CN107474907A - A kind of metalworking fluid - Google Patents

A kind of metalworking fluid Download PDF

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Publication number
CN107474907A
CN107474907A CN201710937708.3A CN201710937708A CN107474907A CN 107474907 A CN107474907 A CN 107474907A CN 201710937708 A CN201710937708 A CN 201710937708A CN 107474907 A CN107474907 A CN 107474907A
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Prior art keywords
parts
acid
derivative
weight
metalworking fluid
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CN201710937708.3A
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Inventor
杨鸿飞
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Dongguan New Mstar Technology Ltd
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Dongguan New Mstar Technology Ltd
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Priority to CN201710937708.3A priority Critical patent/CN107474907A/en
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    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M167/00—Lubricating compositions characterised by the additive being a mixture of a macromolecular compound, a non-macromolecular compound and a compound of unknown or incompletely defined constitution, each of these compounds being essential
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2201/00—Inorganic compounds or elements as ingredients in lubricant compositions
    • C10M2201/087—Boron oxides, acids or salts
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2201/00—Inorganic compounds or elements as ingredients in lubricant compositions
    • C10M2201/10—Compounds containing silicon
    • C10M2201/102—Silicates
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2207/00—Organic non-macromolecular hydrocarbon compounds containing hydrogen, carbon and oxygen as ingredients in lubricant compositions
    • C10M2207/04—Ethers; Acetals; Ortho-esters; Ortho-carbonates
    • C10M2207/046—Hydroxy ethers
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2207/00—Organic non-macromolecular hydrocarbon compounds containing hydrogen, carbon and oxygen as ingredients in lubricant compositions
    • C10M2207/10—Carboxylix acids; Neutral salts thereof
    • C10M2207/18—Tall oil acids
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2207/00—Organic non-macromolecular hydrocarbon compounds containing hydrogen, carbon and oxygen as ingredients in lubricant compositions
    • C10M2207/28—Esters
    • C10M2207/281—Esters of (cyclo)aliphatic monocarboxylic acids
    • C—CHEMISTRY; METALLURGY
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    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2209/00—Organic macromolecular compounds containing oxygen as ingredients in lubricant compositions
    • C10M2209/10—Macromolecular compoundss obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
    • C10M2209/103—Polyethers, i.e. containing di- or higher polyoxyalkylene groups
    • C—CHEMISTRY; METALLURGY
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    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2209/00—Organic macromolecular compounds containing oxygen as ingredients in lubricant compositions
    • C10M2209/10—Macromolecular compoundss obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
    • C10M2209/103—Polyethers, i.e. containing di- or higher polyoxyalkylene groups
    • C10M2209/104—Polyethers, i.e. containing di- or higher polyoxyalkylene groups of alkylene oxides containing two carbon atoms only
    • C—CHEMISTRY; METALLURGY
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    • C10M2209/00—Organic macromolecular compounds containing oxygen as ingredients in lubricant compositions
    • C10M2209/10—Macromolecular compoundss obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
    • C10M2209/103—Polyethers, i.e. containing di- or higher polyoxyalkylene groups
    • C10M2209/105—Polyethers, i.e. containing di- or higher polyoxyalkylene groups of alkylene oxides containing three carbon atoms only
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2215/00—Organic non-macromolecular compounds containing nitrogen as ingredients in lubricant compositions
    • C10M2215/02—Amines, e.g. polyalkylene polyamines; Quaternary amines
    • C10M2215/04—Amines, e.g. polyalkylene polyamines; Quaternary amines having amino groups bound to acyclic or cycloaliphatic carbon atoms
    • C10M2215/042—Amines, e.g. polyalkylene polyamines; Quaternary amines having amino groups bound to acyclic or cycloaliphatic carbon atoms containing hydroxy groups; Alkoxylated derivatives thereof
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2215/00—Organic non-macromolecular compounds containing nitrogen as ingredients in lubricant compositions
    • C10M2215/08—Amides
    • C10M2215/082—Amides containing hydroxyl groups; Alkoxylated derivatives
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2215/00—Organic non-macromolecular compounds containing nitrogen as ingredients in lubricant compositions
