CN114276855A - No-clean type drawing oil and production process thereof - Google Patents
No-clean type drawing oil and production process thereof Download PDFInfo
- Publication number
- CN114276855A CN114276855A CN202111593597.1A CN202111593597A CN114276855A CN 114276855 A CN114276855 A CN 114276855A CN 202111593597 A CN202111593597 A CN 202111593597A CN 114276855 A CN114276855 A CN 114276855A
- Authority
- CN
- China
- Prior art keywords
- acid
- oil
- sulfurized
- container
- agent
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
- 238000004519 manufacturing process Methods 0.000 title claims abstract description 17
- 239000003921 oil Substances 0.000 claims abstract description 82
- 239000003795 chemical substances by application Substances 0.000 claims abstract description 62
- 229910019142 PO4 Inorganic materials 0.000 claims abstract description 42
- 239000002253 acid Substances 0.000 claims abstract description 42
- BXWNKGSJHAJOGX-UHFFFAOYSA-N hexadecan-1-ol Chemical compound CCCCCCCCCCCCCCCCO BXWNKGSJHAJOGX-UHFFFAOYSA-N 0.000 claims abstract description 42
- IPCSVZSSVZVIGE-UHFFFAOYSA-N hexadecanoic acid Chemical compound CCCCCCCCCCCCCCCC(O)=O IPCSVZSSVZVIGE-UHFFFAOYSA-N 0.000 claims abstract description 42
- ZQPPMHVWECSIRJ-KTKRTIGZSA-N oleic acid Chemical compound CCCCCCCC\C=C/CCCCCCCC(O)=O ZQPPMHVWECSIRJ-KTKRTIGZSA-N 0.000 claims abstract description 42
- NBIIXXVUZAFLBC-UHFFFAOYSA-K phosphate Chemical compound [O-]P([O-])([O-])=O NBIIXXVUZAFLBC-UHFFFAOYSA-K 0.000 claims abstract description 42
- 239000010452 phosphate Substances 0.000 claims abstract description 42
- WRIDQFICGBMAFQ-UHFFFAOYSA-N (E)-8-Octadecenoic acid Natural products CCCCCCCCCC=CCCCCCCC(O)=O WRIDQFICGBMAFQ-UHFFFAOYSA-N 0.000 claims abstract description 21
- QMMJWQMCMRUYTG-UHFFFAOYSA-N 1,2,4,5-tetrachloro-3-(trifluoromethyl)benzene Chemical compound FC(F)(F)C1=C(Cl)C(Cl)=CC(Cl)=C1Cl QMMJWQMCMRUYTG-UHFFFAOYSA-N 0.000 claims abstract description 21
- FJLUATLTXUNBOT-UHFFFAOYSA-N 1-Hexadecylamine Chemical compound CCCCCCCCCCCCCCCCN FJLUATLTXUNBOT-UHFFFAOYSA-N 0.000 claims abstract description 21
- LQJBNNIYVWPHFW-UHFFFAOYSA-N 20:1omega9c fatty acid Natural products CCCCCCCCCCC=CCCCCCCCC(O)=O LQJBNNIYVWPHFW-UHFFFAOYSA-N 0.000 claims abstract description 21
- QSBYPNXLFMSGKH-UHFFFAOYSA-N 9-Heptadecensaeure Natural products CCCCCCCC=CCCCCCCCC(O)=O QSBYPNXLFMSGKH-UHFFFAOYSA-N 0.000 claims abstract description 21
- ZQPPMHVWECSIRJ-UHFFFAOYSA-N Oleic acid Natural products CCCCCCCCC=CCCCCCCCC(O)=O ZQPPMHVWECSIRJ-UHFFFAOYSA-N 0.000 claims abstract description 21
- 239000005642 Oleic acid Substances 0.000 claims abstract description 21
- 235000021314 Palmitic acid Nutrition 0.000 claims abstract description 21
- 229960000541 cetyl alcohol Drugs 0.000 claims abstract description 21
- LQZZUXJYWNFBMV-UHFFFAOYSA-N dodecan-1-ol Chemical compound CCCCCCCCCCCCO LQZZUXJYWNFBMV-UHFFFAOYSA-N 0.000 claims abstract description 21
- 125000003438 dodecyl group Chemical group [H]C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])* 0.000 claims abstract description 21
- QXJSBBXBKPUZAA-UHFFFAOYSA-N isooleic acid Natural products CCCCCCCC=CCCCCCCCCC(O)=O QXJSBBXBKPUZAA-UHFFFAOYSA-N 0.000 claims abstract description 21
- WQEPLUUGTLDZJY-UHFFFAOYSA-N n-Pentadecanoic acid Natural products CCCCCCCCCCCCCCC(O)=O WQEPLUUGTLDZJY-UHFFFAOYSA-N 0.000 claims abstract description 21
- FATBGEAMYMYZAF-KTKRTIGZSA-N oleamide Chemical compound CCCCCCCC\C=C/CCCCCCCC(N)=O FATBGEAMYMYZAF-KTKRTIGZSA-N 0.000 claims abstract description 21
- FATBGEAMYMYZAF-UHFFFAOYSA-N oleicacidamide-heptaglycolether Natural products CCCCCCCCC=CCCCCCCCC(N)=O FATBGEAMYMYZAF-UHFFFAOYSA-N 0.000 claims abstract description 21
- 239000004519 grease Substances 0.000 claims abstract description 20
- 125000002811 oleoyl group Chemical group O=C([*])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])/C([H])=C([H])\C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 claims abstract description 20
- 239000013556 antirust agent Substances 0.000 claims abstract description 12
- 241000283222 Physeter catodon Species 0.000 claims abstract description 10
- 239000010698 whale oil Substances 0.000 claims abstract description 10
- VEXZGXHMUGYJMC-UHFFFAOYSA-N Hydrochloric acid Chemical compound Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 claims description 42
- NBIIXXVUZAFLBC-UHFFFAOYSA-N Phosphoric acid Chemical compound OP(O)(O)=O NBIIXXVUZAFLBC-UHFFFAOYSA-N 0.000 claims description 42
- GEHJYWRUCIMESM-UHFFFAOYSA-L sodium sulfite Chemical compound [Na+].[Na+].[O-]S([O-])=O GEHJYWRUCIMESM-UHFFFAOYSA-L 0.000 claims description 42
- -1 fatty acid ester Chemical class 0.000 claims description 30
- 239000000463 material Substances 0.000 claims description 28
- 238000000034 method Methods 0.000 claims description 25
- VQTUBCCKSQIDNK-UHFFFAOYSA-N Isobutene Chemical group CC(C)=C VQTUBCCKSQIDNK-UHFFFAOYSA-N 0.000 claims description 23
- 230000008569 process Effects 0.000 claims description 22
- AROCLDYPZXMJPW-UHFFFAOYSA-N 1-(octyldisulfanyl)octane Chemical compound CCCCCCCCSSCCCCCCCC AROCLDYPZXMJPW-UHFFFAOYSA-N 0.000 claims description 21
- HTIRHQRTDBPHNZ-UHFFFAOYSA-N Dibutyl sulfide Chemical compound CCCCSCCCC HTIRHQRTDBPHNZ-UHFFFAOYSA-N 0.000 claims description 21
- GRYLNZFGIOXLOG-UHFFFAOYSA-N Nitric acid Chemical compound O[N+]([O-])=O GRYLNZFGIOXLOG-UHFFFAOYSA-N 0.000 claims description 21
- 229910000147 aluminium phosphate Inorganic materials 0.000 claims description 21
- 235000014113 dietary fatty acids Nutrition 0.000 claims description 21
- GVGUFUZHNYFZLC-UHFFFAOYSA-N dodecyl benzenesulfonate;sodium Chemical compound [Na].CCCCCCCCCCCCOS(=O)(=O)C1=CC=CC=C1 GVGUFUZHNYFZLC-UHFFFAOYSA-N 0.000 claims description 21
- 239000000194 fatty acid Substances 0.000 claims description 21
- 229930195729 fatty acid Natural products 0.000 claims description 21
- VKYKSIONXSXAKP-UHFFFAOYSA-N hexamethylenetetramine Chemical compound C1N(C2)CN3CN1CN2C3 VKYKSIONXSXAKP-UHFFFAOYSA-N 0.000 claims description 21
