CN114525166A - Formula and preparation method of environment-friendly emulsion special for copper and copper alloy - Google Patents
Formula and preparation method of environment-friendly emulsion special for copper and copper alloy Download PDFInfo
- Publication number
- CN114525166A CN114525166A CN202111573155.0A CN202111573155A CN114525166A CN 114525166 A CN114525166 A CN 114525166A CN 202111573155 A CN202111573155 A CN 202111573155A CN 114525166 A CN114525166 A CN 114525166A
- Authority
- CN
- China
- Prior art keywords
- copper
- copper alloy
- environment
- formula
- special
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
- 229910000881 Cu alloy Inorganic materials 0.000 title claims abstract description 37
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 title claims abstract description 33
- 239000010949 copper Substances 0.000 title claims abstract description 33
- 229910052802 copper Inorganic materials 0.000 title claims abstract description 32
- 239000000839 emulsion Substances 0.000 title claims abstract description 24
- 238000002360 preparation method Methods 0.000 title claims abstract description 15
- 238000009472 formulation Methods 0.000 title description 2
- -1 alcohol amine Chemical class 0.000 claims abstract description 53
- 239000002199 base oil Substances 0.000 claims abstract description 24
- 235000014113 dietary fatty acids Nutrition 0.000 claims abstract description 24
- 239000000194 fatty acid Substances 0.000 claims abstract description 24
- 229930195729 fatty acid Natural products 0.000 claims abstract description 24
- 150000004665 fatty acids Chemical class 0.000 claims abstract description 24
- 230000007797 corrosion Effects 0.000 claims abstract description 21
- 238000005260 corrosion Methods 0.000 claims abstract description 21
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 claims abstract description 18
- 230000000844 anti-bacterial effect Effects 0.000 claims abstract description 18
- 239000002518 antifoaming agent Substances 0.000 claims abstract description 18
- 239000003899 bactericide agent Substances 0.000 claims abstract description 18
- 239000007822 coupling agent Substances 0.000 claims abstract description 18
- 239000003112 inhibitor Substances 0.000 claims abstract description 18
- 239000002736 nonionic surfactant Substances 0.000 claims abstract description 18
- 239000003208 petroleum Substances 0.000 claims abstract description 18
- 229910052708 sodium Inorganic materials 0.000 claims abstract description 18
- 239000011734 sodium Substances 0.000 claims abstract description 18
- 239000003795 chemical substances by application Substances 0.000 claims abstract description 16
- BDHFUVZGWQCTTF-UHFFFAOYSA-M sulfonate Chemical compound [O-]S(=O)=O BDHFUVZGWQCTTF-UHFFFAOYSA-M 0.000 claims abstract description 14
- 239000008233 hard water Substances 0.000 claims abstract description 12
- BTBUEUYNUDRHOZ-UHFFFAOYSA-N Borate Chemical compound [O-]B([O-])[O-] BTBUEUYNUDRHOZ-UHFFFAOYSA-N 0.000 claims abstract description 11
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 22
- 238000002156 mixing Methods 0.000 claims description 19
- RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 claims description 15
- 238000003756 stirring Methods 0.000 claims description 14
- 239000000203 mixture Substances 0.000 claims description 13
- 239000002994 raw material Substances 0.000 claims description 12
- 239000004327 boric acid Substances 0.000 claims description 10
- DNIAPMSPPWPWGF-UHFFFAOYSA-N Propylene glycol Chemical compound CC(O)CO DNIAPMSPPWPWGF-UHFFFAOYSA-N 0.000 claims description 9
- 238000010438 heat treatment Methods 0.000 claims description 7
- KFZMGEQAYNKOFK-UHFFFAOYSA-N Isopropanol Chemical compound CC(C)O KFZMGEQAYNKOFK-UHFFFAOYSA-N 0.000 claims description 6
- WQDUMFSSJAZKTM-UHFFFAOYSA-N Sodium methoxide Chemical compound [Na+].[O-]C WQDUMFSSJAZKTM-UHFFFAOYSA-N 0.000 claims description 6
- ZBCBWPMODOFKDW-UHFFFAOYSA-N diethanolamine Chemical compound OCCNCCO ZBCBWPMODOFKDW-UHFFFAOYSA-N 0.000 claims description 6
- 150000002191 fatty alcohols Chemical class 0.000 claims description 6
- 239000003921 oil Substances 0.000 claims description 6
- 229920002503 polyoxyethylene-polyoxypropylene Polymers 0.000 claims description 6
- 238000009924 canning Methods 0.000 claims description 4
- 238000001816 cooling Methods 0.000 claims description 4
- 238000005070 sampling Methods 0.000 claims description 4
- OYWRDHBGMCXGFY-UHFFFAOYSA-N 1,2,3-triazinane Chemical compound C1CNNNC1 OYWRDHBGMCXGFY-UHFFFAOYSA-N 0.000 claims description 3
- RWNUSVWFHDHRCJ-UHFFFAOYSA-N 1-butoxypropan-2-ol Chemical compound CCCCOCC(C)O RWNUSVWFHDHRCJ-UHFFFAOYSA-N 0.000 claims description 3
- GIAFURWZWWWBQT-UHFFFAOYSA-N 2-(2-aminoethoxy)ethanol Chemical compound NCCOCCO GIAFURWZWWWBQT-UHFFFAOYSA-N 0.000 claims description 3
- HZAXFHJVJLSVMW-UHFFFAOYSA-N 2-Aminoethan-1-ol Chemical compound NCCO HZAXFHJVJLSVMW-UHFFFAOYSA-N 0.000 claims description 3
- POAOYUHQDCAZBD-UHFFFAOYSA-N 2-butoxyethanol Chemical compound CCCCOCCO POAOYUHQDCAZBD-UHFFFAOYSA-N 0.000 claims description 3
- BMOKHTQIBPRXSL-UHFFFAOYSA-N 2h-benzotriazole;sodium Chemical compound [Na].C1=CC=CC2=NNN=C21 BMOKHTQIBPRXSL-UHFFFAOYSA-N 0.000 claims description 3
- 229940099451 3-iodo-2-propynylbutylcarbamate Drugs 0.000 claims description 3
- WYVVKGNFXHOCQV-UHFFFAOYSA-N 3-iodoprop-2-yn-1-yl butylcarbamate Chemical compound CCCCNC(=O)OCC#CI WYVVKGNFXHOCQV-UHFFFAOYSA-N 0.000 claims description 3
- CMGDVUCDZOBDNL-UHFFFAOYSA-N 4-methyl-2h-benzotriazole Chemical compound CC1=CC=CC2=NNN=C12 CMGDVUCDZOBDNL-UHFFFAOYSA-N 0.000 claims description 3
- QXWHDXHJLBWFPV-UHFFFAOYSA-N 4-methyl-2h-benzotriazole;sodium Chemical compound [Na].CC1=CC=CC2=C1N=NN2 QXWHDXHJLBWFPV-UHFFFAOYSA-N 0.000 claims description 3
- GSEJCLTVZPLZKY-UHFFFAOYSA-N Triethanolamine Chemical compound OCCN(CCO)CCO GSEJCLTVZPLZKY-UHFFFAOYSA-N 0.000 claims description 3
- QRUDEWIWKLJBPS-UHFFFAOYSA-N benzotriazole Chemical compound C1=CC=C2N[N][N]C2=C1 QRUDEWIWKLJBPS-UHFFFAOYSA-N 0.000 claims description 3
