CN106590906A - Graphene oxide-containing water-based metal cutting fluid and preparation method thereof - Google Patents

Graphene oxide-containing water-based metal cutting fluid and preparation method thereof Download PDF

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Publication number
CN106590906A
CN106590906A CN201611114697.0A CN201611114697A CN106590906A CN 106590906 A CN106590906 A CN 106590906A CN 201611114697 A CN201611114697 A CN 201611114697A CN 106590906 A CN106590906 A CN 106590906A
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graphene oxide
cutting fluid
fluid containing
aqueous cutting
water
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Inventor
韩生
陈海军
马文飞
韦焕明
蔺华林
钱伟
付宁
刘玉萍
兰国贤
刘金宝
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Shanghai Institute of Technology
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Shanghai Institute of Technology
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    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M173/00—Lubricating compositions containing more than 10% water
    • C10M173/02—Lubricating compositions containing more than 10% water not containing mineral or fatty oils
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M125/00—Lubricating compositions characterised by the additive being an inorganic material
    • C10M125/02—Carbon; Graphite
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2201/00—Inorganic compounds or elements as ingredients in lubricant compositions
    • C10M2201/04—Elements
    • C10M2201/041—Carbon; Graphite; Carbon black
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2201/00—Inorganic compounds or elements as ingredients in lubricant compositions
    • C10M2201/087—Boron oxides, acids or salts
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2201/00—Inorganic compounds or elements as ingredients in lubricant compositions
    • C10M2201/14—Inorganic compounds or elements as ingredients in lubricant compositions inorganic compounds surface treated with organic compounds
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2207/00—Organic non-macromolecular hydrocarbon compounds containing hydrogen, carbon and oxygen as ingredients in lubricant compositions
    • C10M2207/02—Hydroxy compounds
    • C10M2207/021—Hydroxy compounds having hydroxy groups bound to acyclic or cycloaliphatic carbon atoms
    • C10M2207/022—Hydroxy compounds having hydroxy groups bound to acyclic or cycloaliphatic carbon atoms containing at least two hydroxy groups
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2215/00—Organic non-macromolecular compounds containing nitrogen as ingredients in lubricant compositions
    • C10M2215/02—Amines, e.g. polyalkylene polyamines; Quaternary amines
    • C10M2215/04—Amines, e.g. polyalkylene polyamines; Quaternary amines having amino groups bound to acyclic or cycloaliphatic carbon atoms
    • C10M2215/042—Amines, e.g. polyalkylene polyamines; Quaternary amines having amino groups bound to acyclic or cycloaliphatic carbon atoms containing hydroxy groups; Alkoxylated derivatives thereof
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2215/00—Organic non-macromolecular compounds containing nitrogen as ingredients in lubricant compositions
    • C10M2215/22—Heterocyclic nitrogen compounds
    • C10M2215/223—Five-membered rings containing nitrogen and carbon only
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2215/00—Organic non-macromolecular compounds containing nitrogen as ingredients in lubricant compositions
    • C10M2215/22—Heterocyclic nitrogen compounds
    • C10M2215/225—Heterocyclic nitrogen compounds the rings containing both nitrogen and oxygen
    • C10M2215/226—Morpholines
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2217/00—Organic macromolecular compounds containing nitrogen as ingredients in lubricant compositions
    • C10M2217/04—Macromolecular compounds from nitrogen-containing monomers obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
    • C10M2217/041—Macromolecular compounds from nitrogen-containing monomers obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds involving a condensation reaction
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2229/00—Organic macromolecular compounds containing atoms of elements not provided for in groups C10M2205/00, C10M2209/00, C10M2213/00, C10M2217/00, C10M2221/00 or C10M2225/00 as ingredients in lubricant compositions
    • C10M2229/04—Siloxanes with specific structure
    • C10M2229/041—Siloxanes with specific structure containing aliphatic substituents
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
    • C10N2030/00—Specified physical or chemical properties which is improved by the additive characterising the lubricating composition, e.g. multifunctional additives
    • C10N2030/06—Oiliness; Film-strength; Anti-wear; Resistance to extreme pressure
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
    • C10N2030/00—Specified physical or chemical properties which is improved by the additive characterising the lubricating composition, e.g. multifunctional additives
    • C10N2030/64—Environmental friendly compositions
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
    • C10N2040/00—Specified use or application for which the lubricating composition is intended
    • C10N2040/20—Metal working
    • C10N2040/22—Metal working with essential removal of material, e.g. cutting, grinding or drilling
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
    • C10N2040/00—Specified use or application for which the lubricating composition is intended
    • C10N2040/20—Metal working
    • C10N2040/244—Metal working of specific metals
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
    • C10N2040/00—Specified use or application for which the lubricating composition is intended
    • C10N2040/20—Metal working
    • C10N2040/244—Metal working of specific metals
    • C10N2040/246—Iron or steel

