CN1730633A - Hard water resistant water-soluble cutting solution - Google Patents

Hard water resistant water-soluble cutting solution Download PDF

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Publication number
CN1730633A
CN1730633A CN 200510041473 CN200510041473A CN1730633A CN 1730633 A CN1730633 A CN 1730633A CN 200510041473 CN200510041473 CN 200510041473 CN 200510041473 A CN200510041473 A CN 200510041473A CN 1730633 A CN1730633 A CN 1730633A
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China
Prior art keywords
alcohol ether
ether carboxylate
acid
soluble cutting
anion surfactant
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CN 200510041473
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Chinese (zh)
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CN100465254C (en
Inventor
陈寅和
林兴国
常建忠
龚丽一
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
QIDONG YOUXILU CHEMICAL INDUSTRY Co Ltd
Shanghai Yushiro Chemical Industry Co Ltd
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QIDONG YOUXILU CHEMICAL INDUSTRY Co Ltd
Shanghai Yushiro Chemical Industry Co Ltd
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Application filed by QIDONG YOUXILU CHEMICAL INDUSTRY Co Ltd, Shanghai Yushiro Chemical Industry Co Ltd filed Critical QIDONG YOUXILU CHEMICAL INDUSTRY Co Ltd
Priority to CNB2005100414737A priority Critical patent/CN100465254C/en
Publication of CN1730633A publication Critical patent/CN1730633A/en
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  • Preventing Corrosion Or Incrustation Of Metals (AREA)
  • Lubricants (AREA)

Abstract

The invention discloses a hard water resistant water-soluble cutting solution, which comprises base oil or oily agent, anionic surface active agent, antirust agent, couplant, copper alloy inhibitor, anticorrosive agent, defoaming agent and aluminum alloy inhibitor.

