CN105154197A - Plant-oil-based micro-emulsion cutting fluid with high oil content - Google Patents
Plant-oil-based micro-emulsion cutting fluid with high oil content Download PDFInfo
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Abstract
The invention relates to plant-oil-based micro-emulsion cutting fluid with a high oil content. The plant-oil-based micro-emulsion cutting fluid comprises, by weight, 30-50 parts of plant oil, 4-14 parts of pH (potential of hydrogen) regulators, 8-18 parts of extreme-pressure lubricants, 12-22 parts of emulsifiers, 0.1-3.5 parts of corrosion inhibitors, 0.1-3 parts of stabilizers, 0.01-0.3 part of defoaming agents, 1-5 parts of sterilizing agents and 13-23 parts of water. The plant-oil-based micro-emulsion cutting fluid has the advantages of excellent abrasion resistance, extreme-pressure lubricating property, rust protection and biodegradability.
Description
Technical field
The present invention relates to a kind of metal working fluid, be specifically related to a kind of high oil plant oil base micro-emulsion cutting fluid.
Background technology
Along with the intensification of modern manufacturing technology difficulty and the continuous appearance of novel material, cutting fluid lubrication performance requriements is grown with each passing day.But along with the widespread use of cutting fluid, it is found that cutting fluid is the primary pollution source of metal cutting process, can work the mischief to the healthy of operator when not only using, the discharge of waste liquid also can to environment.Mineral oil is as one of the main raw material of metal working fluid, and biodegradability is poor, can drink in soil in water by prolonged stay, makes the pollution that Hu Bo, river, ocean and subterranean stream are subject in various degree.Vegetables oil biodegradability is good, nontoxic, and viscosity temperature characteristic is good, cheap, and aboundresources is renewable, is the best substitute products of mineral oil.
The present invention, on the basis of development Environmental Protection Cutting Fluid, introduces suitable extreme-pressure additive, thus improves the use properties of product, reduces cutting resistance, improves stock-removing efficiency.
Summary of the invention
The object of this invention is to provide a kind of high oil plant oil base micro-emulsion cutting fluid.The object of the invention is to be achieved through the following technical solutions:
A kind of high oil plant oil base micro-emulsion cutting fluid, the composition in described plant oil based micro-emulsion cutting fluid and the parts by weight of various composition comprise: the water of the vegetables oil of 30 ~ 50 parts, the pH adjusting agent of 4 ~ 14 parts, the extreme pressure lubricant of 8 ~ 18 parts, the emulsifying agent of 12 ~ 22 parts, the inhibiter of 0.1 ~ 3.5 part, the stablizer of 0.1 ~ 3 part, the defoamer of 0.01 ~ 0.3 part, the sterilant of 1 ~ 5 part and 13 ~ 23 parts; Further preferably, the composition in described plant oil based micro-emulsion cutting fluid and the parts by weight of various composition comprise: the water of the vegetables oil of 36 ~ 44 parts, the pH adjusting agent of 7 ~ 11 parts, the extreme pressure lubricant of 12 ~ 15 parts, the emulsifying agent of 15 ~ 19 parts, the inhibiter of 1 ~ 2 part, the stablizer of 0.8 ~ 1.2 part, the defoamer of 0.1 ~ 0.2 part, the sterilant of 2 ~ 3 parts and 16 ~ 20 parts; This high oil plant oil base micro-emulsion cutting fluid has good extreme boundary lubrication, erosion resistance, and meanwhile, having splendid biodegradable, can not cause environmental pollution, is environmentally friendly metal working fluid.
Further, described vegetables oil comprises at least one in soybean oil, Viscotrol C, peanut oil, plam oil and rapeseed oil; Thus, the resistance to abrasion of high oil plant oil base micro-emulsion cutting fluid can be improved further.
Further, the pH value of described plant oil based micro-emulsion cutting fluid is 7.5 ~ 9.3, thus, can significantly improve the stability of this high oil plant oil base micro-emulsion cutting fluid.