- 239000012964 benzotriazole Substances 0.000 claims description 3
- KGBXLFKZBHKPEV-UHFFFAOYSA-N boric acid Chemical compound OB(O)O KGBXLFKZBHKPEV-UHFFFAOYSA-N 0.000 claims description 3
- 238000006555 catalytic reaction Methods 0.000 claims description 3
- 238000006243 chemical reaction Methods 0.000 claims description 3
- 229940028356 diethylene glycol monobutyl ether Drugs 0.000 claims description 3
- 150000002148 esters Chemical class 0.000 claims description 3
- 235000019387 fatty acid methyl ester Nutrition 0.000 claims description 3
- MTNDZQHUAFNZQY-UHFFFAOYSA-N imidazoline Chemical compound C1CN=CN1 MTNDZQHUAFNZQY-UHFFFAOYSA-N 0.000 claims description 3
- MGIYRDNGCNKGJU-UHFFFAOYSA-N isothiazolinone Chemical compound O=C1C=CSN1 MGIYRDNGCNKGJU-UHFFFAOYSA-N 0.000 claims description 3
- 150000002780 morpholines Chemical class 0.000 claims description 3
- JCGNDDUYTRNOFT-UHFFFAOYSA-N oxolane-2,4-dione Chemical compound O=C1COC(=O)C1 JCGNDDUYTRNOFT-UHFFFAOYSA-N 0.000 claims description 3
- 239000012188 paraffin wax Substances 0.000 claims description 3
- 239000005077 polysulfide Substances 0.000 claims description 3
- 229920001021 polysulfide Polymers 0.000 claims description 3
- 150000008117 polysulfides Polymers 0.000 claims description 3
- 229920002545 silicone oil Polymers 0.000 claims description 3
- PUXBOBPVMMIFKS-UHFFFAOYSA-N sodium;thiadiazole Chemical compound [Na].C1=CSN=N1 PUXBOBPVMMIFKS-UHFFFAOYSA-N 0.000 claims description 3
- VLLMWSRANPNYQX-UHFFFAOYSA-N thiadiazole Chemical compound C1=CSN=N1.C1=CSN=N1 VLLMWSRANPNYQX-UHFFFAOYSA-N 0.000 claims description 3
- 239000013053 water resistant agent Substances 0.000 claims description 2
- 238000003754 machining Methods 0.000 abstract description 6
- 239000002173 cutting fluid Substances 0.000 abstract description 4
- 238000010002 mechanical finishing Methods 0.000 abstract 1
- 239000002184 metal Substances 0.000 description 8
- 229910052751 metal Inorganic materials 0.000 description 8
- 238000000034 method Methods 0.000 description 7
- 230000000052 comparative effect Effects 0.000 description 5
- 239000000463 material Substances 0.000 description 5
- 230000008569 process Effects 0.000 description 5
- 238000012545 processing Methods 0.000 description 5
- 239000000047 product Substances 0.000 description 5
- QKZIVVMOMKTVIK-UHFFFAOYSA-M anilinomethanesulfonate Chemical compound [O-]S(=O)(=O)CNC1=CC=CC=C1 QKZIVVMOMKTVIK-UHFFFAOYSA-M 0.000 description 4
- 238000004519 manufacturing process Methods 0.000 description 4
- 239000000956 alloy Substances 0.000 description 3
- 229920001296 polysiloxane Polymers 0.000 description 3
- 230000008859 change Effects 0.000 description 2
- 238000005034 decoration Methods 0.000 description 2
- 238000011161 development Methods 0.000 description 2
- 238000005516 engineering process Methods 0.000 description 2
- 230000001050 lubricating effect Effects 0.000 description 2
- 230000002265 prevention Effects 0.000 description 2
- OZWRZVFUZNYXMF-NHDPSOOVSA-N (5z)-10-methoxy-2,2,4-trimethyl-5-[[3-[(2,2,2-trifluoroethylamino)methyl]thiophen-2-yl]methylidene]-1h-chromeno[3,4-f]quinolin-9-ol Chemical compound C1=CC=2NC(C)(C)C=C(C)C=2C2=C1C=1C(OC)=C(O)C=CC=1O\C2=C/C=1SC=CC=1CNCC(F)(F)F OZWRZVFUZNYXMF-NHDPSOOVSA-N 0.000 description 1
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 1
- IOVCWXUNBOPUCH-UHFFFAOYSA-M Nitrite anion Chemical compound [O-]N=O IOVCWXUNBOPUCH-UHFFFAOYSA-M 0.000 description 1
- 238000005299 abrasion Methods 0.000 description 1
- 230000001580 bacterial effect Effects 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 238000003889 chemical engineering Methods 0.000 description 1
- 239000007795 chemical reaction product Substances 0.000 description 1
- 238000004140 cleaning Methods 0.000 description 1
- 238000004891 communication Methods 0.000 description 1
- 150000001875 compounds Chemical class 0.000 description 1
- 238000005536 corrosion prevention Methods 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 230000036541 health Effects 0.000 description 1
- 230000006872 improvement Effects 0.000 description 1
- 230000005764 inhibitory process Effects 0.000 description 1
- JEIPFZHSYJVQDO-UHFFFAOYSA-N iron(III) oxide Inorganic materials O=[Fe]O[Fe]=O JEIPFZHSYJVQDO-UHFFFAOYSA-N 0.000 description 1
- 238000011056 performance test Methods 0.000 description 1
- 150000002989 phenols Chemical class 0.000 description 1
- 238000002791 soaking Methods 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 230000003746 surface roughness Effects 0.000 description 1
- 231100000331 toxic Toxicity 0.000 description 1
- 230000002588 toxic effect Effects 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M173/00—Lubricating compositions containing more than 10% water
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M169/00—Lubricating compositions characterised by containing as components a mixture of at least two types of ingredient selected from base-materials, thickeners or additives, covered by the preceding groups, each of these compounds being essential
- C10M169/04—Mixtures of base-materials and additives
- C10M169/044—Mixtures of base-materials and additives the additives being a mixture of non-macromolecular and macromolecular compounds
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2203/00—Organic non-macromolecular hydrocarbon compounds and hydrocarbon fractions as ingredients in lubricant compositions
- C10M2203/003—Organic non-macromolecular hydrocarbon compounds and hydrocarbon fractions as ingredients in lubricant compositions used as base material
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2203/00—Organic non-macromolecular hydrocarbon compounds and hydrocarbon fractions as ingredients in lubricant compositions
- C10M2203/04—Well-defined cycloaliphatic compounds
- C10M2203/045—Well-defined cycloaliphatic compounds used as base material