Description

Hard water resistant water-soluble cutting solution
Technical field:
The present invention relates to a kind of metal cutting working fluid.
Background technology:
Existing metal cutting working fluid, owing to reasons such as its prescriptions, ability hard water before use, at first needs soften processing to water, not only complexity but also cause the waste of water resources, the cost height; On the other hand, existing water-soluble metal cutting fluid, the difficult treatment of its waste liquid.Simultaneously also there is undesirable part at aspects such as oilness, rust-preventing characteristic, cooling, antifoam performances.
Goal of the invention:
The object of the present invention is to provide a kind of stability in hard water energy good, liquid waste disposal is hard water resistant water-soluble cutting solution easily.
Technical solution of the present invention is:
A kind of hard water resistant water-soluble cutting solution is characterized in that: be made up of following composition by weight:
Base oil or oiliness improver 40~60%
Anion surfactant 30~50%
Rust-preventive agent 5~10%
Couplant 3~4%
Copper alloy inhibiter 0.1~0.15%
Anticorrosive agent 1~2%
Defoamer 0.3~0.6%
Aluminium alloy inhibiter 0.5~1.0%;
Wherein base oil or oiliness improver are mineral oil, poly-alpha olefins, dibasic ester class, pentaerythritol esters, vegetables oil or department of botany's oleic acid ester; Anion surfactant is one or more and Monoethanolamine MEA BASF, diethanolamine, trolamine, a Yi Bingchunan, diisopropanolamine (DIPA), 2-amino-2-methyl-1-propanol, the morpholine in alcohol ether carboxylate or alcohol ether carboxylate and oleic acid, ricinolic acid, dimeracid, appropriate youngster's oleic acid, the isomery stearic acid, one or more the mixture in the N-methylmorpholine; Rust-preventive agent is one or more and Monoethanolamine MEA BASF, diethanolamine, trolamine, a Yi Bingchunan, diisopropanolamine (DIPA), 2-amino-2-methyl-1-propanol, the morpholine in boric acid, p-tert-butyl benzoic acid, p-nitrobenzoic acid, triazines multi-carboxylic acid compounds, the ε-different nonanoyl amino acid derivative, one or more the mixture in the N-methylmorpholine; Couplant is Virahol, propylene glycol or isomery stearyl alcohol; The copper alloy inhibiter is 124 Triazole, tetrahydroglyoxaline, thiadiazoles polysulfide or methyl benzotriazole; Anticorrosive agent is hexahydrotriazine or isothiazolinone; Defoamer is a silicone emulsion; The aluminium alloy inhibiter is one or more in Starso, sodium orthosilicate, tetraethoxysilane, the methyltrimethoxy silane.
Alcohol ether carboxylate or alcohol ether carboxylate account for 3~5% of anion surfactant total amount in anion surfactant.Alcohol ether carboxylate is alcohol ether carboxylate amine salt or alcohol ether carboxylate sodium salt.
The prescription of uniqueness of the present invention makes product can resist the hard water of 7000ppm, generally is applicable to the area that water hardness is high, and dilution water does not need just can directly use through the water demineralization processing, and working fluid reaches more than 2 years work-ing life; Waste liquid after product of the present invention uses, easily breakdown of emulsion is handled, and can adopt the method for calcium chloride, the flocculation of alum breakdown of emulsion to handle, and the CODcr clearance can reach more than 92%, passes through simple biochemical treatment again, and waste water can reach secondary discharge standard.Simultaneously also all has excellent properties at aspects such as oilness, rust-preventing characteristic, cooling, antifoam performances.
The invention will be further described below in conjunction with embodiment.
Embodiment 1:
A kind of hard water resistant water-soluble cutting solution, form by following composition by weight:
Base oil or oiliness improver 40%
Anion surfactant 50%
Rust-preventive agent 5%
Couplant 3%
Copper alloy inhibiter 0.1%
Anticorrosive agent 1%
Defoamer 0.4%
Aluminium alloy inhibiter 0.5%;
Base oil or oiliness improver are the polyoxyethylene polyoxypropylene esters (or mineral oil, poly-alpha olefins, the glycol ester of linoleic acid dimer, tetramethylolmethane four oleic acid esters, pentaerythritol tetrastearate, vegetables oil, Methyl palmitoleinate, oleic acid methyl esters) of linoleic acid dimer.
Anion surfactant is alcohol ether carboxylate (alcohol ether carboxylate amine salt or alcohol ether carboxylate sodium salt) or alcohol ether carboxylate 4~6 weight parts (example 4,5,6 weight parts) and the mixture of oleic acid (or ricinolic acid, dimeracid, appropriate youngster's oleic acid), isomery stearic acid 50 weight parts and Monoethanolamine MEA BASF (or diethanolamine, trolamine, a Yi Bingchunan, diisopropanolamine (DIPA), 2-amino-2-methyl-1-propanol, morpholine, N-methylmorpholine) 44~46 weight parts (example 44,45,46 weight parts).
Rust-preventive agent is the mixture of boric acid (or p-tert-butyl benzoic acid, p-nitrobenzoic acid, triazines multi-carboxylic acid compounds, ε-different nonanoyl amino acid derivative) 1 weight part and Monoethanolamine MEA BASF (or in diethanolamine, trolamine, a Yi Bingchunan, diisopropanolamine (DIPA), 2-amino-2-methyl-1-propanol, morpholine, N-methylmorpholine) 1~2 weight part.
Couplant is Virahol (or propylene glycol, isomery stearyl alcohol).
The copper alloy inhibiter is 124 Triazole (or tetrahydroglyoxaline, thiadiazoles polysulfide, methyl benzotriazole).
Sanitas is hexahydrotriazine (or isothiazolinone); Defoamer is a silicone emulsion.
The aluminium alloy inhibiter is tetraethoxysilane (or Starso, sodium orthosilicate, methyltrimethoxy silane).
Embodiment 2:
A kind of hard water resistant water-soluble cutting solution, form by following composition by weight:
Base oil or oiliness improver 50%
Anion surfactant 32.25%
Rust-preventive agent 10%
Couplant 4%
Copper alloy inhibiter 0.15%
Anticorrosive agent 2%
Defoamer 0.6%
Aluminium alloy inhibiter 1%;
All the other are all with embodiment 1.
Embodiment 3:
A kind of hard water resistant water-soluble cutting solution, form by following composition by weight:
Base oil or oiliness improver 58%
Anion surfactant 30%
Rust-preventive agent 5.88%
Couplant 3.5%
Copper alloy inhibiter 0.12%
Anticorrosive agent 1.5%
Defoamer 0.3%
Aluminium alloy inhibiter 0.7%;
All the other are all with embodiment 1.
Embodiment 4:
A kind of hard water resistant water-soluble cutting solution, form by following composition by weight:
Base oil or oiliness improver 45.6%
Anion surfactant 40%
Rust-preventive agent 8%
Couplant 4%
Copper alloy inhibiter 0.1%
Anticorrosive agent 1%
Defoamer 0.5%
Aluminium alloy inhibiter 0.8%;
All the other are all with embodiment 1.