    • C10M2215/22—Heterocyclic nitrogen compounds
    • C10M2215/221—Six-membered rings containing nitrogen and carbon only
    • C10M2215/222—Triazines
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2215/00—Organic non-macromolecular compounds containing nitrogen as ingredients in lubricant compositions
    • C10M2215/22—Heterocyclic nitrogen compounds
    • C10M2215/223—Five-membered rings containing nitrogen and carbon only
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2215/00—Organic non-macromolecular compounds containing nitrogen as ingredients in lubricant compositions
    • C10M2215/22—Heterocyclic nitrogen compounds
    • C10M2215/225—Heterocyclic nitrogen compounds the rings containing both nitrogen and oxygen
    • C10M2215/226—Morpholines
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2227/00—Organic non-macromolecular compounds containing atoms of elements not provided for in groups C10M2203/00, C10M2207/00, C10M2211/00, C10M2215/00, C10M2219/00 or C10M2223/00 as ingredients in lubricant compositions
    • C10M2227/06—Organic compounds derived from inorganic acids or metal salts
    • C10M2227/061—Esters derived from boron
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
    • C10N2030/00—Specified physical or chemical properties which is improved by the additive characterising the lubricating composition, e.g. multifunctional additives
    • C10N2030/06—Oiliness; Film-strength; Anti-wear; Resistance to extreme pressure
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
    • C10N2030/00—Specified physical or chemical properties which is improved by the additive characterising the lubricating composition, e.g. multifunctional additives
    • C10N2030/12—Inhibition of corrosion, e.g. anti-rust agents or anti-corrosives
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
    • C10N2030/00—Specified physical or chemical properties which is improved by the additive characterising the lubricating composition, e.g. multifunctional additives
    • C10N2030/16—Antiseptic; (micro) biocidal or bactericidal
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
    • C10N2030/00—Specified physical or chemical properties which is improved by the additive characterising the lubricating composition, e.g. multifunctional additives
    • C10N2030/40—Low content or no content compositions
    • C10N2030/41—Chlorine free or low chlorine content compositions
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
    • C10N2030/00—Specified physical or chemical properties which is improved by the additive characterising the lubricating composition, e.g. multifunctional additives
    • C10N2030/40—Low content or no content compositions
    • C10N2030/42—Phosphor free or low phosphor content compositions
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
    • C10N2040/00—Specified use or application for which the lubricating composition is intended
    • C10N2040/20—Metal working
    • C10N2040/22—Metal working with essential removal of material, e.g. cutting, grinding or drilling
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
    • C10N2040/00—Specified use or application for which the lubricating composition is intended
    • C10N2040/20—Metal working
    • C10N2040/244—Metal working of specific metals
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
    • C10N2040/00—Specified use or application for which the lubricating composition is intended
    • C10N2040/20—Metal working
    • C10N2040/244—Metal working of specific metals
    • C10N2040/245—Soft metals, e.g. aluminum
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
    • C10N2040/00—Specified use or application for which the lubricating composition is intended
    • C10N2040/20—Metal working
    • C10N2040/244—Metal working of specific metals
    • C10N2040/247—Stainless steel

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  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • General Chemical & Material Sciences (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Organic Chemistry (AREA)
  • Lubricants (AREA)

Abstract

The present invention provides a kind of metalworking fluid, its formula includes boric acid, triethanolamine, polyethers, ready denier oil acid, tall oil diethanol amine, the alcoxylates of C16/18 alcohol, diglycolamine, dicarboxylic acids, tricarboxylic acid, boric acid diethanol amine ester, benzotriazole derivative, derivative of fatty acid, morpholine derivative, pyrrolotriazine derivatives, benzotriazole derivative used in this metal working fluid, derivative of fatty acid, morpholine derivative, pyrrolotriazine derivatives have excellent anti-extreme pressure energy, non-ferrous metal is not corroded, the additive also has good greasy property simultaneously.

Description

A kind of metalworking fluid
Technical field
The invention belongs to metal working technical area, more particularly to a kind of metalworking fluid of multi-functional oiliness.