Further, the density of described vegetables oil is 0.85 ~ 0.93g/cm3, and the kinematic viscosity at the temperature of 40 degrees Celsius is 30.0 ~ 44.0mm2/s, thus, can significantly improve the resistance to abrasion of high oil plant oil base micro-emulsion cutting fluid.
Further, described pH adjusting agent is one or more in trolamine, Monoethanolamine MEA BASF, diglycolamine, α-amino isopropyl alcohol and 2-amino-2-methyl-1-propanol, thus, can improve the pH stability of this high oil plant oil base micro-emulsion cutting fluid further.
Further, described extreme pressure lubricant comprises at least one in ricinolic acid polymkeric substance, polymeric aliphatic ester and sulfuration (plant) fatty acid ester; Thus, the extreme pressure property of high oil plant oil base micro-emulsion cutting fluid can be significantly improved.
Further, described ricinolic acid polymkeric substance is preferably four poly-ricinolic acids, this four poly-ricinolic acid is more preferably four poly-ricinolic acid L4 of Clariant Corporation, described sulfide aliphatic acid ester can be sulfide aliphatic acid ester and olefine sulfide mixture, thus, the extreme pressure property of high oil plant oil base micro-emulsion cutting fluid can be improved further.
Further, described emulsifying agent comprises at least one in sulfonated petro-leum, fatty alcohol-polyoxyethylene ether, oleic acid, Yatall MA, polyoxyethylene carboxylate and sorbitan monooleate; Thus, the stability of high oil plant oil base micro-emulsion cutting fluid can be significantly improved.
Further, the pH of described sulfonated petro-leum is 7.0 ~ 8.0; Preferably, described sulfonated petro-leum to be mass percent be 50 ~ 60% petroleum sodium sulfonate, thus, the stability of high oil plant oil base micro-emulsion cutting fluid can be improved further.
Further, described inhibiter is at least one in benzotriazole, Benzotriazole Derivative, alkyl phosphate and alkylphosphonic acid carboxylic acid ester derivative; Thus, the work-ing life of high oil plant oil base micro-emulsion cutting fluid can be significantly improved; Preferably, described inhibiter is at least one in benzotriazole and Benzotriazole Derivative; Thus, the non-ferrous metal protection feature of high oil plant oil base micro-emulsion cutting fluid can be improved further.More preferably, described benzotriazole is preferably benzotriazole T706, described Benzotriazole Derivative is preferably Benzotriazole Derivative L39, and described alkylphosphonic acid carboxylic acid ester derivative is preferably at least one in alkyl phosphate inhibiter ASI-80, OPS-75E, MDIT, CPNF-3 and 9218LA.
Further, described stablizer comprises at least one in ethylene glycol monobutyl ether, diethylene glycol monobutyl ether, glycerol and ethylene glycol, thus, can significantly improve the stability of this high oil plant oil base micro-emulsion cutting fluid.
Further, described defoamer is type siloxane defoamer, is more preferably three-dimensional type siloxane defoamer, thus, can improve the antifoam performance of high oil plant oil base micro-emulsion cutting fluid further.
Further, further, described sterilant is the pyridine sodium-mixture (FORTE) of mercaptan oxidation thing-Hexahydrotriazine derivative, N, N '-methylene-bis morpholine (MBM), BIT (BIT), 1, at least one in 3,5-tri-(2-hydroxyethyl) s-triazine (BK) and IPBC (IPBC); The work-ing life of high oil plant oil base micro-emulsion cutting fluid can be improved further.
The invention provides a kind of high oil plant oil base micro-emulsion cutting fluid, its beneficial effect mainly had is: 1. this high oil plant oil base micro-emulsion cutting fluid has good resistance to abrasion, extreme boundary lubrication, erosion resistance and cleaning lubricity; 2. this high oil plant oil base micro-emulsion cutting fluid, is environmentally friendly cutting fluid.And vegetable oil resource is abundant, simple and easy to get, renewable, there is good biological degradability; 3. this cutting fluid production technique is simple, and product stirs by formula normal-temperature dissolution, time saving and energy saving.This cutting fluid has and important prospects for commercial application.
