CN106281593A - Stainless steel tube rolling oil - Google Patents

Stainless steel tube rolling oil Download PDF

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Publication number
CN106281593A
CN106281593A CN201610556413.7A CN201610556413A CN106281593A CN 106281593 A CN106281593 A CN 106281593A CN 201610556413 A CN201610556413 A CN 201610556413A CN 106281593 A CN106281593 A CN 106281593A
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CN
China
Prior art keywords
oil
rolling oil
stainless steel
steel tube
extreme pressure
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
CN201610556413.7A
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Chinese (zh)
Inventor
孙兰凤
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Tianjin Auloop Lubrication Technology Co Ltd
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Tianjin Auloop Lubrication Technology Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Tianjin Auloop Lubrication Technology Co Ltd filed Critical Tianjin Auloop Lubrication Technology Co Ltd
Priority to CN201610556413.7A priority Critical patent/CN106281593A/en
Publication of CN106281593A publication Critical patent/CN106281593A/en
Pending legal-status Critical Current

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    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10MLUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M169/00Lubricating compositions characterised by containing as components a mixture of at least two types of ingredient selected from base-materials, thickeners or additives, covered by the preceding groups, each of these compounds being essential
    • C10M169/04Mixtures of base-materials and additives
    • C10M169/048Mixtures of base-materials and additives the additives being a mixture of compounds of unknown or incompletely defined constitution, non-macromolecular and macromolecular compounds
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10MLUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2205/00Organic macromolecular hydrocarbon compounds or fractions, whether or not modified by oxidation as ingredients in lubricant compositions
    • C10M2205/16Paraffin waxes; Petrolatum, e.g. slack wax
    • C10M2205/163Paraffin waxes; Petrolatum, e.g. slack wax used as base material
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10MLUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2207/00Organic non-macromolecular hydrocarbon compounds containing hydrogen, carbon and oxygen as ingredients in lubricant compositions
    • C10M2207/28Esters
    • C10M2207/283Esters of polyhydroxy compounds
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10MLUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2207/00Organic non-macromolecular hydrocarbon compounds containing hydrogen, carbon and oxygen as ingredients in lubricant compositions
    • C10M2207/40Fatty vegetable or animal oils
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10MLUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2211/00Organic non-macromolecular compounds containing halogen as ingredients in lubricant compositions
    • C10M2211/02Organic non-macromolecular compounds containing halogen as ingredients in lubricant compositions containing carbon, hydrogen and halogen only
    • C10M2211/022Organic non-macromolecular compounds containing halogen as ingredients in lubricant compositions containing carbon, hydrogen and halogen only aliphatic
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10MLUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2219/00Organic non-macromolecular compounds containing sulfur, selenium or tellurium as ingredients in lubricant compositions
    • C10M2219/02Sulfur-containing compounds obtained by sulfurisation with sulfur or sulfur-containing compounds
    • C10M2219/022Sulfur-containing compounds obtained by sulfurisation with sulfur or sulfur-containing compounds of hydrocarbons, e.g. olefines
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10MLUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2219/00Organic non-macromolecular compounds containing sulfur, selenium or tellurium as ingredients in lubricant compositions
    • C10M2219/02Sulfur-containing compounds obtained by sulfurisation with sulfur or sulfur-containing compounds
    • C10M2219/024Sulfur-containing compounds obtained by sulfurisation with sulfur or sulfur-containing compounds of esters, e.g. fats
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10MLUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2219/00Organic non-macromolecular compounds containing sulfur, selenium or tellurium as ingredients in lubricant compositions
    • C10M2219/04Organic non-macromolecular compounds containing sulfur, selenium or tellurium as ingredients in lubricant compositions containing sulfur-to-oxygen bonds, i.e. sulfones, sulfoxides
    • C10M2219/044Sulfonic acids, Derivatives thereof, e.g. neutral salts
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10MLUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2221/00Organic macromolecular compounds containing sulfur, selenium or tellurium as ingredients in lubricant compositions
    • C10M2221/04Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10MLUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2223/00Organic non-macromolecular compounds containing phosphorus as ingredients in lubricant compositions
    • C10M2223/02Organic non-macromolecular compounds containing phosphorus as ingredients in lubricant compositions having no phosphorus-to-carbon bonds
    • C10M2223/04Phosphate esters
    • C10M2223/045Metal containing thio derivatives
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10NINDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
    • C10N2030/00Specified physical or chemical properties which is improved by the additive characterising the lubricating composition, e.g. multifunctional additives
    • C10N2030/06Oiliness; Film-strength; Anti-wear; Resistance to extreme pressure
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10NINDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
    • C10N2030/00Specified physical or chemical properties which is improved by the additive characterising the lubricating composition, e.g. multifunctional additives
    • C10N2030/10Inhibition of oxidation, e.g. anti-oxidants
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10NINDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
    • C10N2040/00Specified use or application for which the lubricating composition is intended
    • C10N2040/20Metal working
    • C10N2040/24Metal working without essential removal of material, e.g. forming, gorging, drawing, pressing, stamping, rolling or extruding; Punching metal