Background technology
The metal application of alloy type is the most universal, and such as aluminium alloy, stainless steel, copper alloy material are widely used in flat board The electronic product industry such as computer, mobile phone, clock and watch.In this field, many metallic elements are all direct using CNC precision machine tools Machining is molded, and carries out such as sandblasting, polishing, oxidation, plated film, plating surface treatment afterwards.It can be used in machining To cutting fluid, cutting fluid mainly plays lubrication and cooling effect.Conventional cutting fluid has oiliness and water-based two major class, water-based cutting at present Although liquid good cooling results, non-combustible, exist easily raw bacterium is smelly, corrode lathe, cause worker is allergic, need periodically more Change, the problems such as waste liquid is difficult to processing, and oiliness cutting fluid is except high lubricating effect, also have not raw bacterium it is smelly, without changing, It need to periodically add, not corrode the advantages that lathe.
It can be used for the metal working fluid of ferrous metal and non-ferrous metal disclosure sets forth a kind of, while be also applied for height The metal working fluid of hardness alloy material.
The content of the invention
The present invention is intended to provide a kind of metalworking fluid, can be used for cutting for the metals such as stainless steel, aluminium alloy, copper alloy Cut, and the metal working fluid has odorlessness, endangers composition without chlorine, inactive sulphur, non-stimulated etc., simultaneously for processing black gold Category and non-ferrous metal can play a very good protection, with strong applicability..
In order to realize above-mentioned task, a kind of concrete technical scheme of metalworking fluid of the present invention is as follows.
A kind of metalworking fluid, its formula include boric acid, triethanolamine, polyethers, ready denier oil acid, tall oil diethanol Amine, the alcoxylates of C16/18 alcohol, diglycolamine, dicarboxylic acids, tricarboxylic acid, boric acid diethanol amine ester, benzotriazole derive Thing, derivative of fatty acid, morpholine derivative, pyrrolotriazine derivatives, parts by weight are respectively：
Boric acid 25-35 parts；
Polyethers 20-30 parts；
Ready denier oil acid 10-15 parts；
Tall oil diethanol amine 15-30 parts；
Alcoxylates 10-20 parts of C16/18 alcohol；
Diglycolamine 10-20 parts；
Carboxylic acid 25-35 parts；
Boric acid diethanol amine ester 20-30 parts；
Benzotriazole derivative 25-35 parts；
Derivative of fatty acid 20-30 parts；
Morpholine derivative 25-35 parts；
Pyrrolotriazine derivatives 20-30 parts.
The defoamer of formula also mould inhibitor IPBC and the 1-3 parts by weight including 3-8 parts by weight.
Carboxylic acid in formula includes dicarboxylic acids and tricarboxylic acid, ratio of weight and number 1：3.
Formula also includes the isopropyl fatty acid ester of 5-10 parts by weight.
The isopropyl fatty acid ester is prepared by following technique：Aliphatic acid and isopropanol are well mixed, in 420- 550r/min rotating speeds stir 28-35min, then add Fe2 (SO4) 3 9H2O and are well mixed for catalyst, are warming up to 70-78 DEG C, 30-35min is incubated, is stirred at reflux, is cooled to room temperature, with 70-90 DEG C of distillation water washing to pH to 7, vacuum dehydration after distillation Obtain isopropyl fatty acid ester.
Formula also includes the auxiliary agent compound of 15-30 parts by weight.
The auxiliary agent compound is alumino-silicate and polyoxyethylene poly-oxygen propylene aether block copolymer in tetrabutyl titanate It is made during catalytic transesterification, its specific preparation method is：Xiang Shuizhong adds aluminosilicate powder and tetrabutyl titanate, fully It is sent into after scattered in ball mill, is milled to fineness less than 5 μm, and utilize microwave treater microwave reflow treatment 5min, is added Polyoxyethylene poly-oxygen propylene aether block copolymer, be well mixed after continue microwave reflow treatment 2min, stand 10min after it is micro- again Ripple reflow treatment 5min, gained mixed liquor are sent into spray dryer, dry gained particle and micro mist is made through micronizer, i.e., Obtain auxiliary agent compound.