Claims (3)

1, a kind of hard water resistant water-soluble cutting solution is characterized in that: be made up of following composition by weight:
Base oil or oiliness improver 40~60%
Anion surfactant 30~50%
Rust-preventive agent 5~10%
Couplant 3~4%
Copper alloy inhibiter 0.1~0.15%
Anticorrosive agent 1~2%
Defoamer 0.3~0.6%
Aluminium alloy inhibiter 0.5~1.0%;
Wherein base oil or oiliness improver are mineral oil, poly-alpha olefins, dibasic ester class, pentaerythritol esters, vegetables oil or department of botany's oleic acid ester; Anion surfactant is one or more and Monoethanolamine MEA BASF, diethanolamine, trolamine, a Yi Bingchunan, diisopropanolamine (DIPA), 2-amino-2-methyl-1-propanol, the morpholine in alcohol ether carboxylate or alcohol ether carboxylate and oleic acid, ricinolic acid, dimeracid, appropriate youngster's oleic acid, the isomery stearic acid, one or more the mixture in the N-methylmorpholine; Rust-preventive agent is one or more and Monoethanolamine MEA BASF, diethanolamine, trolamine, a Yi Bingchunan, diisopropanolamine (DIPA), 2-amino-2-methyl-1-propanol, the morpholine in boric acid, p-tert-butyl benzoic acid, p-nitrobenzoic acid, triazines multi-carboxylic acid compounds, the ε-different nonanoyl amino acid derivative, one or more the mixture in the N-methylmorpholine; Couplant is Virahol, propylene glycol or isomery stearyl alcohol; The copper alloy inhibiter is 124 Triazole, tetrahydroglyoxaline, thiadiazoles polysulfide or methyl benzotriazole; Anticorrosive agent is hexahydrotriazine or isothiazolinone; Defoamer is a silicone emulsion; The aluminium alloy inhibiter is one or more in Starso, sodium orthosilicate, tetraethoxysilane, the methyltrimethoxy silane.
2, hard water resistant water-soluble cutting solution according to claim 1 is characterized in that: alcohol ether carboxylate or alcohol ether carboxylate account for 3~5% of anion surfactant total amount in anion surfactant.
3, hard water resistant water-soluble cutting solution according to claim 1 and 2 is characterized in that: alcohol ether carboxylate is alcohol ether carboxylate amine salt or alcohol ether carboxylate sodium salt.
CNB2005100414737A 2005-08-09 2005-08-09 Hard water resistant water-soluble cutting solution Active CN100465254C (en)

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CN100465254C CN100465254C (en) 2009-03-04

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Cited By (22)

