CN101029271B - Zinc-coated steel-plated punch drawing lube oil and its production - Google Patents
Zinc-coated steel-plated punch drawing lube oil and its production Download PDFInfo
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- CN101029271B CN101029271B CN2007100108783A CN200710010878A CN101029271B CN 101029271 B CN101029271 B CN 101029271B CN 2007100108783 A CN2007100108783 A CN 2007100108783A CN 200710010878 A CN200710010878 A CN 200710010878A CN 101029271 B CN101029271 B CN 101029271B
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Abstract
A galvanized steel plate punch stretch lube oil consists of motor oil 45-55wt%, castor oil 2-4wt%, soya oil 25-35wt%, mersolates 0.5-1.5wt%, zinc naphthenate 0.5-1.5wt%, triethyl phosphate 2-4wt%, chlorinated paraffin 3-5wt%, butyl-octanol zinc salt phosphinothioyl 2-4wt%, poly-n-butyl vinyl ether 4-6wt% and bactericide 0.2-0.3wt%. The process is carried out by adding motor oil into reactor, heating to 90-100degree, agitating at 750-850/min, adding into mersolates, zinc naphthenate, chlorinated paraffin and triethyl phosphate successively, agitating for 1.5-2.5hrs, lowering temperature to 50-60degree, adding into castor oil, soya oil and bactericide, agitating for 0.5-1.5hrs, lowering to normal temperature, adding into butyl-octanol zinc salt phosphinothioyl and poly-n-butyl vinyl ether, and agitating at 75-85/min and agitating 1.5-2.5hrs. It has better oil-film continuity and adsorption and prevents punch work-piece from being scraped and corrosion.
Description
Technical field:
The present invention relates to a kind of Sheet Metal Forming Technology with metalworking coolant and production method, especially a kind ofly prevent that scratching from appearring in the stamped workpieces surface, corrosion, can guarantee the Zinc-coated steel-plated punch drawing lube oil and the production method of surface smoothness.
Background technology:
Punch process is called plate stamping again, is by mould sheet material to be exerted pressure, and makes it to separate or produce viscous deformation, thereby obtains the method for processing parts of certain size, shape and performance.In the punch process process, metallic substance produces plasticity shearing strain, between the shear surface that produces and mold work surface as the generation strong friction, then make localized hyperthermia and cause " seam " and adhesive wear, therefore need to use to have to reduce friction, the lubricant of the effect of cooling, in the hope of form withstand voltage heat-resisting and tough and tensile composite lubricating film in the metallic surface, new life's shear surface and die-face are separated, thereby reach the raising die life, the purpose of steady shear face surface quality.But, because relatively sliding is hard mold and softer processed blank in the punching stretch process, what viscous deformation took place is the whole blank that comprises surface in contact, the contact surface of blank and mould is very big again in addition, therefore is difficult to form on whole surface of friction successive hydrodynamic lubrication film.At present, the lubricating oil that is applied to Zinc-coated steel-plated punch drawing is exactly because of the existing problems of choosing in effective constituent and proportioning, cause the punch of lubricating oil in press tool, between die surface and the workpiece material contact surface formed oil film be difficult to continuous and adsorptivity relatively poor, under powerful stamping press extruding, formed oil film is damaged easily, make between sheet material part and the mould and may be in dry condition, the stamped workpieces surface is scratched easily, and the easy oxidation of plate surface and corrosion (pitting corrosion and spot erosion etc.) occurs, smooth finish, luminance brightness sharply reduces, give the phosphatization in road, back, spraying coating process makes troubles, and has had a strong impact on the visual appearance of product; Also aggravate the wearing and tearing to mould simultaneously, influence the work-ing life of mould, production cost increasing, production cycle are prolonged, manufacturer suffers bigger financial loss.
Summary of the invention:
The present invention is in order to solve the above-mentioned technical problem of existing in prior technology, a kind of oil film continuity and excellent adsorption to be provided, can prevent that scratching from appearring in the stamped workpieces surface, corrosion, can guaranteeing the Zinc-coated steel-plated punch drawing lube oil and the production method of surface smoothness.
