CN106367188A - Water-soluble processing solution for slicing of hard and brittle material and preparation method thereof - Google Patents

Water-soluble processing solution for slicing of hard and brittle material and preparation method thereof Download PDF

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Publication number
CN106367188A
CN106367188A CN201610658653.8A CN201610658653A CN106367188A CN 106367188 A CN106367188 A CN 106367188A CN 201610658653 A CN201610658653 A CN 201610658653A CN 106367188 A CN106367188 A CN 106367188A
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Prior art keywords
water
agent
working fluid
brittle material
hard brittle
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Chinese (zh)
Inventor
赵小军
俞锡芬
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Zhejiang Mould Petrochemical Co Ltd
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Zhejiang Mould Petrochemical Co Ltd
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Priority to CN201610658653.8A priority Critical patent/CN106367188A/en
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    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10MLUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M173/00Lubricating compositions containing more than 10% water
    • C10M173/02Lubricating compositions containing more than 10% water not containing mineral or fatty oils
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10MLUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2207/00Organic non-macromolecular hydrocarbon compounds containing hydrogen, carbon and oxygen as ingredients in lubricant compositions
    • C10M2207/02Hydroxy compounds
    • C10M2207/021Hydroxy compounds having hydroxy groups bound to acyclic or cycloaliphatic carbon atoms
    • C10M2207/022Hydroxy compounds having hydroxy groups bound to acyclic or cycloaliphatic carbon atoms containing at least two hydroxy groups
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10MLUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2209/00Organic macromolecular compounds containing oxygen as ingredients in lubricant compositions
    • C10M2209/10Macromolecular compoundss obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
    • C10M2209/103Polyethers, i.e. containing di- or higher polyoxyalkylene groups
    • C10M2209/109Polyethers, i.e. containing di- or higher polyoxyalkylene groups esterified
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10MLUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2211/00Organic non-macromolecular compounds containing halogen as ingredients in lubricant compositions
    • C10M2211/08Halogenated waxes
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10MLUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2215/00Organic non-macromolecular compounds containing nitrogen as ingredients in lubricant compositions
    • C10M2215/02Amines, e.g. polyalkylene polyamines; Quaternary amines
    • C10M2215/04Amines, e.g. polyalkylene polyamines; Quaternary amines having amino groups bound to acyclic or cycloaliphatic carbon atoms
    • C10M2215/042Amines, e.g. polyalkylene polyamines; Quaternary amines having amino groups bound to acyclic or cycloaliphatic carbon atoms containing hydroxy groups; Alkoxylated derivatives thereof
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10MLUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2215/00Organic non-macromolecular compounds containing nitrogen as ingredients in lubricant compositions
    • C10M2215/08Amides
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10MLUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2219/00Organic non-macromolecular compounds containing sulfur, selenium or tellurium as ingredients in lubricant compositions
    • C10M2219/02Sulfur-containing compounds obtained by sulfurisation with sulfur or sulfur-containing compounds
    • C10M2219/024Sulfur-containing compounds obtained by sulfurisation with sulfur or sulfur-containing compounds of esters, e.g. fats
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10MLUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2223/00Organic non-macromolecular compounds containing phosphorus as ingredients in lubricant compositions
    • C10M2223/02Organic non-macromolecular compounds containing phosphorus as ingredients in lubricant compositions having no phosphorus-to-carbon bonds
    • C10M2223/04Phosphate esters
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10MLUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2223/00Organic non-macromolecular compounds containing phosphorus as ingredients in lubricant compositions
    • C10M2223/02Organic non-macromolecular compounds containing phosphorus as ingredients in lubricant compositions having no phosphorus-to-carbon bonds
    • C10M2223/04Phosphate esters
    • C10M2223/041Triaryl phosphates
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10NINDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
    • C10N2030/00Specified physical or chemical properties which is improved by the additive characterising the lubricating composition, e.g. multifunctional additives
    • C10N2030/04Detergent property or dispersant property
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10NINDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
    • C10N2030/00Specified physical or chemical properties which is improved by the additive characterising the lubricating composition, e.g. multifunctional additives
    • C10N2030/06Oiliness; Film-strength; Anti-wear; Resistance to extreme pressure
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10NINDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
    • C10N2030/00Specified physical or chemical properties which is improved by the additive characterising the lubricating composition, e.g. multifunctional additives
    • C10N2030/12Inhibition of corrosion, e.g. anti-rust agents or anti-corrosives
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10NINDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
    • C10N2030/00Specified physical or chemical properties which is improved by the additive characterising the lubricating composition, e.g. multifunctional additives
    • C10N2030/18Anti-foaming property

