CN101240422B - Water-base metal antirust agent composition - Google Patents
Water-base metal antirust agent composition Download PDFInfo
- Publication number
- CN101240422B CN101240422B CN2008101017790A CN200810101779A CN101240422B CN 101240422 B CN101240422 B CN 101240422B CN 2008101017790 A CN2008101017790 A CN 2008101017790A CN 200810101779 A CN200810101779 A CN 200810101779A CN 101240422 B CN101240422 B CN 101240422B
- Authority
- CN
- China
- Prior art keywords
- water
- rust
- alloy inhibiter
- base metal
- copper alloy
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Fee Related
Links
- 239000000203 mixture Substances 0.000 title claims abstract description 20
- 239000013556 antirust agent Substances 0.000 title description 12
- 239000010953 base metal Substances 0.000 title description 11
- 229910052751 metal Inorganic materials 0.000 claims abstract description 13
- 239000002184 metal Substances 0.000 claims abstract description 13
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 12
- 229910000881 Cu alloy Inorganic materials 0.000 claims abstract description 8
- 239000003755 preservative agent Substances 0.000 claims abstract description 8
- 230000002335 preservative effect Effects 0.000 claims abstract description 8
- KGBXLFKZBHKPEV-UHFFFAOYSA-N boric acid Chemical compound OB(O)O KGBXLFKZBHKPEV-UHFFFAOYSA-N 0.000 claims abstract description 6
- 239000004327 boric acid Substances 0.000 claims abstract description 6
- 239000003795 chemical substances by application Substances 0.000 claims description 9
- 239000003513 alkali Substances 0.000 claims description 8
- 239000013530 defoamer Substances 0.000 claims description 7
- ZZVUWRFHKOJYTH-UHFFFAOYSA-N diphenhydramine Chemical compound C=1C=CC=CC=1C(OCCN(C)C)C1=CC=CC=C1 ZZVUWRFHKOJYTH-UHFFFAOYSA-N 0.000 claims description 7
- 230000000855 fungicidal effect Effects 0.000 claims description 7
- CDBYLPFSWZWCQE-UHFFFAOYSA-L Sodium Carbonate Chemical compound [Na+].[Na+].[O-]C([O-])=O CDBYLPFSWZWCQE-UHFFFAOYSA-L 0.000 claims description 6
- 229910052500 inorganic mineral Inorganic materials 0.000 claims description 6
- 239000011707 mineral Substances 0.000 claims description 6
- 235000010755 mineral Nutrition 0.000 claims description 6
- 229910000838 Al alloy Inorganic materials 0.000 claims description 5
- 239000013543 active substance Substances 0.000 claims description 5
- LVTYICIALWPMFW-UHFFFAOYSA-N diisopropanolamine Chemical compound CC(O)CNCC(C)O LVTYICIALWPMFW-UHFFFAOYSA-N 0.000 claims description 4
- 229940043276 diisopropanolamine Drugs 0.000 claims description 4
- CFQZKFWQLAHGSL-FNTYJUCDSA-N (3e,5e,7e,9e,11e,13e,15e,17e)-18-[(3e,5e,7e,9e,11e,13e,15e,17e)-18-[(3e,5e,7e,9e,11e,13e,15e)-octadeca-3,5,7,9,11,13,15,17-octaenoyl]oxyoctadeca-3,5,7,9,11,13,15,17-octaenoyl]oxyoctadeca-3,5,7,9,11,13,15,17-octaenoic acid Chemical compound OC(=O)C\C=C\C=C\C=C\C=C\C=C\C=C\C=C\C=C\OC(=O)C\C=C\C=C\C=C\C=C\C=C\C=C\C=C\C=C\OC(=O)C\C=C\C=C\C=C\C=C\C=C\C=C\C=C\C=C CFQZKFWQLAHGSL-FNTYJUCDSA-N 0.000 claims description 3
- 229920000570 polyether Polymers 0.000 claims description 3
- 229910000029 sodium carbonate Inorganic materials 0.000 claims description 3
- 235000017550 sodium carbonate Nutrition 0.000 claims description 3
- GIAFURWZWWWBQT-UHFFFAOYSA-N 2-(2-aminoethoxy)ethanol Chemical compound NCCOCCO GIAFURWZWWWBQT-UHFFFAOYSA-N 0.000 claims description 2
- 229940058020 2-amino-2-methyl-1-propanol Drugs 0.000 claims description 2
