CN105820866B - A kind of fully synthetic linear cutter liquid of middle wire - Google Patents

A kind of fully synthetic linear cutter liquid of middle wire Download PDF

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Publication number
CN105820866B
CN105820866B CN201610245451.0A CN201610245451A CN105820866B CN 105820866 B CN105820866 B CN 105820866B CN 201610245451 A CN201610245451 A CN 201610245451A CN 105820866 B CN105820866 B CN 105820866B
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linear cutter
wire
fully synthetic
liquid
synthetic linear
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CN105820866A (en
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李朝圣
李存震
李稳新
孙明
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Dongguan Wei Yao Numerical Control Device Co Ltd
Guangzhou Kelusi Fluid Technology Co Ltd
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Dongguan Wei Yao Numerical Control Device Co Ltd
Guangzhou Kelusi Fluid Technology Co Ltd
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    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M173/00—Lubricating compositions containing more than 10% water
    • C10M173/02—Lubricating compositions containing more than 10% water not containing mineral or fatty oils
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2201/00—Inorganic compounds or elements as ingredients in lubricant compositions
    • C10M2201/06—Metal compounds
    • C10M2201/061—Carbides; Hydrides; Nitrides
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2201/00—Inorganic compounds or elements as ingredients in lubricant compositions
    • C10M2201/087—Boron oxides, acids or salts
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2207/00—Organic non-macromolecular hydrocarbon compounds containing hydrogen, carbon and oxygen as ingredients in lubricant compositions
    • C10M2207/02—Hydroxy compounds
    • C10M2207/021—Hydroxy compounds having hydroxy groups bound to acyclic or cycloaliphatic carbon atoms
    • C10M2207/022—Hydroxy compounds having hydroxy groups bound to acyclic or cycloaliphatic carbon atoms containing at least two hydroxy groups
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2207/00—Organic non-macromolecular hydrocarbon compounds containing hydrogen, carbon and oxygen as ingredients in lubricant compositions
    • C10M2207/04—Ethers; Acetals; Ortho-esters; Ortho-carbonates
    • C10M2207/046—Hydroxy ethers
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2209/00—Organic macromolecular compounds containing oxygen as ingredients in lubricant compositions
    • C10M2209/10—Macromolecular compoundss obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
    • C10M2209/103—Polyethers, i.e. containing di- or higher polyoxyalkylene groups
    • C10M2209/104—Polyethers, i.e. containing di- or higher polyoxyalkylene groups of alkylene oxides containing two carbon atoms only
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2209/00—Organic macromolecular compounds containing oxygen as ingredients in lubricant compositions
    • C10M2209/10—Macromolecular compoundss obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
    • C10M2209/103—Polyethers, i.e. containing di- or higher polyoxyalkylene groups
    • C10M2209/107—Polyethers, i.e. containing di- or higher polyoxyalkylene groups of two or more specified different alkylene oxides covered by groups C10M2209/104 - C10M2209/106
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2209/00—Organic macromolecular compounds containing oxygen as ingredients in lubricant compositions
    • C10M2209/10—Macromolecular compoundss obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
    • C10M2209/103—Polyethers, i.e. containing di- or higher polyoxyalkylene groups
    • C10M2209/108—Polyethers, i.e. containing di- or higher polyoxyalkylene groups etherified
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2215/00—Organic non-macromolecular compounds containing nitrogen as ingredients in lubricant compositions
    • C10M2215/02—Amines, e.g. polyalkylene polyamines; Quaternary amines
    • C10M2215/04—Amines, e.g. polyalkylene polyamines; Quaternary amines having amino groups bound to acyclic or cycloaliphatic carbon atoms
    • C10M2215/042—Amines, e.g. polyalkylene polyamines; Quaternary amines having amino groups bound to acyclic or cycloaliphatic carbon atoms containing hydroxy groups; Alkoxylated derivatives thereof
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2215/00—Organic non-macromolecular compounds containing nitrogen as ingredients in lubricant compositions
    • C10M2215/22—Heterocyclic nitrogen compounds
    • C10M2215/223—Five-membered rings containing nitrogen and carbon only
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2227/00—Organic non-macromolecular compounds containing atoms of elements not provided for in groups C10M2203/00, C10M2207/00, C10M2211/00, C10M2215/00, C10M2219/00 or C10M2223/00 as ingredients in lubricant compositions
    • C10M2227/06—Organic compounds derived from inorganic acids or metal salts
    • C10M2227/061—Esters derived from boron
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
    • C10N2030/00—Specified physical or chemical properties which is improved by the additive characterising the lubricating composition, e.g. multifunctional additives
    • C10N2030/04—Detergent property or dispersant property
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
    • C10N2040/00—Specified use or application for which the lubricating composition is intended
    • C10N2040/14—Electric or magnetic purposes
    • C10N2040/16—Dielectric; Insulating oil or insulators
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
    • C10N2040/00—Specified use or application for which the lubricating composition is intended
    • C10N2040/20—Metal working
    • C10N2040/22—Metal working with essential removal of material, e.g. cutting, grinding or drilling

