CN105001948A - Emulsified oil composition based on castor oil and rolled through stainless steel - Google Patents
Emulsified oil composition based on castor oil and rolled through stainless steel Download PDFInfo
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- CN105001948A CN105001948A CN201510303948.9A CN201510303948A CN105001948A CN 105001948 A CN105001948 A CN 105001948A CN 201510303948 A CN201510303948 A CN 201510303948A CN 105001948 A CN105001948 A CN 105001948A
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Abstract
The invention discloses an emulsified oil composition based on castor oil and rolled through stainless steel. The refined castor oil is adopted as base oil and matched with a plurality of addition agents comprising an oiliness agent, an anti-wear agent, an extreme-pressure agent, a metal deactivator, an antioxidant, an anti-foaming agent, an emulsifying agent, a sterilizing agent, an adjuvant, a friction improving agent and a reinforcing agent. The composition has good lubricity, mobility, wettability, cleaning performance, pressure-bearing performance and cooling performance, and excellent anti-attrition performance, anti-corrosion performance and annealing performance, and is environmentally friendly, a plate with the high surface quality is easy to obtain, foul smells and toxicity are avoided, and less oil mist is generated.
Description
Technical field
The invention belongs to rolled lubricating oil field in intermetallic composite coating, particularly castor-oil plant base rolled stainless steel emulsified oil composition.
Background technology
Due to improving constantly of people's living standard, all kinds of Stainless Steel Products demand is constantly increased, also promote developing rapidly of stainless steel industry.Stainless rolling lubricant is divided into oil type and emulsified two class usually.The rolled stainless steel lubricant of oil type has the sheet material of good oilness, cooling and anti-attrition, the surperficial matter of annealing, easy acquisition.
Along with the development of rolled stainless steel technology, roll speed is also more and more faster, and rolling requirements is more and more higher, and oil type rolled stainless steel lubricant can not meet the requirement of rolling technique under new operating mode.And the stainless steel lubricant of oil-in-water type in use, becoming emulsion by being watered, the requirement of the lubrication of rolling technology, anti-attrition and cooling can be met preferably, also there is good use stability simultaneously.Therefore, the performance requriements of stainless-steel cold-rolling technique to rolling lubricant has:
1. good lubricity, can provide the oil film of adequate thickness, reduces the surface damage because lack of lubrication produces, and reduces the vibrations in the operation of rolling simultaneously;
2. good cooling, takes away the heat produced in rolling in time, makes roll not fever expansion distortion and maintenance satisfactory prod template;
3. excellent annealing cleanness, after rolling and annealing should keep surface quality;
4. good chemical stability, not with rolled metal generation chemical reaction, does not affect the physicals of metal yet, and recycling in process not perishable, workability is stablized, and has longer work-ing life;
5. environment protection health, has no irritating odor, and not containing harmful composition, can not cause health problem, can enter environment after process because of contact.
Summary of the invention
The technical problem to be solved in the present invention is to provide a kind ofly has good oilness, mobility, wetting property, cleaning, pressure-bearing property and cooling performance, excellent anti-attrition, non-corrosibility and annealing and environmental friendliness, the sheet material of the high surperficial matter of easy acquisition, and odorless, the castor-oil plant base rolled stainless steel emulsified oil composition that nontoxic, mist of oil is few.
The present invention adopts following technical scheme to solve the problems of the technologies described above:
Castor-oil plant base rolled stainless steel emulsified oil composition, adopt oil based on refined caster oil, coordinate multiple additives, its each component and mass percent thereof are:
| Component | Mass percent content |
| Base oil | Surplus |
| Oiliness improver | 2.0％～4.0％ |
| Anti-wear agent | 4.0％～6.0％ |
| Extreme pressure agent | 3.0％～5.0％ |
| Metal passivator | 0.4％～0.9％ |
| Oxidation inhibitor | 0.5％～0.8％ |
| Kilfoam | 50～100ppm |
| Emulsifying agent | 15％～25％ |
| Sterilant | 0.06％～0.1％ |
| Auxiliary agent | 3.0％～5.0％ |
| Friction improver | 0.2％～0.8％ |
| Strengthening agent | 1.0％～2.0％ |
Oiliness improver is sulfurized lard; Anti-wear agent is the sulfide isobutene of mass ratio 50% and the aminothio ester compound of 50%; Extreme pressure agent is acid phosphonous acid dibutylester; Metal passivator is 124 Triazole derivative; Oxidation inhibitor is the dialkyl diphenylamine of mass ratio 50% and the phenolic ester type oxidation inhibitor T508 compound of 50%; Kilfoam is dimethyl silicone oil;
Emulsifying agent is the octylphenol ether OFE-15 compound of the octylphenol ether OPE-10 and 50% of mass ratio 50%; Sterilant is hexahydro--diazine-Oxazolidine derivates; Auxiliary agent is Arlacel-80; Friction improver is alkylthio molybdenum phosphate T464; Strengthening agent is oily borate.