Landscapes

  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • General Chemical & Material Sciences (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Organic Chemistry (AREA)
  • Lubricants (AREA)

Abstract

The present invention relates to a kind of stainless steel tube ROLLING OIL, it is mainly composed of base oil, and other additive and weight/mass percentage composition thereof be: extreme pressure agent: 7 17%;Antiwear additive: 1-3%;Oiliness improver: 5 16%;Antirust agent: 0.5-1.5%;Antioxidant: 0.2-1.2%.The present invention determines the antioxygenic property of selected base oil by series of experiments, and phenolic, amine type antioxidant is compounding to reach optimal antioxidant effect.Sulfur-bearing, the type of extreme pressure anti-wear additives phosphorous, chloride and composition is gone out by orthogonal.Select Polymer Synthesizing ester lubricant to improve the greasy property of ROLLING OIL.

Description

Stainless steel tube ROLLING OIL
Technical field
The invention belongs to lubricating oil field, relate to ROLLING OIL, especially a kind of stainless steel tube ROLLING OIL.
Background technology
Stainless steel tube rolling is that rotary roller gives tubing pressure under certain condition, makes tubing produce the one of plastic deformation Planting processing mode, the rolling mill practice condition of stainless steel tube is harsher, it is desirable to ROLLING OIL has good cooling and lubricity, resists Mill property, anti-oxidative stability and defat, reduce the external friction of rolled metal and roll, thus reduce roll wear, reduce Rolling gross pressure and energy expenditure, increase percentage pass reduction, reduces rolling pass, improves mill speed.According to domestic rustless steel The technology condition that seamless steel pipe is cold rolling, the technical performance typical data of reference inlet port stainless steel tube ROLLING OIL, it is determined that this The technical specification of the stainless steel tube ROLLING OIL of invention research and development.
Summary of the invention
In place of it is an object of the invention to overcome the deficiencies in the prior art, it is provided that a kind of have excellent stability, antioxygen Change stability, extreme pressure property, wear resistence, the stainless steel tube ROLLING OIL of rust-preventing characteristic.
The present invention solves technical problem and be the technical scheme is that
A kind of stainless steel tube ROLLING OIL, it is mainly composed of base oil, and other additive and weight/mass percentage composition thereof be:
Extreme pressure agent: 7-17%
Antiwear additive: 1-3%
Oiliness improver: 5-16%
Antirust agent: 0.5-1.5%
Antioxidant: 0.2-1.2%
Base oil: surplus.
And, described base oil is paraffin base oil.
And, described extreme pressure agent is by sulfurized polyisobutylene extreme pressure agent, nonactive sulfurized fatty extreme pressure agent, middle carbochain chlorination Extreme pressure agent forms, and wherein sulfurized polyisobutylene extreme pressure agent accounts for the 2-5% of ROLLING OIL gross mass, nonactive sulfurized fatty extreme pressure agent Account for the 1-4% of ROLLING OIL gross mass, middle carbochain chlorination extreme pressure agent accounts for the 4-8% of ROLLING OIL gross mass.
And, described antiwear additive is T202.
And, described oiliness improver is made up of polyol ester, Petiolus Trachycarpi oil, and wherein polyol ester accounts for ROLLING OIL gross mass 3-10%, Petiolus Trachycarpi oil account for the 2-6% of ROLLING OIL gross mass.
And, described polyol ester is pentaerythritol ester.
And, described antirust agent is oil-soluble sulfonic acid salt.
And, described antioxidant is phenolic antioxidant.
And, described phenolic antioxidant is thioether group high molecular weight phenolic antioxidant.