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  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • General Chemical & Material Sciences (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Organic Chemistry (AREA)
  • Lubricants (AREA)

Abstract

The present invention relates to cutting processing field, in particular to a kind of fully synthetic linear cutter liquid of middle wire.The currently preferred optimized combination of each additive, the middle wire linear cutter liquid obtained has excellent comprehensive performance, inventive formulation system combines the process characteristic of middle wire wire cutting, and the cleaning performance of working solution is controlled using special surface activator composition.The dielectricity and its stability that system is controlled and improved by preferred burster reach and improve simultaneously continual and steady high machining accuracy and efficiency.Suitable, stable antirust and lubricating system are established by preferred pH adjusting agent, antirust agent, lubricant, reach wire wire cutting technology antirust and lubricating requirement in guarantee, improve workpiece surface processing quality, at the same can reach service performance it is excellent and stablize, also taken into account working fluid environmental-protecting performance.

Description

A kind of fully synthetic linear cutter liquid of middle wire
Technical field
The present invention relates to cutting processing field, in particular to a kind of fully synthetic linear cutter liquid of middle wire.
Background technique
With domestic and international manufacturing rapid development, Electric Discharge Wire-cutting Technology is also being developed rapidly, but wire cutting liquid Technology development is relatively slow, cannot meet the performance of the processing technology of wire cutting machine very well.It is originally that fast wire winding adds in the market Work and slow wire feeding are processed, but the two respectively has advantage and disadvantage, have been unable to meet the demand of market development, mainly fast wire winding processing effect Rate and workpiece surface quality are far from the requirement for meeting development of manufacturing, and slow wire feeding workpiece surface quality is good, but add Work efficiency rate is too low, thus the middle wire line cutting technology that had been born in recent years, not only cutting efficiency is high, but also workpieces processing surface matter Amount is high, does not have to secondary operation.Middle wire cutting machine uses multiple cutting processing technology, first time high current fly-cutting Shi Caiyong crosses tracing control, avoids fracture of wire, and when second, third time smoothing cutting adopts the control mode of pressure speed limit feeding, substantially Improve the surface quality of wire cutting efficiency and workpieces processing, the increasingly welcome by market.
But middle wire line cutting technology is very harsh to the requirement of linear cutter liquid, and the superiority and inferiority of linear cutter fluidity energy is straight Connect the performance of wire-moving cutting efficiency in influencing, cut quality and cutting stability etc., middle wire linear cutter technical requirements Linear cutter liquid should have good dielectricity, lubricity, antiseptic and rustproof property, cleaning, chip resistance, feature of environmental protection etc. simultaneously. Since middle wire linear cutter has combined processing quality and processing efficiency, need special wire cutting liquid that it is supplied to make With.
Currently on the market conventional emulsification type, semi-synthetic and aqua type fast wire winding and low-speed WEDM liquid not Far it is able to satisfy its demand.Currently, research and the report of domestic rarely seen middle wire wire cutting liquid, used middle wire-moving is cut in the market The substantially equal existing defects of liquid are cut, mainly wire cutting low efficiency, stability are poor, cleaning is poor, workpiece surface quality is general, anti- Become rusty poor, skin allergy phenomena such as, the wire cutting liquid product for being able to satisfy middle wire linear cutter requirement is few.