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2203/00—Organic non-macromolecular hydrocarbon compounds and hydrocarbon fractions as ingredients in lubricant compositions
- C10M2203/10—Petroleum or coal fractions, e.g. tars, solvents, bitumen
- C10M2203/1006—Petroleum or coal fractions, e.g. tars, solvents, bitumen used as base material
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2205/00—Organic macromolecular hydrocarbon compounds or fractions, whether or not modified by oxidation as ingredients in lubricant compositions
- C10M2205/16—Paraffin waxes; Petrolatum, e.g. slack wax
- C10M2205/163—Paraffin waxes; Petrolatum, e.g. slack wax used as base material
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2207/00—Organic non-macromolecular hydrocarbon compounds containing hydrogen, carbon and oxygen as ingredients in lubricant compositions
- C10M2207/02—Hydroxy compounds
- C10M2207/021—Hydroxy compounds having hydroxy groups bound to acyclic or cycloaliphatic carbon atoms
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2207/00—Organic non-macromolecular hydrocarbon compounds containing hydrogen, carbon and oxygen as ingredients in lubricant compositions
- C10M2207/02—Hydroxy compounds
- C10M2207/021—Hydroxy compounds having hydroxy groups bound to acyclic or cycloaliphatic carbon atoms
- C10M2207/022—Hydroxy compounds having hydroxy groups bound to acyclic or cycloaliphatic carbon atoms containing at least two hydroxy groups
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2207/00—Organic non-macromolecular hydrocarbon compounds containing hydrogen, carbon and oxygen as ingredients in lubricant compositions
- C10M2207/04—Ethers; Acetals; Ortho-esters; Ortho-carbonates
- C10M2207/046—Hydroxy ethers
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2207/00—Organic non-macromolecular hydrocarbon compounds containing hydrogen, carbon and oxygen as ingredients in lubricant compositions
- C10M2207/10—Carboxylix acids; Neutral salts thereof
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2207/00—Organic non-macromolecular hydrocarbon compounds containing hydrogen, carbon and oxygen as ingredients in lubricant compositions
- C10M2207/10—Carboxylix acids; Neutral salts thereof
- C10M2207/12—Carboxylix acids; Neutral salts thereof having carboxyl groups bound to acyclic or cycloaliphatic carbon atoms
- C10M2207/121—Carboxylix acids; Neutral salts thereof having carboxyl groups bound to acyclic or cycloaliphatic carbon atoms having hydrocarbon chains of seven or less carbon atoms
- C10M2207/122—Carboxylix acids; Neutral salts thereof having carboxyl groups bound to acyclic or cycloaliphatic carbon atoms having hydrocarbon chains of seven or less carbon atoms monocarboxylic
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2209/00—Organic macromolecular compounds containing oxygen as ingredients in lubricant compositions
- C10M2209/10—Macromolecular compoundss obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
- C10M2209/103—Polyethers, i.e. containing di- or higher polyoxyalkylene groups
- C10M2209/104—Polyethers, i.e. containing di- or higher polyoxyalkylene groups of alkylene oxides containing two carbon atoms only
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2209/00—Organic macromolecular compounds containing oxygen as ingredients in lubricant compositions
- C10M2209/10—Macromolecular compoundss obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
- C10M2209/103—Polyethers, i.e. containing di- or higher polyoxyalkylene groups
- C10M2209/105—Polyethers, i.e. containing di- or higher polyoxyalkylene groups of alkylene oxides containing three carbon atoms only
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2209/00—Organic macromolecular compounds containing oxygen as ingredients in lubricant compositions
- C10M2209/10—Macromolecular compoundss obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
- C10M2209/103—Polyethers, i.e. containing di- or higher polyoxyalkylene groups
- C10M2209/108—Polyethers, i.e. containing di- or higher polyoxyalkylene groups etherified
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2209/00—Organic macromolecular compounds containing oxygen as ingredients in lubricant compositions
- C10M2209/10—Macromolecular compoundss obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
- C10M2209/103—Polyethers, i.e. containing di- or higher polyoxyalkylene groups
- C10M2209/109—Polyethers, i.e. containing di- or higher polyoxyalkylene groups esterified
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2215/00—Organic non-macromolecular compounds containing nitrogen as ingredients in lubricant compositions
- C10M2215/02—Amines, e.g. polyalkylene polyamines; Quaternary amines
- C10M2215/04—Amines, e.g. polyalkylene polyamines; Quaternary amines having amino groups bound to acyclic or cycloaliphatic carbon atoms
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2215/00—Organic non-macromolecular compounds containing nitrogen as ingredients in lubricant compositions
- C10M2215/02—Amines, e.g. polyalkylene polyamines; Quaternary amines
- C10M2215/04—Amines, e.g. polyalkylene polyamines; Quaternary amines having amino groups bound to acyclic or cycloaliphatic carbon atoms
- C10M2215/042—Amines, e.g. polyalkylene polyamines; Quaternary amines having amino groups bound to acyclic or cycloaliphatic carbon atoms containing hydroxy groups; Alkoxylated derivatives thereof
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2215/00—Organic non-macromolecular compounds containing nitrogen as ingredients in lubricant compositions
- C10M2215/08—Amides
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2215/00—Organic non-macromolecular compounds containing nitrogen as ingredients in lubricant compositions
- C10M2215/22—Heterocyclic nitrogen compounds
- C10M2215/221—Six-membered rings containing nitrogen and carbon only
- C10M2215/222—Triazines
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2215/00—Organic non-macromolecular compounds containing nitrogen as ingredients in lubricant compositions