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  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • General Chemical & Material Sciences (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Organic Chemistry (AREA)
  • Inorganic Chemistry (AREA)
  • Lubricants (AREA)

Abstract

The invention discloses graphene oxide-containing water-based metal cutting fluid and a preparation method thereof. The graphene oxide containing water-based metal cutting fluid consists of a lubricating additive, an anti-rusting agent, a defoaming agent, benzotriazole, triethanolamine oleate, ethanol amine and water. The contents of the raw materials are as follows in percentage by weight: 0.5-5% of the lubricating additive, 30-40% of the anti-rusting agent, 0.4-0.6% of the defoaming agent, 0.2-0.4% of the benzotriazole, 2-4.5% of a detergent, 1-2% of ethanol amine and the balance water, wherein the lubricating additive is a graphene oxide dispersion liquid. The graphene oxide-containing water-based metal cutting fluid has the beneficial effects that due to addition of a graphene oxide additive, not only are properties of the cutting fluid improved, such as the lubrication property, the anti-wearing property and the cooling property, but also graphene oxide has slight environment influence and is beneficial to environmental protection.

Description

A kind of aqueous cutting fluid containing graphene oxide and preparation method thereof
Technical field
The present invention relates to metal working technical area, more particularly, to a kind of aqueous cutting fluid containing graphene oxide And preparation method thereof.
Background technology
Cutting fluid is a kind of to be used to lubricating and cooling down the mixed of machining tool and processing component in metal cutting process Close lubricant.Can be divided into oil type and aqua type by the difference of medium, wherein, oil type cutting fluid is due to its good lubrication Property and rust-preventing characteristic, are widely used in metal processing sectors, but its biological degradability too it is poor can long-term existence in environment, so as to Very serious impact is caused to biological and ecology；Aqua type cutting fluid has good cooling performance and cleaning performance, and cost It is low, it is pollution-free, meet sustainable development requirement, traditional oil type cutting fluid is progressively being replaced now.But aqua type is cut Cutting liquid also has many defects, and such as bearing capacity is low, lubricity is poor, and this can cause seriously to rub very much and examine abrasion.In reality Using in, generally require extraly to add lubricant.At present, the cutting fluid additive for being used is most of containing units such as P, Cl, S Element, the additive containing these elements can be produced a very large impact to environment.With scientific and technological progress, the increasing of mankind's environmental consciousness By force, the environmental resource problem that cutting fluid is brought is increasingly subject to the concern of people, and these additives will certainly will be limited progressively simultaneously Eliminate.In addition, the emergence manufactured with Modern Manufacturing Technology, processing technology, Material Processing and precision equipment, also right Metal working fluid proposes requirements at the higher level.Therefore, new lubricating additive and Development of Novel water-base cutting fluid formula tool is developed There are important practical significance and using value.
Graphene oxide possesses the similar structure of Graphene, and some properties are identical, but its surface has substantial amounts of oxygen-containing group Group, therefore, the dissolving in water or polar solvent is preferable.Based on this, tribology of the graphene oxide as water lubrication additive Performance study finds that the graphene oxide of layer structure has substantially speeded up the friction behavior of ceramic antithesis from running-in period (serious machine Tool weares and teares) to the transformation of stable state (gentle tribochemical wear), make friction run 2 000s contractings when being lubricated by pure water with the cycle It is as short as 250s.In addition, graphene oxide also reduced significantly the coefficient of friction of ceramic antithesis.In order to improve graphite oxide in cutting Stability in liquid, needs suitably to be modified its surface so as to the stable dispersion in decentralized medium.