The remarkable advantage of emulsified oil composition of the present invention has: good lubricity, can provide the oil film of adequate thickness, reduces the surface damage because lack of lubrication produces, and reduces the vibrations in the operation of rolling simultaneously; Good cooling, takes away the heat produced in rolling in time, makes roll not fever expansion distortion and maintenance satisfactory prod template; Excellent annealing cleanness, after rolling and annealing should keep surface quality; Good chemical stability, not with rolled metal generation chemical reaction, does not affect the physicals of metal yet, and recycling in process not perishable, workability is stablized, and has longer work-ing life; Environment protection health, has no irritating odor, and not containing harmful composition, can not cause health problem, can enter environment after process because of contact.
Embodiment
Embodiment 1:
Following component is in harmonious proportion by mass percentage and forms:
| Component | Mass percent content |
| Refined caster oil | Surplus |
| Sulfurized lard | 3.0％ |
| The sulfide isobutene of mass ratio 50% and the aminothio ester compound of 50% | 5.0％ |
| Acid phosphonous acid dibutylester | 3.5％ |
| 124 Triazole derivative | 0.6％ |
| The dialkyl diphenylamine of mass ratio 50% and the phenolic ester type oxidation inhibitor T508 compound of 50% | 0.7％ |
| Dimethyl silicone oil | 70ppm |
| The octylphenol ether OFE-15 compound of the octylphenol ether OPE-10 and 50% of mass ratio 50% | 20.0％ |
| Hexahydro--diazine-Oxazolidine derivates | 0.07％ |
| Arlacel-80 | 4.0％ |
| Alkylthio molybdenum phosphate T 464 | 0.5％ |
| Oily borate | 1.5％ |
Each constituent mass percentage ratio summation is 100% above.
Embodiment 2:
Following component is in harmonious proportion by mass percentage and forms:
| Component | Mass percent content |
| Refined caster oil | Surplus |
| Sulfurized lard | 3.0％ |
| The sulfide isobutene of mass ratio 50% and the aminothio ester compound of 50% | 5.0％ |
| Acid phosphonous acid dibutylester | 4.0％ |
| 124 Triazole derivative | 0.7％ |
| The dialkyl diphenylamine of mass ratio 50% and the phenolic ester type oxidation inhibitor T508 compound of 50% | 0.6％ |
| Dimethyl silicone oil | 75ppm |
| The octylphenol ether OFE-15 compound of the octylphenol ether OPE-10 and 50% of mass ratio 50% | 21.0％ |
| Hexahydro--diazine-Oxazolidine derivates | 0.08％ |
| Arlacel-80 | 4.0％ |
| Alkylthio molybdenum phosphate T 464 | 0.6％ |
| Oily borate | 1.5％ |
Each constituent mass percentage ratio summation is 100% above.
Embodiment 3:
Following component is in harmonious proportion by mass percentage and forms:
| Component | Mass percent content |
| Refined caster oil | Surplus |
| Sulfurized lard | 3.0％ |
| The sulfide isobutene of mass ratio 50% and the aminothio ester compound of 50% | 6.0％ |
| Acid phosphonous acid dibutylester | 4.0％ |
| 124 Triazole derivative | 0.7％ |
| The dialkyl diphenylamine of mass ratio 50% and the phenolic ester type oxidation inhibitor T508 compound of 50% | 0.7％ |
| Dimethyl silicone oil | 70ppm |
| The octylphenol ether OFE-15 compound of the octylphenol ether OPE-10 and 50% of mass ratio 50% | 20.0％ |
| Hexahydro--diazine-Oxazolidine derivates | 0.07％ |
| Arlacel-80 | 3.5％ |
| Alkylthio molybdenum phosphate T 464 | 0.6％ |
| Oily borate | 1.0％ |
Each constituent mass percentage ratio summation is 100% above.
The main physical and chemical index of typical case of embodiment 3 product:
| Project | Quality index |
| 40 DEG C of kinematic viscosity/(mm 2﹒s -1) | 46.66 |
| Saponification value/mg KOH ﹒ g -1 | 168.6 |
| Acid number/(mg KOH ﹒ g -1) | 15.8 |
| Copper corrosion (T 2Copper, 100 DEG C, 3h)/level | 1b |
| Load P instigateed by maximum nothing card B/N | 1188 |
| Sintering load PD/N | 2520 |
| Outward appearance (40 DEG C) | Light yellow clear liquid |
Claims (10)
1. castor-oil plant base rolled stainless steel emulsified oil composition, is characterized in that: adopt oil based on refined caster oil, coordinate multiple additives, the mass percent of its each component is:
2. castor-oil plant base rolled stainless steel emulsified oil composition as claimed in claim 1, is characterized in that: oiliness improver is sulfurized lard.
3. castor-oil plant base rolled stainless steel emulsified oil composition as claimed in claim 1, it is characterized in that, anti-wear agent is the sulfide isobutene of mass ratio 50% and the aminothio ester compound of 50%.