The present invention requires and characteristic and petroleum products blending principle according to stainless steel tube ROLLING OIL, by experimental evaluation, filters out Base oil, antioxidant, oiliness improver, extreme pressure anti-wear additives, antirust agent needed for stainless steel tube ROLLING OIL, in formula for a product development process In, the additive selected is carried out rational compatibility, by orthogonal and formulation optimization, the stainless steel tube ROLLING OIL developed There is excellent stability, anti-oxidative stability, extreme pressure property, wear resistence, rust-preventing characteristic and smokeless, excellent extreme boundary lubrication Property, pipe fitting inside and outside wall can be avoided to abrade;Good antioxygenic property, can effectively stop oil oxidation, extends oil product service life, Healthy and the environmental conservation without harmful material, beneficially operator.
Advantages of the present invention and good effect be:
1, the present invention determines the antioxygenic property of selected base oil by series of experiments, and phenolic, amine type antioxidant Compounding to reach optimal antioxidant effect.
2, the present invention goes out sulfur-bearing, the type of extreme pressure anti-wear additives phosphorous, chloride and composition by orthogonal.
3, the present invention selects Polymer Synthesizing ester lubricant to improve the greasy property of ROLLING OIL.
Detailed description of the invention
Below by specific embodiment, the invention will be further described, and following example are illustrative, is not limit Qualitatively, it is impossible to limit protection scope of the present invention with this.
Embodiment 1
A kind of stainless steel tube ROLLING OIL, it is mainly composed of base oil, and other additive and weight/mass percentage composition thereof be:
Extreme pressure agent: sulfurized polyisobutylene extreme pressure agent 2%
Nonactive sulfurized fatty extreme pressure agent 4%
Middle carbochain chlorination extreme pressure agent 4%
Antiwear additive: T202 3%
Oiliness improver: pentaerythritol ester 3%
Petiolus Trachycarpi oil 6%
Antirust agent: oil-soluble sulfonic acid salt 0.5%
Antioxidant: thioether group high molecular weight phenolic antioxidant 1.2%
Paraffin base oil: surplus
Embodiment 2
A kind of stainless steel tube ROLLING OIL, it is mainly composed of base oil, and other additive and weight/mass percentage composition thereof be:
Extreme pressure agent: sulfurized polyisobutylene extreme pressure agent 5%
Nonactive sulfurized fatty extreme pressure agent 1%
Middle carbochain chlorination extreme pressure agent 8%
Antiwear additive: T202 1%
Oiliness improver: pentaerythritol ester 10%
Petiolus Trachycarpi oil 2%
Antirust agent: oil-soluble sulfonic acid salt 1.5%
Antioxidant: thioether group high molecular weight phenolic antioxidant 0.2%
Paraffin base oil surplus
Embodiment 3
A kind of stainless steel tube ROLLING OIL, it is mainly composed of base oil, and other additive and weight/mass percentage composition thereof be:
Extreme pressure agent: sulfurized polyisobutylene extreme pressure agent 3%
Nonactive sulfurized fatty extreme pressure agent 2%
Middle carbochain chlorination extreme pressure agent 5%
Antiwear additive: T202 2%
Oiliness improver: pentaerythritol ester 7%
Petiolus Trachycarpi oil 4%
Antirust agent: oil-soluble sulfonic acid salt 1%
Antioxidant: thioether group high molecular weight phenolic antioxidant 0.8%
Paraffin base oil surplus
This stainless steel tube ROLLING OIL testing result see table:
Above-described is only the preferred embodiment of the present invention, it is noted that for those of ordinary skill in the art For, on the premise of without departing from inventive concept, it is also possible to make some deformation and improvement, these broadly fall into the protection of the present invention Scope.