Described metalworking fluid, its preparation method are：A, auxiliary agent compound is prepared；B, isopropyl fatty acid ester is prepared；c、 By boric acid, triethanolamine, polyethers, ready denier oil acid, tall oil diethanol amine, the alcoxylates of C16/18 alcohol, diethylene glycol (DEG) Amine, carboxylic acid, boric acid diethanol amine ester, benzotriazole derivative, derivative of fatty acid, morpholine derivative, pyrrolotriazine derivatives, aliphatic acid Isopropyl ester and auxiliary agent compound carry out well mixed obtained metalworking fluid.
Advantage of the invention is that：
1. benzotriazole derivative, derivative of fatty acid, morpholine derivative, pyrrolotriazine derivatives have used in a metal working fluid Excellent anti-extreme pressure energy, non-ferrous metal is not corroded, the additive also has good greasy property simultaneously.
2. carboxylic acid used in a metal working fluid includes dicarboxylic acids and tricarboxylic acid, ratio of weight and number 1：3, can be with Benzotriazole derivative, derivative of fatty acid, morpholine derivative, pyrrolotriazine derivatives play synergy.
3. isopropyl fatty acid ester made from special preparation method used in a metal working fluid, high lubricating effect, and And add mould inhibitor IPBC bactericidal effect.
4. a metal working fluid can be used for the high-speed cutting of the metals such as stainless steel, aluminium alloy, copper alloy, it is about in rotating speed In 15000 ~ 20000 high-speed cutting, the effect of protection cutting tool is can reach, while the product cut has good table Face.
5. a metal working fluid can through being recycled for multiple times and the stable performance of system, extreme boundary lubrication performance will not under Drop.
6. material, the sewage caused by later stage cleaning product such as the not chloride, phosphorus of metal working fluid of the present invention are easy to handle.
7. the non-stimulated harm of personnel of the metal working fluid to operation of the present invention.
Embodiment
The present invention is illustrated below by exemplary embodiment.It should be appreciated that the scope of the present invention should not be limited to The scope of embodiment, any change or change without departing from present subject matter can be understood by the person skilled in the art.This The protection domain of invention is determined by scope of the following claims.
First, embodiment
Embodiment 1
A kind of metalworking fluid, components by weight percent are respectively：
The parts by weight of boric acid 30；
The parts by weight of polyethers 28；
The parts by weight of ready denier oil acid 12；
The parts by weight of tall oil diethanol amine 16；
The parts by weight of alcoxylates 17 of C16/18 alcohol；
The parts by weight of diglycolamine 19；
The parts by weight of carboxylic acid 29；
The parts by weight of boric acid diethanol amine ester 28；
The parts by weight of benzotriazole derivative 32；
The parts by weight of derivative of fatty acid 25；
The parts by weight of morpholine derivative 28；
The parts by weight of pyrrolotriazine derivatives 21.
Mould inhibitor IPBC 3-8 parts by weight；
Defoamer 1-3 parts by weight.
The preparation method of metalworking fluid is：A, auxiliary agent compound is prepared：Xiang Shuizhong adds aluminosilicate powder and metatitanic acid N-butyl, it is sent into after fully dispersed in ball mill, is milled to fineness less than 5 μm, and utilize microwave treater microwave reflow treatment 5min, polyoxyethylene poly-oxygen propylene aether block copolymer is added, continue microwave reflow treatment 2min after being well mixed, stand Microwave reflow treatment 5min, gained mixed liquor are sent into spray dryer again after 10min, dry gained particle through ultramicro grinding Micro mist is made in machine, produces auxiliary agent compound；B, isopropyl fatty acid ester is prepared：By aliphatic acid and isopropanol 8-20 in parts by weight：1 It is well mixed, 28-35min is stirred in 420-550r/min rotating speeds, then adds aliphatic acid and the 0.5-2% of isopropanol gross weight Fe2(SO4)3・9H2O is well mixed for catalyst, is warming up to 70-78 DEG C, is incubated 30-35min, is stirred at reflux, is cooled to room temperature, With 70-90 DEG C of distillation water washing to pH to 7 after distillation, vacuum dehydration obtains isopropyl fatty acid ester；C, by boric acid, triethanolamine, Polyethers, ready denier oil acid, tall oil diethanol amine, the alcoxylates of C16/18 alcohol, diglycolamine, carboxylic acid, boric acid diethyl Alkanolamine ester, benzotriazole derivative, derivative of fatty acid, morpholine derivative, pyrrolotriazine derivatives, isopropyl fatty acid ester and auxiliary agent are compound Thing is well mixed, and the metalworking fluid of embodiment 1 is made.