Technical solution of the present invention is: a kind of Zinc-coated steel-plated punch drawing lube oil is characterized in that making as follows:
A. be that 45～55% machinery oil adds in the reactor with weight percent, be heated to 90～100 ℃, start agitator, rotating speed is 750～850 rev/mins, the weight percent that adds successively is that 0.5～1.5% petroleum sodium sulfonate, weight percent are that 0.5～1.5% zinc naphthenate, weight percent are that 3～5% clorafin, weight percent are 2～4% triethyl phosphates then, and continuously stirring 1.5～2.5h, cool to 50～60 ℃ then;
B. add weight percent more successively and be 2～4% Viscotrol C, weight percent and be 25～35% soybean oil, weight percent and be 0.2～0.3% isothiazolinone, continue to stir 0.5～1.5h, reduce to normal temperature;
C. add weight percent successively and be 2～～4% sulphur phosphorus fourth octyl group zinc salt, weight percent and be 4～～6% polyvinyl n-butyl ether, stir 1.5～2.5h by 75～～85 rev/mins stirring velocitys.
Optimum feed stock component and weight percent are as follows:
Machinery oil 49.75%
Viscotrol C 3%
Soybean oil 30%
Petroleum sodium sulfonate 1%
Zinc naphthenate 1%
Tricresyl phosphate second fat 3%
Clorafin 4%
Sulphur phosphorus fourth octyl group zinc salt 3%
Polyvinyl n-butyl ether 5%
Isothiazolinone 0.25%.
A kind of production method of Zinc-coated steel-plated punch drawing lube oil is characterized in that having the following steps:
A. be that 45～55% machinery oil adds in the reactor with weight percent, be heated to 90～100 ℃, start agitator, rotating speed is 750～850 rev/mins, the weight percent that adds successively is that 0.5～1.5% petroleum sodium sulfonate, weight percent are that 0.5～1.5% zinc naphthenate, weight percent are that 3～5% clorafin, weight percent are 2～4% triethyl phosphates then, and continuously stirring 1.5～2.5h, cool to 50～60 ℃ then;
B. add weight percent more successively and be 2～4% Viscotrol C, weight percent and be 25～35% soybean oil, weight percent and be 0.2～0.3% isothiazolinone, continue to stir 0.5～1.5h, reduce to normal temperature;
C. add weight percent successively and be 2～4% sulphur phosphorus fourth octyl group zinc salt, weight percent and be 4～6% polyvinyl n-butyl ether, stir 1.5～2.5h by 75～85 rev/mins stirring velocitys.
Oiliness improver of the present invention mainly is lipid acid and the alcohols organic compound that long carbochain end has active group, the active group and the metallic surface of these organic compound react, in punching course, just can make chemical transformation takes place himself, generate certain thickness protective membrane at the surface in contact of punching press by the high temperature that produces on the frictional interface; Ultrafine solids stable compound (as triethyl phosphate) is then adopted in the extreme pressure combination, and interpolation has the acidproof compound (as zinc naphthenate) of bigger absorption residual acid etc., can chemisorption take place with the zinc coating surface that passive film is covered with, its active group once in conjunction with being adsorbed on the zinc coating surface, strengthens the adsorptive power of protective membrane by strong; And the product of lipid acid and zinc coating surface bonding is a zinc soap, and the hydrocarbon chain of these soaps partly has the characteristic of arranged vertical and galvanizing surface, thus the film that formation rule is arranged; The rust-preventive agent that is added (petroleum sodium sulfonate), inhibiter (sulphur phosphorus fourth octyl group zinc salt etc.) can effectively stop workpiece surface oxidized, and special feed composition and proportioning combination make the present invention compare with prior art, have following advantage:
1. the chemisorption of lubricant film and physical adsorbability are good, between stamped workpieces and mould, form evenly continuously, complete liquid medium film, the formed lubricant film absorption in surface firmly, the heatproof resistance to compression, be difficult in the punching stretch process destroyed, make and have good oilness between stamped workpieces and the mould, prevent stamped workpieces surface sintering, seam and being scratched, produce corrosion etc., guarantee that workpiece surface has standard compliant smooth finish, wearing and tearing have been reduced simultaneously to mould, prolong the work-ing life of mould, can reduce production cost of products, shorten the production cycle, significantly improve the production efficiency and the economic benefit of enterprise;
2. the present invention is the even thickness oily matter of sundown, is added with sterilant, and is not perishable, uses 3 months, and nontoxic ordorless smell is beneficial to environmental protection, can not influence health of operators.
