CN109504972A - Water-soluble washing agent and preparation method thereof - Google Patents
Water-soluble washing agent and preparation method thereof Download PDFInfo
- Publication number
- CN109504972A CN109504972A CN201811485895.7A CN201811485895A CN109504972A CN 109504972 A CN109504972 A CN 109504972A CN 201811485895 A CN201811485895 A CN 201811485895A CN 109504972 A CN109504972 A CN 109504972A
- Authority
- CN
- China
- Prior art keywords
- agent
- water
- soluble washing
- washing agent
- corrosion inhibitor
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
- 238000005406 washing Methods 0.000 title claims abstract description 24
- 238000002360 preparation method Methods 0.000 title claims abstract description 11
- 239000003795 chemical substances by application Substances 0.000 claims abstract description 43
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Chemical compound O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 14
- 238000006243 chemical reaction Methods 0.000 claims abstract description 12
- 230000007797 corrosion Effects 0.000 claims abstract description 10
- 238000005260 corrosion Methods 0.000 claims abstract description 10
- 239000003112 inhibitor Substances 0.000 claims abstract description 10
- 239000013556 antirust agent Substances 0.000 claims abstract description 8
- 150000001412 amines Chemical class 0.000 claims abstract description 6
- 235000019463 artificial additive Nutrition 0.000 claims abstract description 6
- 239000008367 deionised water Substances 0.000 claims abstract description 6
- 229910021641 deionized water Inorganic materials 0.000 claims abstract description 6
- 238000003756 stirring Methods 0.000 claims description 10
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 claims description 5
- 238000004090 dissolution Methods 0.000 claims description 5
- 230000008595 infiltration Effects 0.000 claims description 5
- 238000001764 infiltration Methods 0.000 claims description 5
- 239000000126 substance Substances 0.000 claims description 5
- 239000000203 mixture Substances 0.000 claims description 4
- CXMXRPHRNRROMY-UHFFFAOYSA-N sebacic acid group Chemical group C(CCCCCCCCC(=O)O)(=O)O CXMXRPHRNRROMY-UHFFFAOYSA-N 0.000 claims description 4
- 239000002253 acid Substances 0.000 claims description 2
- 239000002736 nonionic surfactant Substances 0.000 claims description 2
- 125000002270 phosphoric acid ester group Chemical group 0.000 claims description 2
- 235000019441 ethanol Nutrition 0.000 claims 2
- 230000003213 activating effect Effects 0.000 claims 1
- 125000002091 cationic group Chemical group 0.000 claims 1
- DGXRZJSPDXZJFG-UHFFFAOYSA-N docosanedioic acid Chemical class OC(=O)CCCCCCCCCCCCCCCCCCCCC(O)=O DGXRZJSPDXZJFG-UHFFFAOYSA-N 0.000 claims 1
- UHOVQNZJYSORNB-UHFFFAOYSA-N Benzene Chemical compound C1=CC=CC=C1 UHOVQNZJYSORNB-UHFFFAOYSA-N 0.000 abstract description 9
- 239000012459 cleaning agent Substances 0.000 abstract description 7
- LPXPTNMVRIOKMN-UHFFFAOYSA-M sodium nitrite Chemical compound [Na+].[O-]N=O LPXPTNMVRIOKMN-UHFFFAOYSA-M 0.000 abstract description 6
- ISWSIDIOOBJBQZ-UHFFFAOYSA-N Phenol Chemical compound OC1=CC=CC=C1 ISWSIDIOOBJBQZ-UHFFFAOYSA-N 0.000 abstract description 5
- 238000004140 cleaning Methods 0.000 abstract description 5
- 239000000654 additive Substances 0.000 abstract description 4
- 230000000996 additive effect Effects 0.000 abstract description 4
- VEXZGXHMUGYJMC-UHFFFAOYSA-M Chloride anion Chemical compound [Cl-] VEXZGXHMUGYJMC-UHFFFAOYSA-M 0.000 abstract description 3
- 230000000740 bleeding effect Effects 0.000 abstract description 3
- WSFSSNUMVMOOMR-NJFSPNSNSA-N methanone Chemical compound O=[14CH2] WSFSSNUMVMOOMR-NJFSPNSNSA-N 0.000 abstract description 3
- 235000010288 sodium nitrite Nutrition 0.000 abstract description 3
- 230000015572 biosynthetic process Effects 0.000 abstract description 2
- 231100000252 nontoxic Toxicity 0.000 abstract description 2
- 230000003000 nontoxic effect Effects 0.000 abstract description 2
- 239000000419 plant extract Substances 0.000 abstract description 2
- 239000002904 solvent Substances 0.000 abstract description 2
- 238000003786 synthesis reaction Methods 0.000 abstract description 2
- 239000012752 auxiliary agent Substances 0.000 abstract 1
- 239000006260 foam Substances 0.000 description 3
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 description 2
- TVIDDXQYHWJXFK-UHFFFAOYSA-N dodecanedioic acid Chemical compound OC(=O)CCCCCCCCCCC(O)=O TVIDDXQYHWJXFK-UHFFFAOYSA-N 0.000 description 2
- 238000007689 inspection Methods 0.000 description 2