- 229910017604 nitric acid Inorganic materials 0.000 claims description 21
- 239000001509 sodium citrate Substances 0.000 claims description 21
- NLJMYIDDQXHKNR-UHFFFAOYSA-K sodium citrate Chemical compound O.O.[Na+].[Na+].[Na+].[O-]C(=O)CC(O)(CC([O-])=O)C([O-])=O NLJMYIDDQXHKNR-UHFFFAOYSA-K 0.000 claims description 21
- 229940080264 sodium dodecylbenzenesulfonate Drugs 0.000 claims description 21
- 235000010265 sodium sulphite Nutrition 0.000 claims description 21
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 21
- NWONKYPBYAMBJT-UHFFFAOYSA-L zinc sulfate Chemical compound [Zn+2].[O-]S([O-])(=O)=O NWONKYPBYAMBJT-UHFFFAOYSA-L 0.000 claims description 21
- 229960001763 zinc sulfate Drugs 0.000 claims description 21
- 229910000368 zinc sulfate Inorganic materials 0.000 claims description 21
- 229910052750 molybdenum Inorganic materials 0.000 claims description 17
- 239000011733 molybdenum Substances 0.000 claims description 17
- ZOKXTWBITQBERF-UHFFFAOYSA-N Molybdenum Chemical compound [Mo] ZOKXTWBITQBERF-UHFFFAOYSA-N 0.000 claims description 16
- DKVNPHBNOWQYFE-UHFFFAOYSA-N carbamodithioic acid Chemical compound NC(S)=S DKVNPHBNOWQYFE-UHFFFAOYSA-N 0.000 claims description 16
- 239000012990 dithiocarbamate Substances 0.000 claims description 16
- 238000003756 stirring Methods 0.000 claims description 13
- JEIPFZHSYJVQDO-UHFFFAOYSA-N iron(III) oxide Inorganic materials O=[Fe]O[Fe]=O JEIPFZHSYJVQDO-UHFFFAOYSA-N 0.000 claims description 9
- 239000003112 inhibitor Substances 0.000 claims description 8
- IPCXNCATNBAPKW-UHFFFAOYSA-N zinc;hydrate Chemical compound O.[Zn] IPCXNCATNBAPKW-UHFFFAOYSA-N 0.000 claims description 8
- QZVZCEVBUGOXCL-UHFFFAOYSA-K antimony(3+);tricarbamothioate Chemical compound [Sb+3].NC([O-])=S.NC([O-])=S.NC([O-])=S QZVZCEVBUGOXCL-UHFFFAOYSA-K 0.000 claims description 6
- 238000002156 mixing Methods 0.000 claims description 6
- 239000000203 mixture Substances 0.000 claims description 3
- 230000003647 oxidation Effects 0.000 abstract description 8
- 238000007254 oxidation reaction Methods 0.000 abstract description 8
- 230000003670 easy-to-clean Effects 0.000 abstract description 5
- 238000004880 explosion Methods 0.000 abstract description 4
- 238000005299 abrasion Methods 0.000 abstract description 3
- 230000002950 deficient Effects 0.000 abstract description 3
- 238000000227 grinding Methods 0.000 abstract description 3
- 239000000314 lubricant Substances 0.000 abstract description 3
- 239000010935 stainless steel Substances 0.000 abstract description 3
- 229910001220 stainless steel Inorganic materials 0.000 abstract description 3
- GNVMUORYQLCPJZ-UHFFFAOYSA-M Thiocarbamate Chemical compound NC([S-])=O GNVMUORYQLCPJZ-UHFFFAOYSA-M 0.000 description 7
- 238000007865 diluting Methods 0.000 description 6
- 239000011248 coating agent Substances 0.000 description 4
- 238000000576 coating method Methods 0.000 description 4
- 238000001816 cooling Methods 0.000 description 4
- 235000010299 hexamethylene tetramine Nutrition 0.000 description 4
- KHYKFSXXGRUKRE-UHFFFAOYSA-J molybdenum(4+) tetracarbamodithioate Chemical compound C(N)([S-])=S.[Mo+4].C(N)([S-])=S.C(N)([S-])=S.C(N)([S-])=S KHYKFSXXGRUKRE-UHFFFAOYSA-J 0.000 description 4
- 230000001050 lubricating effect Effects 0.000 description 3
- 238000005461 lubrication Methods 0.000 description 3
- 229910000838 Al alloy Inorganic materials 0.000 description 2
- 201000004624 Dermatitis Diseases 0.000 description 2
- UCKMPCXJQFINFW-UHFFFAOYSA-N Sulphide Chemical compound [S-2] UCKMPCXJQFINFW-UHFFFAOYSA-N 0.000 description 2
- 230000001680 brushing effect Effects 0.000 description 2
- 238000005260 corrosion Methods 0.000 description 2
- 230000007797 corrosion Effects 0.000 description 2
- 238000007598 dipping method Methods 0.000 description 2
- 239000000839 emulsion Substances 0.000 description 2
- 229910052751 metal Inorganic materials 0.000 description 2
- 239000002184 metal Substances 0.000 description 2
- 239000004033 plastic Substances 0.000 description 2
- 238000005507 spraying Methods 0.000 description 2
- 239000000126 substance Substances 0.000 description 2
- KXDHJXZQYSOELW-UHFFFAOYSA-M Carbamate Chemical compound NC([O-])=O KXDHJXZQYSOELW-UHFFFAOYSA-M 0.000 description 1
- 230000009471 action Effects 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 230000009172 bursting Effects 0.000 description 1
- 230000006835 compression Effects 0.000 description 1
- 238000007906 compression Methods 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 238000001125 extrusion Methods 0.000 description 1
- 230000003993 interaction Effects 0.000 description 1
- 239000010699 lard oil Substances 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 238000005406 washing Methods 0.000 description 1
Landscapes
- Lubricants (AREA)
Abstract
The invention relates to the technical field of drawing oil and discloses a no-clean drawing oil and a production process thereof, wherein the no-clean drawing oil comprises drawing oil, and the drawing oil comprises an oiliness agent, an extreme pressure agent and an antirust agent; the oiliness agent comprises cetyl amine, oleamide, palmitic acid, oleic acid, lauryl alcohol, cetyl alcohol, grease, butyl stearate, lauryl acid phosphate, oleoyl acid phosphate, sperm whale oil and sulfurized oleic acid; in the invention, the oiliness agent, the extreme pressure agent and the antirust agent have good lubricity, extreme pressure abrasion resistance, antirust property, oxidation stability and the like; the lubricating agent can effectively protect a die, avoid the phenomena of ' flower pulling ', ' pull explosion ', wrinkling ' and the like of a stainless steel product, has bright workpiece surface, is easy to clean, does not corrode a grinding tool and skin, has excellent comprehensive performances of extreme pressure lubricity, oxidation stability, good antirust property and the like, has good boundary lubricity, and effectively reduces the defective rate.