Embodiment:
Embodiment 1:
A. get feed composition, the per-cent that every kind of raw material accounts for gross weight is as follows:
Machinery oil (No. 32, No. 10, No. 7) 45～55%, Viscotrol C 2～4%, soybean oil 25～35%, petroleum sodium sulfonate 0.5～1.5%, zinc naphthenate 0.5～1.5%, tricresyl phosphate second fat 2～4%, clorafin 3～5%, sulphur phosphorus fourth octyl group zinc salt (T202) 2～4%, polyvinyl n-butyl ether (T601) 4～6%, sterilant (isothiazolinone) 0.2～0.3%, every kind of raw material can be chosen arbitrarily in listed span, and total value should be 100%;
B. machinery oil is added in the reactor, be heated to 90～100 ℃, start agitator, rotating speed is 750～850 rev/mins, add petroleum sodium sulfonate, zinc naphthenate, clorafin, triethyl phosphate then successively, and continuously stirring 1.5～2.5h, cool to 50～60 ℃ then;
C. add Viscotrol C, soybean oil, sterilant more successively, continue to stir 0.5～1.5h, reduce to normal temperature;
D. add sulphur phosphorus fourth octyl group zinc salt, polyvinyl n-butyl ether at last successively, stir 1.5～2.5h by 75～85 rev/mins stirring velocitys and get final product.
Product is a pale brown look translucent thickness oily matter liquid, places 25～30 ℃ to never degenerate in following 12 months.During use, need not to add water, to be directly used in punching press lubricated, with the foregoing description 1, used continuously 3 months, and workpiece surface does not have scuffings, corrosion etc., and surface smoothness meets GB7631.5 (with the serial grade of ISO6740/T) standard-required.
Embodiment 2:
A. get feed composition, the per-cent that every kind of raw material accounts for gross weight is as follows:
Machinery oil No. 32, No. 10, No. 7) 46.7%, Viscotrol C 2%, soybean oil 35%, petroleum sodium sulfonate 1.5%, zinc naphthenate 1.5%, tricresyl phosphate second fat 4%, clorafin 3%, sulphur phosphorus fourth octyl group zinc salt (T202) 2%, polyvinyl n-butyl ether (T601) 4%, sterilant (isothiazolinone) 0.3%;
B. machinery oil is added in the reactor, be heated to 90 ℃, start agitator, rotating speed is 850 rev/mins, adds petroleum sodium sulfonate, zinc naphthenate, clorafin, triethyl phosphate then successively, and continuously stirring 1.5h, cools to 50 ℃ then;
C. add Viscotrol C, soybean oil, sterilant more successively, continue at the same rate to stir 1.5h, reduce to normal temperature;
D. add sulphur phosphorus fourth octyl group zinc salt, polyvinyl n-butyl ether at last successively, stir 2.5h by 75 rev/mins stirring velocitys and get final product.
Product is a pale brown look translucent thickness oily matter liquid, places 25～30 ℃ to never degenerate in following 12 months.During use, need not to add water, to be directly used in punching press lubricated, with the foregoing description 2, used continuously 3 months, and workpiece surface does not have scuffings, corrosion etc., and surface smoothness meets GB7631.5 (with the serial grade of ISO6740/T) standard-required.
Embodiment 3:
A. get feed composition, the per-cent that every kind of raw material accounts for gross weight is as follows:
Machinery oil No. 32, No. 10, No. 7) 52.8%, Viscotrol C 4%, soybean oil 25%, petroleum sodium sulfonate 0.5%, zinc naphthenate 0.5%, tricresyl phosphate second fat 2%, clorafin 5%, sulphur phosphorus fourth octyl group zinc salt (T202) 4%, polyvinyl n-butyl ether (T601) 6%, sterilant (isothiazolinone) 0.2%;
B. machinery oil is added in the reactor, be heated to 100 ℃, start agitator, rotating speed is 750 rev/mins, adds petroleum sodium sulfonate, zinc naphthenate, clorafin, triethyl phosphate then successively, and continuously stirring 2.5h, cools to 60 ℃ then;
C. add Viscotrol C, soybean oil, sterilant more successively, continue at the same rate to stir 0.5h, reduce to normal temperature;
D. add sulphur phosphorus fourth octyl group zinc salt, polyvinyl n-butyl ether at last successively, stir 1.5h by 85 rev/mins stirring velocitys and get final product.