Abstract

The invention discloses a water-soluble processing solution for slicing of a hard and brittle material and a preparation method thereof. The processing solution comprises, by weight, 10 to 25% of aminocarboxylic acid, 5 to 25% of a water-soluble lubricant, 5 to 20% of an anti-rust agent, 10 to 20% of a water-soluble anti-wear agent at extreme pressure, 8 to 15% of an emulsifier, 1 to 4% of a bactericide, 1 to 4% of phosphate, 0.1 to 4% of a settling agent, 5 to 20% of triethanolamine and 0.01 to 0.5% of an antifoaming agent, with the balance being water, wherein the water-soluble lubricant is a mixture of polyether ester glycerol and sulfurized fatty acid in a weight ratio of (10-45): (3-18): (2-20). The processing solution is good in chemical stability and thorough in emulsification, produces little foam and few greasy filth pollutants, has good cooling performance, lubricity, settling performance, defoaming performance, anti-rust performance and cleaning performance, can improve processing precision and processing efficiency of workpieces, and is energy-saving, environment-friendly, safe and reliable. The preparation method is simple, easy to operate and low in cost and can be implemented at normal temperature.

Description

A kind of water solublity working fluid for hard brittle material slice processing and preparation method thereof
Technical field
The present invention relates to working fluid and its preparing technical field, specifically a kind of water-soluble for hard brittle material slice processing Property working fluid and preparation method thereof.
Background technology
It is firmly crisp that inside diameter slicer is primarily adapted for use in magnetic material, semi-conducting material, gem, pottery, crystal, various glass etc. The precision slicing processing of material.The cooling and lubricating synchronizing inevitably is needed during slice processing.But existing cut Piece processing is often lubricated cooling using oiliness cutting oil, has that oil smoke is big, abnormal smells from the patient is pungent, greasy filth sulfuration in process Thing is many, problem that is easily beating naked light, fire hazardous, and can cause environmental pollution, is unfavorable for processing the clean and tidy of place and workman is good for Health, additionally, cooling effect is not good, cutting efficiency low it is impossible to meet the special cermacis of high speed development, photovoltaic industry, sapphire etc. The demand of " efficiently, environmental protection, low cost " to cutting processing for the industry.
Content of the invention
The technical problem to be solved is: for the deficiencies in the prior art, provides one kind to cut for hard brittle material Water solublity working fluid of piece processing and preparation method thereof, this working fluid chemical stability is good, and emulsifying is thorough, foam is few, and greasy filth is dirty Dye thing is few, and cooling, lubricity, settleability, defoaming, rust-preventing characteristic and cleaning are good, and the section being applied to hard brittle material adds In man-hour, machining accuracy and the working (machining) efficiency of workpiece can be effectively improved, and no fire, noise, smog and problem of environmental pollution, energy-conservation Environmental protection, safe and reliable.
The technical scheme that present invention solution above-mentioned technical problem is adopted is: a kind of water for hard brittle material slice processing Soluble working fluid, its percentage by weight consists of: amine carboxylic acid 10~25%, soluble oil 5~25%, antirust agent 5~20%, Water-soluble extreme pressure anti-wear agent 10~20%, emulsifying agent 8~15%, antibacterial 1~4%, phosphate ester 1~4%, sedimentation agent 0.1~4%, three Ethanolamine 5~20%, defoamer 0.01~0.5%, balance of water;Described soluble oil is polyether ester, glycerol and sulfur Change the mixture of fatty acid, the weight ratio of polyether ester, glycerol and sulfide aliphatic acid is (10~45): (3~18): (2~20).
Preferably, described antirust agent is in borate, boric acid, sulfonate, petroleum sodium sulfonate and sodium benzoate Plant or several mixture.
Preferably, described Water-soluble extreme pressure anti-wear agent is the mixing of chlorinated paraffin, phosphate ester and tricresyl phosphate Thing, the weight ratio of chlorinated paraffin, phosphate ester and tricresyl phosphate is (10~60): (3~10): (2~5).