Domestic patent of invention [CN104673470A] discloses " a kind of middle wire-moving cutting working liquid ", main component and ratio Example: lemon acid propylene glycol polyoxyethylene poly-oxygen propylene aether monoesters 15-25%, citric acid alkyl glycosides monoesters 5-10%, central Shanxi plain amino It is triethylenetetraminehexaacetic acid alcohol amine salt 10-15%, butyl 0.3-1%, triazole corrosion inhibiter 0.1-0.3%, fungicide 0-1%, organic Silicon defoaming agent 0-1%, water surplus.This wire cutting efficiency is general with workpiece surface quality, and stability is not good enough, is unable to satisfy big Work piece cut.
[CN103060072A] is disclosed " a kind of fully synthetic liquid composition of high-speed electric spark wire cutting liquid ", main component with Ratio: compound oleate soap 8-20%, polyacid amide 3-15%, Composite borate 3-10%, pH adjusting agent 6-15%, copper inhibitor 0.3-1%, polyethers 1-2%, defoaming agent 0.05-0.15%, pure water surplus.The invention patent is added for high speed WEDM Work, substitution conventional emulsification liquid and semi-synthetic liquid, are not able to satisfy middle wire linear cutter requirement.
[CN104289774A] discloses " a kind of novel water-based Wire EDM liquid ", main component and ratio: surface Activating agent 14-18%, antirust agent 1.4-2%, burster 8-12%, electrolyte 1.5-2.5%, other additives 0.8-2%, remaining be Deionized water.The invention patent is mainly high speed WEDM working fluid, is not suitable for middle wire linear cutter.
[CN104450131A], [CN103725387B] and [CN104289773A] disclose " a kind of novel water-based respectively The preparation method of Wire EDM liquid ", " a kind of Nd-Fe-B permanent magnet material wire cutting liquid " and a kind of " environment-friendly type wire electric discharge Cutting liquid ", the invention are mainly used for high speed WEDM processing, are not suitable for middle wire linear cutter.
Summary of the invention
Technical problem to be solved by the invention is to provide a kind of middle fully synthetic linear cutter liquid of wire.
A kind of fully synthetic linear cutter liquid of middle wire, containing following weight percentage components: pH adjusting agent 10 ~ 20%, Antirust agent 5 ~ 10%, lubricant 3 ~ 8%, burster 12 ~ 18%, moisturizer 4 ~ 6%, cleaning agent 6 ~ 10%, defoaming agent 0.1%, copper inhibition Agent 0.1%, and 100% is supplemented to deionized water.
Further, the burster is the mixture of polyvalent alcohol and glycol.
Further, the polyvalent alcohol is at least one of polyethylene glycol, polypropylene glycol；Glycol be dipropylene glycol and At least one of diethylene glycol.
Further, the pH adjusting agent is at least one of triethanolamine, AMP-95 and N methyldiethanol amine.
Further, the antirust agent is at least one of borate and borate.
Further, the lubricant is the mixture of EO/PO block polyether and nm-class boron nitride.
Further, the molecular weight of the EO/PO block polyether is 2100 ~ 5000.
Further, the moisturizer is glycerol.
Further, the surfactant is fatty alcohol polyoxyethylene ether, at least one in castor oil polyoxyethylene ether Kind.
Further, the copper inhibitor is methyl benzotriazazole analog derivative.
Wherein, the present invention can be realized using the common organic silicon emulsion of the art in defoaming agent.
The present invention is used using the EO/PO block polyether of polyvalent alcohol and glycol collocation and high molecular weight, so that nanometer Boron nitride has better compatibility and dispersibility in whole system, can preferably play mutual effect.
The invention has the following beneficial effects:
The middle wire linear cutter liquid of the currently preferred optimized combination of each additive, acquisition has excellent synthesis Performance, inventive formulation system combines the process characteristic of middle wire wire cutting, and uses special surface activator composition To control the cleaning performance of working solution.The dielectricity and its stability that system is controlled and improved by preferred burster, reach Improve simultaneously continual and steady high machining accuracy and efficiency.By preferred pH adjusting agent, antirust agent, lubricant with establish it is suitable, Stable antirust and lubricating system, service performance can be reached while wire linear cutter technological lubrication requires in guarantee by reaching Excellent and stabilization has also taken into account working fluid environmental-protecting performance.The present invention is also logical to additives such as defoaming agent, copper inhibitor and moisturizer Be used in compounding, improve middle wire linear cutter efficiency, improve skin caused by the direct contact workpiece of worker adaptation Property.
Specific embodiment
Preparation method of the invention is conventional configuration and hybrid technology, is not elaborated herein.
Raw material used in embodiment 1 ~ 5 and comparative example 1 ~ 5 and dosage are as shown in table 1 and table 3:
Wherein, unless otherwise specified, the molecular weight of EO/PO block polyether is 2100 for the embodiment of the present invention and comparative example ~ 5000, the molecular weight of the EO/PO block polyether that wherein comparative example 3 uses is 1600.
The raw material of 1 embodiment of table and use scale
The service performance table of 2 embodiment 1-5 cutting liquid of table
The raw material of 3 comparative example of table and use scale
The service performance table of 4 comparative example 1-5 cutting liquid of table
Remarks: 1, the entire formula of embodiment and comparative example is 100%, and deionized water is surplus；
2, the processing conditions of embodiment and comparative example: cutting liquid uses concentration 10%, thickness of workpiece 100mm；
3, A is represented excellent, and B is represented generally, and C represents poor.
The service performance of the used middle wire wire cutting liquid in 5 market of table
It can be seen that from the embodiment, 4 comparative example of table and the performance detection of the common product of 5 existing market of table of above-mentioned table 2 Fully synthetic middle wire linear cutter liquid of the invention is used in compounding using polyvalent alcohol and glycol, so that the EO/ of high molecular weight PO block polyether and nm-class boron nitride have better compatibility and dispersibility in whole system.So that middle wire wire cutting adds Work liquid has excellent dielectric stability, cleaning, rust-preventing characteristic and skin conformability, and simultaneous processing is high-efficient and processes work Part surface quality is highly polished.It is good to illustrate that the fully synthetic middle wire linear cutter liquid of high-performance of the invention, environment-friendly type has Extreme pressure and antiwear behavior and excellent greasy property, can satisfy the lubricating requirement of middle wire wire cutting technology.The present invention The unique nano material of fully synthetic middle wire linear cutter liquid and the composite lubricated system of polyethers make it that there is preferably profit Sliding and environmental-protecting performance, improves the environmental-protecting performance of linear cutter liquid while improving workpieces processing comprehensive quality, reduces Common linear cutter liquid treatment cost of waste liquor and the injury to environment.
Embodiments of the present invention above described embodiment only expresses, the description thereof is more specific and detailed, but can not Therefore limitations on the scope of the patent of the present invention are interpreted as, as long as skill obtained in the form of equivalent substitutions or equivalent transformations Art scheme should all be fallen within the scope and spirit of the invention.