Product is a pale brown look translucent thickness oily matter liquid, places 25～30 ℃ to never degenerate in following 12 months.During use, need not to add water, to be directly used in punching press lubricated, with the foregoing description 3, used continuously 3 months, and workpiece surface does not have scuffings, corrosion etc., and surface smoothness meets GB7631.5 (with the serial grade of ISO6740/T) standard-required.
Embodiment 4:
A. the per-cent that feed composition, every kind of raw material account for gross weight is as follows:
Machinery oil No. 32, No. 10, No. 7) 49.75%, Viscotrol C 3%, soybean oil 30%, petroleum sodium sulfonate 1%, zinc naphthenate 1%, tricresyl phosphate second fat 3%, clorafin 4%, sulphur phosphorus fourth octyl group zinc salt (T202) 3%, polyvinyl n-butyl ether (T601) 5%, sterilant (isothiazolinone) 0.25%;
B. machinery oil is added in the reactor, be heated to 95 ℃, start agitator, rotating speed is 800 rev/mins, adds petroleum sodium sulfonate, zinc naphthenate, clorafin, triethyl phosphate then successively, and continuously stirring 2h, cools to 55 ℃ then;
C. add Viscotrol C, soybean oil, sterilant more successively, continue at the same rate to stir 1h, reduce to normal temperature;
D. add sulphur phosphorus fourth octyl group zinc salt, polyvinyl n-butyl ether at last successively, stir 1h by 80 rev/mins stirring velocitys and get final product.
Embodiment 4 is illustrated embodiments of the present invention, and result of use is best.Product is a pale brown look translucent thickness oily matter liquid, places 25～30 ℃ to never degenerate in following 12 months.During use, need not to add water, to be directly used in punching press lubricated, with the foregoing description 4, used continuously 3 months, and workpiece surface does not have scuffings, corrosion etc., and surface smoothness meets GB7631.5 (with the serial grade of ISO6740/T) standard-required.
Claims (3)
1. Zinc-coated steel-plated punch drawing lube oil is characterized in that making as follows:
A. be that 45～55% machinery oil adds in the reactor with weight percent, be heated to 90～100 ℃, start agitator, rotating speed is 750～850 rev/mins, the weight percent that adds successively is that 0.5～1.5% petroleum sodium sulfonate, weight percent are that 0.5～1.5% zinc naphthenate, weight percent are that 3～5% clorafin, weight percent are 2～4% triethyl phosphates then, and continuously stirring 1.5～2.5h, cool to 50～60 ℃ then;
B. add weight percent more successively and be 2～4% Viscotrol C, weight percent and be 25～35% soybean oil, weight percent and be 0.2～0.3% isothiazolinone, continue to stir 0.5～1.5h, reduce to normal temperature;
C. add weight percent successively and be 2～4% sulphur phosphorus fourth octyl group zinc salt, weight percent and be 4～6% polyvinyl n-butyl ether, stir 1.5～2.5h by 75～85 rev/mins stirring velocitys.
2. Zinc-coated steel-plated punch drawing lube oil according to claim 1, the weight percent that it is characterized in that described machinery oil is 49.75%, the weight percent of Viscotrol C is 3%, the weight percent of soybean oil is 30%, the weight percent of petroleum sodium sulfonate is 1%, the weight percent of zinc naphthenate is 1%, the weight percent of tricresyl phosphate second fat is 3%, the weight percent of clorafin is 4%, the weight percent of sulphur phosphorus fourth octyl group zinc salt is 3%, the weight percent of polyvinyl n-butyl ether is 5%, the weight percent of isothiazolinone is 0.25%.
