CN108048198A - A kind of environment-friendly type fully synthetic cutting fluid and preparation method thereof - Google Patents
A kind of environment-friendly type fully synthetic cutting fluid and preparation method thereof Download PDFInfo
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- CN108048198A CN108048198A CN201711370005.3A CN201711370005A CN108048198A CN 108048198 A CN108048198 A CN 108048198A CN 201711370005 A CN201711370005 A CN 201711370005A CN 108048198 A CN108048198 A CN 108048198A
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- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M173/00—Lubricating compositions containing more than 10% water
- C10M173/02—Lubricating compositions containing more than 10% water not containing mineral or fatty oils
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2201/00—Inorganic compounds or elements as ingredients in lubricant compositions
- C10M2201/087—Boron oxides, acids or salts
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2207/00—Organic non-macromolecular hydrocarbon compounds containing hydrogen, carbon and oxygen as ingredients in lubricant compositions
- C10M2207/10—Carboxylix acids; Neutral salts thereof
- C10M2207/12—Carboxylix acids; Neutral salts thereof having carboxyl groups bound to acyclic or cycloaliphatic carbon atoms
- C10M2207/125—Carboxylix acids; Neutral salts thereof having carboxyl groups bound to acyclic or cycloaliphatic carbon atoms having hydrocarbon chains of eight up to twenty-nine carbon atoms, i.e. fatty acids
- C10M2207/127—Carboxylix acids; Neutral salts thereof having carboxyl groups bound to acyclic or cycloaliphatic carbon atoms having hydrocarbon chains of eight up to twenty-nine carbon atoms, i.e. fatty acids polycarboxylic
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2207/00—Organic non-macromolecular hydrocarbon compounds containing hydrogen, carbon and oxygen as ingredients in lubricant compositions
- C10M2207/10—Carboxylix acids; Neutral salts thereof
- C10M2207/12—Carboxylix acids; Neutral salts thereof having carboxyl groups bound to acyclic or cycloaliphatic carbon atoms
- C10M2207/125—Carboxylix acids; Neutral salts thereof having carboxyl groups bound to acyclic or cycloaliphatic carbon atoms having hydrocarbon chains of eight up to twenty-nine carbon atoms, i.e. fatty acids
- C10M2207/128—Carboxylix acids; Neutral salts thereof having carboxyl groups bound to acyclic or cycloaliphatic carbon atoms having hydrocarbon chains of eight up to twenty-nine carbon atoms, i.e. fatty acids containing hydroxy groups; Ethers thereof
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2209/00—Organic macromolecular compounds containing oxygen as ingredients in lubricant compositions
- C10M2209/02—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2209/00—Organic macromolecular compounds containing oxygen as ingredients in lubricant compositions
- C10M2209/10—Macromolecular compoundss obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
- C10M2209/103—Polyethers, i.e. containing di- or higher polyoxyalkylene groups
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2215/00—Organic non-macromolecular compounds containing nitrogen as ingredients in lubricant compositions
- C10M2215/02—Amines, e.g. polyalkylene polyamines; Quaternary amines
- C10M2215/04—Amines, e.g. polyalkylene polyamines; Quaternary amines having amino groups bound to acyclic or cycloaliphatic carbon atoms
- C10M2215/042—Amines, e.g. polyalkylene polyamines; Quaternary amines having amino groups bound to acyclic or cycloaliphatic carbon atoms containing hydroxy groups; Alkoxylated derivatives thereof
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2215/00—Organic non-macromolecular compounds containing nitrogen as ingredients in lubricant compositions
- C10M2215/22—Heterocyclic nitrogen compounds
- C10M2215/223—Five-membered rings containing nitrogen and carbon only
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
- C10N2030/00—Specified physical or chemical properties which is improved by the additive characterising the lubricating composition, e.g. multifunctional additives
- C10N2030/06—Oiliness; Film-strength; Anti-wear; Resistance to extreme pressure
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
- C10N2040/00—Specified use or application for which the lubricating composition is intended
- C10N2040/20—Metal working
- C10N2040/22—Metal working with essential removal of material, e.g. cutting, grinding or drilling
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- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- General Chemical & Material Sciences (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Organic Chemistry (AREA)
- Lubricants (AREA)
Abstract
The present invention provides a kind of environment-friendly type fully synthetic cutting fluids, it is made of water, extreme pressure agent, antirust agent, pH adjusting agent, antioxidant and antifoaming agent, weight percent of the water in cutting fluid is 40%~60%, weight percent of the extreme pressure agent in cutting fluid is 5%~10%, weight percent of the antirust agent in cutting fluid is 10%~20%, weight percent of the pH adjusting agent in cutting fluid is 15%~30%, weight percent of the antioxidant in cutting fluid is 0.2%~0.5%, and weight percent of the antifoaming agent in cutting fluid is 1%~2%.The present invention also provides the preparation methods of above-mentioned environment-friendly type fully synthetic cutting fluid, first heat the water to 50 60 DEG C, then add in extreme pressure agent, antirust agent, pH adjusting agent, antioxidant and antifoaming agent, are mixed up to environment-friendly type fully synthetic cutting fluid.The present invention is with water generation oil, for metal cutting and grinding, be not easy it is putrid and deteriorated, it is harmless.