The content of the invention
In order to overcome the deficiencies in the prior art, it is an object of the invention to provide a kind of water-base metal containing graphene oxide Cutting fluid and preparation method thereof.The present invention aqueous cutting fluid have lubricity it is good, it is environmentally friendly the features such as.
Technical scheme is specifically described as follows.
The present invention provides a kind of aqueous cutting fluid containing graphene oxide, count by weight percentage, by with the following group It is grouped into：
Balance of water, its gross weight meets 100%；
Wherein：
The oiliness additive is graphene oxide dispersion, and in percentage by weight, its raw material is constituted and content It is as follows：
Graphene oxide：0.1～0.4%,
Polyvinylpyrrolidone：2～4%
Balance of water；Its gross weight meets 100%.
In the present invention, it is 2 that antirust agent is the mass ratio of the mixture of morpholine and boric acid, morpholine and boric acid:1～4:1.
In the present invention, defoamer is the mixture of ethylene glycol and methyl-silicone oil.
In the present invention, cleaning agent is triethanolamine oleate.
The present invention also provides a kind of preparation method of the aqueous cutting fluid containing graphene oxide, comprises the following steps that：
(1) antirust agent, cleaning agent, BTA, defoamer, monoethanolamine and water are mixed to get into mixed liquor；
(2) graphene oxide dispersion for preparing is added drop-wise in the mixed liquor obtained by step (1), ultrasonic agitation, i.e., The aqueous cutting fluid of graphene oxide must be contained.
Compared to the prior art, the beneficial effects of the present invention is：
The present invention is a kind of aqueous cutting fluid containing graphene oxide, by adding graphene oxide lubrication addition Agent so that the metalworking fluid lubricity, wear resistence have obtained very big lifting.
Further, the present invention is a kind of aqueous cutting fluid containing graphene oxide, because employing lubricating additive for Inorganic nano material, belongs to the category of environment-friendly materials.In use, it is less on ecological environment and healthy impact, Belong to environment-friendly type water base cutting fluid.
Further, a kind of aqueous cutting fluid containing graphene oxide according to the present invention, due to the load of this cutting fluid Body is water, without base oil, therefore, it can reduce the discharge capacity of oily sludge thing, reduces production cost and energy consumption.
Specific embodiment
The present invention is described in further detail with reference to specific embodiment, but the present invention is not limited only to example below.
Embodiment 1
A kind of aqueous cutting fluid containing graphene oxide, its count by weight percentage, its raw material composition and content It is as follows：
Lubricating additive：1%；
Antirust agent：35%；
Defoamer：0.6%；
BTA：0.4%；
Cleaning agent：3%；
Monoethanolamine：1.5%；
Balance of water；
Described oiliness additive is graphene oxide dispersion, and in percentage by weight, its raw material is constituted and contained Amount is as follows：
Graphene oxide：0.2%；
Polyvinylpyrrolidone：3%；
Balance of deionized water；
The compound method of described lubricating additive, i.e. graphene oxide dispersion, specific operating procedure is as follows：
A certain amount of graphene oxide for preparing is placed in deionized water, then ultrasonic disperse, obtains graphite oxide Alkene suspension, the polyvinylpyrrolidonesolution solution for preparing then is added drop-wise in suspension and quickly stir, afterwards will mixing Liquid continues ultrasonically treated, that is, obtain lubricating additive graphene oxide dispersion.