- C10M2215/22—Heterocyclic nitrogen compounds
- C10M2215/223—Five-membered rings containing nitrogen and carbon only
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2215/00—Organic non-macromolecular compounds containing nitrogen as ingredients in lubricant compositions
- C10M2215/22—Heterocyclic nitrogen compounds
- C10M2215/223—Five-membered rings containing nitrogen and carbon only
- C10M2215/224—Imidazoles
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2215/00—Organic non-macromolecular compounds containing nitrogen as ingredients in lubricant compositions
- C10M2215/22—Heterocyclic nitrogen compounds
- C10M2215/225—Heterocyclic nitrogen compounds the rings containing both nitrogen and oxygen
- C10M2215/226—Morpholines
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2219/00—Organic non-macromolecular compounds containing sulfur, selenium or tellurium as ingredients in lubricant compositions
- C10M2219/04—Organic non-macromolecular compounds containing sulfur, selenium or tellurium as ingredients in lubricant compositions containing sulfur-to-oxygen bonds, i.e. sulfones, sulfoxides
- C10M2219/044—Sulfonic acids, Derivatives thereof, e.g. neutral salts
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2219/00—Organic non-macromolecular compounds containing sulfur, selenium or tellurium as ingredients in lubricant compositions
- C10M2219/10—Heterocyclic compounds containing sulfur, selenium or tellurium compounds in the ring
- C10M2219/104—Heterocyclic compounds containing sulfur, selenium or tellurium compounds in the ring containing sulfur and carbon with nitrogen or oxygen in the ring
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2219/00—Organic non-macromolecular compounds containing sulfur, selenium or tellurium as ingredients in lubricant compositions
- C10M2219/10—Heterocyclic compounds containing sulfur, selenium or tellurium compounds in the ring
- C10M2219/104—Heterocyclic compounds containing sulfur, selenium or tellurium compounds in the ring containing sulfur and carbon with nitrogen or oxygen in the ring
- C10M2219/106—Thiadiazoles
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2227/00—Organic non-macromolecular compounds containing atoms of elements not provided for in groups C10M2203/00, C10M2207/00, C10M2211/00, C10M2215/00, C10M2219/00 or C10M2223/00 as ingredients in lubricant compositions
- C10M2227/06—Organic compounds derived from inorganic acids or metal salts
- C10M2227/061—Esters derived from boron
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2229/00—Organic macromolecular compounds containing atoms of elements not provided for in groups C10M2205/00, C10M2209/00, C10M2213/00, C10M2217/00, C10M2221/00 or C10M2225/00 as ingredients in lubricant compositions
- C10M2229/04—Siloxanes with specific structure
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
- C10N2030/00—Specified physical or chemical properties which is improved by the additive characterising the lubricating composition, e.g. multifunctional additives
- C10N2030/06—Oiliness; Film-strength; Anti-wear; Resistance to extreme pressure
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
- C10N2030/00—Specified physical or chemical properties which is improved by the additive characterising the lubricating composition, e.g. multifunctional additives
- C10N2030/12—Inhibition of corrosion, e.g. anti-rust agents or anti-corrosives
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
- C10N2030/00—Specified physical or chemical properties which is improved by the additive characterising the lubricating composition, e.g. multifunctional additives
- C10N2030/16—Antiseptic; (micro) biocidal or bactericidal
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
- C10N2030/00—Specified physical or chemical properties which is improved by the additive characterising the lubricating composition, e.g. multifunctional additives
- C10N2030/64—Environmental friendly compositions
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
- C10N2030/00—Specified physical or chemical properties which is improved by the additive characterising the lubricating composition, e.g. multifunctional additives
- C10N2030/72—Extended drain
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
- C10N2040/00—Specified use or application for which the lubricating composition is intended
- C10N2040/20—Metal working
- C10N2040/22—Metal working with essential removal of material, e.g. cutting, grinding or drilling
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
- C10N2040/00—Specified use or application for which the lubricating composition is intended
- C10N2040/20—Metal working
- C10N2040/244—Metal working of specific metals
Landscapes
- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- General Chemical & Material Sciences (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Organic Chemistry (AREA)
- Preventing Corrosion Or Incrustation Of Metals (AREA)
Abstract
The invention relates to the technical field of preparation of cutting fluid for machining, in particular to a formula of an environment-friendly emulsion special for copper and copper alloy and a preparation method thereof. The emulsion is prepared from the following components in percentage by weight: 40-50% of base oil, 3-5% of borate, 5-10% of mixed alcohol amine, 8-15% of petroleum sodium sulfonate, 3-8% of SP-80, 3-8% of TW-80, 5-8% of fatty acid amide, 1-3% of anti-hard water agent, 1-3% of coupling agent and 4-8% of nonionic surfactant. 0.5-1% of copper alloy corrosion inhibitor, 1-2% of siloxane ketone compound bactericide and 0.2-0.5% of defoaming agent. The invention mainly solves the problems of the prior art that the quality of copper and copper alloy products fluctuates, the product precision is not high, the surface smoothness is low, the surface is easy to discolor, the performance consistency and the stability are poor, and the like in the mechanical finishing industry.