Description
Technical field
The invention belongs to chemical fields, are related to a kind of metal-processing industry liquid more particularly to a kind of cutting fluid, specifically
A kind of environment-friendly type fully synthetic cutting fluid and preparation method thereof.
Background technology
Cutting fluid is a kind of in metal cutting, mill process, the work for cooling down and lubricating cutter and workpiece
Industry liquid plays lubrication, cooling, antirust and a class I liquid I of cleaning action.Cutting fluid is divided into oil base and water base two major class.Tradition
Oil base cutting fluid, greasy property is preferable, but cool down and cleaning performance it is poor;Compared to oil base cutting fluid, water-base cutting fluid is cold
But effect and cleaning performance are preferable, but poor there is also greasy property, it is apt to deteriorate smelly the problem of.
The content of the invention
It is an object of the invention to provide a kind of environment-friendly type fully synthetic cutting fluid and preparation method thereof, this environmental protection
Type fully synthetic cutting fluid and preparation method thereof will solve cutting fluid lubrication in the prior art and cooling is bad, apt to deteriorate
Technical problem.
The present invention provides a kind of environment-friendly type fully synthetic cutting fluid, by water, extreme pressure agent, antirust agent, pH adjusting agent, antioxygen
Agent and antifoaming agent composition, weight percent of the water in cutting fluid are 40%~60%, and the extreme pressure agent is being cut
Weight percent in liquid is 5%~10%, and weight percent of the antirust agent in cutting fluid is 10%~20%, institute
Weight percent of the pH adjusting agent stated in cutting fluid is 15%~30%, weight of the antioxidant in cutting fluid
Percentage is 0.2%~0.5%, and weight percent of the antifoaming agent in cutting fluid is 1%~2%.
Further, the water is tap water.
Further, the extreme pressure agent be ricinoleic acid, in polymerized castor oil acid or smart dimeric dibasic acid any one or
The two or more combination of person.
Further, the antirust agent is any one in boric acid, decanedioic acid or 12 carbon or two or more
Combination.
Further, the pH adjusting agent is any one in monoethanolamine or triethanolamine or two kinds of group
It closes.
Further, the antioxidant is benzotriazole.
Further, the antifoaming agent is any one in 17R2 polyethers or 17R4 polyethers or two or more
Combination.
Specifically, the 17R2 polyethers or 17R4 polyethers are purchased from Huntsman Corporation of the U.S..
The present invention also provides the preparation method of above-mentioned environment-friendly type fully synthetic cutting fluid,
1) water, extreme pressure agent, antirust agent, pH adjusting agent, antioxidant and antifoaming agent are weighed according to mass percent,
2) 50-60 DEG C is first heated the water to, then adds in extreme pressure agent, antirust agent, pH adjusting agent, antioxidant and defoaming
Agent is mixed 30-60 minutes up to environment-friendly type fully synthetic cutting fluid.
A kind of environment-friendly type fully synthetic cutting fluid of the present invention has the following advantages:
1. the term of validity of this product can reach 2 years or more, storage time is long, and product stability and service life are substantially excellent
In traditional product.
2. the concentrate pH value of this product, between 9.5-10.5, this product can effectively prevent that product from going bad hair in alkalescence
Smelly property.
