CN109825199A - A kind of environmentally protective polishing fluid and preparation method thereof - Google Patents
A kind of environmentally protective polishing fluid and preparation method thereof Download PDFInfo
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- CN109825199A CN109825199A CN201910288259.3A CN201910288259A CN109825199A CN 109825199 A CN109825199 A CN 109825199A CN 201910288259 A CN201910288259 A CN 201910288259A CN 109825199 A CN109825199 A CN 109825199A
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Abstract
The invention discloses a kind of environmentally protective polishing fluids and preparation method thereof, a kind of environmentally protective polishing fluid includes that parts by weight are 3~90 parts of mineral type base oil and 97~10 parts of additive, the additive includes the abrasive material that parts by weight are 1~30 part, 2~15 parts of fatty acid, 0~5 part of ethylene glycol monobutyl ether, 1~20 part of emulsifier, 2~15 parts of water-based antirust, 0.1~0.8 part of benzotriazole, 1~8 part of hydramine, 0.1~1.0 part of sodium hydroxide, 0.1~3 part of fungicide, 0.01~0.80 part of defoaming agent and 92.69~1.40 parts of water, odorlessness, non-volatile substance, without the harmful substances such as sodium nitrite and heavy metal, guarantee that worker's body is without damage, guarantee environment damage, it is environmentally protective, it can It is widely used in metal and nonmetallic materials polishing production, there is apparent economic benefit and social benefit.
Description
[technical field]
The present invention relates to the technical field of polishing fluid, the technology of especially a kind of environmentally protective polishing fluid and preparation method thereof
Field.
[background technique]
Polishing fluid is a kind of water fluid developed for a variety of materials polishing.The hard material such as glass and potsherd at present
Polishing fluid in material rough polishing production is largely pure oily burnishing oil.Pure oil burnishing oil has the characteristics that working service is convenient, but
It is that can generate mist of oil, jeopardizes personal health and cause environmental pollution.In addition, current polishing fluid there is also service life it is short and at
This high disadvantage.
[summary of the invention]
The object of the invention is to solve the problems of the prior art, a kind of environmentally protective polishing fluid and its preparation side are proposed
Method can be adjusted by concentration and meet different polishing requirements, and performance meets prescribed requirement, and use cost is low, saves petroleum resources
And can reduce environmental pollution, it is a kind of oily burnishing oil substitute products pure well.
To achieve the above object, the present invention is achieved through the following technical solutions:
A kind of environmentally protective polishing fluid, including parts by weight be 3~90 parts mineral type base oil and 97~10 parts add
Add agent, the additive includes that parts by weight are 1~30 part of abrasive material, 2~15 parts of fatty acid, 0~5 part of ethylene glycol only son
Ether, 1~20 part of emulsifier, 2~15 parts of water-based antirust, 0.1~0.8 part of benzotriazole, 1~8 part of hydramine,
0.1~1.0 part of sodium hydroxide, 0.1~3 part of fungicide, 0.01~0.80 part of defoaming agent and 92.69~1.40 parts
Water.
Preferably, the mineral type base oil is paraffinic base mineral type base oil, intermediate base mineral type base oil and ring
The one such or several combination of alkyl mineral type base oil.
Preferably, the abrasive material is that bortz powder, silicon dioxide powder and alumina powder are one such or several
Combination.
Preferably, the fatty acid is the one such or several combination of organic acid, such as animal oleic acid, vegetable oil
Acid, ricinoleic acid, ready denier oil acid, palmitinic acid or stearic acid.
Preferably, the water-based antirust is organic amine acid salt, organic acid amide ester, boric acid amine salt, amine borate ester, 12
Alkenyl succinic acid amine salt and the one such or several combination of dodecenylsuccinic acid amine ester, such as 12 binary acid monoethanols
Amine salt, 11 binary acid monoethanolamine salts, ternary acid monoethanolamine salt, boric acid monoethanolamine salt or boric acid monoethanol ester.
Preferably, the hydramine be monoethanolamine, diethanol amine, triethanolamine, monoisopropanolamine, diisopropanolamine (DIPA) and
The one such or several combination of triisopropanolamine.