Description
Technical Field
The invention relates to the technical field of preparation of cutting fluid for machining, in particular to a formula of an environment-friendly emulsion special for copper and copper alloy and a preparation method thereof.
Background
With the improvement of the material culture life of people and the coming of the information age, copper and copper alloy become important basic materials which are indispensable in human life. Copper and copper alloy have a series of excellent performances such as electric conductivity, heat conductivity, corrosion resistance, wear resistance, bacterial inhibition, platability, decoration, easy processing and the like. And the method is widely applied to factories in the fields of electric power, electronics, communication, transportation, architectural decoration, chemical engineering, machinery, ocean engineering, aerospace and the like, and plays a great role in human life and national economy. The development of the process technology and equipment for processing copper and copper alloy materials is increasingly rapid, a plurality of new materials are developed, new process technologies are continuously broken through, and the copper and copper alloy materials are widely applied to actual production. And with the trend of thin-wall and large-batch products, the requirements on the precision, the straightness, the surface roughness, the glossiness and the color change prevention of the strip materials for lead frames, terminals and connectors are higher and higher, but the production capacity of a large number of copper and copper alloy materials in China is excessive, the production capacity of high-end products is insufficient, the quality level of copper products is unbalanced, the product quality is fluctuated, the product precision is not high, the surface smoothness is low, the performance consistency and the stability are poor, and a series of problems are always to be solved urgently.
The metal cutting fluid is one of indispensable production factors in most machining industries as an important matching material for machining, and is also an important factor influencing product quality, so that how to prepare the environment-friendly special emulsion for copper and copper alloy, which is environment-friendly, nuisanceless to human bodies, and has good lubricity, cleaning property, rust prevention, corrosion prevention and cooling property, is of great importance to the development of the machining industries.
Disclosure of Invention
In order to solve the technical problems, the technical scheme adopted by the invention is as follows:
an environment-friendly emulsion formula special for copper and copper alloy comprises the following raw materials in parts by weight: 40-50% of base oil, 3-5% of boric acid ester, 5-10% of mixed alcohol amine, 8-15% of petroleum sodium sulfonate, 3-8% of SP-80, 3-8% of TW-80, 5-8% of fatty acid amide, 1-3% of water-resistant agent, 1-3% of coupling agent, 4-8% of nonionic surfactant, 0.5-1% of copper alloy corrosion inhibitor, 1-2% of siloxane ketone compound bactericide, 0.2-0.5% of defoaming agent and the balance of water.
The preparation method of the borate comprises the following steps: adding boric acid, diethanolamine and water into a blending kettle according to the mass ratio of 1:2:1, stirring and heating to 80 ℃, stirring for 1 hour, and cooling to normal temperature.
The preparation method of the fatty acid amide comprises the following steps: adding fatty acid methyl ester and mixed alcohol amine into a reaction kettle according to the molar ratio of 1:1.5, controlling the temperature at 100-120 ℃ and the vacuum degree at 0.03-0.05MPa, reacting for 24 hours under the catalysis of sodium methoxide, distilling and concentrating to obtain the fatty acid amide.
The base oil comprises any one or a mixture of two of naphthenic base oil, paraffin base oil, 10# white oil and 15# white oil; the mixed alcohol amine comprises one or more of monoethanolamine, diethanolamine, triethanolamine, diglycolamine and special alcohol amine; the molecular weight of the petroleum sodium sulfonate is 460.
The coupling agent comprises one or a mixture of more of isopropanol, propylene glycol, ethylene glycol monobutyl ether, diethylene glycol monobutyl ether, propylene glycol monobutyl ether or isomeric fatty alcohols.
The nonionic surfactant comprises one or more of fatty acid polyoxyethylene polyoxypropylene ester, fatty alcohol polyoxyethylene polyoxypropylene ether or ether carboxylic acid.
The hard water resisting agent comprises any one or a mixture of more of ether carboxylic acid, alcohol ether carboxylic acid and EDTA-2 NA.
The copper alloy corrosion inhibitor comprises any one or a mixture of more of benzotriazole, imidazoline, thiadiazole polysulfide, methylbenzotriazole, benzotriazole sodium salt, methylbenzotriazole sodium salt and thiadiazole sodium salt.
The bactericide is any one or a mixture of more of hexahydrotriazine, morpholine derivatives, iodopropynyl butyl carbamate, 3-methylene bis and isothiazolinone; the defoaming agent is emulsified silicone oil.
A preparation method of environment-friendly emulsion special for copper and copper alloy comprises the following steps:
s1: adding 40-50% of base oil, 3-5% of boric acid ester, 5-10% of mixed alcohol amine, 8-15% of petroleum sodium sulfonate, 3-8% of SP-80, 3-8% of TW-80, 5-8% of fatty acid amide, 1-3% of anti-hard water agent, 1-3% of coupling agent and 4-8% of nonionic surfactant into a blending kettle in sequence according to the weight percentage, then heating to 40 ℃, and stirring for 1 hour;
s2: adding 0.5-1% of copper alloy corrosion inhibitor, 1-2% of siloxane ketone compound bactericide, 0.2-0.5% of defoaming agent and the balance of water into a blending kettle in batches according to the weight percentage, and then stirring for 2 hours;
s3: closing the blending kettle and standing for 1 hour;
s4: opening the bin gate of the blending kettle, sampling and detecting, and canning after detecting without errors.
Compared with the prior art, the invention has the following beneficial effects:
the cutting fluid prepared by the method can effectively improve the processing efficiency, the processing precision and the surface smoothness in the processing process, can reduce the abrasion of a cutter and prevent the color change of the placed surface of a workpiece, and has excellent lubricating property, corrosion resistance and outstanding hard water resistance. The service life is long, and toxic and harmful substances such as nitrite and phenols are not contained, so that the pollution to the environment is avoided, and the health of workers is protected.
Detailed Description
The technical solutions in the embodiments of the present invention will be clearly and completely described below, and it is obvious that the described embodiments are only a part of the embodiments of the present invention, and not all embodiments. All other embodiments, which can be derived by a person skilled in the art from the embodiments given herein without making any creative effort, shall fall within the protection scope of the present invention.