Embodiment 2
A kind of metalworking fluid, components by weight percent are respectively：
The parts by weight of boric acid 29；
The parts by weight of polyethers 26；
The parts by weight of ready denier oil acid 12；
The parts by weight of tall oil diethanol amine 17；
The parts by weight of alcoxylates 16 of C16/18 alcohol；
The parts by weight of diglycolamine 18；
The parts by weight of carboxylic acid 25；
The parts by weight of boric acid diethanol amine ester 29；
The parts by weight of benzotriazole derivative 30；
The parts by weight of derivative of fatty acid 28；
The parts by weight of morpholine derivative 26；
The parts by weight of pyrrolotriazine derivatives 23.
The parts by weight of mould inhibitor IPBC 6；
The parts by weight of defoamer 1.
The preparation method of metalworking fluid is：A, auxiliary agent compound is prepared：Xiang Shuizhong adds aluminosilicate powder and metatitanic acid N-butyl, it is sent into after fully dispersed in ball mill, is milled to fineness less than 5 μm, and utilize microwave treater microwave reflow treatment 5min, polyoxyethylene poly-oxygen propylene aether block copolymer is added, continue microwave reflow treatment 2min after being well mixed, stand Microwave reflow treatment 5min, gained mixed liquor are sent into spray dryer again after 10min, dry gained particle through ultramicro grinding Micro mist is made in machine, produces auxiliary agent compound；B, isopropyl fatty acid ester is prepared：It is 15 by aliphatic acid and isopropanol ratio of weight and number：1 It is well mixed, 28-35min is stirred in 420-550r/min rotating speeds, then adds aliphatic acid and the 0.5-2% of isopropanol gross weight Fe2(SO4)3・9H2O is well mixed for catalyst, is warming up to 70-78 DEG C, is incubated 30-35min, is stirred at reflux, is cooled to room temperature, With 70-90 DEG C of distillation water washing to pH to 7 after distillation, vacuum dehydration obtains isopropyl fatty acid ester；C, by boric acid, triethanolamine, Polyethers, ready denier oil acid, tall oil diethanol amine, the alcoxylates of C16/18 alcohol, diglycolamine, carboxylic acid, boric acid diethyl Alkanolamine ester, benzotriazole derivative, derivative of fatty acid, morpholine derivative, pyrrolotriazine derivatives, isopropyl fatty acid ester and auxiliary agent are compound Thing carries out the metalworking fluid of well mixed obtained embodiment 2.
Embodiment 3
A kind of metalworking fluid, components by weight percent are respectively：
The parts by weight of boric acid 28；
The parts by weight of polyethers 23；
The parts by weight of ready denier oil acid 12；
The parts by weight of tall oil diethanol amine 19；
The parts by weight of alcoxylates 15 of C16/18 alcohol；
The parts by weight of diglycolamine 14；
The parts by weight of carboxylic acid 28；
The parts by weight of boric acid diethanol amine ester 27；
The parts by weight of benzotriazole derivative 26；
The parts by weight of derivative of fatty acid 25；
The parts by weight of morpholine derivative 28；
The parts by weight of pyrrolotriazine derivatives 21.
The parts by weight of mould inhibitor IPBC 5；
The parts by weight of defoamer 3.
