CN101831360B - Cleaning agent for automobile windshield - Google Patents
Cleaning agent for automobile windshield Download PDFInfo
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- CN101831360B CN101831360B CN 200910079367 CN200910079367A CN101831360B CN 101831360 B CN101831360 B CN 101831360B CN 200910079367 CN200910079367 CN 200910079367 CN 200910079367 A CN200910079367 A CN 200910079367A CN 101831360 B CN101831360 B CN 101831360B
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- cleaning agent
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- automobile windscreen
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Abstract
The invention relates to a cleaning agent for an automobile windshield, which consists of the following components in percentage by weight: 1 to 50 percent of monobasic alcohol, 1 to 10 percent of ethylene glycol, 0.005 to 0.1 percent of complexing agent, 0.005 to 0.1 percent of cationic surfactant, 0.005 to 0.1 percent of nonionic surfactant, 0.1 to 3 percent of composite corrosion inhibitor, 0.005 to 0.1 percent of colorant and the balance of water. The cleaning agent has cleaning, anti-freezing, anti-fog, anti-corrosion, anti-static, lubricating properties, can effectively remove dust, dirt, spray mark, gum, lac and the like on the windshield, and has high stability of high and low temperature and no damage to the automobile windshield.
Description
Technical field
The present invention relates to a kind of automobile windscreen cleaning agent.
Technical background
Along with the develop rapidly of automotive industry in recent years, the expense of automobile maintenance articles for use is also increasing day by day, and automobile windscreen cleaning agent is wherein important a kind of, and its consumption is also increasing year by year, has attracted a lot of production firms unexpectedly by the production of this product.Make a general survey of domestic industry situation, be not difficult to find that the production of this product mainly concentrates on private workshop at home, and big manufacturing enterprise and fine automobile windscreen cleaning agent are few in number.
The prescription development of automobile windscreen cleaning agent product can be divided into three phases basically, and stain remover kind the earliest is inorganic salt, like sodium phosphate, sodium sulfate, water glass, boric acid, tripoly phosphate sodium STPP etc., addition 1-5%.Though these inorganic salt have certain soil-removing action, solvency power is relatively poor, separates out easily under the low-temperature condition, and friction produces cut to glass, is eliminated.Adopt the acid-basicity stain remover in addition, like acid detergent Hydrocerol A, formic acid, acetate etc. are arranged, alkaline stain remover has sodium hydroxide, ammoniacal liquor, trolamine etc., addition 0.5-2.5%.Compare with inorganic salt, this type stain remover solvency power is better, but life-time service is corrosive to wiper metal, automobile finish, also is eliminated.Develop at last and adopt tensio-active agent as stain remover, surfactant molecule can be with the earth soil dispersion that tightly is attached to the surface in water; Can water-fast common grease molecule be sealed through separation, form water-soluble emulsion, thereby reach cleaning, soil-removing action; It is the ideal stain remover.
From the angle of product standard, the most perfect is JIS K2398-2001---" automobile windscreen cleaning agent " of Japan.This standard specified in more detail each item technical indicator: outward appearance, freezing point, pH value, high-temperature stability, low-temperature stability, detersive power, to influence of metal, rubber, plastics, coating etc.The motor corporation of developed country like AM General company, U.S. Department of Defense and U.K. Ministry of Defence, to the civil and military product of automobile glass cleaning agent, has formulated relevant standard.And China does not also have relevant country or industry standard to this product, thereby has given chance for private workshop.
China starts late to the research of automobile windscreen cleaning agent, and the domestic majority product is that handicraft workshop adopts methyl alcohol and water blended low grade products, and is bigger at the performance difference of aspects such as security, decontamination, antistatic, protection against corrosion.Simultaneously, the patent report that does not also have relevant automobile windscreen cleaning agent at home.
Summary of the invention
The objective of the invention is defective and deficiency in order to overcome the automobile windscreen cleaning agent prior art; On the basis of monohydroxy-alcohol; Add terepthaloyl moietie, cats product, nonionogenic tenside, complexing agent and composite corrosion inhibitor etc., improved its oilness, static resistance and antiseptic property.
Technical scheme of the present invention is: a kind of automobile windscreen cleaning agent, to form by monohydroxy-alcohol, terepthaloyl moietie, complexing agent, cats product, nonionogenic tenside, composite corrosion inhibitor, tinting material and water, and the weight proportion of each component is following:
Monohydroxy-alcohol 1～50%
Terepthaloyl moietie 1～10%
Cats product 0.005～1%
Nonionogenic tenside 0.005～1%
Complexing agent 0.005～1%
Composite corrosion inhibitor 0.1～3%
Tinting material 0.0001～0.1%
The softening water surplus
Described monohydroxy-alcohol is one or more the mixture in methyl alcohol, ethanol, the Virahol, and its content is preferably 5～50%, and its major function is to reduce freezing point, and with little, the no stink of alcohol toxicity first-selection.