Preferably, the product of model v20 that described emulsifying agent provides for Shanghai Dai Le trade Co., Ltd.
Preferably, described antibacterial is BIT.
Preferably, described sedimentation agent is cationic quaternary ammonium salt sedimentation agent.
Preferably, described defoamer is water solublity non-silicon defoaming agent.
The preparation method of the above-mentioned water solublity working fluid for hard brittle material slice processing, comprises the following steps:
(1) weigh according to proportion speed and prepare each raw material needed for working fluid;
(2) first water is put into and be in harmonious proportion in kettle, amine carboxylic acid and soluble oil are put into be in harmonious proportion in kettle afterwards, at normal temperatures fully Stir 15 min, then put into sedimentation agent be sufficiently stirred for 15 min at normal temperatures, then put into phosphate ester, antirust agent, antibacterial, Water-soluble extreme pressure anti-wear agent, triethanolamine and emulsifying agent are simultaneously sufficiently stirred for 20 min at normal temperatures;
(3) put into defoamer into mediation kettle under room temperature, be sufficiently stirred for 30 min under room temperature, that is, prepare for hard brittle material The water solublity working fluid of slice processing.
Compared with prior art, it is an advantage of the current invention that: the water for hard brittle material slice processing disclosed by the invention Soluble working fluid with water as carrier, add amine carboxylic acid, soluble oil, antirust agent, Water-soluble extreme pressure anti-wear agent, emulsifying agent, Antibacterial, phosphate ester, sedimentation agent, triethanolamine and defoamer, each additive is dispersed in water, the compounding processing obtaining Good stability is learned in liquefaction, and emulsifying is thorough, foam is few, and greasy filth pollutant are few, and cooling, lubricity, settleability, defoaming, anti- Rust property and cleaning good, be applied to hard brittle material slice processing when, machining accuracy and the working (machining) efficiency of workpiece can be effectively improved, And no fire, noise, smog and problem of environmental pollution, energy-conserving and environment-protective, safe and reliable.The preparation method letter of this aqueous machining fluid Single, easy to operate, low cost, its preparation can complete at normal temperatures.
Specific embodiment
With reference to embodiments the present invention is described in further detail.
The percentage by weight of the water solublity working fluid for hard brittle material slice processing of embodiment 1 consists of: amine carboxylic acid 20%, soluble oil 15%, antirust agent 10%, Water-soluble extreme pressure anti-wear agent 15%, emulsifying agent 10%, antibacterial 2%, phosphate ester 3%, sedimentation agent 0.4%, triethanolamine 10%, defoamer 0.05%, balance of water;Soluble oil be polyether ester, glycerol and The mixture of sulfide aliphatic acid, the weight of polyether ester, glycerol and sulfide aliphatic acid is than for 10:3:3, Water-soluble extreme pressure anti-wear agent For the mixture of chlorinated paraffin, phosphate ester and tricresyl phosphate, the weight ratio of chlorinated paraffin, phosphate ester and tricresyl phosphate For 4:1:1.
The percentage by weight of the water solublity working fluid for hard brittle material slice processing of embodiment 2 consists of: amine carboxylic acid 12%, soluble oil 22%, antirust agent 6%, Water-soluble extreme pressure anti-wear agent 12%, emulsifying agent 8%, antibacterial 3%, phosphate ester 2%, Sedimentation agent 1%, triethanolamine 16%, defoamer 0.3%, balance of water;Soluble oil is polyether ester, glycerol and sulfurized fat The mixture of fat acid, for 6:3:2, Water-soluble extreme pressure anti-wear agent is chlorination to the weight of polyether ester, glycerol and sulfide aliphatic acid ratio The mixture of paraffin, phosphate ester and tricresyl phosphate, the weight of chlorinated paraffin, phosphate ester and tricresyl phosphate is than for 15: 2:1.
The percentage by weight of the water solublity working fluid for hard brittle material slice processing of embodiment 3 consists of: amine carboxylic acid 24%, soluble oil 11%, antirust agent 5%, Water-soluble extreme pressure anti-wear agent 20%, emulsifying agent 13%, antibacterial 4%, phosphate ester 1%, Sedimentation agent 3.5%, triethanolamine 7%, defoamer 0.5%, balance of water;Soluble oil is polyether ester, glycerol and sulfurized fat The mixture of fat acid, for 9:3:2, Water-soluble extreme pressure anti-wear agent is chlorination to the weight of polyether ester, glycerol and sulfide aliphatic acid ratio The mixture of paraffin, phosphate ester and tricresyl phosphate, the weight of chlorinated paraffin, phosphate ester and tricresyl phosphate is than for 10: 2:1.