Description
Technical Field
The invention relates to the technical field of drawing oil, in particular to wash-free drawing oil and a production process thereof.
Background
The die used for stamping and drawing is generally composed of a male die, a female die and a blank holder. The clearance between the male die and the female die is larger than the thickness of the plate, and because the diameter of the female die is smaller than that of the blank, the plate generates plastic flow in the stamping and stretching process, one part increases the height of a workpiece, and the other part increases the thickness of the cylinder wall. In the stamping and stretching process, internal stress is generated between each unit body in the metal due to the internal interaction of the metal caused by the stress of the material, and under the action of the internal stress, a strain state is generated, so that the material is subjected to plastic deformation and is continuously pulled into the concave die to finally form a cylindrical workpiece. The deformation point of the stamping and drawing process is a cylindrical workpiece which is transformed from a large section of material to a small section.
In the process, the material surface is inevitably contacted with the surface of the die to generate friction, and the stamping drawing oil with good performance is needed to reduce the friction coefficient and the extrusion force. If the other conditions meet the premise of the stretching process, the lubrication quality directly affects the stretching force, the service life of the die, the product quality and the like, and even becomes the key of the success or failure of the stamping and stretching process.
Therefore, the wash-free drawing oil and the production process thereof are provided.
Disclosure of Invention
The invention mainly solves the technical problems in the prior art and provides the no-clean stretching oil and the production process thereof.
In order to achieve the purpose, the invention adopts the following technical scheme that the no-clean stretching oil comprises stretching oil, wherein the stretching oil comprises an oiliness agent, an extreme pressure agent and an antirust agent;
the oiliness agent comprises cetyl amine, oleamide, palmitic acid, oleic acid, lauryl alcohol, cetyl alcohol, grease, butyl stearate, lauryl acid phosphate, oleoyl acid phosphate, sperm whale oil and sulfurized oleic acid;
the extreme pressure agent comprises sulfurized lard, sulfurized fatty acid ester, dibutyl sulfide, dioctyl disulfide, sulfurized isobutylene, dibutyl thiocarbamate antimony, and molybdenum dialkyl dithiocarbamate;
the rust inhibitor comprises phosphoric acid, nitric acid, hydrochloric acid, sodium citrate, sodium sulfite, urotropine, sodium dodecyl benzene sulfonate, zinc sulfate and water.
Preferably, the composition comprises 0.1-0.3 part of cetylamine, 0.3-0.5 part of oleamide, 0.2-0.7 part of palmitic acid, 0.2-0.4 part of oleic acid, 0.15-0.3 part of lauryl alcohol, 0.23-0.4 part of cetyl alcohol, 0.14-0.3 part of oil and fat, 0.17-0.25 part of butyl stearate, 0.32-0.45 part of lauryl acid phosphate, 0.17-0.31 part of oleoyl acid phosphate, 0.26-0.35 part of sperm whale oil and 0.33-0.5 part of sulfurized oleic acid.
Preferably, the vulcanized lard oil is 0.3-0.5 part, the vulcanized fatty acid ester is 0.4-0.6 part, the dibutyl sulfide is 0.25-0.45 part, the dioctyl disulfide is 0.6-0.75 part, the vulcanized isobutene is 0.26-0.36 part, the dibutyl sulfo-antimony carbamate is 0.39-0.48 part, and the dialkyl dithio-molybdenum carbamate is 0.15-0.35 part.
Preferably, the phosphoric acid is 0.12-0.34 part, the nitric acid is 0.6-0.75 part, the hydrochloric acid is 0.8-0.96 part, the sodium citrate is 0.21-0.35 part, the sodium sulfite is 0.23-0.46 part, the urotropine is 0.46-0.68 part, the sodium dodecyl benzene sulfonate is 0.52-0.66 part, the zinc sulfate is 0.64-0.83 part, and the balance is water.
A production process of wash-free stretching oil comprises the following steps:
the first step is as follows: preparing an oiliness agent;
the second step is that: preparing an extreme pressure agent;
the third step: mixing materials;
the fourth step: the finished product of the drawing oil is obtained,
preferably, in the first step, the temperature of the container is raised to 150 ℃, and then 0.1-0.3 part of cetylamine, 0.3-0.5 part of oleamide, 0.2-0.7 part of palmitic acid, 0.2-0.4 part of oleic acid, 0.15-0.3 part of lauryl alcohol, 0.23-0.4 part of cetyl alcohol, 0.14-0.3 part of grease, 0.17-0.25 part of butyl stearate, 0.32-0.45 part of lauryl acid phosphate, 0.17-0.31 part of oleoyl acid phosphate, 0.26-0.35 part of sperm oil and 0.33-0.5 part of sulfurized oleic acid are poured into the container in sequence and stirred for 50 minutes at the speed of 360r/min, and then the finished oily agent is taken out for standby.