Preferably, the emulsifier is ionic emulsifying agent, nonionic emulsifier and amphoteric emulsifier therein one
Kind or several combinations, the ionic emulsifying agent are fatty alcohol ether sulfate salt, fatty alcohol sulfate salt, alkyl sulfonic acid
Sodium, alkyl ether carboxylic acid, aromatic radical ether carboxylic acid, fatty alcohol carboxylate, petroleum sodium sulfonate, petroleum sulphur calcium, nekal, wood
Mahogany sulfonate, octadecyltrimethylammonium chloride or Cetyltrimethylammonium bromide, the nonionic emulsifier are poly-
Ethylene oxide fatty alcohol ether, polyoxyethylene fatty acid esters, sorbitan fatty acid ester, gathers polyoxyethylene nonyl phenyl vinethene
Ethylene oxide fat alcohol phosphate, anhydrous sorbitol phosphate, polyoxyethylene nonyl phenyl ethylene phosphate or fatty acid methyl ester polyoxy second
Alkene ether, the amphoteric emulsifier are alkyl betaine, Cocoamidopropyl betaine, hydroxyl sulfo betaine, lecithin both sexes
Guanidine-acetic acid sodium, osmanthus acyl both sexes guanidine-acetic acid sodium, alkyl aminopropionic mono-sodium salt or ethoxy iso-octyl alanine mono-sodium salt.
A kind of preparation method of environmentally protective polishing fluid, includes the following steps:
It a) is 92.69~1.40 parts of water, 0.1~1.0 part of sodium hydroxide, 2~15 parts water base anti-by parts by weight
15~60min is mixed in agent, 1~8 part of hydramine and 0.1~0.8 part of the benzotriazole of becoming rusty, and obtains homogeneous transparent solution I；
B) the mineral type base oil by parts by weight for 3~90 parts, 0~5 part of ethylene glycol monobutyl ether, 1~20 part of cream
Agent and 2~15 parts of fatty acid are added in homogeneous transparent solution I and are mixed 15~60min, obtain homogeneous transparent solution
Ⅱ；
C) fungicide and 0.01~0.80 part of defoaming agent addition homogeneous transparent solution for being 0.1~3 part by parts by weight
In II and 15~30min is mixed, obtains homogeneous transparent solution III；
D) abrasive material that parts by weight are 1~30 part is added in homogeneous transparent solution III and is mixed 15~30min, obtain
To finished product.
Beneficial effects of the present invention: polishing fluid prepared by the present invention is by abrasive material, corrosion inhibiter, lubricant, surface-active
Agent and other additives are configured to a kind of aqueous polishing liquid, odorlessness, and non-volatile substance has without sodium nitrite and heavy metal etc.
Evil substance guarantees that worker's body is without damage, guarantees environment damage, environmentally protective, can throw in metal and nonmetallic materials
Photoproduction is widely used in producing, and has apparent economic benefit and social benefit.
[specific embodiment]
The preparation of Examples 1 to 8 polishing fluid:
Formula is as shown in table 1 by mass fraction:
The formula of 1 Examples 1 to 8 polishing fluid of table
Preparation method includes the following steps:
It a) is 92.69~1.40 parts of water, 0.1~1.0 part of sodium hydroxide, 2~15 parts water base anti-by parts by weight
15~60min is mixed in agent, 1~8 part of hydramine and 0.1~0.8 part of the benzotriazole of becoming rusty, and obtains homogeneous transparent solution I；
B) the mineral type base oil by parts by weight for 3~90 parts, 0~5 part of ethylene glycol monobutyl ether, 1~20 part of cream
Agent and 2~15 parts of fatty acid are added in homogeneous transparent solution I and are mixed 15~60min, obtain homogeneous transparent solution
Ⅱ；
C) fungicide and 0.01~0.80 part of defoaming agent addition homogeneous transparent solution for being 0.1~3 part by parts by weight
In II and 15~30min is mixed, obtains homogeneous transparent solution III；
D) abrasive material that parts by weight are 1~30 part is added in homogeneous transparent solution III and is mixed 15~30min, obtain
To finished product.
Prepared polishing fluid can be used for metal and nonmetallic, such as in mobile phone, wrist-watch, digital camera, electric appliance, instrument face
In the hard non-metallic materials such as high quality glass, potsherd needed for plate and ornament etc., or in stainless steel and other metal materials
In, there is apparent economic benefit and social benefit.Use is diluted with water when use, it is recommended to use 5~50%v/v of concentration.
In prepared polishing fluid, Minerals type base oil plays lubricating action；Fatty acid plays antirust, light and lubrication and makees
With；Ethylene glycol monobutyl ether plays coupled action, it is ensured that water phase and oil phase are transparent；Benzotriazole plays anti-non-ferrous metal and becomes
Color effect；Hydramine plays PH stabilization.
Product of the present invention has selected refined mineral oil and environmentally protective additive, at low cost, long service life, green ring
It protects, the requirement of the hard materials rough polishing such as glass, potsherd can be met.
Above-described embodiment is the description of the invention, is not limitation of the invention, after any pair of simple transformation of the present invention
Scheme all belong to the scope of protection of the present invention.