The preparation method of metalworking fluid is：A, auxiliary agent compound is prepared：Xiang Shuizhong adds aluminosilicate powder and metatitanic acid N-butyl, it is sent into after fully dispersed in ball mill, is milled to fineness less than 5 μm, and utilize microwave treater microwave reflow treatment 5min, polyoxyethylene poly-oxygen propylene aether block copolymer is added, continue microwave reflow treatment 2min after being well mixed, stand Microwave reflow treatment 5min, gained mixed liquor are sent into spray dryer again after 10min, dry gained particle through ultramicro grinding Micro mist is made in machine, produces auxiliary agent compound；B, isopropyl fatty acid ester is prepared：Aliphatic acid and isopropanol are well mixed, in 420- 550r/min rotating speeds stir 28-35min, then add Fe2(SO4)3・9H2O is well mixed for catalyst, is warming up to 70-78 DEG C, 30-35min is incubated, is stirred at reflux, is cooled to room temperature, with 70-90 DEG C of distillation water washing to pH to 7 after distillation, vacuum dehydration obtains To isopropyl fatty acid ester；C, by boric acid, triethanolamine, polyethers, ready denier oil acid, tall oil diethanol amine, C16/18 alcohol Alcoxylates, diglycolamine, carboxylic acid, boric acid diethanol amine ester, benzotriazole derivative, derivative of fatty acid, morpholine derivative, Pyrrolotriazine derivatives, isopropyl fatty acid ester and auxiliary agent compound are well mixed, and the metalworking fluid of embodiment 3 is made.
Embodiment 4
A kind of metalworking fluid, components by weight percent are respectively：
The parts by weight of boric acid 25；
The parts by weight of polyethers 26；
The parts by weight of ready denier oil acid 12；
The parts by weight of tall oil diethanol amine 17；
The parts by weight of alcoxylates 15 of C16/18 alcohol；
The parts by weight of diglycolamine 18；
The parts by weight of carboxylic acid 28；
The parts by weight of boric acid diethanol amine ester 27；
The parts by weight of benzotriazole derivative 28；
The parts by weight of derivative of fatty acid 25；
The parts by weight of morpholine derivative 26；
The parts by weight of pyrrolotriazine derivatives 25.
The parts by weight of mould inhibitor IPBC 5；
The parts by weight of defoamer 2.
The preparation method of metalworking fluid is：A, auxiliary agent compound is prepared：Xiang Shuizhong adds aluminosilicate powder and metatitanic acid N-butyl, it is sent into after fully dispersed in ball mill, is milled to fineness less than 5 μm, and utilize microwave treater microwave reflow treatment 5min, polyoxyethylene poly-oxygen propylene aether block copolymer is added, continue microwave reflow treatment 2min after being well mixed, stand Microwave reflow treatment 5min, gained mixed liquor are sent into spray dryer again after 10min, dry gained particle through ultramicro grinding Micro mist is made in machine, produces auxiliary agent compound；B, isopropyl fatty acid ester is prepared：Aliphatic acid and isopropanol are well mixed, in 420- 550r/min rotating speeds stir 28-35min, then add Fe2(SO4)3・9H2O is well mixed for catalyst, is warming up to 70-78 DEG C, 30-35min is incubated, is stirred at reflux, is cooled to room temperature, with 70-90 DEG C of distillation water washing to pH to 7 after distillation, vacuum dehydration obtains To isopropyl fatty acid ester；C, by boric acid, triethanolamine, polyethers, ready denier oil acid, tall oil diethanol amine, C16/18 alcohol Alcoxylates, diglycolamine, carboxylic acid, boric acid diethanol amine ester, benzotriazole derivative, derivative of fatty acid, morpholine derivative, Pyrrolotriazine derivatives, isopropyl fatty acid ester and auxiliary agent compound are well mixed, and the metalworking fluid of embodiment 4 is made.
The foregoing examples are merely illustrative of the technical concept and features of the invention, its purpose is to allow person skilled in the art Member can understand present disclosure, and it is not intended to limit the scope of the present invention, all according to spirit of the invention institute The equivalent change or modification done, it should all be included within the scope of the present invention.

