/00—Organic non-macromolecular hydrocarbon compounds containing hydrogen, carbon and oxygen as ingredients in lubricant compositions
- C10M2207/28—Esters
- C10M2207/283—Esters of polyhydroxy compounds
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2209/00—Organic macromolecular compounds containing oxygen as ingredients in lubricant compositions
- C10M2209/10—Macromolecular compoundss obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
- C10M2209/102—Polyesters
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2215/00—Organic non-macromolecular compounds containing nitrogen as ingredients in lubricant compositions
- C10M2215/08—Amides
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2215/00—Organic non-macromolecular compounds containing nitrogen as ingredients in lubricant compositions
- C10M2215/22—Heterocyclic nitrogen compounds
- C10M2215/223—Five-membered rings containing nitrogen and carbon only
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
- C10N2030/00—Specified physical or chemical properties which is improved by the additive characterising the lubricating composition, e.g. multifunctional additives
- C10N2030/06—Oiliness; Film-strength; Anti-wear; Resistance to extreme pressure
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
- C10N2030/00—Specified physical or chemical properties which is improved by the additive characterising the lubricating composition, e.g. multifunctional additives
- C10N2030/12—Inhibition of corrosion, e.g. anti-rust agents or anti-corrosives
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
- C10N2040/00—Specified use or application for which the lubricating composition is intended
- C10N2040/20—Metal working
- C10N2040/24—Metal working without essential removal of material, e.g. forming, gorging, drawing, pressing, stamping, rolling or extruding; Punching metal
Landscapes
- Chemical & Material Sciences (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Chemical Kinetics & Catalysis (AREA)
- General Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Lubricants (AREA)
Abstract
The invention discloses an environment-friendly cleaning-free antirust punching oil which is composed of the following components in parts by mass: 0.5-2 parts of synthetic lubricating extreme pressure additive, 1-2 parts of oily brightening agent, 0.1-1 part of metal passivator, 1-3 parts of vapor phase corrosion inhibitor, 1-3 parts of wetting and emulsifying surfactant and 80-95 parts of refined solvent oil. The synthetic lubricating extreme pressure additive is a synthetic high-polymer ester polymer, and is free of sulfur, phosphorus and chlorine; and the wetting and emulsifying surfactant is a fatty acid ester. The product has the characteristics of environment friendliness and high safety, is convenient to use, does not need cleaning, and has excellent lubricating extreme pressure properties.
Description
[technical field]
The present invention relates to metal forming technical field, particularly relate to antirust punching oil technology of preparing used in Punching Process.
[background technology]
Punch process is to adopt precision die, directly processes close to finished product accuracy or directly processes finished product, and workpiece accuracy is up to micron order, and stamping parts is compared with foundry goods, has thin, even, light, strong feature.For meeting environment protection requirement, reduce the use of chemicals, trended towards reducing fewer and fewerily and cut grinding, therefore along with China's automobile, household electrical appliances, the quick of IT industry increase, the demand of high accuracy stamping parts is grown with each passing day.
At present, commercially available punching oil, its greasy property substantially can meet the instructions for use of user, but generally adopt the light petroleum solvent containing aromatic hydrocarbon, bigger by this light petroleum solvent odor containing aromatic hydrocarbon, the personnel of operator and this material of Long Term Contact are produced pessimal stimulation and impact, there is certain healthy hidden danger, additionally cause press workshop environmental pollution；In addition, common on the market punching oil performance there is also three problems demand solve:
One be product antirust, wet-hot aging performance is poor, the atmospheric exposure test time is short, it is impossible to meet antirust requirement when stamping parts stored for extended periods；
Two is that product is in order to meet the greasy property requirement of punch process, with the addition of as higher in viscosity such as middle long-chain chlorinated paraffin, vulcanizing agents or that adhesiveness is relatively strong and flash-point is higher additive, need to use the organic solvents such as a large amount of halogenated hydrocarbon solvent, aromatic hydrocarbon to be carried out, and these organic solvents can bring secondary pollution, working environment and operator is all very unfavorable；
Three is that in recipe ingredient, major part, containing poisonous and harmful substances such as chlorine, sulfur, heavy metals, is detrimental to health and Environmental security.