3. this product can be widely used in cast iron, steel part, the grinding and cutting of a series of materials such as plastics and composite material.
4. the low foam of this product and low aerosol, harmless without sodium nitrite antirust agent and phenolic antiseptic,.
5. this product is water-base cutting fluid, production cost is not high, and the machine amount of taking away is especially few, and operating cost is very low.
The present invention is compared with prior art, and effect is positive and apparent.Compared with traditional oil base cutting fluid, the present invention
The term of validity of fully synthetic cutting fluid can reach 2 years or more, harmless without sodium nitrite antirust agent and phenolic antiseptic,
It is smelly to solve the problems, such as that traditional water-base cutting fluid goes bad well, the lubricity of this product is also excellent in addition, effective to solve
Traditional oil base and water-base cutting fluid there are the problem of.
Specific embodiment:
Embodiment 1
The present invention provides a kind of environment-friendly type fully synthetic cutting fluid, by water, extreme pressure agent, antirust agent, pH adjusting agent, antioxygen
Agent and antifoaming agent composition, weight percent of the water in cutting fluid are 52.7%, and water is squeezed into reaction kettle, is heated to
55 DEG C, add in extreme pressure agent A, B, antirust agent A, B, C, pH adjusting agent A, B, antioxidant and antifoaming agent A, B, mixing in water afterwards
Stirring 50 minutes.Weight percent of the extreme pressure agent A in cutting fluid is 5%, and the extreme pressure agent B is in cutting fluid
Weight percent is 5%;Weight percent of the antirust agent A in cutting fluid is 5%, and the antirust agent B is being cut
Weight percent in liquid is 5%, and weight percent of the antirust agent C in cutting fluid is 5%;The pH value is adjusted
Weight percent of the agent A in cutting fluid is 10%, and weight percent of the pH adjusting agent B in cutting fluid is
10%;Weight percent of the antioxidant in cutting fluid is 0.3%, weight of the antifoaming agent A in cutting fluid
Percentage is 1%, and weight percent of the antifoaming agent B in cutting fluid is 1%.
Further, the water is tap water.
Further, the extreme pressure agent A is ricinoleic acid, and extreme pressure agent B is polymerized castor oil acid.
Further, the antirust agent A is boric acid, and antirust agent B is decanedioic acid, and antirust agent C is 12 carbon.
Further, the pH adjusting agent A is monoethanolamine, and pH adjusting agent B is triethanolamine.
Further, the antioxidant is benzotriazole.
Further, the antifoaming agent A is 17R2 polyethers, and antifoaming agent B is 17R4 polyethers.
Every physical and chemical index is shown in Table 1.
Embodiment 2
The present invention provides a kind of environment-friendly type fully synthetic cutting fluid, by water, extreme pressure agent, antirust agent, pH adjusting agent, antioxygen
Agent and antifoaming agent composition, weight percent of the water in cutting fluid are 60%, and water is squeezed into reaction kettle, is heated to 60
DEG C, it adds in extreme pressure agent A, antirust agent A, pH adjusting agent A, antioxidant and antifoaming agent A in water afterwards, is mixed 40 minutes.
Weight percent of the extreme pressure agent A in cutting fluid is 8%;Weight percent of the antirust agent A in cutting fluid
For 15%;Weight percent of the pH adjusting agent A in cutting fluid is 15%, and the antioxidant is in cutting fluid
Weight percent is 0.5%, and weight percent of the antifoaming agent A in cutting fluid is 1.5%.
Further, the water is tap water.
Further, the extreme pressure agent A is smart dimeric dibasic acid.
Further, the antirust agent A is boric acid.
Further, the pH adjusting agent A is monoethanolamine.
Further, the antioxidant is benzotriazole.
Further, the antifoaming agent A is 17R2 polyethers.
Every physical and chemical index is shown in Table 1.