Embodiment
One described in the embodiment of the present invention high oil plant oil base micro-emulsion cutting fluid.For specific experiment case, embodiment is described below, should be appreciated that specific embodiment described herein only in order to explain the present invention, be not intended to limit the present invention.
Embodiment 1
A kind of high oil plant oil base micro-emulsion cutting fluid, its composition of this plant oil based micro-emulsion cutting fluid and the amount of various composition can be:
1. the water of the stablizer of the inhibiter of the emulsifying agent of the extreme pressure lubricant of the pH adjusting agent of the vegetables oil of 30g, 4g, 8g, 12g, 3.5g, 0.1g, the defoamer of 0.3g, the sterilant of 1g and 23g.
2. the water of the stablizer of the inhibiter of the emulsifying agent of the extreme pressure lubricant of the pH adjusting agent of the vegetables oil of 50g, 4g, 18g, 22g, 0.1g, 3g, the defoamer of 0.01g, the sterilant of 5g and 13g.
3. the water of the stablizer of the inhibiter of the emulsifying agent of the extreme pressure lubricant of the pH adjusting agent of the vegetables oil of 36g, 11g, 12g, 19g, 1g, 1.2g, the defoamer of 0.1g, the sterilant of 3g and 16g.
4. the water of the stablizer of the inhibiter of the emulsifying agent of the extreme pressure lubricant of the pH adjusting agent of the vegetables oil of 44g, 7g, 15g, 15g, 2g, 0.8g, the defoamer of 0.2g, the sterilant of 2g and 20g.
5. the water of the stablizer of the inhibiter of the emulsifying agent of the extreme pressure lubricant of the pH adjusting agent of the vegetables oil of 40g, 9g, 13g, 17g, 1.5g, 1.0g, the defoamer of 0.15g, the sterilant of 2.5g and 18g.
6. the water of the stablizer of the inhibiter of the emulsifying agent of the extreme pressure lubricant of the pH adjusting agent of the vegetables oil of 45g, 8g, 14g, 13g, 0.8g, 2g, the defoamer of 0.08g, the sterilant of 4g and 21g.
Embodiment 2
According to embodiments of the invention, the particular type of vegetables oil is also not particularly limited, and according to a particular embodiment of the invention, vegetables oil can be 0.85 ~ 0.93g/cm for density
3, the kinematic viscosity at the temperature of 40 degrees Celsius is 30.0 ~ 44.0mm
2the vegetables oil of/s,
According to concrete example of the present invention, the particular type of vegetables oil is also not particularly limited, for in embodiment 1 1. ~ 6. in vegetables oil can be at least one in soybean oil, Viscotrol C, peanut oil, plam oil and rapeseed oil, such vegetables oil can as the basal component forming water-soluble metalworking liquid microemulsion, and the system formed has good oilness and thermal conduction.Such as, this vegetables oil can be: 1. soybean oil; 2. Viscotrol C; 3. peanut oil; 4. plam oil; 5. rapeseed oil; 6. soybean oil and peanut oil; 7. plam oil and rapeseed oil; 8. peanut oil, plam oil and rapeseed oil; 9. soybean oil, Viscotrol C and peanut oil; 10. soybean oil, Viscotrol C, peanut oil, plam oil and rapeseed oil.This vegetables oil can be 0.85 ~ 0.93g/cm for density
3(such as: can 0.88g/cm be preferably
3), the kinematic viscosity at the temperature of 40 degrees Celsius is 30.0 ~ 44.0mm
2/ s (such as: can be preferably 35mm
2/ s) vegetables oil, particularly, this vegetables oil can be: 1. 40 DEG C, and viscosity is 35mm
2the soybean oil of/s; 2. 40 DEG C, viscosity is 38mm
2the rapeseed oil of/s; 3. 40 DEG C, viscosity is 32mm
2the Viscotrol C of/s; 4. 40 DEG C, density is 0.88g/cm
3peanut oil; 5. 40 DEG C, density is 0.86g/cm
3plam oil.