Example one
An environment-friendly emulsion formula special for copper and copper alloy comprises the following raw materials in parts by weight: 40% of base oil, 3% of boric acid ester, 5% of mixed alcohol amine, 8% of petroleum sodium sulfonate, 3% of SP-80, 5% of TW-80, 5% of fatty acid amide, 1% of hard water resisting agent, 1% of coupling agent, 5% of nonionic surfactant, 0.5% of copper alloy corrosion inhibitor, 1% of siloxane ketone compound bactericide, 0.2% of defoaming agent and the balance of water.
The preparation method of the borate comprises the following steps: adding boric acid, diethanolamine and water into a blending kettle according to the mass ratio of 1:2:1, stirring and heating to 80 ℃, stirring for 1 hour, and cooling to normal temperature.
The preparation method of the fatty acid amide comprises the following steps: adding fatty acid methyl ester and mixed alcohol amine into a reaction kettle according to the molar ratio of 1:1.5, controlling the temperature at 100-120 ℃ and the vacuum degree at 0.03-0.05MPa, reacting for 24 hours under the catalysis of sodium methoxide, distilling and concentrating to obtain the fatty acid amide.
The base oil comprises any one or a mixture of two of naphthenic base oil, paraffin base oil, 10# white oil and 15# white oil; the mixed alcohol amine comprises one or more of monoethanolamine, diethanolamine, triethanolamine, diglycolamine and special alcohol amine; the petroleum sodium sulfonate has a molecular weight of 460.
The coupling agent comprises one or more of isopropanol, propylene glycol, ethylene glycol monobutyl ether, diethylene glycol monobutyl ether, propylene glycol monobutyl ether or isomeric fatty alcohol.
The nonionic surfactant comprises one or more of fatty acid polyoxyethylene polyoxypropylene ester, fatty alcohol polyoxyethylene polyoxypropylene ether or ether carboxylic acid.
The hard water resisting agent comprises one or more of ether carboxylic acid, alcohol ether carboxylic acid and EDTA-2 NA.
The copper alloy corrosion inhibitor comprises any one or a mixture of more of benzotriazole, imidazoline, thiadiazole polysulfide, methylbenzotriazole, benzotriazole sodium salt, methylbenzotriazole sodium salt and thiadiazole sodium salt.
The bactericide is any one or a mixture of more of hexahydrotriazine, morpholine derivatives, iodopropynyl butyl carbamate, 3-methylene bis and isothiazolinone; the defoaming agent is emulsified silicone oil.
A preparation method of environment-friendly emulsion special for copper and copper alloy comprises the following steps:
s1: adding 40% of base oil, 3% of boric acid ester, 5% of mixed alcohol amine, 8% of petroleum sodium sulfonate, 3% of SP-80, 5% of TW-80, 5% of fatty acid amide, 1% of hard water resisting agent, 1% of coupling agent and 5% of nonionic surfactant into a blending kettle in sequence according to weight percentage, then heating to 40 ℃, and stirring for 1 hour;
s2: adding 0.5 percent of copper alloy corrosion inhibitor, 1 percent of siloxane ketone compound bactericide, 0.2 percent of defoaming agent and the balance of water into a mixing kettle in batches according to the weight percentage, and then stirring for 2 hours;
s3: closing the blending kettle and standing for 1 hour;
s4: opening the bin gate of the blending kettle, sampling and detecting, and canning after detecting without errors.
Example two
Different from the embodiment 1, the weight ratio of the raw materials is as follows: 40% of base oil, 3% of borate, 5% of mixed alcohol amine, 10% of petroleum sodium sulfonate, 3% of SP-80, 5% of TW-80, 5% of fatty acid amide, 1% of anti-hard water agent, 5% of nonionic surfactant, 1% of coupling agent, 0.5% of copper metal corrosion inhibitor, 1% of siloxane ketone compound, 0.3% of defoaming agent, 0.2% of bactericide and the balance of water.
EXAMPLE III
Different from the embodiment 1, the weight ratio of the raw materials is as follows: 42% of base oil, 5% of borate, 8% of mixed alcohol amine, 12% of petroleum sodium sulfonate, 3% of SP-80, 5% of TW-80, 8% of fatty acid amide, 1% of anti-hardening water agent, 5% of nonionic surfactant, 1% of coupling agent, 0.6% of copper metal corrosion inhibitor, 1% of silicone ketone compound, 0.2% of defoaming agent, 0.2% of bactericide and the balance of water.
Example four
Different from the embodiment 1, the weight ratio of the raw materials is as follows: 45% of base oil, 3% of borate, 8% of mixed alcohol amine, 12% of sodium petroleum sulfonate, 5% of SP-80, 5% of TW-80, 7% of fatty acid amide, 2% of hard water resisting agent, 6% of nonionic surfactant, 1% of coupling agent, 0.7% of copper metal corrosion inhibitor, 1% of silicone ketone compound, 0.3% of defoaming agent, 0.2% of bactericide and the balance of water.
EXAMPLE five
Different from the embodiment 1, the weight ratio of the raw materials is as follows: 47% of base oil, 5% of borate, 6% of mixed alcohol amine, 13% of petroleum sodium sulfonate, 5% of SP-80, 3% of TW-80, 8% of fatty acid amide, 2% of anti-hardening water agent, 8% of nonionic surfactant, 3% of coupling agent, 0.8% of copper metal corrosion inhibitor, 1% of silicone compound, 0.3% of defoaming agent, 0.2% of bactericide and the balance of water.
EXAMPLE six
Different from the embodiment 1, the weight ratio of the raw materials is as follows: 50% of base oil, 5% of borate, 10% of mixed alcohol amine, 15% of petroleum sodium sulfonate, 5% of SP-80, 5% of TW-80, 10% of fatty acid amide, 3% of anti-hardening water agent, 8% of nonionic surfactant, 3% of coupling agent, 1% of copper metal corrosion inhibitor, 1% of siloxane ketone compound, 0.2% of defoaming agent, 0.2% of bactericide and the balance of water.
The following are comparative examples of the above examples:
comparative example 1
Different from the embodiment 1, the weight ratio of the raw materials is as follows: 30% of base oil, 5% of borate, 10% of mixed alcohol amine, 15% of petroleum sodium sulfonate, 5% of SP-80, 5% of TW-80, 2% of fatty acid amide, 3% of anti-hardening water agent, 3% of nonionic surfactant, 3% of coupling agent, 1% of copper metal corrosion inhibitor, 1% of siloxane ketone compound, 0.2% of defoaming agent, 0.2% of bactericide and the balance of water.
