CN103275792A - Environment-friendly stainless steel pipe rolling oil - Google Patents
Environment-friendly stainless steel pipe rolling oil Download PDFInfo
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- CN103275792A CN103275792A CN2013101844065A CN201310184406A CN103275792A CN 103275792 A CN103275792 A CN 103275792A CN 2013101844065 A CN2013101844065 A CN 2013101844065A CN 201310184406 A CN201310184406 A CN 201310184406A CN 103275792 A CN103275792 A CN 103275792A
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Abstract
The invention discloses environment-friendly stainless steel pipe rolling oil. The stainless steel pipe rolling oil consists of the following components in percentage by mass: 88 to 92 percent of base oil, and 12 to 8 percent of other additive. Castor-based dioctyl sebacate and pentaerythritol tetraoctyl ester are compounded to form the base oil of the stainless steel pipe rolling oil. The environment-friendly stainless steel pipe rolling oil has the significant advantages that the comprehensive performance is good, and various performance indexes meet the using requirements; the rolling oil has high high-temperature oxidative stability, cleanliness, heat conductance, degreasing property, biodegradability, anti-attrition property, extreme pressure property, corrosion resistance and predominant lubricating performance; and the rolling oil can meet the requirements for lubrication when stainless steel pipes are rolled and corrosion resistance of machined workpieces.
Description
Technical field
The present invention relates to a kind of environmentally friendly stainless steel tube ROLLING OIL.
Background technology
Stainless steel is a kind of steel alloy that obtains great development in recent years, and the principal feature of cold-rolling stainless steel is to pay attention to surface quality, material height not only, and require surface luster.The lubricating condition that stainless steel tube is cold rolling to add man-hour normally has an important effect for the surface quality of steel pipe and die life and processing, so rolled stainless steel oil should have good extreme boundary lubrication performance.Usually after the rolling processing of stainless steel tube, adopt acid solution to carry out degreasing, remove the greasy dirt of steel tube surface by cleaning.Therefore degreasing speed also is to weigh the important indicator of stainless steel tube ROLLING OIL quality; Simultaneously, the stainless steel tube ROLLING OIL also should have the rust prevention during manufacture performance, to satisfy the protection against corrosion requirement of following process part.
Because people constantly strengthen environmental protection consciousness, the particularly execution of relevant laws and regulations, the environmental friendliness performance of stainless steel tube ROLLING OIL also becomes an important techniques and carries out index.The stainless steel tube ROLLING OIL should have following characteristics: 1. good lubricating property, can effectively reduce frictional coefficient; 2. the cooling efficiency height has high heat conductivility and thermal capacity, be conducive to heat to the cooling fluid transmission, nontoxic, antirust, be conducive to protect the surface of rolled products; 3. detergency is good, satisfies the cleaning of rolling back and annealing requirement.Solution surface luster, roll banding, the easy melanism of oil product are the rolling keys of stainless steel tube, the rational base oil of choice structure, and adding associated additives and adopting active media to filter is the necessary guarantee that addresses the above problem.
Summary of the invention
The technical problem to be solved in the present invention provides a kind of environmentally friendly stainless steel tube ROLLING OIL with good high-temperature oxidation stability, detergency, thermal conductivity, degreasing, biological degradability, anti-attrition, extreme pressure property, erosion resistance and outstanding oilness.
The present invention solves the problems of the technologies described above with following technical scheme: adopt castor-oil plant base dioctyl sebacate and the compound base oil as environmentally friendly stainless steel tube ROLLING OIL of tetramethylolmethane four monooctyl esters, cooperate multiple composite additive, its each component and mass percent thereof are as follows:
| Component | Content (mass percent) |
| Composite foundation oil | 88%～92% |
| Oxidation inhibitor | 0.5%～1.5% |
| Extreme pressure agent | 4.0%～7.0% |
| Oiliness improver | 1.5%～3.0% |
| Rust-preventive agent | 0.2%～0.5% |
| Foam reducing composition | 0.001%～0.01% |
Base oil is that tetramethylolmethane four monooctyl esters of the basic dioctyl sebacate of the castor-oil plant of mass ratio 50%～40% and 50%～60% are compound.
Oxidation inhibitor is that thiadiazoles derivative and 40%～50% the alkyl diphenylamine of mass ratio 60%～50% is compound.