- BPQQTUXANYXVAA-UHFFFAOYSA-N Orthosilicate Chemical compound [O-][Si]([O-])([O-])[O-] BPQQTUXANYXVAA-UHFFFAOYSA-N 0.000 claims description 2
- GSEJCLTVZPLZKY-UHFFFAOYSA-N Triethanolamine Chemical compound OCCN(CCO)CCO GSEJCLTVZPLZKY-UHFFFAOYSA-N 0.000 claims description 2
- CBTVGIZVANVGBH-UHFFFAOYSA-N aminomethyl propanol Chemical compound CC(C)(N)CO CBTVGIZVANVGBH-UHFFFAOYSA-N 0.000 claims description 2
- DMSMPAJRVJJAGA-UHFFFAOYSA-N benzo[d]isothiazol-3-one Chemical class C1=CC=C2C(=O)NSC2=C1 DMSMPAJRVJJAGA-UHFFFAOYSA-N 0.000 claims description 2
- 239000012964 benzotriazole Substances 0.000 claims description 2
- 125000003354 benzotriazolyl group Chemical group N1N=NC2=C1C=CC=C2* 0.000 claims description 2
- 239000003518 caustics Substances 0.000 claims description 2
- ZBCBWPMODOFKDW-UHFFFAOYSA-N diethanolamine Chemical group OCCNCCO ZBCBWPMODOFKDW-UHFFFAOYSA-N 0.000 claims description 2
- KPUWHANPEXNPJT-UHFFFAOYSA-N disiloxane Chemical class [SiH3]O[SiH3] KPUWHANPEXNPJT-UHFFFAOYSA-N 0.000 claims description 2
- 150000002780 morpholines Chemical class 0.000 claims description 2
- 150000003014 phosphoric acid esters Chemical class 0.000 claims description 2
- 150000003918 triazines Chemical group 0.000 claims description 2
- 229960004418 trolamine Drugs 0.000 claims description 2
- JEIPFZHSYJVQDO-UHFFFAOYSA-N iron(III) oxide Inorganic materials O=[Fe]O[Fe]=O JEIPFZHSYJVQDO-UHFFFAOYSA-N 0.000 abstract description 7
- 238000003860 storage Methods 0.000 abstract description 4
- 229910001385 heavy metal Inorganic materials 0.000 abstract description 3
- 238000004519 manufacturing process Methods 0.000 abstract description 3
- -1 alcohol amine Chemical class 0.000 abstract description 2
- 230000002265 prevention Effects 0.000 abstract description 2
- 239000003112 inhibitor Substances 0.000 abstract 3
- 229910002651 NO3 Inorganic materials 0.000 abstract 1
- NHNBFGGVMKEFGY-UHFFFAOYSA-N Nitrate Chemical compound [O-][N+]([O-])=O NHNBFGGVMKEFGY-UHFFFAOYSA-N 0.000 abstract 1
- 239000008367 deionised water Substances 0.000 abstract 1
- 229910021641 deionized water Inorganic materials 0.000 abstract 1
- 239000006260 foam Substances 0.000 abstract 1
- 150000007529 inorganic bases Chemical class 0.000 abstract 1
- 230000001954 sterilising effect Effects 0.000 abstract 1
- 230000005068 transpiration Effects 0.000 abstract 1
- 238000004140 cleaning Methods 0.000 description 4
- KWYUFKZDYYNOTN-UHFFFAOYSA-M Potassium hydroxide Chemical compound [OH-].[K+] KWYUFKZDYYNOTN-UHFFFAOYSA-M 0.000 description 3
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 description 3
- 239000002585 base Substances 0.000 description 3
- SOCTUWSJJQCPFX-UHFFFAOYSA-N dichromate(2-) Chemical compound [O-][Cr](=O)(=O)O[Cr]([O-])(=O)=O SOCTUWSJJQCPFX-UHFFFAOYSA-N 0.000 description 3
- 238000005516 engineering process Methods 0.000 description 3
- 238000000034 method Methods 0.000 description 3
- IOVCWXUNBOPUCH-UHFFFAOYSA-M Nitrite anion Chemical compound [O-]N=O IOVCWXUNBOPUCH-UHFFFAOYSA-M 0.000 description 2
- 230000007797 corrosion Effects 0.000 description 2
- 238000005260 corrosion Methods 0.000 description 2
- 239000007788 liquid Substances 0.000 description 2
- 238000012986 modification Methods 0.000 description 2
- 230000004048 modification Effects 0.000 description 2
- FBUKVWPVBMHYJY-UHFFFAOYSA-N nonanoic acid Chemical compound CCCCCCCCC(O)=O FBUKVWPVBMHYJY-UHFFFAOYSA-N 0.000 description 2
- 239000002994 raw material Substances 0.000 description 2