Claims (9)

1. a stainless steel tube ROLLING OIL, it is mainly composed of base oil, and other additive and weight/mass percentage composition thereof be:
Extreme pressure agent: 7-17%
Antiwear additive: 1-3%
Oiliness improver: 5-16%
Antirust agent: 0.5-1.5%
Antioxidant: 0.2-1.2%
Base oil: surplus.
Stainless steel tube ROLLING OIL the most according to claim 1, it is characterised in that: described base oil is paraffinic base basis Oil.
Stainless steel tube ROLLING OIL the most according to claim 1, it is characterised in that: described extreme pressure agent is by sulfurized polyisobutylene Extreme pressure agent, nonactive sulfurized fatty extreme pressure agent, middle carbochain chlorination extreme pressure agent form, and wherein sulfurized polyisobutylene extreme pressure agent accounts for rolling The oil 2-5% of gross mass, nonactive sulfurized fatty extreme pressure agent account for the 1-4% of ROLLING OIL gross mass, middle carbochain chlorination extreme pressure agent Account for the 4-8% of ROLLING OIL gross mass.
Stainless steel tube ROLLING OIL the most according to claim 1, it is characterised in that: described antiwear additive is T202.
Stainless steel tube ROLLING OIL the most according to claim 1, it is characterised in that: described oiliness improver is by polyol ester, palm fibre Palmitic acid line of oils becomes, and wherein polyol ester accounts for the 3-10% of ROLLING OIL gross mass, Petiolus Trachycarpi oil accounts for the 2-6% of ROLLING OIL gross mass.
Stainless steel tube ROLLING OIL the most according to claim 5, it is characterised in that: described polyol ester is tetramethylolmethane Ester.
Stainless steel tube ROLLING OIL the most according to claim 1, it is characterised in that: described antirust agent is oil-soluble sulfonic acid Salt.
Stainless steel tube ROLLING OIL the most according to claim 1, it is characterised in that: described antioxidant is phenolic antioxidant.
Stainless steel tube ROLLING OIL the most according to claim 8, it is characterised in that: described phenolic antioxidant is that thioether group is high Molecular weight phenolic antioxidant.
CN201610556413.7A 2016-07-14 2016-07-14 Stainless steel tube rolling oil Pending CN106281593A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN201610556413.7A CN106281593A (en) 2016-07-14 2016-07-14 Stainless steel tube rolling oil

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN201610556413.7A CN106281593A (en) 2016-07-14 2016-07-14 Stainless steel tube rolling oil

Publications (1)

Publication Number Publication Date
CN106281593A true CN106281593A (en) 2017-01-04

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Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN110408460A (en) * 2019-08-15 2019-11-05 宝钢湛江钢铁有限公司 The control method that strip macula lutea corrodes after a kind of continuous annealing

Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN103275792A (en) * 2013-05-19 2013-09-04 广西大学 Environment-friendly stainless steel pipe rolling oil
CN103725383A (en) * 2013-12-23 2014-04-16 天津市金岛润滑油有限公司 Stamping and stretching oil for sheet metal and preparation method thereof

Patent Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN103275792A (en) * 2013-05-19 2013-09-04 广西大学 Environment-friendly stainless steel pipe rolling oil
CN103725383A (en) * 2013-12-23 2014-04-16 天津市金岛润滑油有限公司 Stamping and stretching oil for sheet metal and preparation method thereof

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN110408460A (en) * 2019-08-15 2019-11-05 宝钢湛江钢铁有限公司 The control method that strip macula lutea corrodes after a kind of continuous annealing

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Application publication date: 20170104