Therefore, a kind of lubricity is good, be beneficial to environmental protection, the punching oil of the easy cleaning or No clean that stamping parts can be played longer rust inhibition becomes the important selection that domestic and international punching press industry is paid close attention to, and especially this kind of product is had bigger demand by high-end market especially.
[summary of the invention]
The present invention is directed to case above propose a kind of greasy property good, can the Environmental-protection cleaning-free punching oil of long-acting antirust, this punching oil is big without penetrating odors such as aromatic hydrocarbon, human body and environment have the organic substance of harm, make only with the significantly high synthesis lubrication extreme pressure agent of environmental protection and biological degradability, metal deactivator, solvent-refined oil, the lubrication of this punching oil, the function admirable such as antirust, after punching operation, surface dry, without cleaning, save cost, safety and environmental protection, also has good rust-preventing characteristic.
The antirust punching oil of environmental protection No clean of the present invention, it is characterised in that be made up of according to mass ratio following component:
Synthesis lubrication extreme pressure agent: 0.5～2 part；
Light oiliness improver: 1～2 part；
Metal deactivator: 0.1～1 part；
Vapor phase inhibitor: 1～3 part；
Moistening, oil-in-water type surfactant: 1～3 part；
Solvent-refined oil: 80 parts～95 parts
Wherein synthesis lubrication extreme pressure agent is synthesis macromolecule ester base polymer, not sulfur-bearing, phosphorus, chlorine component, wherein moistening, oil-in-water type surfactant are a kind of fatty acid esters.
This light oiliness improver is monoesters, with monohydric aliphatic alcohols esterification gained such as Palmic acid, lauric acid etc. and lauryl alcohols.
This metal deactivator is liquid methyl benzotriazazole/butanedioic acid derivative.
This vapor phase inhibitor is by N-Oleoylsarcosine, stearic acid etc. and 18-amine. and a kind of organic compound antirust agent with vapor phase corrosion inhibitor performance of reaction.
This moistening, oil-in-water type surfactant are sorbitan fatty acid esters, fatty acid formed with sorbitol anhydride or anhydro sorbitol, have the performance such as moistening, emulsifying, ferrous metal has corrosion protection effect simultaneously.
This solvent-refined oil is free from the isomery dodecane hydrocarbon solvent oil of aromatic hydrocarbon.
Further, the antirust punching oil of this environmental protection No clean, is made up of according to mass ratio following component: the synthesis lubrication extreme pressure agent of 1 part, the bright oiliness improver of 1.5 parts, 0.8 part metal deactivator, 2 parts vapor phase inhibitor, 2 parts moistening, oil-in-water type surfactant, the solvent-refined oil of 85 parts；Wherein synthesis lubrication extreme pressure agent be synthesis macromolecule ester base polymer, not sulfur-bearing, phosphorus, chlorine component, wherein moistening, oil-in-water type surfactant are sorbitan fatty acid esters.
Furthermore, the antirust punching oil of this environmental protection No clean, is made up of according to mass ratio following component: the synthesis lubrication extreme pressure agent of 1.5 parts, the bright oiliness improver of 2 parts, 0.5 part metal deactivator, 2.5 parts vapor phase inhibitor, 1.5 parts moistening, oil-in-water type surfactant, the solvent-refined oil of 90 parts；Wherein synthesis lubrication extreme pressure agent be synthesis macromolecule ester base polymer, not sulfur-bearing, phosphorus, chlorine component, wherein moistening, oil-in-water type surfactant are sorbitan fatty acid esters.
The preparation method that the present invention also provides for the antirust punching oil of a kind of environmental protection No clean, comprises the following steps:
Step one, in mix and blend reactor, in the bottom installation outlet valve of reactor, puts into the solvent-refined oil that mass ratio is 80～95 parts in mix and blend reactor, starts mixing pump；
Step 2, adds other component by following mass ratio respectively:
The synthesis lubrication extreme pressure agent of 0.5～2 part, the bright oiliness improver of 1～2 part, the metal deactivator of 0.1～1 part, the vapor phase inhibitor of 1～3 part.When normal temperature and pressure, by above component circulation stirring 15～20 minutes；
Step 3, takes moistening, the oil-in-water type surfactant of 1～3 part normal temperature and pressure circulation stirring 5～8 minutes, then stands 10～15 minutes.