Embodiment 3
The present invention provides a kind of environment-friendly type fully synthetic cutting fluid, by water, extreme pressure agent, antirust agent, pH adjusting agent, antioxygen
Agent and antifoaming agent composition, weight percent of the water in cutting fluid are 57%, and water is squeezed into reaction kettle, is heated to 50
DEG C, it adds in extreme pressure agent A, B, antirust agent A, B, pH adjusting agent A, antioxidant and antifoaming agent A in water afterwards, is mixed 60 points
Clock.Weight percent of the extreme pressure agent A in cutting fluid is 5%, weight percents of the extreme pressure agent B in cutting fluid
Than for 5%;Weight percent of the antirust agent A in cutting fluid is 8%, weights of the antirust agent B in cutting fluid
It is 8% to measure percentage;Weight percent of the pH adjusting agent A in cutting fluid is 15%;The antioxidant is being cut
It is 0.5% to cut the weight percent in liquid, and weight percent of the antifoaming agent A in cutting fluid is 1.5%.
Further, the water is tap water.
Further, the extreme pressure agent A is ricinoleic acid, and extreme pressure agent B is smart dimeric dibasic acid.
Further, the antirust agent A is decanedioic acid, and antirust agent B is 12 carbon.
Further, the pH adjusting agent A is triethanolamine.
Further, the antioxidant is benzotriazole.
Further, the antifoaming agent A is 17R4 polyethers.
Every physical and chemical index is shown in Table 1.
Embodiment 4
The present invention provides a kind of environment-friendly type fully synthetic cutting fluid, by water, extreme pressure agent, antirust agent, pH adjusting agent, antioxygen
Agent and antifoaming agent composition, weight percent of the water in cutting fluid are 48.6%, and water is squeezed into reaction kettle, is heated to
60 DEG C, add in extreme pressure agent A, B, C, antirust agent A, B, pH adjusting agent A, B, antioxidant and antifoaming agent A, B, mixing in water afterwards
Stirring 50 minutes.Weight percent of the extreme pressure agent A in cutting fluid is 3%, and the extreme pressure agent B is in cutting fluid
Weight percent is 3%, and weight percent of the extreme pressure agent C in cutting fluid is 3%;The antirust agent A is being cut
Weight percent in liquid is 8%, and weight percent of the antirust agent B in cutting fluid is 8%;The pH value is adjusted
Weight percent of the agent A in cutting fluid is 12%, and weight percent of the pH adjusting agent B in cutting fluid is
12%;Weight percent of the antioxidant in cutting fluid is 0.4%, weight of the antifoaming agent A in cutting fluid
Percentage is 1%, and weight percent of the antifoaming agent B in cutting fluid is 1%.
Further, the water is tap water.
Further, the extreme pressure agent A is ricinoleic acid, and extreme pressure agent B is polymerized castor oil acid, and extreme pressure agent C is essence two
Polyacids.
Further, the antirust agent A is boric acid, and antirust agent B is 12 carbon.
Further, the pH adjusting agent A is monoethanolamine, and pH adjusting agent B is triethanolamine.
Further, the antioxidant is benzotriazole.
Further, the antifoaming agent A is 17R2 polyethers, and antifoaming agent B is 17R4 polyethers.
Every physical and chemical index is shown in Table 1.
Table 1
The present invention is relatively shown in Table 2 with certain external fully synthetic cutting fluid, traditional each physical and chemical performance of cutting fluid
Table 2
As can be seen from Table 2 with the present invention has higher pH value compared with certain external fully synthetic cutting fluid, can be effective
It prevents cutting fluid from going bad, prolongs the service life.The present invention has higher pH value compared with traditional cutting fluid, and defoaming is better than
Traditional product.
The beneficial effects of the present invention are:First, compared with traditional cutting fluid, this product is water-base cutting fluid, without Asia
Sodium nitrate antirust agent and phenolic antiseptic, security performance is splendid, non-toxic and safe is environmentally friendly harmless;Secondly, this product part
Index is less than import brand due to international import brand, technological precedence, price;3rd, this product is superior on indices
National standard and the traditional cutting fluid of use, substantially increase the service life of the various devices of metal processing sectors, have saved production
Cost.
Claims (8)
1. a kind of environment-friendly type fully synthetic cutting fluid, it is characterised in that:By water, extreme pressure agent, antirust agent, pH adjusting agent, antioxidant
It is formed with antifoaming agent, weight percent of the water in cutting fluid is 40%~60%, and the extreme pressure agent is in cutting fluid
In weight percent for 5%~10%, weight percent of the antirust agent in cutting fluid is 10%~20%, described
Weight percent of the pH adjusting agent in cutting fluid be 15%~30%, weight hundred of the antioxidant in cutting fluid
Divide than being 0.2%~0.5%, weight percent of the antifoaming agent in cutting fluid is 1%~2%.