Claims (8)

  1. A kind of 1. metalworking fluid, it is characterised in that：It, which is formulated, includes boric acid, triethanolamine, polyethers, ready denier oil acid, appropriate Your oily diethanol amine, the alcoxylates of C16/18 alcohol, diglycolamine, dicarboxylic acids, tricarboxylic acid, boric acid diethanol amine ester, Benzotriazole derivative, derivative of fatty acid, morpholine derivative, pyrrolotriazine derivatives, parts by weight are respectively：
    Boric acid 25-35 parts；
    Polyethers 20-30 parts；
    Ready denier oil acid 10-15 parts；
    Tall oil diethanol amine 15-30 parts；
    Alcoxylates 10-20 parts of C16/18 alcohol；
    Diglycolamine 10-20 parts；
    Carboxylic acid 25-35 parts；
    Boric acid diethanol amine ester 20-30 parts；
    Benzotriazole derivative 25-35 parts；
    Derivative of fatty acid 20-30 parts；
    Morpholine derivative 25-35 parts；
    Pyrrolotriazine derivatives 20-30 parts.
  2. 2. metalworking fluid according to claim 1, it is characterised in that：Formula also includes the mould inhibitor of 3-8 parts by weight The defoamer of IPBC and 1-3 parts by weight.
  3. 3. metalworking fluid according to claim 1, it is characterised in that：Carboxylic acid in formula includes dicarboxylic acids and ternary Carboxylic acid.
  4. 4. metalworking fluid according to claim 1, it is characterised in that：The formula also aliphatic acid including 5-10 parts by weight is different Propyl ester.
  5. 5. metalworking fluid according to claim 4, it is characterised in that：The isopropyl fatty acid ester is carried out by following technique Prepare：Aliphatic acid and isopropanol are well mixed, 28-35min is stirred in 420-550r/min rotating speeds, then adds Fe2 (SO4)3・9H2O is well mixed for catalyst, is warming up to 70-78 DEG C, is incubated 30-35min, is stirred at reflux, is cooled to room temperature, steams With 70-90 DEG C of distillation water washing to pH to 7 after evaporating, vacuum dehydration obtains isopropyl fatty acid ester.
  6. 6. metalworking fluid according to claim 5, it is characterised in that：The formula also auxiliary agent including 15-30 parts by weight is answered Compound.
  7. 7. metalworking fluid according to claim 6, it is characterised in that：The auxiliary agent compound is alumino-silicate and polyoxy Ethene polyoxypropylene ether block copolymers are made during the catalytic transesterification of tetrabutyl titanate, and its specific preparation method is： Xiang Shuizhong adds aluminosilicate powder and tetrabutyl titanate, is sent into after fully dispersed in ball mill, is milled to fineness less than 5 μm, And microwave treater microwave reflow treatment 5min is utilized, polyoxyethylene poly-oxygen propylene aether block copolymer is added, is well mixed Microwave reflow treatment 5min, gained mixed liquor are sent into spray drying again after continuation microwave reflow treatment 2min afterwards, standing 10min In machine, dry gained particle and micro mist is made through micronizer, produce auxiliary agent compound.
  8. 8. metalworking fluid according to claim 7, its preparation method are：A, auxiliary agent compound is prepared；B, fat is prepared Isopropyl propionate；C, by boric acid, triethanolamine, polyethers, ready denier oil acid, tall oil diethanol amine, C16/18 alcohol alkoxy Compound, diglycolamine, carboxylic acid, boric acid diethanol amine ester, benzotriazole derivative, derivative of fatty acid, morpholine derivative, triazine are spread out Biology, isopropyl fatty acid ester and auxiliary agent compound carry out well mixed obtained metalworking fluid.
CN201710937708.3A 2017-10-09 2017-10-09 A kind of metalworking fluid Pending CN107474907A (en)

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CN108949303A (en) * 2018-08-30 2018-12-07 江苏欧仕达润滑油有限公司 A kind of solar silicon wafers cutting fluid and preparation method thereof
CN112119123A (en) * 2018-03-06 2020-12-22 瀚森公司 Catalyst system for curing phenolic resole resins

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CN105733790A (en) * 2016-03-11 2016-07-06 东莞市纳晟润滑油科技有限公司 Total-synthesis special aluminum alloy cutting fluid
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Application publication date: 20171215