The preparation method of the water solublity working fluid in above-described embodiment comprises the following steps:
(1) weigh according to proportion speed and prepare each raw material needed for working fluid;
(2) first water is put into and be in harmonious proportion in kettle, amine carboxylic acid and soluble oil are put into be in harmonious proportion in kettle afterwards, at normal temperatures fully Stir 15 min, then put into sedimentation agent be sufficiently stirred for 15 min at normal temperatures, then put into phosphate ester, antirust agent, antibacterial, Water-soluble extreme pressure anti-wear agent, triethanolamine and emulsifying agent are simultaneously sufficiently stirred for 20 min at normal temperatures;
(3) put into defoamer into mediation kettle under room temperature, be sufficiently stirred for 30 min under room temperature, that is, prepare for hard brittle material The water solublity working fluid of slice processing.
In embodiments above, antirust agent can be from borate, boric acid, sulfonate, petroleum sodium sulfonate and benzoic acid The mixture of one or more of sodium, antibacterial can select BIT, and sedimentation agent can be from sun Cationic quaternary ammonium salt sedimentation agent, defoamer can select water solublity non-silicon defoaming agent.Emulsifying agent can wear Le trade from Shanghai The product of model v20 that company limited provides, it is one vegetable oil/synthetic ester emulsifying agent, and physicochemical property parameter is: product Consist of polyoxyethylene ether -20 oleoyl ricinoleate, 25 DEG C of outward appearance is clear liquid, and hlb value (± 1) is 8.4, color and luster value Maximum 30, acid number (koh/g) maximum 7mg, saponification number (mg koh/g) 100-120, hydroxyl value (mg koh/g) 43-53, water < 1%, It is dissolved in most of artificial oils and vegetable oil.
The outward appearance of the diluent of the 5% of the working fluid of above example 1~embodiment 3 is colourless liquid, and after testing, this is dilute The ph value releasing liquid is 8.5~9.0, and refraction coefficient is 1.8~2.0.For cutting for hard brittle material of embodiment 1~embodiment 3 The water solublity working fluid of piece processing, all carries out defoaming test, settleability test and rust-preventing characteristic test, concrete process of the test is such as Under:
1st, defoaming test
For embodiment 1~embodiment 3, respectively take a certain amount of working fluid stock solution, plus distilled water diluting, it is configured to the dilute of 5% concentration Release liquid and pour in tool plug graduated cylinder, stopper the stopper of tool plug graduated cylinder, rock, when observing the froth breaking situation of diluent and recording froth breaking Between, test obtains: the foam time of the diluent of the working fluid of embodiment 1 is 10s;The diluent of the working fluid of embodiment 2 Foam time is 10s;The foam time of the diluent of the working fluid of embodiment 3 is 12 s.
2nd, settleability test
In 3 tool plug graduated cylinders of the diluent equipped with 5% concentration, it is separately added into the graphite powder of equivalent, rocks, observe graphite powder Sedimentation situation and record the sedimentation time, test obtains: graphite powder deposition time in the diluent of the working fluid of embodiment 1 For 10 min;In the diluent of the working fluid of embodiment 2, graphite powder deposition time is 11 min;The working fluid of embodiment 3 Diluent in graphite powder deposition time be 12 min.
3rd, rust-preventing characteristic test
5.6 sections " corrosion test " with reference to gb/t 6144-2010 " synthesis working fluid " carry out the examination of one-level grey cast-iron rust-preventing characteristic Test, respectively the working fluid stock solution of 3 embodiments is diluted, in the diluent of each embodiment, the content of stock solution is 2% and 5% Two kinds.Find after the test of 35 ± 2 DEG C/24h monolithic, one-level grey cast-iron piece equal non-corroding phenomenon, lustrous surface is as newly, reached a Level criterion of acceptability.