The concrete preparation method of the described aqueous cutting fluid containing graphene oxide, wherein antirust agent is as follows：Will Quinoline presses 3 with boric acid：1 mass ratio mixing, then continuously stir at normal temperatures until solution is changed into clarifying color.Obtain final product above-mentioned antirust Agent；
The defoamer is mixed by ethylene glycol with methyl-silicone oil；The cleaning agent is triethanolamine oleate, and it passes through It is prepared by following methods：Oleic acid is mixed with triethanolamine by certain mass ratio and at normal temperatures reaction 1h is obtained；
According to the preparation method of the aqueous cutting fluid containing graphene oxide of the present invention, it includes following step Suddenly：
(1) at normal temperatures and pressures, antirust agent, cleaning agent and deionized water are uniformly mixed and obtain mixed liquor；
(2) at normal temperatures and pressures, BTA and defoamer are added in the mixed liquor obtained by step (1), and is stirred Uniformly；
(3) at normal temperatures and pressures, monoethanolamine is added in the mixed liquor obtained by step (2), continue to stir until It is transparent；
(4) the advance graphene oxide dispersion prepared is added drop-wise in the mixed liquor obtained by step (3), and ultrasound 30min, obtains final product the aqueous cutting fluid containing graphene oxide.
Embodiment 2
A kind of aqueous cutting fluid containing graphene oxide, its count by weight percentage, its raw material composition and content It is as follows：
Lubricating additive：3%；
Antirust agent：40%；
Defoamer：0.5%；
BTA：0.3%；
Cleaning agent：4%；
Monoethanolamine：2%；
Balance of water；
Described oiliness additive is graphene oxide dispersion, and in percentage by weight, its raw material is constituted and contained Amount is as follows：Graphene oxide, 0.1%；Polyvinylpyrrolidone, 2%；Balance of deionized water.
The compound method of described lubricating additive graphene oxide dispersion, its specific operating procedure is with embodiment 1.
The concrete preparation method of above-mentioned metalworking fluid containing graphene oxide, wherein antirust agent is with embodiment 1.
The concrete preparation method of above-mentioned defoamer is with embodiment 1.
Above-mentioned cleaning agent preparation method is with embodiment 1.
According to the preparation method of the aqueous cutting fluid containing graphene oxide of the present invention, its preparation process is with real Apply example 1.
Embodiment 3
A kind of aqueous cutting fluid containing graphene oxide, its count by weight percentage, its raw material composition and content It is as follows：
Lubricating additive：4.5%；
Antirust agent：30%；
Defoamer：0.4%；
BTA：0.2%；
Cleaning agent：2%；
Monoethanolamine：1%；
Balance of water；
Described oiliness additive is graphene oxide dispersion, and in percentage by weight, its raw material is constituted and contained Amount is as follows：Graphene oxide, 0.4%；Polyvinylpyrrolidone, 4%；Balance of deionized water.
The compound method of described lubricating additive graphene oxide dispersion, its specific operating procedure is with embodiment 1.
The concrete preparation method of the above-mentioned aqueous cutting fluid containing graphene oxide, wherein antirust agent is with embodiment 1.
The concrete preparation method of above-mentioned defoamer is with embodiment 1.
Above-mentioned cleaning agent preparation method is with embodiment 1.
According to the preparation method of the aqueous cutting fluid containing graphene oxide of the present invention, its preparation process is with real Apply example 1.
Performance test is tested
The test data of cutting fluid containing graphene oxide of above-described embodiment 1-3 is as shown in table 1.
Table 1
In sum, the invention discloses a kind of metalworking fluid of graphene-containing, its lubricity, wear resistence are fabulous, and And with carrier as water, it is without hazardous substances such as base oil, nitrous acid therefore little to environment and harm, belong to environment-friendly type and cut Cut liquid.The above is only the basic explanation under present inventive concept, and according to technical scheme made it is any equivalent Conversion, belongs to protection scope of the present invention.