- CXMXRPHRNRROMY-UHFFFAOYSA-N sebacic acid Chemical compound OC(=O)CCCCCCCCC(O)=O CXMXRPHRNRROMY-UHFFFAOYSA-N 0.000 description 2
- YPIFGDQKSSMYHQ-UHFFFAOYSA-N 7,7-dimethyloctanoic acid Chemical compound CC(C)(C)CCCCCC(O)=O YPIFGDQKSSMYHQ-UHFFFAOYSA-N 0.000 description 1
- VYZAMTAEIAYCRO-UHFFFAOYSA-N Chromium Chemical compound [Cr] VYZAMTAEIAYCRO-UHFFFAOYSA-N 0.000 description 1
- 230000001680 brushing effect Effects 0.000 description 1
- 239000003183 carcinogenic agent Substances 0.000 description 1
- 229910052804 chromium Inorganic materials 0.000 description 1
- 239000011651 chromium Substances 0.000 description 1
- 230000007613 environmental effect Effects 0.000 description 1
- 238000007654 immersion Methods 0.000 description 1
- 238000009434 installation Methods 0.000 description 1
- 238000003754 machining Methods 0.000 description 1
- 150000002826 nitrites Chemical class 0.000 description 1
- 239000007921 spray Substances 0.000 description 1
- 239000002699 waste material Substances 0.000 description 1
Abstract
The invention discloses a water-based metal rust inhibitor, comprising mixed alcohol amine, inorganic base, boric acid, rust inhibitor, copper alloy inhibitor, sterilizing preservative, foam suppressor, deionized water, etc. The composition is mainly applied to rust prevention during manufacture, storage and transpiration in metal processing industry, has no nitrate or heavy metal, and is environment-friendly and easy to operate.
Description
Technical field
The present invention relates to metal rust preventing technology in the mechanical workout, particularly the composition of water-based metal antirust composition.
Background technology
Metal processing industry, the corrosion of workpiece metal are the problems that often runs into, between workpiece metal manufacturing procedure, storage period, delivery period etc. the antirust of process just seem extremely important.At present, mainly contain water base and oil base two big class rust-preventive agent, water-base metal antirust agent is widely used in the rust prevention during manufacture of metal machining process, perhaps storage period, for oil base was antirust, water-base metal antirust agent had easy and simple to handle at 3～4 months metal rust preventing, technology is simple, the postorder easy cleaning, processing does not have characteristics such as influence to postorder, more and more is subjected to numerous clients' favor.Simultaneously, the water-base metal antirust agent in early stage mostly is compositions such as containing nitrite, dichromate, as everyone knows, nitrites is a carcinogenic substance, operator's health is had harm, simultaneously, the dichromate composition is because of containing heavy metals such as chromium, harmful to environment, and in processing work, introduce heavy metal in the course of processing, influence the performance and the quality of workpiece.The invention provides a kind of environmentally-friendly water-based metal antirust agent composition that does not contain nitrite and dichromate composition; use easy; can be by modes such as immersion, spray, brushings; effectively the protection metal is exempted from corrosion; be widely used in the antirust of inter process and metal processing a middle or short term; under the home, rust-proof life can reach 3～4 months, and the present invention simultaneously also is applicable to the hydraulic efficiency system that needs antirust occasion.