Preferably, in the second step, the temperature of the container is raised to 120 ℃, and then the temperature of the container is raised to 200 ℃ according to 0.3-0.5 part of sulfurized lard, 0.4-0.6 part of sulfurized fatty acid ester, 0.25-0.45 part of dibutyl sulfide, 0.6-0.75 part of dioctyl disulfide, 0.26-0.36 part of sulfurized isobutylene, 0.39-0.48 part of dibutyl sulfo-antimony carbamate and 0.15-0.35 part of molybdenum dialkyl dithiocarbamate which are sequentially poured into the container, stirred for 20 minutes according to the rotating speed of 500 r/min.
Preferably, the finished oiliness agent taken out in the first step is poured into the container in the second step, after the materials in the container are diluted, 0.12-0.34 part of phosphoric acid, 0.6-0.75 part of nitric acid, 0.8-0.96 part of hydrochloric acid, 0.21-0.35 part of sodium citrate, 0.23-0.46 part of sodium sulfite, 0.46-0.68 part of urotropine, 0.52-0.66 part of sodium dodecyl benzene sulfonate, 0.64-0.83 part of zinc sulfate and the balance of water are poured into the container, and the mixture is stirred for 30 minutes at the rotating speed of 400 r/min.
Preferably, in the fourth step, the material mixed in the third step is cooled to reduce the temperature of the container to 35 ℃, and then the material is taken out of the container to obtain the finished drawing oil.
Advantageous effects
The invention provides a washing-free type drawing oil and a production process thereof. The method has the following beneficial effects:
(1) the no-clean stretching oil and the production process thereof have good lubricity, extreme pressure abrasion resistance, rust resistance, oxidation stability and the like through an oiliness agent, an extreme pressure agent and an antirust agent. The lubricating agent can effectively protect a die, avoid the phenomena of ' flower pulling ', ' pull explosion ', wrinkling ' and the like of a stainless steel product, has bright workpiece surface, is easy to clean, does not corrode a grinding tool and skin, has excellent comprehensive performances of extreme pressure lubricity, oxidation stability, good antirust property and the like, has good boundary lubricity, and effectively reduces the defective rate.
(2) The washing-free drawing oil and the production process thereof have simple and convenient use process, can directly coat oil products on workpieces and dies by brushing, dipping or spraying, and generally adopt the drawing oil with lower viscosity, better lubricating property and extreme pressure property for precise and high-speed drawing process.
(3) The washing-free stretching oil and the production process thereof have high compressive strength and do not cause flower drawing and explosion drawing; contains special chemical factors, so that the subsequent process is easy to clean; contains corrosion inhibitor, does not corrode the mould; the product is environment-friendly and has no skin allergy; the decorative property is good, the coating can be quickly spread on the surface of the plate after coating, and the lubrication is sufficient.
(4) The non-washing type stretching oil and the production process thereof have the advantages that the cetylamine, the oleamide, the palmitic acid, the oleic acid, the lauryl alcohol, the cetyl alcohol, the grease, the butyl stearate, the lauryl acid phosphate, the acyl ester of the oil acid phosphate, the sperm oil and the sulfurized oleic acid in the oiliness agent are adopted, oil with higher viscosity is also adopted for the process with larger stretching degree, and soluble oil is mostly used for diluting into emulsion for the thinning and stretching process with higher forming speed.
(5) The no-clean stretching oil is prepared by the steps of adding lard sulfide, fatty acid sulfide, dibutyl sulfide, dioctyl disulfide, sulfurized isobutylene, dibutyl sulfur antimony carbamate, molybdenum dialkyl dithiocarbamate and phosphoric acid, nitric acid, hydrochloric acid, sodium citrate, sodium sulfite, urotropine, sodium dodecyl benzene sulfonate, zinc sulfate and water in an extreme pressure agent, wherein the lard sulfide, the fatty acid sulfide, the dibutyl sulfide, the dioctyl disulfide, the sulfurized isobutylene, the dibutyl sulfur antimony carbamate, the molybdenum dialkyl dithiocarbamate and the phosphoric acid, the nitric acid, the hydrochloric acid, the sodium citrate, the sodium sulfite, the urotropine, the sodium dodecyl benzene sulfonate, the zinc sulfate and the water are added in an anti-rust agent, so that the no-clean stretching oil has good lubricating property, extreme pressure anti-wear property, anti-rust property, oxidation stability and the like. The die can be effectively protected, and the requirements of the stamping and stretching process of the aluminum alloy are met.
Detailed Description
All other embodiments, which can be derived by a person skilled in the art from the embodiments given herein without making any creative effort, shall fall within the protection scope of the present invention.
The first embodiment is as follows: the no-clean stretching oil comprises stretching oil, and the stretching oil comprises an oiliness agent, an extreme pressure agent and an antirust agent.
The oiliness agent comprises cetyl amine, oleamide, palmitic acid, oleic acid, lauryl alcohol, cetyl alcohol, grease, butyl stearate, lauryl acid phosphate, oleoyl acid phosphate, sperm whale oil and sulfurized oleic acid.
The extreme pressure agent comprises sulfurized lard, sulfurized fatty acid ester, dibutyl sulfide, dioctyl disulfide, sulfurized isobutylene, dibutyl thiocarbamate antimony and dialkyl molybdenum dithiocarbamate.
The rust inhibitor comprises phosphoric acid, nitric acid, hydrochloric acid, sodium citrate, sodium sulfite, urotropine, sodium dodecyl benzene sulfonate, zinc sulfate and water.
0.1 part of cetylamine, 0.3 part of oleamide, 0.2 part of palmitic acid, 0.2 part of oleic acid, 0.15 part of lauryl alcohol, 0.23 part of cetyl alcohol, 0.14 part of grease, 0.17 part of butyl stearate, 0.32 part of lauryl acid phosphate, 0.17 part of oleoyl acid phosphate, 0.26 part of sperm oil and 0.33 part of sulfurized oleic acid.
0.3 part of sulfurized lard, 0.4 part of sulfurized fatty acid ester, 0.25 part of dibutyl sulfide, 0.6 part of dioctyl disulfide, 0.26 part of sulfurized isobutylene, 0.39 part of dibutyl thiocarbamate and 0.15 part of molybdenum dialkyl dithiocarbamate.
0.12 part of phosphoric acid, 0.6 part of nitric acid, 0.8 part of hydrochloric acid, 0.21 part of sodium citrate, 0.23 part of sodium sulfite, 0.46 part of urotropin, 0.52 part of sodium dodecyl benzene sulfonate, 0.64 part of zinc sulfate and the balance of water.