Comparative example 2
Different from the embodiment 1, the weight ratio of the raw materials is as follows: 35% of base oil, 5% of borate, 10% of mixed alcohol amine, 5% of petroleum sodium sulfonate, 5% of SP-80, 5% of TW-80, 2% of fatty acid amide, 3% of anti-hardening water agent, 3% of nonionic surfactant, 3% of coupling agent, 1% of copper metal corrosion inhibitor, 1% of siloxane ketone compound, 0.2% of defoaming agent, 0.2% of bactericide and the balance of water.
Watch 1
The first table is a performance test table of different examples and comparative examples, wherein the larger the PB value and the number of machining workpieces per cutter is, the better the lubricating effect of the emulsion is, the more stable the quality is and the higher the precision is; the smaller the surface finish of the workpiece, the better the finish of the workpiece is represented; the longer the time for changing color in the soaking and placing process is, the better the effect of the emulsion of the invention on improving the corrosion resistance of the workpiece is. As can be seen from the table I, the emulsion prepared by the raw material weight in the example has greatly improved various properties compared with the emulsion prepared by the raw material weight in the comparative example.
The working process of the invention is as follows: s1: sequentially adding base oil, boric acid ester, mixed alcohol amine, petroleum sodium sulfonate, SP-80, TW-80, fatty acid amide, hard water resisting agent, coupling agent and nonionic surfactant into a blending kettle according to the weight percentage, then heating to 40 ℃, and stirring for 1 hour; s2: adding a copper alloy corrosion inhibitor, a siloxane ketone compound bactericide, a defoaming agent and water into a mixing kettle in batches according to the weight percentage, and then stirring for 2 hours; s3: closing the blending kettle and standing for 1 hour; s4: opening the bin gate of the blending kettle, sampling and detecting, and canning after detecting without errors.
Although only the preferred embodiments of the present invention have been described in detail, the present invention is not limited to the above embodiments, and various changes can be made without departing from the spirit of the present invention within the knowledge of those skilled in the art, and the scope of the present invention is intended to be covered by the various changes.
Claims (10)
1. The formula of the environment-friendly special emulsion for copper and copper alloy is characterized by comprising the following raw materials in parts by weight: 40-50% of base oil, 3-5% of boric acid ester, 5-10% of mixed alcohol amine, 8-15% of petroleum sodium sulfonate, 3-8% of SP-80, 3-8% of TW-80, 5-8% of fatty acid amide, 1-3% of water-resistant agent, 1-3% of coupling agent, 4-8% of nonionic surfactant, 0.5-1% of copper alloy corrosion inhibitor, 1-2% of siloxane ketone compound bactericide, 0.2-0.5% of defoaming agent and the balance of water.
2. The formula of the environment-friendly emulsion special for copper and copper alloy as claimed in claim 1, wherein: the preparation method of the borate comprises the following steps: adding boric acid, diethanolamine and water into a blending kettle according to the mass ratio of 1:2:1, stirring and heating to 80 ℃, stirring for 1 hour, and cooling to normal temperature.
3. The formula of the environment-friendly emulsion special for copper and copper alloy as claimed in claim 1, wherein: the preparation method of the fatty acid amide comprises the following steps: adding fatty acid methyl ester and mixed alcohol amine into a reaction kettle according to the molar ratio of 1:1.5, controlling the temperature at 100-120 ℃ and the vacuum degree at 0.03-0.05MPa, reacting for 24 hours under the catalysis of sodium methoxide, distilling and concentrating to obtain the fatty acid amide.
4. The formula of the environment-friendly emulsion special for copper and copper alloy as claimed in claim 1, wherein: the base oil comprises any one or a mixture of two of naphthenic base oil, paraffin base oil, 10# white oil and 15# white oil; the mixed alcohol amine comprises one or more of monoethanolamine, diethanolamine, triethanolamine, diglycolamine and special alcohol amine; the molecular weight of the petroleum sodium sulfonate is 460.
5. The formula of the special emulsion for environment-friendly copper and copper alloy as claimed in claim 1, wherein the formula comprises: the coupling agent comprises one or a mixture of more of isopropanol, propylene glycol, ethylene glycol monobutyl ether, diethylene glycol monobutyl ether, propylene glycol monobutyl ether or isomeric fatty alcohols.
6. The formula of the environment-friendly emulsion special for copper and copper alloy as claimed in claim 1, wherein: the nonionic surfactant comprises one or more of fatty acid polyoxyethylene polyoxypropylene ester, fatty alcohol polyoxyethylene polyoxypropylene ether or ether carboxylic acid.
7. The formula of the environment-friendly emulsion special for copper and copper alloy as claimed in claim 1, wherein: the hard water resisting agent comprises any one or a mixture of more of ether carboxylic acid, alcohol ether carboxylic acid and EDTA-2 NA.
8. The formula of the environment-friendly emulsion special for copper and copper alloy as claimed in claim 1, wherein: the copper alloy corrosion inhibitor comprises any one or a mixture of more of benzotriazole, imidazoline, thiadiazole polysulfide, methylbenzotriazole, benzotriazole sodium salt, methylbenzotriazole sodium salt and thiadiazole sodium salt.
9. The formula of the environment-friendly emulsion special for copper and copper alloy as claimed in claim 1, wherein: the bactericide is any one or a mixture of more of hexahydrotriazine, morpholine derivatives, iodopropynyl butyl carbamate, 3-methylene bis and isothiazolinone; the defoaming agent is emulsified silicone oil.