3. the production method of a Zinc-coated steel-plated punch drawing lube oil is characterized in that having the following steps:
A. be that 45～55% machinery oil adds in the reactor with weight percent, be heated to 90～100 ℃, start agitator, rotating speed is 750～850 rev/mins, the weight percent that adds successively is that 0.5～1.5% petroleum sodium sulfonate, weight percent are that 0.5～1.5% zinc naphthenate, weight percent are that 3～5% clorafin, weight percent are 2～4% triethyl phosphates then, and continuously stirring 1.5～2.5h, cool to 50～60 ℃ then;
B. add weight percent more successively and be 2～4% Viscotrol C, weight percent and be 25～35% soybean oil, weight percent and be 0.2～0.3% isothiazolinone, continue to stir 0.5～1.5h, reduce to normal temperature;
C. add weight percent successively and be 2～4% sulphur phosphorus fourth octyl group zinc salt, weight percent and be 4～6% polyvinyl n-butyl ether, stir 1.5～2.5h by 75～85 rev/mins stirring velocitys.
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| CN101029271B true CN101029271B (en) | 2010-10-13 |
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| CN101255372B (en) * | 2008-04-22 | 2012-02-15 | 大连三达奥克化学股份有限公司 | Carbon steel work-piece tapping oil and production method |
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| CN101993757A (en) * | 2009-08-18 | 2011-03-30 | 邵阳市创捷化工有限公司 | Powdered lubricant special for special steel and production method thereof |
| CN102051252A (en) * | 2009-10-27 | 2011-05-11 | 薛淑芳 | Energy-saving gear oil of worm gear |
| CN104450084A (en) * | 2014-11-20 | 2015-03-25 | 无锡鸿声铝业有限公司 | Aluminum alloy plate stamping and drawing lubricating oil and preparation method thereof |
| CN104497879A (en) * | 2014-12-31 | 2015-04-08 | 芜湖协诚金属制品有限公司 | Coating agent for punch forming of automobile guide plate |
| CN105397413A (en) * | 2015-11-30 | 2016-03-16 | 惠州学院 | Production process of electric rice cooker |
| CN106350175A (en) * | 2016-08-29 | 2017-01-25 | 四川正梁机械有限公司 | Lubricant for automobile chassis stampings and a preparing method thereof |
| CN111142203B (en) * | 2019-12-26 | 2022-04-08 | 江苏英杰光缆科技有限公司 | Method for improving flexibility of optical cable |
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|---|---|---|---|---|
| US4612127A (en) * | 1983-09-28 | 1986-09-16 | Hitachi, Ltd. | Lubricant for metal forming and process for metal forming |
| CN1077737A (en) * | 1992-04-14 | 1993-10-27 | 上海工业大学 | The process for preparing compound chlorinated paraffin antiwear additive of addition of epoxy vegetable oil |
| CN1270210A (en) * | 2000-04-17 | 2000-10-18 | 中国科学院兰州化学物理研究所 | Composite lubricant additive for drawing copper tubes |
| CN1321734A (en) * | 2000-04-28 | 2001-11-14 | 徐欣渡 | Anti-rusting antibiotic water base cutting fluid and its preparation method |
| CN1580214A (en) * | 2003-07-31 | 2005-02-16 | 中国石油化工股份有限公司 | Alkyl lubricating grease composition |
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2007
- 2007-04-09 CN CN2007100108783A patent/CN101029271B/en not_active Expired - Fee Related
Patent Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4612127A (en) * | 1983-09-28 | 1986-09-16 | Hitachi, Ltd. | Lubricant for metal forming and process for metal forming |
| CN1077737A (en) * | 1992-04-14 | 1993-10-27 | 上海工业大学 | The process for preparing compound chlorinated paraffin antiwear additive of addition of epoxy vegetable oil |
| CN1270210A (en) * | 2000-04-17 | 2000-10-18 | 中国科学院兰州化学物理研究所 | Composite lubricant additive for drawing copper tubes |
| CN1321734A (en) * | 2000-04-28 | 2001-11-14 | 徐欣渡 | Anti-rusting antibiotic water base cutting fluid and its preparation method |
| CN1580214A (en) * | 2003-07-31 | 2005-02-16 | 中国石油化工股份有限公司 | Alkyl lubricating grease composition |
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