Claims (7)

1. a kind of fully synthetic linear cutter liquid of middle wire, it is characterised in that containing following weight percentage components: pH is adjusted Agent 10 ~ 20%, antirust agent 5 ~ 10%, lubricant 3 ~ 8%, burster 12 ~ 18%, moisturizer 4 ~ 6%, cleaning agent 6 ~ 10%, defoaming agent 0.1%, copper inhibitor 0.1%, and 100% is supplemented to deionized water；
The burster is the mixture of polyvalent alcohol and glycol；
The lubricant is the mixture of EO/PO block polyether and nm-class boron nitride；
The molecular weight of the EO/PO block polyether is 2100 ~ 5000.
2. a kind of middle fully synthetic linear cutter liquid of wire according to claim 1, which is characterized in that the polyvalent alcohol For at least one of polyethylene glycol, polypropylene glycol；Glycol is at least one of dipropylene glycol and diethylene glycol.
3. a kind of middle fully synthetic linear cutter liquid of wire according to claim 1, which is characterized in that the pH adjusting agent For at least one of triethanolamine, AMP-95 and N methyldiethanol amine.
4. a kind of middle fully synthetic linear cutter liquid of wire according to claim 1, which is characterized in that the antirust agent is At least one of borate and borate.
5. a kind of middle fully synthetic linear cutter liquid of wire according to claim 1, which is characterized in that the moisturizer is Glycerol.
6. a kind of middle fully synthetic linear cutter liquid of wire according to claim 1, which is characterized in that the cleaning agent is At least one of fatty alcohol polyoxyethylene ether, castor oil polyoxyethylene ether.
7. a kind of middle fully synthetic linear cutter liquid of wire according to claim 1, which is characterized in that the copper inhibitor For methyl benzotriazazole analog derivative.
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CN108277071A (en) * 2018-01-19 2018-07-13 长沙艾森设备维护技术有限公司 A kind of hard alloy wire cutting liquid and preparation method
CN109266430A (en) * 2018-10-31 2019-01-25 三达奥克化学股份有限公司 Silicon materials wire cutting liquid and preparation method thereof
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CN109705964A (en) * 2019-02-25 2019-05-03 无锡泽众高科科技有限公司 A kind of water-soluble graphene lubricant
CN110551559A (en) * 2019-08-20 2019-12-10 苏州仁光智能科技有限公司 medium-speed wire processing fluid and preparation method thereof
CN111154546B (en) * 2020-01-20 2022-08-26 惠州迪赛恩润滑科技有限公司 High-performance environment-friendly wire cutting fluid
CN114644956B (en) * 2022-04-29 2023-05-09 泰伦特生物工程股份有限公司 Dysprosium-iron alloy wire cutting fluid and preparation method and use method thereof

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CN103725387A (en) * 2012-10-11 2014-04-16 沈阳工业大学 Linear cutting fluid for neodymium-iron-boron permanent magnet material
CN104342277A (en) * 2014-09-28 2015-02-11 无锡阳工机械制造有限公司 Water-based working solution for wire electrical discharge machining and preparation method thereof
CN104403748A (en) * 2014-10-22 2015-03-11 安徽荣达阀门有限公司 High-dispersion and high-stability nano abrasive material emulsified cutting oil and preparation method thereof
CN105441181A (en) * 2015-12-25 2016-03-30 富耐克超硬材料股份有限公司 Metal cutting fluid and preparation method thereof

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CN101161797A (en) * 2007-09-28 2008-04-16 北京东兴润滑剂有限公司 Water-soluble discharging medium compound for electrospark wire-electrode cutting
CN102628000A (en) * 2012-03-22 2012-08-08 天津中澳星环保科技发展有限公司 Novel totally-synthetic processing fluid for wire-cutting metal by electric sparks
CN102660366A (en) * 2012-04-20 2012-09-12 广州机械科学研究院有限公司 Water-based synthetic cutting fluid lubricating agent, and preparation method and application thereof
CN103725387A (en) * 2012-10-11 2014-04-16 沈阳工业大学 Linear cutting fluid for neodymium-iron-boron permanent magnet material
CN104342277A (en) * 2014-09-28 2015-02-11 无锡阳工机械制造有限公司 Water-based working solution for wire electrical discharge machining and preparation method thereof
CN104403748A (en) * 2014-10-22 2015-03-11 安徽荣达阀门有限公司 High-dispersion and high-stability nano abrasive material emulsified cutting oil and preparation method thereof
CN105441181A (en) * 2015-12-25 2016-03-30 富耐克超硬材料股份有限公司 Metal cutting fluid and preparation method thereof

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