10. The preparation method of the environment-friendly emulsion special for copper and copper alloy is characterized by comprising the following steps of:
s1: adding 40-50% of base oil, 3-5% of boric acid ester, 5-10% of mixed alcohol amine, 8-15% of petroleum sodium sulfonate, 3-8% of SP-80, 3-8% of TW-80, 5-8% of fatty acid amide, 1-3% of anti-hard water agent, 1-3% of coupling agent and 4-8% of nonionic surfactant into a blending kettle in sequence according to the weight percentage, then heating to 40 ℃, and stirring for 1 hour;
s2: adding 0.5-1% of copper alloy corrosion inhibitor, 1-2% of siloxane ketone compound bactericide, 0.2-0.5% of defoaming agent and the balance of water into a blending kettle in batches according to the weight percentage, and then stirring for 2 hours;
s3: closing the blending kettle and standing for 1 hour;
s4: opening the bin gate of the blending kettle, sampling and detecting, and canning after detecting without errors.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN202111573155.0A CN114525166A (en) | 2021-12-21 | 2021-12-21 | Formula and preparation method of environment-friendly emulsion special for copper and copper alloy |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN202111573155.0A CN114525166A (en) | 2021-12-21 | 2021-12-21 | Formula and preparation method of environment-friendly emulsion special for copper and copper alloy |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN114525166A true CN114525166A (en) | 2022-05-24 |
Family
ID=81619804
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN202111573155.0A Pending CN114525166A (en) | 2021-12-21 | 2021-12-21 | Formula and preparation method of environment-friendly emulsion special for copper and copper alloy |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN114525166A (en) |
Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US20060142167A1 (en) * | 2000-02-08 | 2006-06-29 | Francis Prince | Water-soluble copper, copper alloys and non-ferrous metals intermediate cold and hot rolling composition |
| CN102618374A (en) * | 2012-03-07 | 2012-08-01 | 东莞市安美润滑科技有限公司 | Water-based cutting fluid used in slice machining of hard brittle crystal material and preparation method of water-based cutting fluid |
| CN105154187A (en) * | 2015-09-18 | 2015-12-16 | 南京科润工业介质股份有限公司 | Emulsified liquid capable of replacing oil products and preparation method of emulsified liquid |
| CN105670738A (en) * | 2016-03-11 | 2016-06-15 | 东莞市纳晟润滑油科技有限公司 | Rust-proof emulsified type metal cutting fluid |
| CN113621432A (en) * | 2021-08-28 | 2021-11-09 | 西安思凯石化科技有限公司 | Special cutting fluid for water-based environment-friendly titanium alloy saw and preparation method thereof |
-
2021
- 2021-12-21 CN CN202111573155.0A patent/CN114525166A/en active Pending
Patent Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US20060142167A1 (en) * | 2000-02-08 | 2006-06-29 | Francis Prince | Water-soluble copper, copper alloys and non-ferrous metals intermediate cold and hot rolling composition |
| CN102618374A (en) * | 2012-03-07 | 2012-08-01 | 东莞市安美润滑科技有限公司 | Water-based cutting fluid used in slice machining of hard brittle crystal material and preparation method of water-based cutting fluid |
| CN105154187A (en) * | 2015-09-18 | 2015-12-16 | 南京科润工业介质股份有限公司 | Emulsified liquid capable of replacing oil products and preparation method of emulsified liquid |
| CN105670738A (en) * | 2016-03-11 | 2016-06-15 | 东莞市纳晟润滑油科技有限公司 | Rust-proof emulsified type metal cutting fluid |
| CN113621432A (en) * | 2021-08-28 | 2021-11-09 | 西安思凯石化科技有限公司 | Special cutting fluid for water-based environment-friendly titanium alloy saw and preparation method thereof |
Non-Patent Citations (1)
| Title |
|---|
| 汪多仁: "《催化剂化学品生产新技术》", 31 May 2001, 科学技术文献出版社 * |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN111004676B (en) | Emulsified cutting fluid and preparation method thereof | |
| CN106479654A (en) | Aqueous cutting fluid | |
| CN111961522A (en) | Universal micro-emulsion cutting fluid for aluminum material processing, and preparation method and application thereof | |
| CN104263476A (en) | Biodegradable micro-lubricating oil and preparation method thereof | |
| CN106590906A (en) | Graphene oxide-containing water-based metal cutting fluid and preparation method thereof | |
| CN102559355A (en) | Self-bacteriostasis general emulsion cutting fluid and preparing method thereof | |
| CN111378520B (en) | MoS-containing 2 Water-soluble trace lubricating fluid | |
| CN103351927A (en) | Multifunctional fully-synthetic cutting fluid and preparation method thereof | |
| CN102703190A (en) | Semisynthetic metal cutting fluid with pentaerythritol oleate serving as base oil and preparation method thereof | |
| CN103242933A (en) | Synthesized metal cutting fluid taking poly-alpha olefin as base oil and preparation method thereof | |
| CN107746741A (en) | A kind of water-soluble synthesis ester type metal working fluid and preparation method thereof | |
| CN102839043A (en) | Cutting fluid complexing agent and preparation method thereof | |
| CN106675736A (en) | Multifunctional cutting solution composition | |
| CN114525166A (en) | Formula and preparation method of environment-friendly emulsion special for copper and copper alloy | |
| CN114381319B (en) | Emulsified oil for copper and copper alloy wire drawing and preparation method thereof | |
| CN113563958A (en) | Cutting cooling liquid applied to 7-series aviation aluminum material processing, preparation method and use method thereof | |
| KR20170005742A (en) | Boron-free corrosion inhibitors for metalworking fluids | |
| CN113621432A (en) | Special cutting fluid for water-based environment-friendly titanium alloy saw and preparation method thereof | |
| CN108441310B (en) | Semisynthesis cutting fluid for metal processing and preparation method thereof | |
| CN108485788A (en) | A kind of long-life type water-glycol fire-retardand hydraulic fluid | |
| CN107418693B (en) | Aluminum alloy cutting fluid and preparation method thereof | |
| CN112522016B (en) | Copper wire drawing agent and preparation method and application thereof | |
| CN110804484B (en) | Environment-friendly carborundum wire cutting liquid | |
| CN111040827B (en) | Organic carboxylic acid compound, preparation method and steel plate water-based processing fluid | |
| CN111019745B (en) | MoS-containing 2 Water insoluble trace amount of lubricating fluid |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| PB01 | Publication | ||
| PB01 | Publication | ||
| SE01 | Entry into force of request for substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| RJ01 | Rejection of invention patent application after publication | ||
| RJ01 | Rejection of invention patent application after publication |
Application publication date: 20220524 |