Summary of the invention
The object of the invention provides a kind of water-base metal antirust agent composition of environment-friendly high-efficiency.
Technical solution of the present invention:
A kind of water-base metal antirust agent composition is characterized in that being made up of following components by weight percent:
Mix hydramine 30～40%
Mineral alkali 0～6%
Boric acid 4～10%
Tensio-active agent 0～6%
Rust-preventive agent 7～15%
Copper alloy inhibiter 0.3～1%
Aluminium alloy inhibiter 0～5%
Fungicidal preservative 2～5%
Defoamer 0.1～0.5%
Water surplus
Wherein, the mixing hydramine is diethanolamine, trolamine, a Yi Bingchunan, diisopropanolamine (DIPA), 2-amino-2-methyl-1-propanol, diglycolamine, and domestic with international supply commercial city can provide the fine above-mentioned raw materials, as Tao Shi;
Mineral alkali is caustic alkali, soda ash etc., and as potassium hydroxide, sodium hydroxide, yellow soda ash, domestic raw material can meet the demands;
Tensio-active agent is a polyethers, the polyethers of preferred good water solubility, the surface property and the cleaning of raising rust-preventive agent;
Rust-preventive agent is long-chain dimeracid or trimer acid etc., as different n-nonanoic acid, neodecanoic acid, bay diacid, sebacic acid, trimer acid (Switzerland CIBA company, L190);
The copper alloy inhibiter is benzotriazole and derivative thereof;
The aluminium alloy inhibiter is water-soluble silicate or phosphoric acid ester;
Fungicidal preservative is triazines, morpholine class, BIT class etc.;
Defoamer is one or more of modified siloxane class.
Water-base metal antirust agent of the present invention, can use according to the rust protection liquid of concrete operating mode configuration different concns, environmental protection, efficient, waste liquid are removed the oil removal treatment step from, the cleaning easy cleaning, processing does not have influence to postorder, be mainly used in the antirust of inter process, short-term storage and transportation, also can be used for the antirust hydraulic efficiency installation of needs.
Embodiment
In conjunction with example the present invention is done further and to describe, but embodiments of the present invention are not limited thereto.
1 one kinds of water-base metal antirust agent compositions of embodiment are made up of following components by weight percent:
Mix hydramine 37%
Boric acid 4.5%
Tensio-active agent 3%
Rust-preventive agent 11%
Copper alloy inhibiter 0.3%
Fungicidal preservative 3%
Defoamer 0.1%
Water 41.1%
2 one kinds of water-base metal antirust agent compositions of embodiment are made up of following components by weight percent:
Mix hydramine 31%
Mineral alkali 1%
Boric acid 5%
Rust-preventive agent 9%
Copper alloy inhibiter 0.3%
Fungicidal preservative 2%
Defoamer 0.2%
Water 51.5%
3 one kinds of water-base metal antirust agent compositions of embodiment are made up of following components by weight percent:
Mix hydramine 33%
Mineral alkali 2%
Boric acid 8%
Rust-preventive agent 8%
Copper alloy inhibiter 0.3%
Aluminium alloy inhibiter 2.5%
Fungicidal preservative 2%
Defoamer 0.2%
Water 44%
Though above the present invention is described in detail with a general description of the specific embodiments, on basis of the present invention, can make some modifications or improvements it, this will be apparent to those skilled in the art.Therefore, these modifications or improvements all belong to the scope of protection of present invention without departing from theon the basis of the spirit of the present invention.