Claims (8)
1. a kind of environmentally protective polishing fluid, it is characterised in that: including parts by weight be 3~90 parts mineral type base oil and 97~
10 parts of additive, the additive include that parts by weight are 1~30 part of abrasive material, 2~15 parts of fatty acid, 0~5 part of second
Glycol monobutyl ether, 1~20 part of emulsifier, 2~15 parts of water-based antirust, 0.1~0.8 part of benzotriazole, 1~8 part
Hydramine, 0.1~1.0 part of sodium hydroxide, 0.1~3 part of fungicide, 0.01~0.80 part of defoaming agent and 92.69~
1.40 parts of water.
2. a kind of environmentally protective polishing fluid as described in claim 1, it is characterised in that: the mineral type base oil is paraffinic base
Mineral type base oil, intermediate base mineral type base oil and the one such or several combination of naphthenic mineral type base oil.
3. a kind of environmentally protective polishing fluid as described in claim 1, it is characterised in that: the abrasive material is bortz powder, dioxy
SiClx powder and the one such or several combination of alumina powder.
4. a kind of environmentally protective polishing fluid as described in claim 1, it is characterised in that: the fatty acid is that organic acid is therein
One or several kinds of combination, such as animal oleic acid, vegetable oil acid, ricinoleic acid, ready denier oil acid, palmitinic acid or stearic acid.
5. a kind of environmentally protective polishing fluid as described in claim 1, it is characterised in that: the water-based antirust is organic acid amide
Salt, organic acid amide ester, boric acid amine salt, amine borate ester, dodecenylsuccinic acid amine salt and dodecenylsuccinic acid amine ester are therein
One or several kinds of combinations, such as 12 binary acid monoethanolamine salts, 11 binary acid monoethanolamine salts, ternary acid monoethanolamine
Salt, boric acid monoethanolamine salt or boric acid monoethanol ester.
6. a kind of environmentally protective polishing fluid as described in claim 1, it is characterised in that: the hydramine is monoethanolamine, diethyl
Hydramine, triethanolamine, monoisopropanolamine, diisopropanolamine (DIPA) and the one such or several combination of triisopropanolamine.
7. a kind of environmentally protective polishing fluid as described in claim 1, it is characterised in that: the emulsifier is ionic emulsification
Agent, nonionic emulsifier and the one such or several combination of amphoteric emulsifier, the ionic emulsifying agent are fat
Alcohol ether sulphates salt, fatty alcohol sulfate salt, sodium alkyl sulfonate, alkyl ether carboxylic acid, aromatic radical ether carboxylic acid, fatty alcohol carboxylate,
Petroleum sodium sulfonate, petroleum sulphur calcium, nekal, lignosulfonates, octadecyltrimethylammonium chloride or octadecane
Base trimethylammonium bromide, the nonionic emulsifier are polyoxyethylene aliphatic alcohol ether, polyoxyethylene nonyl phenyl vinethene, polyoxy
Change ethylene aliphatic ester, sorbitan fatty acid ester, polyethylene glycol oxide fat alcohol phosphate, anhydrous sorbitol phosphate, nonyl
Phenol polyoxyethylene phosphate ester or fatty acid methyl ester APEO, the amphoteric emulsifier are alkyl betaine, coconut oleoyl amine
Propyl betaine, hydroxyl sulfo betaine, lecithin both sexes guanidine-acetic acid sodium, osmanthus acyl both sexes guanidine-acetic acid sodium, alkyl aminopropionic list sodium
Salt or ethoxy iso-octyl alanine mono-sodium salt.
8. a kind of preparation method of environmentally protective polishing fluid, it is characterised in that include the following steps:
A) by parts by weight be 92.69~1.40 parts of water, 0.1~1.0 part of sodium hydroxide, 2~15 parts of water-based antirust,
15~60min is mixed in 1~8 part of hydramine and 0.1~0.8 part of benzotriazole, obtains homogeneous transparent solution I；
B) the mineral type base oil by parts by weight for 3~90 parts, 0~5 part of ethylene glycol monobutyl ether, 1~20 part of emulsifier
Fatty acid with 2~15 parts is added in homogeneous transparent solution I and is mixed 15~60min, obtains homogeneous transparent solution II；
C) in the fungicide and 0.01~0.80 part of defoaming agent addition homogeneous transparent solution II for being 0.1~3 part by parts by weight
And 15~30min is mixed, obtain homogeneous transparent solution III；
D) abrasive material that parts by weight are 1~30 part is added in homogeneous transparent solution III and is mixed 15~30min, obtain into
Product.
