CN103232880B - Environment friendly energy-efficient heavy-load compression machine oil - Google Patents

Environment friendly energy-efficient heavy-load compression machine oil Download PDF

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Publication number
CN103232880B
CN103232880B CN201310126519.XA CN201310126519A CN103232880B CN 103232880 B CN103232880 B CN 103232880B CN 201310126519 A CN201310126519 A CN 201310126519A CN 103232880 B CN103232880 B CN 103232880B
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compound
oil
heavy
mass ratio
compressor
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CN103232880A (en
Inventor
黄福川
唐兴中
卢朝霞
莫宇飞
梁景
粟满荣
唐彩珍
蓝明新
李宏君
肖友程
李胜
梁慧
田宗义
赵钟兴
唐丹葵
刘琨
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Guangxi University
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Guangxi University
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Abstract

The invention provides environment friendly energy-efficient heavy-load compression machine oil, which comprises the following components by mass percentage: 90-95% of base oil and 10-5% of other additives. Metallocene poly alpha-olefins (mPAO), poly internal olefin (PIO) and dioctyl sebacate are composited as base oil of heavy-load compressor oil. One main component of the base oil of the compressor oil is dioctyl sebacate which has a sufficient raw material source, and the product is a reproducible resource with high economic benefit and social benefit, and the preparation technology is simple. Each physical and chemical index of the heavy-load compressor oil reaches the usage requirement, and the polyisobutylene can be blended with the product for producing a product which meets the performance requirements of L-DAC heavy-load compressor oil with viscosity grades as follows: N32, N46, N68, N100 and N150. The product is suitable for lubricating, cooling and sealing the cylinder and the crankcase of the middle and heavy-load piston compressor and the large-scale rotary compressor.