A production process of wash-free stretching oil comprises the following steps:
the first step is as follows: preparing an oiliness agent, namely raising the temperature of a container to 150 ℃, then sequentially pouring 0.1 part of cetylamine, 0.3 part of oleamide, 0.2 part of palmitic acid, 0.2 part of oleic acid, 0.15 part of lauryl alcohol, 0.23 part of cetyl alcohol, 0.14 part of grease, 0.17 part of butyl stearate, 0.32 part of lauryl acid phosphate, 0.17 part of oleoyl acid phosphate, 0.26 part of sperm oil and 0.33 part of sulfurized oleic acid into the container, stirring for 50 minutes at the speed of 360r/min, and taking out the finished oiliness agent for later use;
the second step is that: preparing an extreme pressure agent, namely raising the temperature of a container to 120 ℃, then sequentially pouring 0.3 part of sulfurized lard, 0.4 part of sulfurized fatty acid ester, 0.25 part of dibutyl sulfide, 0.6 part of dioctyl disulfide, 0.26 part of sulfurized isobutylene, 0.39 part of dibutyl thiocarbamate and 0.15 part of molybdenum dialkyl dithiocarbamate into the container, stirring for 20 minutes at the rotating speed of 500r/min, and raising the temperature of the container to 200 ℃;
the third step: mixing the materials, pouring the finished oiliness agent taken out in the first step into the container in the second step, after diluting the materials in the container, then pouring 0.12 part of phosphoric acid, 0.6 part of nitric acid, 0.8 part of hydrochloric acid, 0.21 part of sodium citrate, 0.23 part of sodium sulfite, 0.46 part of urotropine, 0.52 part of sodium dodecyl benzene sulfonate, 0.64 part of zinc sulfate and the balance of water into the container, and stirring for 30 minutes at the rotating speed of 400 r/min;
the fourth step: and (4) drawing the oil finished product, cooling the material mixed in the third step to reduce the temperature of the container to 35 ℃, and taking the material out of the container to obtain the finished drawing oil.
Example two: the no-clean stretching oil comprises stretching oil, and the stretching oil comprises an oiliness agent, an extreme pressure agent and an antirust agent.
The oiliness agent comprises cetyl amine, oleamide, palmitic acid, oleic acid, lauryl alcohol, cetyl alcohol, grease, butyl stearate, lauryl acid phosphate, oleoyl acid phosphate, sperm whale oil and sulfurized oleic acid.
The extreme pressure agent comprises sulfurized lard, sulfurized fatty acid ester, dibutyl sulfide, dioctyl disulfide, sulfurized isobutylene, dibutyl thiocarbamate antimony and dialkyl molybdenum dithiocarbamate.
The rust inhibitor comprises phosphoric acid, nitric acid, hydrochloric acid, sodium citrate, sodium sulfite, urotropine, sodium dodecyl benzene sulfonate, zinc sulfate and water.
0.3 part of cetylamine, 0.5 part of oleamide, 0.7 part of palmitic acid, 0.4 part of oleic acid, 0.3 part of lauryl alcohol, 0.4 part of cetyl alcohol, 0.3 part of grease, 0.25 part of butyl stearate, 0.45 part of lauryl acid phosphate, 0.31 part of oleoyl acid phosphate, 0.35 part of sperm oil and 0.5 part of sulfurized oleic acid.
0.5 part of sulfurized lard, 0.6 part of sulfurized fatty acid ester, 0.45 part of dibutyl sulfide, 0.75 part of dioctyl disulfide, 0.36 part of sulfurized isobutylene, 0.48 part of dibutyl thiocarbamate and 0.35 part of molybdenum dialkyl dithiocarbamate.
0.34 part of phosphoric acid, 0.75 part of nitric acid, 0.96 part of hydrochloric acid, 0.35 part of sodium citrate, 0.46 part of sodium sulfite, 0.68 part of urotropin, 0.66 part of sodium dodecyl benzene sulfonate, 0.83 part of zinc sulfate and the balance of water.
A production process of wash-free stretching oil comprises the following steps:
the first step is as follows: preparing an oiliness agent, namely raising the temperature of a container to 150 ℃, then sequentially pouring 0.3 part of cetylamine, 0.5 part of oleamide, 0.7 part of palmitic acid, 0.4 part of oleic acid, 0.3 part of lauryl alcohol, 0.4 part of cetyl alcohol, 0.3 part of grease, 0.25 part of butyl stearate, 0.45 part of lauryl acid phosphate, 0.31 part of oleoyl acid phosphate, 0.35 part of sperm oil and 0.5 part of sulfurized oleic acid into the container, stirring for 50 minutes at the speed of 360r/min, and taking out the finished oiliness agent for later use;
the second step is that: preparing an extreme pressure agent, namely raising the temperature of a container to 120 ℃, then sequentially pouring 0.5 part of sulfurized lard, 0.6 part of sulfurized fatty acid ester, 0.45 part of dibutyl sulfide, 0.75 part of dioctyl disulfide, 0.36 part of sulfurized isobutylene, 0.48 part of dibutyl thiocarbamate and 0.35 part of molybdenum dialkyl dithiocarbamate into the container, stirring for 20 minutes at the rotating speed of 500r/min, and raising the temperature of the container to 200 ℃;
the third step: mixing the materials, pouring the finished oiliness agent taken out in the first step into the container in the second step, after diluting the materials in the container, then pouring 0.34 parts of phosphoric acid, 0.75 parts of nitric acid, 0.96 parts of hydrochloric acid, 0.35 parts of sodium citrate, 0.46 parts of sodium sulfite, 0.68 parts of urotropine, 0.66 parts of sodium dodecyl benzene sulfonate, 0.83 parts of zinc sulfate and the balance of water into the container, and stirring for 30 minutes at the rotating speed of 400 r/min;
the fourth step: and (4) drawing the oil finished product, cooling the material mixed in the third step to reduce the temperature of the container to 35 ℃, and taking the material out of the container to obtain the finished drawing oil.
Example three: the no-clean stretching oil comprises stretching oil, and the stretching oil comprises an oiliness agent, an extreme pressure agent and an antirust agent.
The oiliness agent comprises cetyl amine, oleamide, palmitic acid, oleic acid, lauryl alcohol, cetyl alcohol, grease, butyl stearate, lauryl acid phosphate, oleoyl acid phosphate, sperm whale oil and sulfurized oleic acid.
The extreme pressure agent comprises sulfurized lard, sulfurized fatty acid ester, dibutyl sulfide, dioctyl disulfide, sulfurized isobutylene, dibutyl thiocarbamate antimony and dialkyl molybdenum dithiocarbamate.
The rust inhibitor comprises phosphoric acid, nitric acid, hydrochloric acid, sodium citrate, sodium sulfite, urotropine, sodium dodecyl benzene sulfonate, zinc sulfate and water.
0.2 part of cetylamine, 0.4 part of oleamide, 0.2 part of palmitic acid, 0.2 part of oleic acid, 0.15 part of lauryl alcohol, 0.23 part of cetyl alcohol, 0.14 part of grease, 0.17 part of butyl stearate, 0.32 part of lauryl acid phosphate, 0.17 part of oleoyl acid phosphate, 0.26 part of sperm oil and 0.33 part of sulfurized oleic acid.