The antirust punching oil of environmental protection No clean involved in the present invention, prepares out the product with safety and environmental protection by adding pollution-free nonhazardous component, and itself possesses very excellent lubrication extreme pressure property, No clean function and antirust function；By generating oil film at product surface, and this oil film can be evaporated to only trapped fuel film thickness≤0.05 μm in the high temperature of punching course, is fully achieved No clean effect, and the vapor phase inhibitor of interpolation can protect product not easily to get rusty more resistant to stock.
[detailed description of the invention]
Below in conjunction with detailed description of the invention, the present invention is described in further detail.
The preparation method that the invention provides the antirust punching oil of a kind of environmental protection No clean, comprises the following steps:
Step one, in mix and blend reactor, in the bottom installation outlet valve of reactor, puts into the solvent-refined oil that mass ratio is 80～95 parts in mix and blend reactor, starts mixing pump；
This solvent-refined oil is free from the isomery dodecane hydrocarbon solvent oil of aromatic hydrocarbon.
Step 2, adds other component by following mass ratio respectively:
The synthesis lubrication extreme pressure agent of 0.5～2 part, the bright oiliness improver of 1～2 part, the metal deactivator of 0.1～1 part, the vapor phase inhibitor of 1～3 part.When normal temperature and pressure, by above component circulation stirring 15～20 minutes；
Wherein synthesis lubrication extreme pressure agent is synthesis macromolecule ester base polymer, not sulfur-bearing, phosphorus, chlorine component, wherein moistening, oil-in-water type surfactant are a kind of fatty acid esters.
This light oiliness improver is monoesters, with monohydric aliphatic alcohols esterification gained such as Palmic acid, lauric acid etc. and lauryl alcohols.
This metal deactivator is liquid methyl benzotriazazole/butanedioic acid derivative.
This vapor phase inhibitor is by N-Oleoylsarcosine, stearic acid etc. and 18-amine. and a kind of organic compound antirust agent with vapor phase corrosion inhibitor performance of reaction.
Step 3, takes moistening, the oil-in-water type surfactant of 1～3 part normal temperature and pressure circulation stirring 5～8 minutes, then stands 10～15 minutes.
This moistening, oil-in-water type surfactant are sorbitan fatty acid esters, fatty acid formed with sorbitol anhydride or anhydro sorbitol, have the performance such as moistening, emulsifying, ferrous metal has corrosion protection effect simultaneously.
Described synthesis lubrication extreme pressure agent is synthesis macromolecule ester base polymer.Synthesis macromolecule ester base polymer is a kind of polyester, and for very good lubrication extreme pressure anti-wear additives, thick white shape liquid, Ashless type, biological degradation rate reaches more than 99%, and environmental protection is nontoxic.
Described bright oiliness improver is monoesters.Monoesters is with the monohydric aliphatic alcohols esterification gained such as the fat acid such as Palmic acid, lauric acid and lauryl alcohol, colourless shallow taste transparency liquid, the significant property of light of excellence, boundary lubrication and solvability, efficient cleaning efficiency.
Described metal deactivator is liquid methyl benzotriazazole/butanedioic acid derivative.Liquid methyl benzotriazazole/butanedioic acid derivative is light yellow clear liquid, the active metal materials such as copper aluminum zinc-magnesium has the deactivation corrosion inhibition of excellence, carbon steel, cast iron also have good inhibition rust-preventing characteristic.
Described vapor phase inhibitor is by N-Oleoylsarcosine, stearic acid etc. and 18-amine. and a kind of organic compound antirust agent with vapor phase corrosion inhibitor performance of reaction.N-Oleoylsarcosine 18-amine. salt, amber thick liquid, its vapour phase inhibitor volatilized can effectively protect ferrous metal or nonferrous metal product from the impact of corrosive medium.
Described surfactant is sorbitan fatty acid ester.Sorbitan fatty acid ester is a kind of fatty acid and the mixed ester of sorbitol anhydride or anhydro sorbitol, light amber transparency liquid, has the functions such as good hydrotropy, dispersion, cleaning, and iron and steel has certain rust-preventing characteristic.