Claims (5)

1. a kind of aqueous cutting fluid containing graphene oxide, it is characterised in that count by weight percentage, by following components Composition：
Wherein：
The oiliness additive is graphene oxide dispersion, and in percentage by weight, its raw material composition and content are as follows：
Graphene oxide：0.1～0.4%,
Polyvinylpyrrolidone：2～4%
Balance of water；Its gross weight meets 100%.
2. the aqueous cutting fluid containing graphene oxide according to claim 1, it is characterised in that antirust agent is morpholine It is 2 with the mass ratio of the mixture of boric acid, morpholine and boric acid:1～4:1.
3. the aqueous cutting fluid containing graphene oxide according to claim 1, it is characterised in that defoamer is second two The mixture of alcohol and methyl-silicone oil.
4. the aqueous cutting fluid containing graphene oxide according to claim 1, it is characterised in that cleaning agent is oleic acid Triethanolamine.
5. a kind of preparation method of the aqueous cutting fluid containing graphene oxide according to claim 1, its feature exists In comprising the following steps that：
(1) antirust agent, cleaning agent, BTA, defoamer, monoethanolamine and water are mixed to get into mixed liquor；
(2) graphene oxide dispersion for preparing is added drop-wise in the mixed liquor obtained by step (1), ultrasonic agitation is obtained final product and contained The aqueous cutting fluid of graphene oxide.
CN201611114697.0A 2016-12-07 2016-12-07 Graphene oxide-containing water-based metal cutting fluid and preparation method thereof Pending CN106590906A (en)

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Cited By (9)

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CN107312609A (en) * 2017-06-27 2017-11-03 济南天健碳纳米材料有限公司 A kind of graphene synthetic cutting fluid and preparation method thereof
CN107603724A (en) * 2017-09-22 2018-01-19 广西大学 A kind of graphene synergy need not discharge environment-friendly type water-base cutting fluid and preparation method thereof
CN107880973A (en) * 2017-10-30 2018-04-06 湖南金泰检测检验有限公司 A kind of graphene oxide enhancing lubricant and preparation method thereof
CN108277075A (en) * 2018-03-12 2018-07-13 北京科技大学 A kind of lubricant for titanium or titanium alloy board rolling
CN108485783A (en) * 2018-04-26 2018-09-04 清华大学 Water-based lubricating liquid
CN108865388A (en) * 2018-07-24 2018-11-23 上海应用技术大学 A kind of synthesis type cutting fluid of the molybdenum sulfide containing nano particle and preparation method thereof
CN112111321A (en) * 2020-05-29 2020-12-22 上海工程技术大学 Functionalized graphene lubricant for metal plastic processing and preparation method thereof
CN113736551A (en) * 2021-09-08 2021-12-03 长沙艾森设备维护技术有限公司 Metal extrusion tapping liquid
CN115386415A (en) * 2021-05-25 2022-11-25 常州海纳环保科技有限公司 Formula for improving dispersion stability of graphene in superfinishing liquid and preparation method

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Cited By (10)

* Cited by examiner, † Cited by third party
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CN107312609A (en) * 2017-06-27 2017-11-03 济南天健碳纳米材料有限公司 A kind of graphene synthetic cutting fluid and preparation method thereof
CN107603724A (en) * 2017-09-22 2018-01-19 广西大学 A kind of graphene synergy need not discharge environment-friendly type water-base cutting fluid and preparation method thereof
CN107880973A (en) * 2017-10-30 2018-04-06 湖南金泰检测检验有限公司 A kind of graphene oxide enhancing lubricant and preparation method thereof
CN108277075A (en) * 2018-03-12 2018-07-13 北京科技大学 A kind of lubricant for titanium or titanium alloy board rolling
CN108277075B (en) * 2018-03-12 2019-10-22 北京科技大学 A kind of lubricant for titanium or titanium alloy board rolling
CN108485783A (en) * 2018-04-26 2018-09-04 清华大学 Water-based lubricating liquid
CN108865388A (en) * 2018-07-24 2018-11-23 上海应用技术大学 A kind of synthesis type cutting fluid of the molybdenum sulfide containing nano particle and preparation method thereof
CN112111321A (en) * 2020-05-29 2020-12-22 上海工程技术大学 Functionalized graphene lubricant for metal plastic processing and preparation method thereof
CN115386415A (en) * 2021-05-25 2022-11-25 常州海纳环保科技有限公司 Formula for improving dispersion stability of graphene in superfinishing liquid and preparation method
CN113736551A (en) * 2021-09-08 2021-12-03 长沙艾森设备维护技术有限公司 Metal extrusion tapping liquid

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Application publication date: 20170426