Claims (1)
1. water-based metal antirust composition is characterized in that being made up of following components by weight percent:
Mix hydramine 30～40%
Mineral alkali 0～6%
Boric acid 4～10%
Tensio-active agent 0～6%
Rust-preventive agent 7～15%
Copper alloy inhibiter 0.3～1%
Aluminium alloy inhibiter 0～5%
Fungicidal preservative 2～5%
Defoamer 0.1～0.5%
Water surplus
Wherein, mixing hydramine is diethanolamine, trolamine, a Yi Bingchunan, diisopropanolamine (DIPA), 2-amino-2-methyl-1-propanol, diglycolamine; Mineral alkali is caustic alkali, soda ash; Tensio-active agent is a polyethers; Rust-preventive agent is long-chain dimeracid or trimer acid; The copper alloy inhibiter is benzotriazole and derivative thereof; The aluminium alloy inhibiter is water-soluble silicate or phosphoric acid ester; Fungicidal preservative is triazines, morpholine class, BIT class; Defoamer is one or more of modified siloxane class.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN2008101017790A CN101240422B (en) | 2008-03-12 | 2008-03-12 | Water-base metal antirust agent composition |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN2008101017790A CN101240422B (en) | 2008-03-12 | 2008-03-12 | Water-base metal antirust agent composition |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN101240422A CN101240422A (en) | 2008-08-13 |
| CN101240422B true CN101240422B (en) | 2010-04-07 |
Family
ID=39932242
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN2008101017790A Expired - Fee Related CN101240422B (en) | 2008-03-12 | 2008-03-12 | Water-base metal antirust agent composition |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN101240422B (en) |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN104559945A (en) * | 2013-10-21 | 2015-04-29 | 中国石油化工股份有限公司 | Inverter cooling liquid and preparation method thereof |
Families Citing this family (22)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101994107B (en) * | 2009-08-18 | 2013-10-30 | 邵阳市创捷化工有限公司 | Antiseptic film and production process thereof |
| CN101812695B (en) * | 2009-12-18 | 2012-08-15 | 益田润石（北京）化工有限公司 | Aluminum alloy oil-removing cleaning agent |
| CN101812363B (en) * | 2009-12-18 | 2013-01-02 | 益田润石（北京）化工有限公司 | Full synthetic aluminum drawing fluid composition |
| CN102051611B (en) * | 2010-12-31 | 2012-07-11 | 大连工业大学 | Metal surface treating agent |
| CN102860309A (en) * | 2011-07-07 | 2013-01-09 | 爱环吴世(苏州)环保有限公司 | Corrosion mitigation sterilization composite medicament and processing technique thereof |
| CN103031564A (en) * | 2011-10-10 | 2013-04-10 | 洛科斯润滑油（上海）有限公司 | Environment-friendly water-based cleaning agent |
| CN102776052B (en) * | 2012-05-14 | 2014-12-24 | 清华大学 | Water-soluble metal antirusting agent and preparation method thereof |
| CN102977720B (en) * | 2012-11-02 | 2015-07-29 | 铜陵市明诚铸造有限责任公司 | A kind of preparation method of the metal antirusting agent containing 1-hydroxy benzo triazole |
| WO2014086026A1 (en) * | 2012-12-06 | 2014-06-12 | 中国石油集团工程设计有限责任公司 | Oil-gas field gas transmission pipeline corrosion inhibitor and preparation method thereof |
| CN103265834B (en) * | 2013-05-24 | 2016-03-09 | 河北欧狮顿石油化工有限公司 | A kind of water-based antirust and preparation technology thereof |
| CN103757619A (en) * | 2013-12-26 | 2014-04-30 | 常熟市美尔特金属制品有限公司 | Metal surface treating agent |
| CN105441959B (en) * | 2014-12-01 | 2018-07-10 | 阜阳师范学院 | A kind of water-based antirust agent and preparation method thereof |
| CN104862706A (en) * | 2015-04-08 | 2015-08-26 | 安徽豪鼎金属制品有限公司 | Environment-friendly water-based metal surface treatment agent |
| CN104862683A (en) * | 2015-04-08 | 2015-08-26 | 安徽豪鼎金属制品有限公司 | Sericin potassium soap metal surface treatment agent |
| CN104910980A (en) * | 2015-05-12 | 2015-09-16 | 北京绿涯风节能科技有限公司 | Environmentally-friendly gasoline additive, and preparation method and application thereof |