Described solvent-refined oil is free from the isomery dodecane hydrocarbon solvent oil of aromatic hydrocarbon.Isomery dodecane, is a kind of solvent naphtha with the hydrocarbon structure of side chain, and colorless and odorless transparency liquid, volatility is good, and without aromatic hydrocarbon, biological degradability is excellent, and environmental protection is nontoxic.
Embodiment 1:
In mix and blend reactor, in the bottom installation outlet valve of reactor, the isomery dodecane by 93.3% puts in mix and blend reactor, starts mixing pump；
Be separately added into 0.8% polyester, the monoesters of 1.2%, the liquid methyl benzotriazazole/butanedioic acid derivative of 0.3% and 2.6% N-Oleoylsarcosine 18-amine. salt, normal temperature and pressure circulation stirring 15～20 minutes；
Take sorbitan fatty acid ester the normal temperature and pressure circulation stirring 5～8 minutes of 1.8%, after then standing 10～15 minutes, be catalog 1 of the present invention.
Embodiment 2:
In mix and blend reactor, in the bottom installation outlet valve of reactor, the isomery dodecane by 93.0% puts in mix and blend reactor, starts mixing pump；
Be separately added into 1.2% polyester, the monoesters of 1.8%, the liquid methyl benzotriazazole/butanedioic acid derivative of 0.3% and 2.0% N-Oleoylsarcosine 18-amine. salt, normal temperature and pressure circulation stirring 15～20 minutes；
Take sorbitan fatty acid ester the normal temperature and pressure circulation stirring 5～8 minutes of 1.7%, after then standing 10～15 minutes, be catalog 2 of the present invention.
Embodiment 3:
In mix and blend reactor, in the bottom installation outlet valve of reactor, the isomery dodecane by 93.0% puts in mix and blend reactor, starts mixing pump；
Be separately added into 1.5% polyester, the monoesters of 1.5%, the liquid methyl benzotriazazole/butanedioic acid derivative of 0.3% and 1.3% N-Oleoylsarcosine 18-amine. salt, normal temperature and pressure circulation stirring 15～20 minutes；
Take sorbitan fatty acid ester the normal temperature and pressure circulation stirring 5～8 minutes of 2.4%, after then standing 10～15 minutes, be catalog 3 of the present invention.
By above 3 samples sampling sampling observation, indices is table 1 below such as:
Environmental condition: temperature 20 DEG C, humidity 55%.
Sample situation: sampling.
1: three sample sampling observation value of table and standard value synopsis
The present invention compared with prior art has the advantage that and good effect:
Colourless transparent liquid, it is simple to operation observability, almost tasteless, not chloride, sulfur, heavy metal etc., skin mildness is good, it is ensured that health and Environmental security, environmental protection.Having very active, especially in a heated condition, working surface is dry and comfortable, it is not necessary to clean, and reduces and cleans the correlative charges such as cost, manual operation cost and power cost in a large number.Having the lubrication extreme pressure property of excellence, cooling is excellent, can extend the mold use life-span, it is ensured that the crudy that surface of the work is good, improves good bright property.Stamping parts, mould and cutter had good antirust function, it is simple to the storage of stamping parts long period.
The above, it it is only present pre-ferred embodiments, not the present invention is done any pro forma restriction, although the present invention is disclosed above with preferred embodiment, but it is not limited to the present invention, any those skilled in the art, without departing within the scope of technical solution of the present invention, when the technology contents of available the disclosure above makes a little change or is modified to the Equivalent embodiments of equivalent variations, in every case it is without departing from technical solution of the present invention content, any simple modification that above example is made is referred to according to the technology of the present invention, equivalent variations and modification, belong in the scope of technical solution of the present invention.
Claims (10)
1. the antirust punching oil of an environmental protection No clean, it is characterised in that be made up of according to mass ratio following component:
Synthesis lubrication extreme pressure agent: 0.5～2 part；
Light oiliness improver: 1～2 part；
Metal deactivator: 0.1～1 part；
Vapor phase inhibitor: 1～3 part；
Moistening, oil-in-water type surfactant: 1～3 part；
Solvent-refined oil: 80 parts～95 parts；
Wherein synthesis lubrication extreme pressure agent is synthesis macromolecule ester base polymer, not sulfur-bearing, phosphorus, chlorine component, wherein moistening, oil-in-water type surfactant are a kind of fatty acid esters.