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| CN201910288259.3A CN109825199A (en) | 2019-04-11 | 2019-04-11 | A kind of environmentally protective polishing fluid and preparation method thereof |
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| CN201910288259.3A CN109825199A (en) | 2019-04-11 | 2019-04-11 | A kind of environmentally protective polishing fluid and preparation method thereof |
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Cited By (8)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN110746890A (en) * | 2019-11-21 | 2020-02-04 | 广东纳德新材料有限公司 | Ceramic polishing solution for pearlescent brick |
| CN111100558A (en) * | 2019-12-25 | 2020-05-05 | 浙江星星科技股份有限公司 | Rare earth polishing solution for polishing glass panel and polishing method using rare earth polishing solution |
| CN111961541A (en) * | 2020-08-24 | 2020-11-20 | 上海斯瑞文特种油品科技有限公司 | Environment-friendly metal surface cleaning agent and preparation method thereof |
| CN112029564A (en) * | 2020-09-09 | 2020-12-04 | 南京科润工业介质股份有限公司 | Neutral water-based antirust agent |
| CN113444456A (en) * | 2021-06-29 | 2021-09-28 | 广西立之亿新材料有限公司 | Polishing solution for stainless steel surface processing, preparation method and polishing process |
| CN114106702A (en) * | 2021-12-13 | 2022-03-01 | 广东凯盟钝化防锈技术有限公司 | Stainless steel fluid rough polishing wax and preparation method thereof |
| CN115305012A (en) * | 2022-09-21 | 2022-11-08 | 锦西化工研究院有限公司 | Polishing solution for aviation organic glass and preparation method thereof |
| CN115305013A (en) * | 2022-09-21 | 2022-11-08 | 歌尔光学科技有限公司 | Diamond polishing solution and preparation method thereof |
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| US20110111595A1 (en) * | 2009-11-12 | 2011-05-12 | Zhendong Liu | Chemical mechanical polishing composition and methods relating thereto |
| CN102585705A (en) * | 2011-12-21 | 2012-07-18 | 上海新安纳电子科技有限公司 | CMP (chemical mechanical polishing) liquid with high polishing rate for sapphire supporting base |
| CN103468382A (en) * | 2013-08-30 | 2013-12-25 | 广州机械科学研究院有限公司 | Boron-free chlorine-free formaldehyde-free microemulsified cutting fluid and application thereof |
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Patent Citations (3)
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| US20110111595A1 (en) * | 2009-11-12 | 2011-05-12 | Zhendong Liu | Chemical mechanical polishing composition and methods relating thereto |
| CN102585705A (en) * | 2011-12-21 | 2012-07-18 | 上海新安纳电子科技有限公司 | CMP (chemical mechanical polishing) liquid with high polishing rate for sapphire supporting base |
| CN103468382A (en) * | 2013-08-30 | 2013-12-25 | 广州机械科学研究院有限公司 | Boron-free chlorine-free formaldehyde-free microemulsified cutting fluid and application thereof |
Cited By (11)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN110746890A (en) * | 2019-11-21 | 2020-02-04 | 广东纳德新材料有限公司 | Ceramic polishing solution for pearlescent brick |
| CN111100558A (en) * | 2019-12-25 | 2020-05-05 | 浙江星星科技股份有限公司 | Rare earth polishing solution for polishing glass panel and polishing method using rare earth polishing solution |
| CN111100558B (en) * | 2019-12-25 | 2021-08-27 | 浙江星星科技股份有限公司 | Rare earth polishing solution for polishing glass panel and polishing method using rare earth polishing solution |
| CN111961541A (en) * | 2020-08-24 | 2020-11-20 | 上海斯瑞文特种油品科技有限公司 | Environment-friendly metal surface cleaning agent and preparation method thereof |
| CN112029564A (en) * | 2020-09-09 | 2020-12-04 | 南京科润工业介质股份有限公司 | Neutral water-based antirust agent |
| CN113444456A (en) * | 2021-06-29 | 2021-09-28 | 广西立之亿新材料有限公司 | Polishing solution for stainless steel surface processing, preparation method and polishing process |
| CN114106702A (en) * | 2021-12-13 | 2022-03-01 | 广东凯盟钝化防锈技术有限公司 | Stainless steel fluid rough polishing wax and preparation method thereof |
| CN114106702B (en) * | 2021-12-13 | 2022-11-18 | 广东凯盟钝化防锈技术有限公司 | Stainless steel fluid rough polishing wax and preparation method thereof |
| CN115305012A (en) * | 2022-09-21 | 2022-11-08 | 锦西化工研究院有限公司 | Polishing solution for aviation organic glass and preparation method thereof |
| CN115305013A (en) * | 2022-09-21 | 2022-11-08 | 歌尔光学科技有限公司 | Diamond polishing solution and preparation method thereof |
| CN115305013B (en) * | 2022-09-21 | 2023-11-21 | 歌尔光学科技有限公司 | Diamond polishing solution and preparation method thereof |
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