| CN105419439B (en) * | 2015-12-31 | 2018-05-01 | 东莞市隆海新材料科技有限公司 | A kind of anti-flash rusting agent and its preparation method and application of water paint ink |
| CN105951108A (en) * | 2016-06-30 | 2016-09-21 | 无锡伊佩克科技有限公司 | Steel surface corrosion-resistance rust removing agent and preparation method thereof |
| CN106191841A (en) * | 2016-08-10 | 2016-12-07 | 天长市润达金属防锈助剂有限公司 | A kind of aqueous protective fluids and preparation method thereof |
| CN106337186A (en) * | 2016-08-10 | 2017-01-18 | 天长市润达金属防锈助剂有限公司 | Sterilizing water-based antirust liquid and preparation method thereof |
| CN107213672A (en) * | 2017-07-26 | 2017-09-29 | 苏州天承化工有限公司 | A kind of compound multipurposes of PCB are without silicon defoaming agent and preparation method |
| CN107365990A (en) * | 2017-07-27 | 2017-11-21 | 江苏捷达油品有限公司 | Environment-friendly type aqua antirust agent |
| CN112813440A (en) * | 2020-12-31 | 2021-05-18 | 上海福岛新材料科技有限公司 | Water-based cleaning agent for improving coating adhesion force for coating pretreatment and preparation method thereof |
Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1075747A (en) * | 1992-02-22 | 1993-09-01 | 中国石油化工总公司石油化工科学研究院 | A kind of water-soluble metalworking liquid |
| CN1498938A (en) * | 2002-11-11 | 2004-05-26 | 浙江万丰奥特集团有限公司 | Compsn. of impregnating and antifreezing fluid and preparation method |
| CN1730633A (en) * | 2005-08-09 | 2006-02-08 | 启东尤希路化学工业有限公司 | Hard water resistant water-soluble cutting solution |
| CN1730634A (en) * | 2005-08-02 | 2006-02-08 | 广州机械科学研究院 | Extreme pressure cutting fuild microemulsion free of chlorine and its preparation method and uses |
-
2008
- 2008-03-12 CN CN2008101017790A patent/CN101240422B/en not_active Expired - Fee Related
Patent Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1075747A (en) * | 1992-02-22 | 1993-09-01 | 中国石油化工总公司石油化工科学研究院 | A kind of water-soluble metalworking liquid |
| CN1498938A (en) * | 2002-11-11 | 2004-05-26 | 浙江万丰奥特集团有限公司 | Compsn. of impregnating and antifreezing fluid and preparation method |
| CN1730634A (en) * | 2005-08-02 | 2006-02-08 | 广州机械科学研究院 | Extreme pressure cutting fuild microemulsion free of chlorine and its preparation method and uses |
| CN1730633A (en) * | 2005-08-09 | 2006-02-08 | 启东尤希路化学工业有限公司 | Hard water resistant water-soluble cutting solution |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN104559945A (en) * | 2013-10-21 | 2015-04-29 | 中国石油化工股份有限公司 | Inverter cooling liquid and preparation method thereof |
| CN104559945B (en) * | 2013-10-21 | 2018-01-16 | 中国石油化工股份有限公司 | Inverter coolant and preparation method thereof |
Also Published As
| Publication number | Publication date |
|---|---|
| CN101240422A (en) | 2008-08-13 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN101240422B (en) | Water-base metal antirust agent composition | |
| CN102311860B (en) | Water-based cutting fluid used for processing neodymium-iron-boron material slices and application method thereof | |
| CN101550376B (en) | Environment-friendly energy-saving lubricating rust-proof water-based cutting liquid | |
| CN101240221A (en) | Water-soluble total synthesis metal processing liquid composition | |
| CN106281616A (en) | A kind of aluminium alloy machining long-life low bubble emulsion | |
| CN105670738A (en) | Rust-proof emulsified type metal cutting fluid | |
| CN104277902A (en) | Heavy-load metal machining total synthesis cutting fluid as well as preparation method and application thereof | |
| CN101113524B (en) | Cleaning antirust agent and preparation method thereof | |
| CN102703196B (en) | Environment-friendly water-based metal cutting fluid | |
| JPS6017829B2 (en) | Corrosion inhibitor for metal surfaces | |
| JPH07145491A (en) | Water-soluble anti-corrosive agent for metal | |
| CN103046066A (en) | High-performance and environment-friendly water-based cleaning agent | |
| CN105754698A (en) | Water-soluble magnesium alloy machining fluid | |