2. the antirust punching oil of environmental protection No clean according to claim 1, it is characterised in that this light oiliness improver is monoesters, with monohydric aliphatic alcohols esterification gained such as Palmic acid, lauric acid etc. and lauryl alcohols.
3. the antirust punching oil of environmental protection No clean according to claim 1, it is characterised in that this metal deactivator is liquid methyl benzotriazazole/butanedioic acid derivative.
4. the antirust punching oil of environmental protection No clean according to claim 1, it is characterised in that this vapor phase inhibitor is by N-Oleoylsarcosine, stearic acid etc. and 18-amine. and a kind of organic compound antirust agent with vapor phase corrosion inhibitor performance of reaction.
5. the antirust punching oil of environmental protection No clean according to claim 1; it is characterized in that; this moistening, oil-in-water type surfactant are sorbitan fatty acid esters; formed with sorbitol anhydride or anhydro sorbitol by fatty acid; there is the performance such as moistening, emulsifying, ferrous metal is had corrosion protection effect simultaneously.
6. the antirust punching oil of environmental protection No clean according to claim 1, it is characterised in that this solvent-refined oil is free from the isomery dodecane hydrocarbon solvent oil of aromatic hydrocarbon.
7. the antirust punching oil of environmental protection No clean according to claim 1, it is characterized in that, be made up of according to mass ratio following component: the synthesis lubrication extreme pressure agent of 1 part, the bright oiliness improver of 1.5 parts, 0.8 part metal deactivator, 2 parts vapor phase inhibitor, 2 parts moistening, oil-in-water type surfactant, the solvent-refined oil of 85 parts；Wherein synthesis lubrication extreme pressure agent be synthesis macromolecule ester base polymer, not sulfur-bearing, phosphorus, chlorine component, wherein moistening, oil-in-water type surfactant are sorbitan fatty acid esters.
8. the antirust punching oil of environmental protection No clean according to claim 1, it is characterized in that, be made up of according to mass ratio following component: the synthesis lubrication extreme pressure agent of 1.5 parts, the bright oiliness improver of 2 parts, 0.5 part metal deactivator, 2.5 parts vapor phase inhibitor, 1.5 parts moistening, oil-in-water type surfactant, the solvent-refined oil of 90 parts；Wherein synthesis lubrication extreme pressure agent be synthesis macromolecule ester base polymer, not sulfur-bearing, phosphorus, chlorine component, wherein moistening, oil-in-water type surfactant are sorbitan fatty acid esters.
9. a preparation method for the antirust punching oil of environmental protection No clean, comprises the following steps:
Step one, in mix and blend reactor, in the bottom installation outlet valve of reactor, puts into the solvent-refined oil that mass ratio is 80～95 parts in mix and blend reactor, starts mixing pump；
Step 2, adds other component by following mass ratio respectively:
The synthesis lubrication extreme pressure agent of 0.5～2 part, the bright oiliness improver of 1～2 part, the metal deactivator of 0.1～1 part, the vapor phase inhibitor of 1～3 part.When normal temperature and pressure, by above component circulation stirring 15-20 minute；
Step 3, takes moistening, the oil-in-water type surfactant of 1～3 part normal temperature and pressure circulation stirring 5-8 minute, then stands 10-15 minute.