4. castor-oil plant base rolled stainless steel emulsified oil composition as claimed in claim 1, it is characterized in that, extreme pressure agent is acid phosphonous acid dibutylester.
5. castor-oil plant base rolled stainless steel emulsified oil composition as claimed in claim 1, it is characterized in that, metal passivator is 124 Triazole derivative.
6. castor-oil plant base rolled stainless steel emulsified oil composition as claimed in claim 1, it is characterized in that, oxidation inhibitor is the dialkyl diphenylamine of mass ratio 50% and the phenolic ester type oxidation inhibitor T508 compound of 50%.
7. castor-oil plant base rolled stainless steel emulsified oil composition as claimed in claim 1, it is characterized in that, kilfoam is dimethyl silicone oil.
8. castor-oil plant base rolled stainless steel emulsified oil composition as claimed in claim 1, it is characterized in that, emulsifying agent is the octylphenol ether OFE-15 compound of the octylphenol ether OPE-10 and 50% of mass ratio 50%.
9. castor-oil plant base rolled stainless steel emulsified oil composition as claimed in claim 1, it is characterized in that, sterilant is hexahydro--diazine-Oxazolidine derivates; Auxiliary agent is Arlacel-80.
10. castor-oil plant base rolled stainless steel emulsified oil composition as claimed in claim 1, it is characterized in that, friction improver is alkylthio molybdenum phosphate T464; Strengthening agent is oily borate.
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| Application Number | Priority Date | Filing Date | Title |
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| CN201510303948.9A CN105001948A (en) | 2015-06-05 | 2015-06-05 | Emulsified oil composition based on castor oil and rolled through stainless steel |
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| CN201510303948.9A CN105001948A (en) | 2015-06-05 | 2015-06-05 | Emulsified oil composition based on castor oil and rolled through stainless steel |
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| CN105001948A true CN105001948A (en) | 2015-10-28 |
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Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN106753282A (en) * | 2016-11-29 | 2017-05-31 | 大庆市加通石油化工有限公司 | A kind of industrial composite environmental-friendly oil and preparation method thereof |
| CN106929131A (en) * | 2017-04-20 | 2017-07-07 | 合肥浦尔菲电线科技有限公司 | A kind of machining emulsion type lubricant |
| CN112063435A (en) * | 2019-06-10 | 2020-12-11 | 广州加美隆润滑油有限公司 | Cleaning-free stainless steel rolling lubricant |
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| CN103275792A (en) * | 2013-05-19 | 2013-09-04 | 广西大学 | Environment-friendly stainless steel pipe rolling oil |
| CN103589194A (en) * | 2012-08-16 | 2014-02-19 | 深圳市红叶杰科技有限公司 | Hydrophobic treatment method of gas phase white carbon black |
| CN103789071A (en) * | 2014-02-25 | 2014-05-14 | 广州粤晖金属机械防护技术有限公司 | Environment-friendly steel pipe expanding extreme-pressure antirust emulsified oil as well as preparation method and application thereof |
| CN104293443A (en) * | 2014-09-24 | 2015-01-21 | 中国石油化工股份有限公司 | Rolling emulsified oil composition and application thereof |
| CN104342255A (en) * | 2014-09-24 | 2015-02-11 | 中国石油化工股份有限公司 | Emulsified oil for precise copper strip rolling, and preparation method and application thereof |
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2015
- 2015-06-05 CN CN201510303948.9A patent/CN105001948A/en active Pending
Patent Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN103589194A (en) * | 2012-08-16 | 2014-02-19 | 深圳市红叶杰科技有限公司 | Hydrophobic treatment method of gas phase white carbon black |
| CN103275792A (en) * | 2013-05-19 | 2013-09-04 | 广西大学 | Environment-friendly stainless steel pipe rolling oil |
| CN103789071A (en) * | 2014-02-25 | 2014-05-14 | 广州粤晖金属机械防护技术有限公司 | Environment-friendly steel pipe expanding extreme-pressure antirust emulsified oil as well as preparation method and application thereof |
| CN104293443A (en) * | 2014-09-24 | 2015-01-21 | 中国石油化工股份有限公司 | Rolling emulsified oil composition and application thereof |
| CN104342255A (en) * | 2014-09-24 | 2015-02-11 | 中国石油化工股份有限公司 | Emulsified oil for precise copper strip rolling, and preparation method and application thereof |
Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN106753282A (en) * | 2016-11-29 | 2017-05-31 | 大庆市加通石油化工有限公司 | A kind of industrial composite environmental-friendly oil and preparation method thereof |
| CN106929131A (en) * | 2017-04-20 | 2017-07-07 | 合肥浦尔菲电线科技有限公司 | A kind of machining emulsion type lubricant |
| CN112063435A (en) * | 2019-06-10 | 2020-12-11 | 广州加美隆润滑油有限公司 | Cleaning-free stainless steel rolling lubricant |
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Application publication date: 20151028 |