- 238000003860 storage Methods 0.000 description 2
- 230000002159 abnormal effect Effects 0.000 description 1
- 150000001447 alkali salts Chemical class 0.000 description 1
- 239000004411 aluminium Substances 0.000 description 1
- 229910052782 aluminium Inorganic materials 0.000 description 1
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 1
- 239000002518 antifoaming agent Substances 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 239000003093 cationic surfactant Substances 0.000 description 1
- 239000011248 coating agent Substances 0.000 description 1
- 238000000576 coating method Methods 0.000 description 1
- 239000002131 composite material Substances 0.000 description 1
- 238000005238 degreasing Methods 0.000 description 1
- 238000002845 discoloration Methods 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 239000003205 fragrance Substances 0.000 description 1
- 230000005484 gravity Effects 0.000 description 1
- 229910052742 iron Inorganic materials 0.000 description 1
- 229910052751 metal Inorganic materials 0.000 description 1
- 239000002184 metal Substances 0.000 description 1
- 238000000034 method Methods 0.000 description 1
- 230000035699 permeability Effects 0.000 description 1
- 239000004094 surface-active agent Substances 0.000 description 1
- 238000010998 test method Methods 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
- C23G—CLEANING OR DE-GREASING OF METALLIC MATERIAL BY CHEMICAL METHODS OTHER THAN ELECTROLYSIS
- C23G1/00—Cleaning or pickling metallic material with solutions or molten salts
- C23G1/02—Cleaning or pickling metallic material with solutions or molten salts with acid solutions
- C23G1/04—Cleaning or pickling metallic material with solutions or molten salts with acid solutions using inhibitors
- C23G1/06—Cleaning or pickling metallic material with solutions or molten salts with acid solutions using inhibitors organic inhibitors
- C23G1/066—Cleaning or pickling metallic material with solutions or molten salts with acid solutions using inhibitors organic inhibitors phosphorus-containing compounds
Landscapes
- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- General Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Mechanical Engineering (AREA)
- Metallurgy (AREA)
- Organic Chemistry (AREA)
- Detergent Compositions (AREA)
Abstract
The present invention relates to a kind of water-soluble washing agents and preparation method thereof, cleaning agent specifically includes the component of following mass percent: amine 5-15%, antirust agent 1-5%, corrosion inhibitor 0-2%, interfacial agent 5-10%, the deionized water or pure water of special synthetic additive 5-10%, bleeding agent 2-5%, auxiliary agent 5-10% and surplus.The present invention is using components such as interfacial agent, the bleeding agents of plant extracts reaction synthesis, and harmful additive such as chloride, phenol, benzene, formaldehyde, sodium nitrite, does not take water as a solvent, nontoxic, harmless, environmentally friendly, and energy effective protection environment reduces cleaning cost.
Description
Technical field
The present invention relates to cleaning agent preparation fields, and in particular to a kind of water-soluble washing agent and preparation method thereof.
Background technique
Cleaning agent is mainly used in surface cleaning part iron filings remained on surface, greasy dirt, antirust oil etc., metal after intermetallic composite coating
Cleaning agent is made of surfactant and the cleaning additive of addition (such as basic salt), defoaming agent, fragrance, existing cleaning agent
It is middle to there is a problem of that foam is more, the effect that degreases difference, and chloride, phenol, benzene, formaldehyde, sodium nitrite are added in cleaning agent
Etc. harmful additive, baneful influence is generated to environment.
Summary of the invention
The purpose of the present invention is to provide a kind of water-soluble washing agents and preparation method thereof, in the prior art to solve
The problem of cleaning agent foam is more and pollutes environment.
The present invention provides a kind of water-soluble washing agents, specifically include the component of following mass percent:
Further, the antirust agent is the mixture of one or more of sebacic acid, ternary acid, dodecanedioic acid.
Further, the corrosion inhibitor is phosphoric acid ester corrosion inhibitor.
Further, the interfacial agent is cationic surfactant or low bubble nonionic surfactant and second
The mixture of the mixed alcohol of alcohol or C14-C15.