0.4 part of sulfurized lard, 0.45 part of sulfurized fatty acid ester, 0.25 part of dibutyl sulfide, 0.6 part of dioctyl disulfide, 0.26 part of sulfurized isobutylene, 0.39 part of dibutyl thiocarbamate and 0.15 part of molybdenum dialkyl dithiocarbamate.
0.25 part of phosphoric acid, 0.65 part of nitric acid, 0.8 part of hydrochloric acid, 0.21 part of sodium citrate, 0.23 part of sodium sulfite, 0.46 part of urotropin, 0.52 part of sodium dodecyl benzene sulfonate, 0.64 part of zinc sulfate and the balance of water.
A production process of wash-free stretching oil comprises the following steps:
the first step is as follows: preparing an oiliness agent, namely raising the temperature of a container to 150 ℃, then sequentially pouring 0.2 part of cetylamine, 0.4 part of oleamide, 0.2 part of palmitic acid, 0.2 part of oleic acid, 0.15 part of lauryl alcohol, 0.23 part of cetyl alcohol, 0.14 part of grease, 0.17 part of butyl stearate, 0.32 part of lauryl acid phosphate, 0.17 part of oleoyl acid phosphate, 0.26 part of sperm oil and 0.33 part of sulfurized oleic acid into the container, stirring for 50 minutes at the speed of 360r/min, and taking out the finished oiliness agent for later use;
the second step is that: preparing an extreme pressure agent, namely raising the temperature of a container to 120 ℃, then pouring 0.4 part of vulcanized lard, 0.45 part of vulcanized fatty acid ester, 0.25 part of dibutyl sulfide, 0.6 part of dioctyl disulfide, 0.26 part of vulcanized isobutene, 0.39 part of dibutyl sulfo-substituted antimony carbamate and 0.15 part of molybdenum dialkyl dithiocarbamate into the container, stirring for 20 minutes at the rotating speed of 500r/min, and raising the temperature of the container to 200 ℃;
the third step: mixing the materials, pouring the finished product oiliness agent taken out in the first step into the container in the second step, after diluting the materials in the container, then pouring 0.25 part of phosphoric acid, 0.65 part of nitric acid, 0.8 part of hydrochloric acid, 0.21 part of sodium citrate, 0.23 part of sodium sulfite, 0.46 part of urotropine, 0.52 part of sodium dodecyl benzene sulfonate, 0.64 part of zinc sulfate and the balance of water into the container, and stirring for 30 minutes at the rotating speed of 400 r/min;
the fourth step: and (4) drawing the oil finished product, cooling the material mixed in the third step to reduce the temperature of the container to 35 ℃, and taking the material out of the container to obtain the finished drawing oil.
Example four: the no-clean stretching oil comprises stretching oil, and the stretching oil comprises an oiliness agent, an extreme pressure agent and an antirust agent.
The oiliness agent comprises cetyl amine, oleamide, palmitic acid, oleic acid, lauryl alcohol, cetyl alcohol, grease, butyl stearate, lauryl acid phosphate, oleoyl acid phosphate, sperm whale oil and sulfurized oleic acid.
The extreme pressure agent comprises sulfurized lard, sulfurized fatty acid ester, dibutyl sulfide, dioctyl disulfide, sulfurized isobutylene, dibutyl thiocarbamate antimony and dialkyl molybdenum dithiocarbamate.
The rust inhibitor comprises phosphoric acid, nitric acid, hydrochloric acid, sodium citrate, sodium sulfite, urotropine, sodium dodecyl benzene sulfonate, zinc sulfate and water.
0.1 part of cetylamine, 0.3 part of oleamide, 0.5 part of palmitic acid, 0.3 part of oleic acid, 0.15 part of lauryl alcohol, 0.23 part of cetyl alcohol, 0.14 part of grease, 0.17 part of butyl stearate, 0.32 part of lauryl acid phosphate, 0.17 part of oleoyl acid phosphate, 0.26 part of sperm oil and 0.33 part of sulfurized oleic acid.
0.3 part of sulfurized lard, 0.4 part of sulfurized fatty acid ester, 0.35 part of dibutyl sulfide, 0.65 part of dioctyl disulfide, 0.26 part of sulfurized isobutylene, 0.39 part of dibutyl thiocarbamate and 0.15 part of molybdenum dialkyl dithiocarbamate.
0.12 part of phosphoric acid, 0.6 part of nitric acid, 0.8 part of hydrochloric acid, 0.32 part of sodium citrate, 0.4 part of sodium sulfite, 0.46 part of urotropin, 0.52 part of sodium dodecyl benzene sulfonate, 0.64 part of zinc sulfate and the balance of water.
A production process of wash-free stretching oil comprises the following steps:
the first step is as follows: preparing an oiliness agent, namely raising the temperature of a container to 150 ℃, then sequentially pouring 0.1 part of cetylamine, 0.3 part of oleamide, 0.5 part of palmitic acid, 0.3 part of oleic acid, 0.15 part of lauryl alcohol, 0.23 part of cetyl alcohol, 0.14 part of grease, 0.17 part of butyl stearate, 0.32 part of lauryl acid phosphate, 0.17 part of oleoyl acid phosphate, 0.26 part of sperm oil and 0.33 part of sulfurized oleic acid into the container, stirring for 50 minutes at the speed of 360r/min, and taking out the finished oiliness agent for later use;
the second step is that: preparing an extreme pressure agent, namely raising the temperature of a container to 120 ℃, then sequentially pouring 0.3 part of sulfurized lard, 0.4 part of sulfurized fatty acid ester, 0.35 part of dibutyl sulfide, 0.65 part of dioctyl disulfide, 0.26 part of sulfurized isobutylene, 0.39 part of dibutyl thiocarbamate and 0.15 part of molybdenum dialkyl dithiocarbamate into the container, stirring for 20 minutes at the rotating speed of 500r/min, and raising the temperature of the container to 200 ℃;
the third step: mixing the materials, pouring the finished product oiliness agent taken out in the first step into the container in the second step, after diluting the materials in the container, then pouring 0.12 part of phosphoric acid, 0.6 part of nitric acid, 0.8 part of hydrochloric acid, 0.32 part of sodium citrate, 0.4 part of sodium sulfite, 0.46 part of urotropine, 0.52 part of sodium dodecyl benzene sulfonate, 0.64 part of zinc sulfate and the balance of water into the container, and stirring for 30 minutes at the rotating speed of 400 r/min;
the fourth step: and (4) drawing the oil finished product, cooling the material mixed in the third step to reduce the temperature of the container to 35 ℃, and taking the material out of the container to obtain the finished drawing oil.