Description

Environmental friendliness energy-saving heavy-loading compressor oil
Technical field
The present invention relates to a kind of environmental friendliness energy-saving heavy-loading compressor oil.
Background technology
Compressor be a kind of be used for pressurized gas, improve the universal machine of gaseous tension or delivering gas, be widely used in the fields such as refrigeration, petrochemical complex, gas conveying, civil construction, pipeline network of fuel gas in city, national defence, medicine, weaving, food, machinofacture, mining metallurgy, engineering machinery.In recent years, along with the maximization of reciprocating compressor equipment with towards heavy loading, high-temperature, high pressure, large flow direction of operating development, compressor safe reliability is had higher requirement, guarantee the safe and reliable work of compressor, lubricated is one of important step.Because compressor oil directly contacts compression medium, pressure is high, easily the impact of compressed gas character; Compressor oil constantly contacts with the compressed air of high temperature at cylinder piston position, can cause the oxygenolysis of oil product and be condensed into the products such as colloid, bituminous matter, coking; Under condition of high voltage, be easy to inhale people's medium in the tramp material that contains mix, be deposited on surface of the work, produce colloid carbon deposit.When operating mode is severe, also there is metal filings, accelerated the oxidation of compressor oil, carbon deposit increases, and even causes the danger of compressor oil spontaneous combustion and blast.Solve this class problem, with existing compressor oil (DAA, DAB), cannot meet the demands.Therefore the lubricating oil that, need to develop higher category is to meet harsh operating mode demand.
At present, domestic production is main mainly with mineral type compressor oil.Mineral type compressor oil be oil through a series of fractionation, purification, refining, add additive blending and form; Because its biological degradability is extremely low, thereby be difficult to decompose at nature, physical environment is caused to day by day serious pollution.Along with technical progress, performance requriements, market requirement aspect pull and the more and more attention of people to environment protection, the friendly energy-saving compressor oil of research environment will become the focus of people's concern.As everyone knows, biomass grease not only nontoxic, there is good biodegradable, and be recyclability resource, be one of principal direction of environmental friendly lubricant technical development.The present invention will have good lubricity, demulsification resistance, preservative property, high thermal resistance, dioctyl sebacate and the metallocene poly-alpha olefins (mPAO) of the features such as low condensation point and low viscosity, the poly-compound base oil as compressor oil of internal olefin (PIO), adopt the effect of artificial neural network algorithm research several functions additive, carry out mathematical model analog calculation and screening, additive kind and usage quantity and compatibleness in the hope of best cost performance, finally obtain environmental friendliness energy-saving compressor oil formula, can accomplish energy-conservation simultaneously, reduce discharging, reduce granular material discharged, to adapt to social development.
Summary of the invention
The technical problem to be solved in the present invention is to provide a kind of environmental friendliness energy-saving heavy-loading compressor oil, this compressor oil not only has good low viscosity, viscosity temperature characteristic, low-temperature performance, low volatility, high flash point, high viscosity index (HVI), oxidation stability, thermostability, sediment monitoring ability, rust-preventing characteristic, erosion resistance, lubricity, abrasion resistance, oil-water separativeness, the anti-spumescence of high temperature, resistance to emulsion, drain period is long, the relative conventional lubrication innage of biodegradability, extremely low carbon deposit generates tendency and stronger oil film retentivity, but also improved the reliability of compressor, and can adapt to strict environmental regulation requirement, more can effectively extend work-ing life and the oil draining period of compressor.
The present invention solves the problems of the technologies described above with following technical scheme:
Each component and the mass percent of environmental friendliness energy-saving heavy-loading compressor oil are as follows:
Component Content (mass percent)
Composite foundation oil 90%~95%
Compound extreme pressure anti-wear additives 0.5%~3%
Compound antioxidant preservative 2%~4%
Composition metal purification agent 0.5%~2%
Compound ashless dispersant 0.5%~1.5%
Composition metal passivator 0.2%~0.6%
Composite antirust agent 0.2%~1%
Foam reducing composition 0.002%~0.05%
Anti-emulsifying compound agent 0.05%~0.3%
Composite foundation oil is that metallocene poly-alpha olefins (mPAO), 25%~30% the poly-internal olefin (PIO) of mass ratio 40%~30% is compound with 35%~40% dioctyl sebacate.
Compound extreme pressure anti-wear additives is that the sulfide isobutene of mass ratio 40%~35% is, the sulphur phosphorus type nitrogen containing derivative of the tritolyl phosphate of 20%-15% and 40~50% is compound.
Compound antioxidant preservative is that sulphur phosphorus brothers alcohol radical zinc salt and 60%~50% the secondary alcohol groups zinc dialkyl dithiophosphate of mass ratio 40%~50% is compound.
Composition metal purification agent is that low alkali value calcium alkylbenzenesulfonate, 30%~35% SULFURIZED CALCIUM ALKYL PHENATE WITH HIGH BASE NUMBER and 40~30% the Overbased magnesium sulphonates of mass ratio 30%~35% is compound.
Compound ashless dispersant is that the polyisobutene succinimide (high nitrogen) of mass ratio 40%~50% is compound with many succimides (low nitrogen) of 60%~50%.
Composition metal passivator is that thiadiazoles derivative and 60%~70% the nonyl diphenylamine of mass ratio 40%~30% is compound.
Composite antirust agent is that petroleum sodium sulfonate and 30%~20% the dodecenylsuccinic acid ester of mass ratio 70%~80% is compound.
Foam reducing composition is the homopolymer of acrylate.
Anti-emulsifying compound agent is that mass ratio 50% propylene oxide/ethylene oxide copolymer and 50% amine and oxyethane polycondensate are compound.
The remarkable advantage of environmental friendliness energy-saving heavy-loading compressor oil of the present invention has:
1. this compressor oil can meet multiple different applying working condition requirement.Perfection has realized the technical program and has required the quality and the performance that reach.
2. adopt metallocene poly-alpha olefins (mPAO), poly-internal olefin (PIO) and the compound base oil as heavy load air compressor oil of dioctyl sebacate, its sufficient raw, be recyclability resource, and preparation technology is simple, there is higher economic benefit and social benefit.
3. the every physical and chemical index of this heavy load air compressor oil all reaches service requirements, adopts polyisobutene to concoct out to meet L-DAC heavy load air compressor oil viscosity grade to be: the performance requriements of N32, N46, N68, N100, N150.
4. during this heavy load air compressor oil is applicable to, the cylinder of heavy loading reciprocating compressor and huge revolving formula compressor and lubricated, the cooling and sealing of crankcase.
Embodiment
The present invention is directed to the day by day harsh applying working condition requirement of heavy load air compressor oil, adopt metallocene poly-alpha olefins (mPAO), poly-internal olefin (PIO) and the compound base oil as environmental friendliness energy-saving heavy-loading compressor oil of dioctyl sebacate; By adopting artificial neural network algorithm, targetedly to several functions selection of additives and prediction; And adopt genetic algorithm to carry out choosing of Optimization design, seek to obtain the heavy load air compressor oil component of different size, cost performance.This compressor oil has the performances such as good viscosity temperature characteristic, low-temperature performance, oxidation stability, sediment monitoring ability, rust-preventing characteristic, erosion resistance, lubricity, abrasion resistance, the anti-spumescence of high temperature, biodegradability; Its every physical and chemical index all reaches service requirements, adopts polyisobutene to concoct out to meet L-DAC heavy load air compressor oil viscosity grade to be: the performance requriements of N32, N46, N68, N100, N150.
The base oil that the present invention adopts, compares with mineral oil, has excellent low-temperature performance, oxidation stability, antiwear property.Basic oil Viscosity temperature influence is very little, can in low temperature environment, flow smooth and easy, can in hot environment, keep suitable viscosity again; Reduce compressor abrasion, extend the work-ing life of compressor.Under compressor continuous high temperature, high pressure running, be difficult for oxygenolysis and generate greasy filth and carbon distribution.The dioctyl sebacate adopting is that Semen Ricini obtains Viscotrol C through squeezing or dipping extraction; Viscotrol C generates after ricinolic acid through catalytic hydrolysis or alkaline saponification; Using phenol as thinner, alkaline splitting at 260 ℃~280 ℃ temperature again; Through acidifying and purifying treatment, obtain sebacic acid; Sebacic acid and two octanols are carried out to esterification under sulfuric acid catalysis, and obtain dioctyl sebacate after a series of refining.The physico-chemical property of dioctyl sebacate is in Table 1.
The physico-chemical property of table 1 dioctyl sebacate
More and more ripe along with dioctyl sebacate preparation technique and process for refining, the dioctyl sebacate of usining also must become one of following lubricating oil development trend as environmental friendliness, the base oil that biodegradable, energy-saving compressor is oily.
Embodiment 1:
By following each component and mass percent thereof, be in harmonious proportion and form:
Embodiment 2:
By following each component and mass percent thereof, be in harmonious proportion and form:
Embodiment 3:
By following each component and mass percent thereof, be in harmonious proportion and form:
Through provincial technical supervision department, measure, the every physical and chemical index of oil product of the present invention all reaches service requirements, adopts polyisobutene to concoct out to meet L-DAC heavy load air compressor oil viscosity grade to be: the performance requriements of N32, N46, N68, N100, N150.Its every typical physical and chemical index is in Table 2.
Table 2 environmental friendliness energy-saving heavy-loading compressor oil typical case physical and chemical index