Another aspect of the present invention provides a kind of preparation method of water-soluble washing agent, includes the following steps:
(1) it weighs in the deionized water or pure water investment reaction kettle of certain mass;
(2) start to stir, and put into amine substance, be heated to 60 ± 5 DEG C, be subsequently agitated for dissolution 10-30min to completely it is molten
Solution;
(3) antirust agent, corrosion inhibitor, interfacial agent, special synthetic additive, infiltration agent aid sequence are thrown to
In reaction kettle, stirring and dissolving obtains water-soluble washing agent.
Beneficial effect using aforementioned present invention technical solution is:
The present invention using the components such as interfacial agent, bleeding agent of plant extracts reaction synthesis, not chloride, phenol,
The nocuousness additive such as benzene, formaldehyde, sodium nitrite, takes water as a solvent, nontoxic, harmless, environmentally friendly, and energy effective protection environment reduces
Clean cost;
With superpower ground rust-preventing characteristic, cleaning permeability, low bubble performance, and storage stability is strong, solves conventional cleaning
The problems such as agent foam is more, it is ineffective to degrease, storage is unstable.
Specific embodiment
It in order to make the object, technical scheme and advantages of the embodiment of the invention clearer, below will be in the embodiment of the present invention
Technical solution be clearly and completely described, it is clear that described embodiments are some of the embodiments of the present invention, rather than
Whole embodiments.
Embodiment 1
A kind of water-soluble washing agent specifically includes the component of following mass percent:
The preparation method of the water-soluble washing agent, includes the following steps:
(1) it weighs in deionized water or pure water investment reaction kettle;
(2) start to stir, and put into amine substance, be heated to 60 ± 5 DEG C, be subsequently agitated for dissolution 30min to being completely dissolved;
(3) antirust agent, corrosion inhibitor, interfacial agent, special synthetic additive, infiltration agent aid sequence are thrown to
In reaction kettle, stirring and dissolving obtains water-soluble washing agent.
Embodiment 2
A kind of water-soluble washing agent specifically includes the component of following mass percent:
The preparation method of the water-soluble washing agent, includes the following steps:
(1) it weighs in deionized water or pure water investment reaction kettle;
(2) start to stir, and put into amine substance, be heated to 60 ± 5 DEG C, be subsequently agitated for dissolution 30min to being completely dissolved;
(3) antirust agent, corrosion inhibitor, interfacial agent, special synthetic additive, infiltration agent aid sequence are thrown to
In reaction kettle, stirring and dissolving obtains water-soluble washing agent.
Embodiment 3
A kind of water-soluble washing agent specifically includes the component of following mass percent:
The preparation method of the water-soluble washing agent, includes the following steps:
(1) it weighs in deionized water or pure water investment reaction kettle;
(2) start to stir, and put into amine substance, be heated to 60 ± 5 DEG C, be subsequently agitated for dissolution 30min to being completely dissolved;
(3) antirust agent, corrosion inhibitor, interfacial agent, special synthetic additive, infiltration agent aid sequence are thrown to
In reaction kettle, stirring and dissolving obtains water-soluble washing agent.
Wherein, the performance indicator of 3 gained water-soluble washing agent of embodiment is as shown in the table:
Inspection item | Inspection result | Test method |
Appearance (stoste) | Colourless or yellow transparent | Range estimation |
Specific gravity (15/4 DEG C) | 1.03 | GB/T1884-2000 |
PH (Vol 10%) | 8.3 | GB/T 259-1988 |
Concentration ((Vol 10%) | 29.0 | Densimeter |
It stores stability (50 DEG C, room temperature, -5 DEG C) | January is without abnormal | Range estimation |
Aluminium changes colour (room temperature, 50 DEG C) | Without discoloration | Range estimation |
Degreasing Brix 2% | 100% | Range estimation |
Finally, it should be noted that the above embodiments are only used to illustrate the technical solution of the present invention., rather than its limitations;To the greatest extent
Pipe present invention has been described in detail with reference to the aforementioned embodiments, those skilled in the art should understand that: its according to
So be possible to modify the technical solutions described in the foregoing embodiments, or to some or all of the technical features into
Row equivalent replacement;And these are modified or replaceed, various embodiments of the present invention technology that it does not separate the essence of the corresponding technical solution
The range of scheme.
Claims (5)
1. a kind of water-soluble washing agent, which is characterized in that specifically include the component of following mass percent:
2. water-soluble washing agent according to claim 1, which is characterized in that the antirust agent is sebacic acid, ternary acid, ten
The mixture of one or more of two docosandioic acids.