Extreme pressure agent is that the amino monothioester of oxidized petroleum wax 52#40%～50% of mass ratio 60%～50% is compound.
Oiliness improver is that Voranol EP 2001 phosphoric acid ester and 40%～30% the 124 Triazole fatty amine salt of quality 60%～70% is compound.
Rust-preventive agent is that dialkylene succinate mass ratio 50%～60% and triazole and 50%～40% is compound.
Foam reducing composition is basic silicone oil ester.
The remarkable advantage of stainless steel tube ROLLING OIL of the present invention has:
Good combination property, every performance index all reach service requirements.Have good high-temperature oxidation stability, detergency, thermal conductivity, degreasing, biological degradability, anti-attrition, extreme pressure property, erosion resistance and outstanding oilness; Can satisfy the protection against corrosion requirement of the rolling lubricating requirement of stainless steel tube and processing back workpiece.
Embodiment
The lubricating oil that The present invention be directed to the service requirements of stainless steel tube ROLLING OIL harshness and environment friendly comes into one's own more and more and uses, adopt castor-oil plant base dioctyl sebacate and tetramethylolmethane four monooctyl esters compound as base oil, by adopting artificial neural network algorithm, targetedly to multiple functional additive screening and prediction; And adopt genetic algorithm to carry out choosing of optimization prescription, seek to obtain the stainless steel tube ROLLING OIL component of different size, cost performance.
Embodiment 1
Following component by mass percent mediation is made:
More than each component sum be 100%.
Embodiment 2
The component mediation of following mass percent is made:
More than each component sum be 100%.
Embodiment 3
The component mediation of following mass percent is made:
The branch sum is 100%.
By the evaluation of lubricating oil over-all properties, the every physical and chemical index of oil product of the present invention all reaches service requirements, and the physical and chemical index of embodiment 2 sees Table 1.
The physical and chemical index of the environmentally friendly stainless steel tube ROLLING OIL of table 1
Claims (7)
1. an environmentally friendly stainless steel tube ROLLING OIL is characterized in that adopting castor-oil plant base dioctyl sebacate and tetramethylolmethane four monooctyl esters compound as base oil, cooperates multiple composite additive, and the mass percent of its each component is:
2. environmentally friendly stainless steel tube ROLLING OIL as claimed in claim 1 is characterized in that base oil is that mass ratio is that tetramethylolmethane four monooctyl esters of 50%～40% castor-oil plant base dioctyl sebacate and 50%～60% are compound.
3. environmentally friendly stainless steel tube ROLLING OIL as claimed in claim 1 is characterized in that oxidation inhibitor is that mass ratio is that the alkyl diphenylamine of 60%～50% thiadiazoles derivative and 40%～50% is compound.
4. environmentally friendly stainless steel tube ROLLING OIL as claimed in claim 1 is characterized in that extreme pressure agent is that mass ratio is that the amino monothioester of 60%～50% clorafin 52# and 40%～50% is compound.
5. environmentally friendly stainless steel tube ROLLING OIL as claimed in claim 1 is characterized in that oiliness improver is that mass ratio is that the 124 Triazole fatty amine salt of 60%～70% Voranol EP 2001 phosphoric acid ester and 40%～30% is compound.
6. environmentally friendly stainless steel tube rolling oil composition as claimed in claim 1 is characterized in that rust-preventive agent is that mass ratio is that the dodecenylsuccinic acid ester of 50%～60% benzotriazole and 50%～40% is compound.