2. environment-friendly type fully synthetic cutting fluid according to claim 1, it is characterised in that:The water is tap water.
3. environment-friendly type fully synthetic cutting fluid according to claim 1, it is characterised in that:The extreme pressure agent is castor oil
Any one in acid, polymerized castor oil acid or smart dimeric dibasic acid or two or more combinations.
4. environment-friendly type fully synthetic cutting fluid according to claim 1, it is characterised in that:The antirust agent is boric acid, the last of the ten Heavenly stems
Any one in diacid or 12 carbon or two or more combinations.
5. environment-friendly type fully synthetic cutting fluid according to claim 1, it is characterised in that:The pH adjusting agent is a second
The combination of any one or two kinds in hydramine or triethanolamine.
6. environment-friendly type fully synthetic cutting fluid according to claim 1, it is characterised in that:The antioxidant is three nitrogen of benzo
Azoles.
7. environment-friendly type fully synthetic cutting fluid according to claim 1, it is characterised in that:The antifoaming agent is 17R2 polyethers
Or any one in 17R4 polyethers or two or more combinations.
A kind of 8. method for preparing environment-friendly type fully synthetic cutting fluid as described in claim 1, it is characterised in that:Including walking as follows
Suddenly:
1) water, extreme pressure agent, antirust agent, pH adjusting agent, antioxidant and antifoaming agent are weighed according to mass percent,
2) 50-60 DEG C is first heated the water to, then adds in extreme pressure agent, antirust agent, pH adjusting agent, antioxidant and antifoaming agent, is mixed
Stirring is closed 30-60 minutes up to environment-friendly type fully synthetic cutting fluid.
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CN108048198B CN108048198B (en) | 2020-07-07 |
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Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN111205919A (en) * | 2020-01-13 | 2020-05-29 | 库勃智能科技(上海)有限公司 | Environment-friendly biostable cutting fluid and preparation method thereof |
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CN107312608A (en) * | 2017-06-19 | 2017-11-03 | 骏雁新材料科技(上海)有限公司 | A kind of environmental type total synthesis water-base cutting fluid and preparation method thereof |
CN107384561A (en) * | 2017-08-01 | 2017-11-24 | 屏南县康迈精选科技有限公司 | A kind of fully synthetic cutting fluid |
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JPS5692998A (en) * | 1979-12-26 | 1981-07-28 | Mazda Motor Corp | Antiseptic and water-soluble cutting oil |
US7312185B2 (en) * | 2002-10-31 | 2007-12-25 | Tomlin Scientific Inc. | Rock bit grease composition |
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CN101230305A (en) * | 2007-12-29 | 2008-07-30 | 广州机械科学研究院 | Totally synthesized cutting fluid adapted for cobalt-containing alloy material and preparation method thereof |
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CN104357203A (en) * | 2014-09-30 | 2015-02-18 | 苏州长盛机电有限公司 | Fully-synthetic cutting fluid applicable to aluminum alloy material machining and preparation method thereof |
CN105154197A (en) * | 2015-08-26 | 2015-12-16 | 开封市奥科宝特种油剂有限公司 | Plant-oil-based micro-emulsion cutting fluid with high oil content |
CN107312608A (en) * | 2017-06-19 | 2017-11-03 | 骏雁新材料科技(上海)有限公司 | A kind of environmental type total synthesis water-base cutting fluid and preparation method thereof |
CN107384561A (en) * | 2017-08-01 | 2017-11-24 | 屏南县康迈精选科技有限公司 | A kind of fully synthetic cutting fluid |
Cited By (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN111205919A (en) * | 2020-01-13 | 2020-05-29 | 库勃智能科技(上海)有限公司 | Environment-friendly biostable cutting fluid and preparation method thereof |
CN111205919B (en) * | 2020-01-13 | 2021-11-16 | 库勃智能科技(上海)有限公司 | Environment-friendly biostable cutting fluid and preparation method thereof |
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