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CN101240422B (en) * 2008-03-12 2010-04-07 益田润石(北京)化工有限公司 Water-base metal antirust agent composition
CN101265435B (en) * 2008-04-23 2010-09-29 常州市夏雷化学有限公司 Method for preparing water-soluble anti-rust lubricating additive
CN101108897B (en) * 2007-08-31 2010-10-06 田欣利 Highly effective grinding fluid for silicon ceramic
CN101914411A (en) * 2010-08-24 2010-12-15 安庆市中天石油化工有限公司 Anti-rust cutting fluid and preparation method thereof
CN101608310B (en) * 2008-06-16 2011-03-02 南京科润工业介质有限公司 Long-acting emulsion-type antirust fluid
CN102220183A (en) * 2011-05-11 2011-10-19 广州市联诺化工科技有限公司 Vegetable oil-based water-soluble cutting fluid
CN102250673A (en) * 2011-06-15 2011-11-23 启东尤希路化学工业有限公司 Environment-friendly emulsion cutting oil with high lubricity and high permeability for metal working
CN102250676A (en) * 2011-06-15 2011-11-23 启东尤希路化学工业有限公司 High-performance environmentally-friendly semisynthetic water-soluble metal working fluid
CN101240218B (en) * 2008-02-29 2011-12-07 益田润石(北京)化工有限公司 Emulsification type metal cutting liquor composition
CN102295976A (en) * 2011-07-13 2011-12-28 李胜 Lubricant for heavy-load machining of metals and preparation method thereof
CN102311864A (en) * 2011-08-05 2012-01-11 安庆市中天石油化工有限公司 Cutting fluid special for NC machine tools
CN101560433B (en) * 2009-05-11 2012-03-07 启东尤希路化学工业有限公司 Anti-magnesium hard water anti-magnesium corrosion environmentally-friendly water soluble cutting solution
CN101550376B (en) * 2009-05-07 2012-04-18 龚如纯 Environment-friendly energy-saving lubricating rust-proof water-based cutting liquid
CN102757849A (en) * 2012-05-31 2012-10-31 天长市润达金属防锈助剂有限公司 Preparation method of environment-friendly micro-emulsion type cutting liquid having no corrosion to machine tool
CN102766518A (en) * 2012-07-24 2012-11-07 东莞市安美润滑科技有限公司 Totally-synthetic magnesium alloy cutting fluid with resistance to ultrahigh hard water, preparation method and using method thereof
CN102766515A (en) * 2012-05-31 2012-11-07 天长市润达金属防锈助剂有限公司 Microemulsion-type cutting fluid with good defoaming performance
CN101595156B (en) * 2006-12-21 2013-01-09 有利凯玛美国有限责任公司 Composition and method
CN103627490A (en) * 2013-11-18 2014-03-12 青岛广联达精密机械有限公司 Improved high-permeability cutting fluid
CN103756740A (en) * 2014-01-17 2014-04-30 陕西延长中立新能源股份有限公司 Vehicle methanol fuel corrosion-inhibitor for various metals
CN104711099A (en) * 2013-12-15 2015-06-17 刘现梅 Aluminum alloy micro-emulsion cutting fluid and preparation method thereof
CN106635358A (en) * 2016-12-28 2017-05-10 滁州品之达电器科技有限公司 Mechanical lubricating cutting agent and preparation method thereof
CN109337751A (en) * 2018-11-13 2019-02-15 无锡市高润杰化学有限公司 A kind of universal cutting fluid

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JP2001262176A (en) * 2000-03-21 2001-09-26 Nippon Mitsubishi Oil Corp Lubricant oil composition for transmission
TW575660B (en) * 2001-09-07 2004-02-11 Dai Ichi Kogyo Seiyaku Co Ltd Nonflammable water-based cutting fluid composition and nonflammable water-based cutting fluid