Embodiment 3
According to all embodiments of the present invention, the pH value of this high oil plant oil base micro-emulsion cutting fluid is also not particularly limited, for in embodiment 1 1. ~ 6. in the pH value of cutting fluid of cutting fluid can be 7.5 ~ 9.3, preferably, pH value can be 8.0 ~ 9.0, the machining oil of this pH scope can the breeding of anti-bacteria, is unlikely to again because too high pH value is brought operator's skin contact and the discomfort that causes.
According to embodiments of the invention, this cutting fluid pH value regulator is also not particularly limited, for in embodiment 1 1. ~ 6. in the pH adjusting agent of cutting fluid can be in trolamine, Monoethanolamine MEA BASF, diglycolamine, α-amino isopropyl alcohol and 2-amino-2-methyl-1-propanol one or more mixture, the reasonable employment of this pH adjusting agent meets performance requriements and the environmental requirement of Water-soluble cutting oil, and there is good pH stability, thus be beneficial to keep its long-term work-ing life; Particularly, this pH value regulator can be: 1. trolamine; 2. Monoethanolamine MEA BASF; 3. 2-amino-2-methyl-1-propanol; 4. diglycolamine; 5. α-amino isopropyl alcohol; 6. trolamine and 2-amino-2-methyl-1-propanol; 7. α-amino isopropyl alcohol and 2-amino-2-methyl-1-propanol; 8. diglycolamine and α-amino isopropyl alcohol; 9. trolamine and monoethanolamine; 10. trolamine, Monoethanolamine MEA BASF, diglycolamine, α-amino isopropyl alcohol and 2-amino-2-methyl-1-propanol.
Embodiment 4
According to embodiments of the invention, the particular type of extreme pressure lubricant is also not particularly limited, in embodiment 1 1. ~ 6. in extreme pressure lubricant can be at least one in polymerized castor oil acid (i.e. ricinolic acid polymkeric substance), polymeric aliphatic ester and sulfuration (plant) fatty acid ester; Such as, this extreme pressure lubricant can be: 1. polymerized castor oil acid; 2. polymeric aliphatic ester; 3. in sulfuration (plant) fatty acid ester; 4. polymerized castor oil acid and polymeric aliphatic ester; 5. polymeric aliphatic ester and sulfuration (plant) fatty acid ester; 6. polymerized castor oil acid and sulfuration (plant) fatty acid ester; 7. polymerized castor oil acid, polymeric aliphatic ester and sulfuration (plant) fatty acid ester.
For the present embodiment 1. ~ 7. described in polymerized castor oil acid be preferably four poly-ricinolic acids, this four poly-ricinolic acid is more preferably four poly-ricinolic acid L4 of Clariant Corporation; Described sulfide aliphatic acid ester can be sulfide aliphatic acid ester and olefine sulfide mixture.
Embodiment 5
According to embodiments of the invention, the composition of emulsifying agent is also not particularly limited, in embodiment 1 1. ~ 6. in emulsifying agent can be at least one in sulfonated petro-leum, oleic acid, Yatall MA, fatty alcohol-polyoxyethylene ether, polyoxyethylene carboxylate and sorbitan monooleate; This emulsifying agent (mixture) proportioning can form highly stable working fluid, makes it in use can not separate out oil and soap-like matter, thus can ensure that cutting fluid has desirable working order; Such as, this emulsifying agent can be: 1. sulfonated petro-leum; 2. polyoxyethylene carboxylate; 3. sorbitan monooleate; 4. oleic acid and Yatall MA; 5. oleic acid; 6. Yatall MA; 7. fatty alcohol-polyoxyethylene ether; 8. sulfonated petro-leum and polyoxyethylene carboxylate; 9. sulfonated petro-leum and Yatall MA; 10. sulfonated petro-leum, oleic acid, Yatall MA, fatty alcohol-polyoxyethylene ether, polyoxyethylene carboxylate and sorbitan monooleate.
The pH value of the sulfonated petro-leum (emulsifying agent) in the present embodiment is also not particularly limited, the pH value of this sulfonated petro-leum (emulsifying agent) can be 7.0 ~ 8.0, such as, this sulfonated petro-leum (emulsifying agent) can for mass percent be 50 ~ 60% mahogany acid sodium solution.