| CN103351929A (en) | Antirust metal cutting fluid | |
| JPH02240286A (en) | Improved corrosionproof composition | |
| CN104277904A (en) | Environment-friendly rust-proof water-based cutting fluid | |
| CN112745983A (en) | Phosphorus-free alkaline water-based spray cleaning antirust agent and preparation method thereof | |
| CN102286749A (en) | Wet leveling liquid | |
| CN108441310B (en) | Semisynthesis cutting fluid for metal processing and preparation method thereof | |
| CN103351914A (en) | Water-based cutting fluid | |
| CN103805330B (en) | Fully synthetic cutting fluid and preparation method thereof | |
| CN107630223A (en) | A kind of environmentally-friendly water-based metal cleaner of high efficiency microbubble | |
| CN104451698A (en) | Metal rust inhibitor for transformer and preparation method of metal rust inhibitor | |
| CN103305328A (en) | Oil-based metal cutting fluid and preparation method thereof | |
| CN112481011A (en) | Multipurpose fully-synthetic cutting fluid for processing neodymium-iron-boron material and preparation method thereof |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| C06 | Publication | ||
| PB01 | Publication | ||
| C10 | Entry into substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| C14 | Grant of patent or utility model | ||
| GR01 | Patent grant | ||
| PE01 | Entry into force of the registration of the contract for pledge of patent right |
Denomination of invention: Water-base metal antirust agent composition Effective date of registration: 20110601 Granted publication date: 20100407 Pledgee: Zhongguancun Beijing science and technology Company limited by guarantee Pledgor: Masuda Rissoil (Beijing) Chemicals Co., Ltd. Registration number: 2011990000201 |
|
| PC01 | Cancellation of the registration of the contract for pledge of patent right |
Date of cancellation: 20120418 Granted publication date: 20100407 Pledgee: Zhongguancun Beijing science and technology Company limited by guarantee Pledgor: Masuda Rissoil (Beijing) Chemicals Co., Ltd. Registration number: 2011990000201 |
|
| PE01 | Entry into force of the registration of the contract for pledge of patent right |
Denomination of invention: Water-base metal antirust agent composition Effective date of registration: 20120428 Granted publication date: 20100407 Pledgee: Zhongguancun Beijing science and technology Company limited by guarantee Pledgor: Masuda Rissoil (Beijing) Chemicals Co., Ltd. Registration number: 2012990000180 |
|
| PC01 | Cancellation of the registration of the contract for pledge of patent right |
Date of cancellation: 20160819 Granted publication date: 20100407 Pledgee: Zhongguancun Beijing technology financing Company limited by guarantee Pledgor: Masuda Rissoil (Beijing) Chemicals Co., Ltd. Registration number: 2012990000180 |
|
| PLDC | Enforcement, change and cancellation of contracts on pledge of patent right or utility model | ||
| PM01 | Change of the registration of the contract for pledge of patent right |
Change date: 20160819 Registration number: 2012990000180 Pledgee after: Zhongguancun Beijing technology financing Company limited by guarantee Pledgee before: Zhongguancun Beijing science and technology Company limited by guarantee |
|
| TR01 | Transfer of patent right | ||
| TR01 | Transfer of patent right |
Effective date of registration: 20170620 Address after: 062650 North Zone, Qingxian County Economic Development Zone, Hebei, Cangzhou Patentee after: Hebei nine hee new Mstar Technology Ltd Address before: 100043 West Street, Shijingshan District, Beijing, No. 19 Patentee before: Masuda Rissoil (Beijing) Chemicals Co., Ltd. |
|
| CF01 | Termination of patent right due to non-payment of annual fee |
Granted publication date: 20100407 Termination date: 20180312 |
|
| CF01 | Termination of patent right due to non-payment of annual fee |