7. environmentally friendly stainless steel tube ROLLING OIL as claimed in claim 1 is characterized in that foam reducing composition is the methyl-silicone oil ester.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN2013101844065A CN103275792A (en) | 2013-05-19 | 2013-05-19 | Environment-friendly stainless steel pipe rolling oil |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN2013101844065A CN103275792A (en) | 2013-05-19 | 2013-05-19 | Environment-friendly stainless steel pipe rolling oil |
Publications (1)
| Publication Number | Publication Date |
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| CN103275792A true CN103275792A (en) | 2013-09-04 |
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| Application Number | Title | Priority Date | Filing Date |
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| CN2013101844065A Pending CN103275792A (en) | 2013-05-19 | 2013-05-19 | Environment-friendly stainless steel pipe rolling oil |
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Cited By (8)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN104862034A (en) * | 2015-06-05 | 2015-08-26 | 广西大学 | Lubricant combination for cold spinning copper alloy tube |
| CN105001948A (en) * | 2015-06-05 | 2015-10-28 | 广西大学 | Emulsified oil composition based on castor oil and rolled through stainless steel |
| CN106281593A (en) * | 2016-07-14 | 2017-01-04 | 天津市澳路浦润滑科技股份有限公司 | Stainless steel tube rolling oil |
| CN106281600A (en) * | 2016-07-26 | 2017-01-04 | 中国石油化工股份有限公司 | Anticorrosion type rolling oil composition and application thereof |
| CN106520292A (en) * | 2016-11-04 | 2017-03-22 | 广西大学 | An environment friendly stainless steel pipe cold rolling lubricant composition |
| CN107523389A (en) * | 2017-09-06 | 2017-12-29 | 吴江华威特种油有限公司 | A kind of ROLLING OIL being readily biodegradable |
| CN108153955A (en) * | 2017-12-20 | 2018-06-12 | 湖州师范学院 | Silicone oil damper for diesel engine multiple target dynamic matching method based on genetic algorithm |
| CN108865371A (en) * | 2018-08-01 | 2018-11-23 | 武汉钢铁有限公司 | A kind of environmentally friendly ROLLING OIL of secondary cold-rolling |
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| CN101338240A (en) * | 2008-08-15 | 2009-01-07 | 鞍山海华油脂化学有限公司 | Synthetic environment protection type hot-rolled oil and method for preparing same |
| CN101353607A (en) * | 2007-07-26 | 2009-01-28 | 颜克绳 | Manufacturing method of biomass environment-protective lubricant oil |
| CN102421881A (en) * | 2009-05-08 | 2012-04-18 | 出光兴产株式会社 | Biodegradable lubricating oil composition |
| CN102492528A (en) * | 2011-11-16 | 2012-06-13 | 济南钢铁股份有限公司 | Rolling oil composition for double frame reversible rolling mill |
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2013
- 2013-05-19 CN CN2013101844065A patent/CN103275792A/en active Pending
Patent Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101353607A (en) * | 2007-07-26 | 2009-01-28 | 颜克绳 | Manufacturing method of biomass environment-protective lubricant oil |
| CN101338240A (en) * | 2008-08-15 | 2009-01-07 | 鞍山海华油脂化学有限公司 | Synthetic environment protection type hot-rolled oil and method for preparing same |
| CN102421881A (en) * | 2009-05-08 | 2012-04-18 | 出光兴产株式会社 | Biodegradable lubricating oil composition |
| CN102492528A (en) * | 2011-11-16 | 2012-06-13 | 济南钢铁股份有限公司 | Rolling oil composition for double frame reversible rolling mill |
Cited By (9)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN104862034A (en) * | 2015-06-05 | 2015-08-26 | 广西大学 | Lubricant combination for cold spinning copper alloy tube |
| CN105001948A (en) * | 2015-06-05 | 2015-10-28 | 广西大学 | Emulsified oil composition based on castor oil and rolled through stainless steel |
| CN106281593A (en) * | 2016-07-14 | 2017-01-04 | 天津市澳路浦润滑科技股份有限公司 | Stainless steel tube rolling oil |
| CN106281600A (en) * | 2016-07-26 | 2017-01-04 | 中国石油化工股份有限公司 | Anticorrosion type rolling oil composition and application thereof |
| CN106281600B (en) * | 2016-07-26 | 2019-03-08 | 中国石油化工股份有限公司 | Anticorrosion type rolling oil composition and application thereof |
| CN106520292A (en) * | 2016-11-04 | 2017-03-22 | 广西大学 | An environment friendly stainless steel pipe cold rolling lubricant composition |
| CN107523389A (en) * | 2017-09-06 | 2017-12-29 | 吴江华威特种油有限公司 | A kind of ROLLING OIL being readily biodegradable |
| CN108153955A (en) * | 2017-12-20 | 2018-06-12 | 湖州师范学院 | Silicone oil damper for diesel engine multiple target dynamic matching method based on genetic algorithm |
| CN108865371A (en) * | 2018-08-01 | 2018-11-23 | 武汉钢铁有限公司 | A kind of environmentally friendly ROLLING OIL of secondary cold-rolling |
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Application publication date: 20130904 |