Claims (1)

1. an environmental friendliness energy-saving heavy-loading compressor oil, is characterized in that each component and mass percent are:
Each component concentration percentage ratio sum is 100% above;
Wherein:
Composite foundation oil be mass ratio 40% ~ 30% metallocene poly-alpha olefins mPAO, 25% ~ 30% poly-internal olefin PIO with
35% ~ 40% dioctyl sebacate is compound, and each component concentration percentage ratio sum is 100%;
Compound extreme pressure anti-wear additives be the sulfide isobutene of mass ratio 40% ~ 35%, the sulphur phosphorus type nitrogen containing derivative of the tritolyl phosphate of 20%-15% and 40 ~ 50% is compound, each component concentration percentage ratio sum is 100%;
Compound antioxidant preservative is that sulphur phosphorus brothers alcohol radical zinc salt and 60% ~ 50% the secondary alcohol groups zinc dialkyl dithiophosphate of mass ratio 40% ~ 50% is compound;
Composition metal purification agent is that low alkali value calcium alkylbenzenesulfonate, 30% ~ 35% SULFURIZED CALCIUM ALKYL PHENATE WITH HIGH BASE NUMBER and 40 ~ 30% the Overbased magnesium sulphonates of mass ratio 30% ~ 35% is compound, and each component concentration percentage ratio sum is 100%;
Compound ashless dispersant is that high nitrogen polyisobutene succinimide and 60% ~ 50% the many succimides of low nitrogen of mass ratio 40% ~ 50% are compound;
Composition metal passivator is that thiadiazoles derivative and 60% ~ 70% the nonyl diphenylamine of mass ratio 40% ~ 30% is compound;
Composite antirust agent is that petroleum sodium sulfonate and 30% ~ 20% the dodecenylsuccinic acid ester of mass ratio 70% ~ 80% is compound;
Foam reducing composition is the homopolymer of acrylate;
Anti-emulsifying compound agent is that mass ratio 50% propylene oxide/ethylene oxide copolymer and 50% amine and oxyethane polycondensate are compound;
Adopt polyisobutene to concoct out meeting L-DAC heavy load air compressor oil viscosity grade is the performance requriements of N32, N46, N68, N100, N150.
CN201310126519.XA 2013-04-12 2013-04-12 Environment friendly energy-efficient heavy-load compression machine oil Expired - Fee Related CN103232880B (en)

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CN103525519B (en) * 2013-10-15 2015-03-11 广西大学 Closed-cycle turbine lubricant
CN103525525B (en) * 2013-10-21 2015-03-11 广西大学 Closed cycle steam turbine lubricant
CN106318533B (en) * 2015-06-16 2019-05-17 中国石油化工股份有限公司 A kind of crankcase system lubricant oil composite and preparation method thereof
CN105219499A (en) * 2015-10-24 2016-01-06 崔子扬 A kind of strong resistance to abrasion magnetic protects machine oil
CN106479642A (en) * 2016-09-26 2017-03-08 广西谛恒生物能源投资有限公司 A kind of composition of low temperature high capability of anti-salt mist ships heavy load universal air compressor oil
CN106867641A (en) * 2017-04-01 2017-06-20 江苏奥克化学有限公司 A kind of air compressor oil composition, air compressor oil and preparation method thereof
CN107216935A (en) * 2017-05-12 2017-09-29 广西大学 A kind of nitrous oxide compressor oil composition
CN109536255A (en) * 2018-11-29 2019-03-29 苏州惠丰润滑材料有限公司 A kind of pumping fluid

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US20090247436A1 (en) * 2008-03-31 2009-10-01 Exxonmobil Research And Engineering Company Lubricant composition with improved varnish deposit resistance
CN102618360B (en) * 2011-01-27 2014-06-04 中国石油化工股份有限公司 Compressor oil composition
CN102952615A (en) * 2012-11-02 2013-03-06 北京欧陆宝石化产品有限公司 Synthetic compressor lubricating oil composition and production method thereof

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