3. water-soluble washing agent according to claim 1, which is characterized in that the corrosion inhibitor is phosphoric acid ester corrosion
Inhibitor.
4. water-soluble washing agent according to claim 1, which is characterized in that the interfacial agent is cationic surface
The mixture of activating agent or low bubble nonionic surfactant and ethyl alcohol or the mixed alcohol of C14-C15.
5. a kind of preparation method of water-soluble washing agent, which comprises the steps of:
(1) it weighs in the deionized water or pure water investment reaction kettle of certain mass;
(2) start to stir, and put into amine substance, be heated to 60 ± 5 DEG C, be subsequently agitated for dissolution 10-30min to being completely dissolved;
(3) antirust agent, corrosion inhibitor, interfacial agent, special synthetic additive, infiltration agent aid sequence are thrown to reaction
In kettle, stirring and dissolving obtains water-soluble washing agent.
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
CN201811485895.7A CN109504972A (en) | 2018-12-06 | 2018-12-06 | Water-soluble washing agent and preparation method thereof |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
CN201811485895.7A CN109504972A (en) | 2018-12-06 | 2018-12-06 | Water-soluble washing agent and preparation method thereof |
Publications (1)
Publication Number | Publication Date |
---|---|
CN109504972A true CN109504972A (en) | 2019-03-22 |
Family
ID=65751730
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
CN201811485895.7A Pending CN109504972A (en) | 2018-12-06 | 2018-12-06 | Water-soluble washing agent and preparation method thereof |
Country Status (1)
Country | Link |
---|---|
CN (1) | CN109504972A (en) |
Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN111154563A (en) * | 2020-01-10 | 2020-05-15 | 汎宇化学(昆山)有限公司 | High-decontamination-performance cleaning agent and preparation method thereof |
Citations (6)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN102660752A (en) * | 2012-05-09 | 2012-09-12 | 上海福岛化工科技发展有限公司 | Environment-friendly efficient bubble-free cleaning agent |
CN102732899A (en) * | 2012-07-19 | 2012-10-17 | 长沙艾森设备维护技术有限公司 | Water-based anti-rusting type washing agent for metal parts |
CN103046066A (en) * | 2013-01-08 | 2013-04-17 | 上海尤希路化学工业有限公司 | High-performance and environment-friendly water-based cleaning agent |
CN104711616A (en) * | 2015-03-25 | 2015-06-17 | 武汉工程大学 | Water-based metal detergent and preparation method thereof |
CN108034954A (en) * | 2017-11-30 | 2018-05-15 | 珠海横琴思国科技发展有限公司 | A kind of anti-rust cleaning agent of aluminium and aluminium alloy and preparation method thereof |
CN108690736A (en) * | 2018-05-14 | 2018-10-23 | 上海中孚特种油品有限公司 | A kind of environment-friendly type exterior aircraft cleaner and preparation method thereof |
-
2018
- 2018-12-06 CN CN201811485895.7A patent/CN109504972A/en active Pending
Patent Citations (6)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN102660752A (en) * | 2012-05-09 | 2012-09-12 | 上海福岛化工科技发展有限公司 | Environment-friendly efficient bubble-free cleaning agent |
CN102732899A (en) * | 2012-07-19 | 2012-10-17 | 长沙艾森设备维护技术有限公司 | Water-based anti-rusting type washing agent for metal parts |
CN103046066A (en) * | 2013-01-08 | 2013-04-17 | 上海尤希路化学工业有限公司 | High-performance and environment-friendly water-based cleaning agent |
CN104711616A (en) * | 2015-03-25 | 2015-06-17 | 武汉工程大学 | Water-based metal detergent and preparation method thereof |
CN108034954A (en) * | 2017-11-30 | 2018-05-15 | 珠海横琴思国科技发展有限公司 | A kind of anti-rust cleaning agent of aluminium and aluminium alloy and preparation method thereof |
CN108690736A (en) * | 2018-05-14 | 2018-10-23 | 上海中孚特种油品有限公司 | A kind of environment-friendly type exterior aircraft cleaner and preparation method thereof |
Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN111154563A (en) * | 2020-01-10 | 2020-05-15 | 汎宇化学(昆山)有限公司 | High-decontamination-performance cleaning agent and preparation method thereof |
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PB01 | Publication | ||
PB01 | Publication | ||
SE01 | Entry into force of request for substantive examination | ||
SE01 | Entry into force of request for substantive examination | ||
RJ01 | Rejection of invention patent application after publication |
Application publication date: 20190322 |
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RJ01 | Rejection of invention patent application after publication |