Embodiment 6
According to embodiments of the invention, the particular type of inhibiter is also not particularly limited, for in embodiment 1 1. ~ 6. in inhibiter can be at least one in benzotriazole, Benzotriazole Derivative, alkyl phosphate and alkylphosphonic acid carboxylic acid ester derivative, this inhibiter to be significantly better than the work-ing life that other inhibiter improves the Water-soluble cutting oil that this lubricates for machining and guide rail, thus can reduce production cost; Such as: this inhibiter can be: 1. benzotriazole; 2. at least one in Benzotriazole Derivative; 3. alkyl phosphate; 4. at least one in alkyl phosphate derivative; 5. benzotriazole and alkyl phosphate; 6. at least one in benzotriazole and Benzotriazole Derivative; 7. at least one in benzotriazole and alkyl phosphate derivative; 8. at least one in benzene Benzotriazole Derivative and alkyl phosphate; 9. at least one in Benzotriazole Derivative and at least one in alkyl phosphate derivative; 10. at least one in benzotriazole, alkyl phosphate and Benzotriazole Derivative.
Further preferred embodiment, described benzotriazole is preferably benzotriazole T706, described Benzotriazole Derivative is preferably Benzotriazole Derivative L39, and described alkylphosphonic acid carboxylic acid ester derivative is preferably at least one in alkyl phosphate inhibiter ASI-80, OPS-75E, MDIT, CPNF-3 and 9218LA.
Embodiment 7
According to embodiments of the invention, the particular type of stablizer is also not particularly limited, for in embodiment 1 1. ~ 6. in stablizer can be at least one in ethylene glycol monobutyl ether, diethylene glycol monobutyl ether, glycerol and ethylene glycol, this stablizer can significantly improve the over-all properties of this cutting fluid.Such as, this stablizer can be: 1. ethylene glycol monobutyl ether; 2. diethylene glycol monobutyl ether; 3. glycerol; 4. ethylene glycol; 5. ethylene glycol monobutyl ether and diethylene glycol monobutyl ether; 6. diethylene glycol monobutyl ether and glycerol; 7. glycerol and ethylene glycol; 8. ethylene glycol monobutyl ether, glycerol and ethylene glycol; 9. ethylene glycol monobutyl ether, diethylene glycol monobutyl ether and ethylene glycol; 10. ethylene glycol monobutyl ether, diethylene glycol monobutyl ether, glycerol and ethylene glycol.
Embodiment 8
According to embodiments of the invention, the particular type of defoamer is also not particularly limited, for in embodiment 1 1. ~ 6. in defoamer can be type siloxane defoamer, this type siloxane defoamer is preferably three-dimensional type siloxane defoamer, there is very excellent antifoam performance and suds suppressing properties, and easily clean, namely trace mineral supplement has the defoaming effect meeting working fluid requirement.
Embodiment 9
According to embodiments of the invention, the particular type of sterilant is also not particularly limited, for in embodiment 1 1. ~ 6. in sterilant can be the mixture (FORTE) of pyridine sodium-mercaptan oxidation thing-Hexahydrotriazine derivative, N, N '-methylene-bis morpholine (MBM), BIT (BIT), 1, 3, at least one in 5-tri-(2-hydroxyethyl) s-triazine (BK) and IPBC (IPBC), this sterilant is to improve the sterilization and anticorrosion performance of machining oil due to other sterilant, make it have lasting bacteriostasis, thus can guarantee that cutting fluid life-time service does not go bad, extend the work-ing life of working fluid, such as, this sterilant can be: 1. FORTE, 2. MBM, 3. BIT, 4. BK, 5. IPBC, 6. FORTE and MBM, 7. MBM and BIT, 8. BK and IPBC, 9. FORTE and BIT, 10. FORTE, MBM, BIT, BK and IPBC.
Embodiment 10
Below by reference specific embodiment, and provide technique effect; It should be noted that, these embodiments are only descriptive, and do not limit the present invention in any way.