10. the preparation method of the antirust punching oil of environmental protection No clean according to claim 9, it is characterised in that comprise the following steps:
Step one, in mix and blend reactor, in the bottom installation outlet valve of reactor, puts into the solvent-refined oil that mass ratio is 85 parts in mix and blend reactor, starts mixing pump；
Step 2, adds other component by following mass ratio respectively:
The synthesis lubrication extreme pressure agent of 1 part, the bright oiliness improver of 1.5 parts, the metal deactivator of 0.5 part, the vapor phase inhibitor of 2 parts.When normal temperature and pressure, by above component circulation stirring 15-20 minute；
Step 3, takes moistening, the oil-in-water type surfactant of 3 parts normal temperature and pressure circulation stirring 5-8 minute, then stands 10～15 minutes；
Wherein synthesis lubrication extreme pressure agent is synthesis macromolecule ester base polymer, not sulfur-bearing, phosphorus, chlorine component, wherein moistening, oil-in-water type surfactant are a kind of fatty acid esters；
This light oiliness improver is monoesters, with monohydric aliphatic alcohols esterification gained such as Palmic acid, lauric acid etc. and lauryl alcohols；
This metal deactivator is liquid methyl benzotriazazole/butanedioic acid derivative；
This vapor phase inhibitor is by N-Oleoylsarcosine, stearic acid etc. and 18-amine. and a kind of organic compound antirust agent with vapor phase corrosion inhibitor performance of reaction；
This moistening, oil-in-water type surfactant are sorbitan fatty acid esters, fatty acid formed with sorbitol anhydride or anhydro sorbitol, have the performance such as moistening, emulsifying, ferrous metal has corrosion protection effect simultaneously；
This solvent-refined oil is free from the isomery dodecane hydrocarbon solvent oil of aromatic hydrocarbon.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201610051063.9A CN105733765A (en) | 2016-01-26 | 2016-01-26 | Environment-friendly cleaning-free antirust punching oil |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201610051063.9A CN105733765A (en) | 2016-01-26 | 2016-01-26 | Environment-friendly cleaning-free antirust punching oil |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN105733765A true CN105733765A (en) | 2016-07-06 |
Family
ID=56246570
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201610051063.9A Pending CN105733765A (en) | 2016-01-26 | 2016-01-26 | Environment-friendly cleaning-free antirust punching oil |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN105733765A (en) |
Cited By (8)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN106190472A (en) * | 2016-07-11 | 2016-12-07 | 沈阳帕卡濑精有限总公司 | A kind of for the stamping forming emulsifiable type punching oil of vehicle body |
| CN106221877A (en) * | 2016-07-26 | 2016-12-14 | 中国石油化工股份有限公司 | Punching oil compositions and purposes |
| CN108018112A (en) * | 2017-12-14 | 2018-05-11 | 诺而曼环保科技（江苏）有限公司 | A kind of tasteless safe volatility punching oil |
| CN108130170A (en) * | 2017-12-14 | 2018-06-08 | 诺而曼环保科技（江苏）有限公司 | A kind of tasteless safe volatile rust preventive oil |
| CN110982597A (en) * | 2019-12-11 | 2020-04-10 | 富兰克润滑科技（太仓）有限公司 | Electronic product stainless steel part cutting oil for improving cooling performance and method |
| CN112175704A (en) * | 2020-10-30 | 2021-01-05 | 苏州德韬科技有限公司 | Ultralong antirust stamping oil for ferrous metal |
| CN112552984A (en) * | 2020-12-11 | 2021-03-26 | 江苏保捷锻压有限公司 | Corrosion-resistant and yellow spot-resistant stable stamping oil |
| CN114276855A (en) * | 2021-12-23 | 2022-04-05 | 东莞市英飞特润滑科技有限公司 | No-clean type drawing oil and production process thereof |
Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102199476A (en) * | 2011-04-29 | 2011-09-28 | 上海德润宝特种润滑剂有限公司 | Volatile stamping cutting oil composite for machining for machining of moderate-thickness aluminum plate and preparation method thereof |
| US20120088704A1 (en) * | 2010-10-08 | 2012-04-12 | Material Engineering and Technical Support Services Corp., dba METSS Corporation | Lubricant and functional fluid additive package, and lubricants and functional fluids containing same |
| CN104694234A (en) * | 2015-03-18 | 2015-06-10 | 启东尤希路化学工业有限公司 | High-performance environmentally-friendly medium- and long-period antirust punching oil |
-
2016
- 2016-01-26 CN CN201610051063.9A patent/CN105733765A/en active Pending