Claims (8)

1. a kind of water solublity working fluid for hard brittle material slice processing is it is characterised in that its percentage by weight consists of: carboxylic Acid amide 10~25%, soluble oil 5~25%, antirust agent 5~20%, Water-soluble extreme pressure anti-wear agent 10~20%, emulsifying agent 8~ 15%, antibacterial 1~4%, phosphate ester 1~4%, sedimentation agent 0.1~4%, triethanolamine 5~20%, defoamer 0.01~0.5%, remaining Measure as water;Described soluble oil be polyether ester, glycerol and sulfide aliphatic acid mixture, polyether ester, glycerol and The weight ratio of sulfide aliphatic acid is (10~45): (3~18): (2~20).
2. a kind of water solublity working fluid for hard brittle material slice processing according to claim 1 is it is characterised in that institute The antirust agent stated is the mixture of one or more of borate, boric acid, sulfonate, petroleum sodium sulfonate and sodium benzoate.
3. a kind of water solublity working fluid for hard brittle material slice processing according to claim 1 is it is characterised in that institute The Water-soluble extreme pressure anti-wear agent stated be chlorinated paraffin, phosphate ester and tricresyl phosphate mixture, chlorinated paraffin, phosphate ester and The weight ratio of tricresyl phosphate is (10~60): (3~10): (2~5).
4. a kind of water solublity working fluid for hard brittle material slice processing according to claim 1 is it is characterised in that institute The product of model v20 that the emulsifying agent stated provides for Shanghai Dai Le trade Co., Ltd.
5. a kind of water solublity working fluid for hard brittle material slice processing according to claim 1 is it is characterised in that institute The antibacterial stated is 1,2- benzisothiazole-3-ketone.
6. a kind of water solublity working fluid for hard brittle material slice processing according to claim 1 is it is characterised in that institute The sedimentation agent stated is cationic quaternary ammonium salt sedimentation agent.
7. a kind of water solublity working fluid for hard brittle material slice processing according to claim 1 is it is characterised in that institute The defoamer stated is water solublity non-silicon defoaming agent.
8. the preparation method of the water solublity working fluid for hard brittle material slice processing any one of claim 1-7, It is characterized in that, comprise the following steps:
(1) weigh according to proportion speed and prepare each raw material needed for working fluid;
(2) first water is put into and be in harmonious proportion in kettle, amine carboxylic acid and soluble oil are put into be in harmonious proportion in kettle afterwards, at normal temperatures fully Stir 15 min, then put into sedimentation agent be sufficiently stirred for 15 min at normal temperatures, then put into phosphate ester, antirust agent, antibacterial, Water-soluble extreme pressure anti-wear agent, triethanolamine and emulsifying agent are simultaneously sufficiently stirred for 20 min at normal temperatures;
(3) put into defoamer into mediation kettle under room temperature, be sufficiently stirred for 30 min under room temperature, that is, prepare for hard brittle material The water solublity working fluid of slice processing.
CN201610658653.8A 2016-08-12 2016-08-12 Water-soluble processing solution for slicing of hard and brittle material and preparation method thereof Pending CN106367188A (en)

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CN110129118A (en) * 2019-03-24 2019-08-16 北京工业大学 ELID is ground dedicated grinding fluid of aluminum matrix composite and preparation method thereof
CN111136771A (en) * 2019-12-27 2020-05-12 湖南加美乐素新材料股份有限公司 Release agent prepared from polyoxyethylene ether-20 oleoyl ricinoleate
CN115678658A (en) * 2022-11-03 2023-02-03 福建省佑达环保材料有限公司 Glass cutting fluid with high settling property
CN115786023A (en) * 2023-02-06 2023-03-14 广州市蔚森节能科技有限公司 Neodymium iron boron permanent magnet processing liquid and preparation method thereof

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Cited By (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN110129118A (en) * 2019-03-24 2019-08-16 北京工业大学 ELID is ground dedicated grinding fluid of aluminum matrix composite and preparation method thereof
CN110129118B (en) * 2019-03-24 2022-01-14 北京工业大学 Grinding fluid special for ELID grinding aluminum-based composite material and preparation method thereof
CN111136771A (en) * 2019-12-27 2020-05-12 湖南加美乐素新材料股份有限公司 Release agent prepared from polyoxyethylene ether-20 oleoyl ricinoleate
CN115678658A (en) * 2022-11-03 2023-02-03 福建省佑达环保材料有限公司 Glass cutting fluid with high settling property
CN115786023A (en) * 2023-02-06 2023-03-14 广州市蔚森节能科技有限公司 Neodymium iron boron permanent magnet processing liquid and preparation method thereof

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