Table 1
The machining oil of comparative example 1 (comparative example 1 is certain reputable brand Water-soluble cutting oil commercially available), embodiment 1-3 is added deionized water and is mixed with 5% cutting fluid, gained cutting fluid performance is as shown in table 2.
Table 2
The present invention is not limited to above-mentioned preferred forms, anyone for the present invention any modification done under enlightenment of the present invention or change, and every have identical with the application or akin technical scheme, all drops within protection scope of the present invention.
Claims (10)
1. a high oil plant oil base micro-emulsion cutting fluid, is characterized in that: the composition in described plant oil based micro-emulsion cutting fluid and the parts by weight of various composition comprise: the water of the vegetables oil of 30 ~ 50 parts, the pH adjusting agent of 4 ~ 14 parts, the extreme pressure lubricant of 8 ~ 18 parts, the emulsifying agent of 12 ~ 22 parts, the inhibiter of 0.1 ~ 3.5 part, the stablizer of 0.1 ~ 3 part, the defoamer of 0.01 ~ 0.3 part, the sterilant of 1 ~ 5 part and 13 ~ 23 parts;
Described vegetables oil comprises at least one in soybean oil, Viscotrol C, peanut oil, plam oil and rapeseed oil;
Described extreme pressure lubricant comprises at least one in ricinolic acid polymkeric substance, polymeric aliphatic ester and sulfide aliphatic acid ester;
Described emulsifying agent comprises at least one in sulfonated petro-leum, fatty alcohol-polyoxyethylene ether, oleic acid, Yatall MA, polyoxyethylene carboxylate and sorbitan monooleate;
Described inhibiter is at least one in benzotriazole, Benzotriazole Derivative, alkyl phosphate and alkylphosphonic acid carboxylic acid ester derivative;
The pH value of described plant oil based micro-emulsion cutting fluid is 7.5 ~ 9.3.
2. high oil plant oil base micro-emulsion cutting fluid according to claim 1, is characterized in that: the density of described vegetables oil is 0.85 ~ 0.93g/cm
3, the kinematic viscosity at the temperature of 40 degrees Celsius is 30.0 ~ 44.0mm
2/ s.
3. high oil plant oil base micro-emulsion cutting fluid according to claim 1, is characterized in that: described pH adjusting agent is one or more in trolamine, Monoethanolamine MEA BASF, diglycolamine, α-amino isopropyl alcohol and 2-amino-2-methyl-1-propanol.
4. high oil plant oil base micro-emulsion cutting fluid according to claim 1, is characterized in that: described ricinolic acid polymkeric substance is four poly-ricinolic acids, and described sulfide aliphatic acid ester can be sulfide aliphatic acid ester and olefine sulfide mixture.
5. high oil plant oil base micro-emulsion cutting fluid according to claim 1, is characterized in that: the pH of described sulfonated petro-leum is 7.0 ~ 8.0.
6. high oil plant oil base micro-emulsion cutting fluid according to claim 5, is characterized in that: described sulfonated petro-leum to be mass percent be 50 ~ 60% petroleum sodium sulfonate.
7. high oil plant oil base micro-emulsion cutting fluid according to claim 1, is characterized in that: described inhibiter is at least one in benzo nitrogen triazole and benzo nitrogen triazole derivative.
8. high oil plant oil base micro-emulsion cutting fluid according to claim 1, is characterized in that: described stablizer comprises at least one in ethylene glycol monobutyl ether, diethylene glycol monobutyl ether, glycerol and ethylene glycol.
9. high oil plant oil base micro-emulsion cutting fluid according to claim 1, is characterized in that: described defoamer is type siloxane defoamer.
10. high oil plant oil base micro-emulsion cutting fluid according to claim 1, it is characterized in that: described sterilant is the pyridine sodium-mercaptan oxidation thing-mixture of Hexahydrotriazine derivative, N, N '-methylene-bis morpholine, BIT, 1, at least one in 3,5-tri-(2-hydroxyethyl) s-triazine and IPBC.
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