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CN101595156B (en) * 2006-12-21 2013-01-09 有利凯玛美国有限责任公司 Composition and method
CN101108897B (en) * 2007-08-31 2010-10-06 田欣利 Highly effective grinding fluid for silicon ceramic
CN101240218B (en) * 2008-02-29 2011-12-07 益田润石(北京)化工有限公司 Emulsification type metal cutting liquor composition
CN101240422B (en) * 2008-03-12 2010-04-07 益田润石(北京)化工有限公司 Water-base metal antirust agent composition
CN101265435B (en) * 2008-04-23 2010-09-29 常州市夏雷化学有限公司 Method for preparing water-soluble anti-rust lubricating additive
CN101608310B (en) * 2008-06-16 2011-03-02 南京科润工业介质有限公司 Long-acting emulsion-type antirust fluid
CN101550376B (en) * 2009-05-07 2012-04-18 龚如纯 Environment-friendly energy-saving lubricating rust-proof water-based cutting liquid
CN101560433B (en) * 2009-05-11 2012-03-07 启东尤希路化学工业有限公司 Anti-magnesium hard water anti-magnesium corrosion environmentally-friendly water soluble cutting solution
CN101914411A (en) * 2010-08-24 2010-12-15 安庆市中天石油化工有限公司 Anti-rust cutting fluid and preparation method thereof
CN101914411B (en) * 2010-08-24 2013-01-09 安庆市中天石油化工有限公司 Anti-rust cutting fluid and preparation method thereof
CN102220183A (en) * 2011-05-11 2011-10-19 广州市联诺化工科技有限公司 Vegetable oil-based water-soluble cutting fluid
CN102250673A (en) * 2011-06-15 2011-11-23 启东尤希路化学工业有限公司 Environment-friendly emulsion cutting oil with high lubricity and high permeability for metal working
CN102250676B (en) * 2011-06-15 2013-03-27 启东尤希路化学工业有限公司 High-performance environmentally-friendly semisynthetic water-soluble metal working fluid
CN102250676A (en) * 2011-06-15 2011-11-23 启东尤希路化学工业有限公司 High-performance environmentally-friendly semisynthetic water-soluble metal working fluid
CN102295976A (en) * 2011-07-13 2011-12-28 李胜 Lubricant for heavy-load machining of metals and preparation method thereof
CN102311864A (en) * 2011-08-05 2012-01-11 安庆市中天石油化工有限公司 Cutting fluid special for NC machine tools
CN102311864B (en) * 2011-08-05 2013-04-03 安庆市中天石油化工有限公司 Cutting fluid special for NC machine tools
CN102766515A (en) * 2012-05-31 2012-11-07 天长市润达金属防锈助剂有限公司 Microemulsion-type cutting fluid with good defoaming performance
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CN102757849B (en) * 2012-05-31 2015-07-01 天长市润达金属防锈助剂有限公司 Preparation method of environment-friendly micro-emulsion type cutting liquid having no corrosion to machine tool
CN102766515B (en) * 2012-05-31 2015-07-01 天长市润达金属防锈助剂有限公司 Microemulsion-type cutting fluid with good defoaming performance
CN102766518A (en) * 2012-07-24 2012-11-07 东莞市安美润滑科技有限公司 Totally-synthetic magnesium alloy cutting fluid with resistance to ultrahigh hard water, preparation method and using method thereof
CN103627490A (en) * 2013-11-18 2014-03-12 青岛广联达精密机械有限公司 Improved high-permeability cutting fluid
CN103627490B (en) * 2013-11-18 2016-04-13 青岛祥嘉知识产权服务有限公司 A kind of hypertonicity cutting fluid of improvement
CN104711099A (en) * 2013-12-15 2015-06-17 刘现梅 Aluminum alloy micro-emulsion cutting fluid and preparation method thereof
CN104711099B (en) * 2013-12-15 2018-08-21 烟台道平化工材料有限公司 A kind of aluminium alloy micro emulsion cutting fluid and preparation method thereof
CN103756740B (en) * 2014-01-17 2015-05-20 陕西延长中立新能源股份有限公司 Vehicle methanol fuel corrosion-inhibitor for various metals
CN103756740A (en) * 2014-01-17 2014-04-30 陕西延长中立新能源股份有限公司 Vehicle methanol fuel corrosion-inhibitor for various metals
CN106635358A (en) * 2016-12-28 2017-05-10 滁州品之达电器科技有限公司 Mechanical lubricating cutting agent and preparation method thereof
CN109337751A (en) * 2018-11-13 2019-02-15 无锡市高润杰化学有限公司 A kind of universal cutting fluid
CN109337751B (en) * 2018-11-13 2021-09-10 无锡市高润杰化学有限公司 Universal cutting fluid

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