Patent Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US20120088704A1 (en) * | 2010-10-08 | 2012-04-12 | Material Engineering and Technical Support Services Corp., dba METSS Corporation | Lubricant and functional fluid additive package, and lubricants and functional fluids containing same |
| CN102199476A (en) * | 2011-04-29 | 2011-09-28 | 上海德润宝特种润滑剂有限公司 | Volatile stamping cutting oil composite for machining for machining of moderate-thickness aluminum plate and preparation method thereof |
| CN104694234A (en) * | 2015-03-18 | 2015-06-10 | 启东尤希路化学工业有限公司 | High-performance environmentally-friendly medium- and long-period antirust punching oil |
Non-Patent Citations (1)
| Title |
|---|
| 肖学福等: "《车辆装备封存技术》", 30 April 2013, 国防工业出版社 * |
Cited By (8)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN106190472A (en) * | 2016-07-11 | 2016-12-07 | 沈阳帕卡濑精有限总公司 | A kind of for the stamping forming emulsifiable type punching oil of vehicle body |
| CN106221877A (en) * | 2016-07-26 | 2016-12-14 | 中国石油化工股份有限公司 | Punching oil compositions and purposes |
| CN108018112A (en) * | 2017-12-14 | 2018-05-11 | 诺而曼环保科技（江苏）有限公司 | A kind of tasteless safe volatility punching oil |
| CN108130170A (en) * | 2017-12-14 | 2018-06-08 | 诺而曼环保科技（江苏）有限公司 | A kind of tasteless safe volatile rust preventive oil |
| CN110982597A (en) * | 2019-12-11 | 2020-04-10 | 富兰克润滑科技（太仓）有限公司 | Electronic product stainless steel part cutting oil for improving cooling performance and method |
| CN112175704A (en) * | 2020-10-30 | 2021-01-05 | 苏州德韬科技有限公司 | Ultralong antirust stamping oil for ferrous metal |
| CN112552984A (en) * | 2020-12-11 | 2021-03-26 | 江苏保捷锻压有限公司 | Corrosion-resistant and yellow spot-resistant stable stamping oil |
| CN114276855A (en) * | 2021-12-23 | 2022-04-05 | 东莞市英飞特润滑科技有限公司 | No-clean type drawing oil and production process thereof |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN105733765A (en) | Environment-friendly cleaning-free antirust punching oil | |
| Mannekote et al. | Environmentally friendly functional fluids from renewable and sustainable sources-A review | |
| CN102660364B (en) | Non-phosphorus non-silicon aluminum alloy cutting fluid and preparation method thereof | |
| EP2520639A1 (en) | Environmental friendly cutting fluid | |
| CN101016498A (en) | Composition of cold rolling sheet rolling oil | |
| CN107502437B (en) | Semi-synthetic water-soluble cutting fluid for stainless steel and preparation method thereof | |
| US2455659A (en) | Oily composition | |
| EP2928992A1 (en) | Additive compositions and industrial process fluids | |
| CN102559352A (en) | Self-emulsified total synthesis cutting solution | |
| US4215002A (en) | Water-based phosphonate lubricants | |
| MX2011002295A (en) | Emulsifiers for metal working fluids. | |
| CN102559355A (en) | Self-bacteriostasis general emulsion cutting fluid and preparing method thereof | |
| CN104073327A (en) | Emulsified cutting fluid, cutting diluent and preparation and application methods thereof | |
| US20080051613A1 (en) | Lubricants for use in processing of metallic material | |
| WO2008084884A1 (en) | Lubricants for use in processing of metallic material and methods for processing the metallic material using the lubricants | |
| KR930010573B1 (en) | Lubricating oil composiiton for working metal | |
| JP5281007B2 (en) | Aqueous metalworking fluid | |
| CN105567400A (en) | Lubricating oil for automobile | |
| CN106566625B (en) | One vegetable oil base titanium alloy emulsifies working fluid | |
| KR100761557B1 (en) | Water soluble metal working fluids using soybean oil and metal working fluids thereof | |
| US3929656A (en) | Drawing oil | |
| JP6088842B2 (en) | Aqueous metalworking fluid | |
| CN113736544B (en) | Environment-friendly water-soluble stainless steel sheet stamping oil and preparation method thereof | |
| JP2623058B2 (en) | Water-soluble lubricant for cold pilger rolling and lubrication method in cold pilger rolling mill | |
| RU2713896C1 (en) | Concentrate of water-soluble lubricating-cooling liquid |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| C06 | Publication | ||
| PB01 | Publication | ||
| C10 | Entry into substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| RJ01 | Rejection of invention patent application after publication |
Application publication date: 20160706 |
|
| RJ01 | Rejection of invention patent application after publication |