The working principle of the invention is as follows:
in the invention, the oiliness agent, the extreme pressure agent and the antirust agent have good lubricity, extreme pressure abrasion resistance, antirust property, oxidation stability and the like. The lubricating agent can effectively protect a die, avoid the phenomena of ' flower pulling ', ' pull explosion ', wrinkling ' and the like of a stainless steel product, has bright workpiece surface, is easy to clean, does not corrode a grinding tool and skin, has excellent comprehensive performances of extreme pressure lubricity, oxidation stability, good antirust property and the like, has good boundary lubricity, and effectively reduces the defective rate.
The invention has simple and convenient use process, can directly coat oil on a workpiece and a die by brushing, dipping or spraying, and generally adopts the stamping and stretching oil with lower viscosity and better lubricating property and extreme pressure property for the precise and high-speed stamping and stretching process.
In the invention, the compression strength is high, and the method does not cause 'flower drawing' or 'bursting'; contains special chemical factors, so that the subsequent process is easy to clean; contains corrosion inhibitor, does not corrode the mould; the product is environment-friendly and has no skin allergy; the decorative property is good, the coating can be quickly spread on the surface of the plate after coating, and the lubrication is sufficient.
In the invention, by adopting cetyl amine, oleamide, palmitic acid, oleic acid, lauryl alcohol, cetyl alcohol, grease, butyl stearate, lauryl acid phosphate, oleoyl acid phosphate, sperm oil and sulfurized oleic acid in the oiliness agent, oil with higher viscosity is also used for the process with larger stretching degree, and soluble oil is mostly used for diluting into emulsion for the thinning and stretching process with higher forming speed.
In the invention, the extreme pressure agent comprises sulfurized lard, sulfurized fatty acid ester, dibutyl sulfide, dioctyl disulfide, sulfurized isobutylene, dibutyl antimony thiocarbamate, molybdenum dialkyl dithiocarbamate and phosphoric acid, nitric acid, hydrochloric acid, sodium citrate, sodium sulfite, urotropine, sodium dodecyl benzene sulfonate, zinc sulfate and water in the anti-rust agent, and the extreme pressure agent has good lubricity, extreme pressure anti-wear property, anti-rust property, oxidation stability and the like. The die can be effectively protected, and the requirements of the stamping and stretching process of the aluminum alloy are met.
The foregoing shows and describes the general principles and broad features of the present invention and advantages thereof. It will be understood by those skilled in the art that the present invention is not limited to the embodiments described above, which are described in the specification and illustrated only to illustrate the principle of the present invention, but that various changes and modifications may be made therein without departing from the spirit and scope of the present invention, which fall within the scope of the invention as claimed. The scope of the invention is defined by the appended claims and equivalents thereof.
Claims (9)
1. The washing-free stretching oil comprises stretching oil and is characterized in that: the tensile oil comprises an oiliness agent, an extreme pressure agent and an antirust agent;
the oiliness agent comprises cetyl amine, oleamide, palmitic acid, oleic acid, lauryl alcohol, cetyl alcohol, grease, butyl stearate, lauryl acid phosphate, oleoyl acid phosphate, sperm whale oil and sulfurized oleic acid;
the extreme pressure agent comprises sulfurized lard, sulfurized fatty acid ester, dibutyl sulfide, dioctyl disulfide, sulfurized isobutylene, dibutyl thiocarbamate antimony, and molybdenum dialkyl dithiocarbamate;
the rust inhibitor comprises phosphoric acid, nitric acid, hydrochloric acid, sodium citrate, sodium sulfite, urotropine, sodium dodecyl benzene sulfonate, zinc sulfate and water.
2. A leave-on stretching oil as claimed in claim 1, wherein: 0.1-0.3 part of cetylamine, 0.3-0.5 part of oleamide, 0.2-0.7 part of palmitic acid, 0.2-0.4 part of oleic acid, 0.15-0.3 part of lauryl alcohol, 0.23-0.4 part of cetyl alcohol, 0.14-0.3 part of grease, 0.17-0.25 part of butyl stearate, 0.32-0.45 part of lauryl acid phosphate, 0.17-0.31 part of oleoyl acid phosphate, 0.26-0.35 part of sperm whale oil and 0.33-0.5 part of sulfurized oleic acid.
3. A leave-on stretching oil as claimed in claim 1, wherein: 0.3-0.5 part of sulfurized lard, 0.4-0.6 part of sulfurized fatty acid ester, 0.25-0.45 part of dibutyl sulfide, 0.6-0.75 part of dioctyl disulfide, 0.26-0.36 part of sulfurized isobutylene, 0.39-0.48 part of dibutyl sulfo-antimony carbamate and 0.15-0.35 part of molybdenum dialkyl dithiocarbamate.
4. A leave-on stretching oil as claimed in claim 1, wherein: 0.12-0.34 part of phosphoric acid, 0.6-0.75 part of nitric acid, 0.8-0.96 part of hydrochloric acid, 0.21-0.35 part of sodium citrate, 0.23-0.46 part of sodium sulfite, 0.46-0.68 part of urotropine, 0.52-0.66 part of sodium dodecyl benzene sulfonate, 0.64-0.83 part of zinc sulfate and the balance of water.
5. A production process of wash-free stretching oil is characterized by comprising the following steps: the method comprises the following steps:
the first step is as follows: preparing an oiliness agent;
the second step is that: preparing an extreme pressure agent;
the third step: mixing materials;
the fourth step: and (5) stretching the oil finished product.
6. The process for producing a leave-on drawing oil according to claim 5, wherein: in the first step, the temperature of the container is raised to 150 ℃, then 0.1-0.3 part of cetylamine, 0.3-0.5 part of oleamide, 0.2-0.7 part of palmitic acid, 0.2-0.4 part of oleic acid, 0.15-0.3 part of lauryl alcohol, 0.23-0.4 part of cetyl alcohol, 0.14-0.3 part of grease, 0.17-0.25 part of butyl stearate, 0.32-0.45 part of lauryl acid phosphate, 0.17-0.31 part of oleoyl acid phosphate, 0.26-0.35 part of sperm whale oil and 0.33-0.5 part of sulfurized oleic acid are poured into the container in turn, and are stirred for 50 minutes at the speed of 360r/min, and then the finished oily agent is taken out for standby.
7. The process for producing a leave-on drawing oil according to claim 6, wherein: and in the second step, raising the temperature of the container to 120 ℃, then sequentially pouring 0.3-0.5 part of sulfurized lard, 0.4-0.6 part of sulfurized fatty acid ester, 0.25-0.45 part of dibutyl sulfide, 0.6-0.75 part of dioctyl disulfide, 0.26-0.36 part of sulfurized isobutylene, 0.39-0.48 part of dibutyl sulfo-substituted antimony carbamate and 0.15-0.35 part of molybdenum dialkyl dithiocarbamate into the container, stirring for 20 minutes at the rotating speed of 500r/min, and then raising the temperature of the container to 200 ℃.
8. The process for producing a leave-on drawing oil according to claim 7, wherein: and in the third step, the finished product oiliness agent taken out in the first step is poured into the container in the second step, after the materials in the container are diluted, 0.12-0.34 part of phosphoric acid, 0.6-0.75 part of nitric acid, 0.8-0.96 part of hydrochloric acid, 0.21-0.35 part of sodium citrate, 0.23-0.46 part of sodium sulfite, 0.46-0.68 part of urotropine, 0.52-0.66 part of sodium dodecyl benzene sulfonate, 0.64-0.83 part of zinc sulfate and the balance of water are poured into the container, and the mixture is stirred for 30 minutes at the rotating speed of 400 r/min.
9. The process for producing a leave-on drawing oil according to claim 8, wherein: and in the fourth step, the material mixed in the third step is cooled to reduce the temperature of the container to 35 ℃, and then the material is taken out of the container to obtain the finished product of the stretching oil.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN202111593597.1A CN114276855A (en) | 2021-12-23 | 2021-12-23 | No-clean type drawing oil and production process thereof |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN202111593597.1A CN114276855A (en) | 2021-12-23 | 2021-12-23 | No-clean type drawing oil and production process thereof |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN114276855A true CN114276855A (en) | 2022-04-05 |
Family
ID=80875235
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN202111593597.1A Pending CN114276855A (en) | 2021-12-23 | 2021-12-23 | No-clean type drawing oil and production process thereof |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN114276855A (en) |
Citations (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPH10231494A (en) * | 1996-12-20 | 1998-09-02 | Nippon Steel Corp | Lubricating oil for water-dispersed steel-sheet cold-rolling mill lubricant and method for steel-sheet cold rolling |
| CN103725383A (en) * | 2013-12-23 | 2014-04-16 | 天津市金岛润滑油有限公司 | Stamping and stretching oil for sheet metal and preparation method thereof |
| CN105733765A (en) * | 2016-01-26 | 2016-07-06 | 深圳市鑫昌龙新材料科技股份有限公司 | Environment-friendly cleaning-free antirust punching oil |
| CN106085371A (en) * | 2016-06-14 | 2016-11-09 | 山东沾化莱斯特石油化工有限公司 | A kind of height leads conduction oil and preparation method thereof |
| CN108251200A (en) * | 2018-02-28 | 2018-07-06 | 北京科技大学 | A kind of clean type copper-aluminum composite board cold rolling oil and preparation method thereof |
| CN108998169A (en) * | 2018-09-05 | 2018-12-14 | 安徽富控电梯有限公司 | A kind of elevator motor bearing special lube |
-
2021
- 2021-12-23 CN CN202111593597.1A patent/CN114276855A/en active Pending
Patent Citations (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPH10231494A (en) * | 1996-12-20 | 1998-09-02 | Nippon Steel Corp | Lubricating oil for water-dispersed steel-sheet cold-rolling mill lubricant and method for steel-sheet cold rolling |
| CN103725383A (en) * | 2013-12-23 | 2014-04-16 | 天津市金岛润滑油有限公司 | Stamping and stretching oil for sheet metal and preparation method thereof |
| CN105733765A (en) * | 2016-01-26 | 2016-07-06 | 深圳市鑫昌龙新材料科技股份有限公司 | Environment-friendly cleaning-free antirust punching oil |
| CN106085371A (en) * | 2016-06-14 | 2016-11-09 | 山东沾化莱斯特石油化工有限公司 | A kind of height leads conduction oil and preparation method thereof |
| CN108251200A (en) * | 2018-02-28 | 2018-07-06 | 北京科技大学 | A kind of clean type copper-aluminum composite board cold rolling oil and preparation method thereof |
| CN108998169A (en) * | 2018-09-05 | 2018-12-14 | 安徽富控电梯有限公司 | A kind of elevator motor bearing special lube |
Non-Patent Citations (1)
| Title |
|---|
| 北京联合润科技公司著: "《车用润滑宝典》", 31 March 2003, 中国石化出版社, pages: 74 - 76 * |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN103695125B (en) | Lubricating agent for gold cold die forging of low-alloy steel and carbon steel plates | |
| CN103725377B (en) | The lubricant that stainless material cold forging is made | |
| CN101029271B (en) | Zinc-coated steel-plated punch drawing lube oil and its production | |
| CN103695114B (en) | Lubricant for sheet steel punch-forming | |
| CN103725376B (en) | Lubricating agent for drawing steel pipe | |
| JP2018030988A (en) | Lubricant for hot stamping process of aluminum alloy plate | |
| CN103725378A (en) | Lubricant for drawing high-finish aluminum and aluminum alloy pipes | |
| CN103725381A (en) | Lubricant for cold forging of carbon steel and low alloy steel materials | |
| CN103695126B (en) | Lubricating agent for drawing of permalloy stainless steel plate | |
| CN101029272A (en) | Cold-rolling steel-plate punch drawing lube oil and its production | |
| CN103710103B (en) | Lubricant for cold extrusion of zinc and zinc alloy materials | |
| CN103710110B (en) | Lubricant for drawing high-tension steel plate | |
| CN103571585B (en) | Lubricant for punch forming of automobile panel component | |
| US5584201A (en) | Elevated temperature metal forming lubrication method | |
| CN114276855A (en) | No-clean type drawing oil and production process thereof | |
| CN103695128B (en) | Lubricant of small aluminum-drawing bucket box | |
| CN102510895B (en) | Lubricating oil composition for die forging and die forging device | |
| CN104059740A (en) | Lubricating agent for special-shaped steel tube cold-drawing production | |
| CN103666704B (en) | Lubricant for extruding lead and lead alloy materials | |
| CN103725379A (en) | Lubricant for high-speed drawing of minor-diameter aluminum and aluminum alloy pipes | |
| JP3881269B2 (en) | Surface treatment method for plastic working of metal materials | |
| CN103695124A (en) | Lubricant for drawing of aluminum and aluminum alloy tubes | |
| CN103695090B (en) | Lubricant for aluminum wire finish-broaching | |
| CN107629836A (en) | A kind of Tube Drawing oil | |
| CA1311462C (en) | Process for lubricating the surface of metal parts, made of copper or of iron- or copper- based alloys, to be cold or warm worked and means of lubrication implemented |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| PB01 | Publication | ||
| PB01 | Publication | ||
| SE01 | Entry into force of request for substantive examination | ||
| SE01 | Entry into force of request for substantive examination |