Terepthaloyl moietie among the present invention cooperates with monohydroxy-alcohol on the one hand and reduces freezing point.On the other hand, its viscosity is big than monohydroxy-alcohol, and volatility is little, can keep after the adding clean-out system on windshield the residence time and strengthen washing effect.Simultaneously, can reduce friction between windshield wiper and the glass.
Described cats product is that dodecyl benzyl dimethyl ammonium chloride, lauryl trimethyl ammonium chloride and methyl diethylammonium gather at least a in the propoxy-ammonium chloride, and its content is preferably 0.1～1%.Its major function is to eliminate the static of windshield glass and air friction generation, plays the sterilization and anticorrosion effect simultaneously.And composite with the nonionogenic tenside of selecting, have wetting and soil-removing action.First-selected with dodecyl benzyl dimethyl ammonium chloride.
Described nonionogenic tenside is at least a in aliphatic alcohol polyethenoxy (9) ether, Nonyl pheno (10) ether and LAURIC ACID 99 MIN polyoxyethylene glycol (20) ester, and its content is preferably 0.01～1%.It mainly is to play soil-removing action as wetting agent and emulsifying agent, has low foaming characteristics simultaneously.First-selected with Nonyl pheno (10) ether.
Described complexing agent is at least a in adjacent cyclohexanediaminetetraacetic acid sodium, EDTA Disodium and the Trisodium Citrate, and its content is preferably 0.1～1%.Add in the product of the present invention, remove glass surface inorganic type dirt through complexing action on the one hand, simultaneously, can reduce incrustation scale with calcium, the magnesium complexing in the system water and produce, prevent the car cleaning system jams.First-selected with EDTA Disodium.
Described composite corrosion inhibitor is the mixture of TTA, SODIUMNITRATE, tsp, trolamine, Sodium orthomolybdate, Sodium Benzoate, sebacic acid sodium composition, and its content is preferably 1～3%.Water pump and pipeline in order to effective protection car cleaning system are not corroded, and guarantee that simultaneously remaining in other positions of automobile after the clean-out system ejection does not corrode yet.
Described automobile windscreen cleaning agent is characterized in that described tinting material is tetrabromo-mcresolsulfonphthalein and/or Bromothymol blue, and its content is preferably 0.0001～0.0005%.Its effect is leak detection when being convenient to identification and maintenance.
The preparation method of automobile windscreen cleaning agent of the present invention: according to each amount of substance of prescription regulation; Get in monohydroxy-alcohol, terepthaloyl moietie, the softening water input reaction kettle; Stirred at normal temperatures 10 minutes; And then get cats product, nonionogenic tenside, complexing agent and composite corrosion inhibitor and add successively in the reaction kettle, stir after 30 minutes, add tinting material and get final product until dissolving fully.
Functions such as that the tensio-active agent that adopts the automobile windscreen cleaning agent of the present invention's prescription to contain has is wetting, infiltration, solubilising, thus the effect of good cleaning decontamination is arranged.The existence of organic solvents such as alcohol, terepthaloyl moietie is arranged, can significantly reduce the freezing point of liquid, thereby play antifreeze effect, can dissolve frost very soon.Can form one deck unit molecule resist at glass surface, this layer protective membrane can prevent to form droplet, guarantees that windshield glass is as clear as crystal, gets a clear view.Be adsorbed on the cats product of glass surface, can eliminate the electric charge of glass surface, have antistatic property.Contain terepthaloyl moietie, viscosity is bigger, can lubricate, reduce the friction between rain brush and the glass, and prevent to produce cut.Contain composite corrosion inhibitor, the various metals that the windshield cleaning system is contacted have good protective action.Method according to SH/T 0084 makes an experiment, and automobile finish is not had influence.Rubber components to using on the automobile does not have swelling.The automobile windscreen cleaning agent of the present invention preparation can effectively be protected each parts of automobile of contact, and is safe and reliable.”
Embodiment
Automobile windscreen cleaning agent prescription of the present invention has obtained economical rationality, technological excellent formula combination through a large amount of screening experiments.Following table is 6 Example formulations:
Table 1 Example formulations
With embodiment 3 is example, and automobile windscreen cleaning agent performance index data of the present invention are seen table 2
Table 2 performance index
| Sequence number | Project | Standard-required | Test-results |
| 1 | Outward appearance | As clear as crystal, no solid particulate and suspended substance | As clear as crystal, no solid particulate and suspended substance |
| 2 | Smell | The fixed aromatising flavour is arranged | The fixed aromatising flavour is arranged |
| 3 | Freezing point (℃)<= | -40 | -42.3 |
| 4 | Low-temperature stability (15 ℃ ± 2 ℃ deposit 8h after) | No crystalline deposit | No crystalline deposit |
| 5 | High-temperature stability (50 ℃ ± 2 ℃ deposit 8h after) | No crystalline deposit | No crystalline deposit |
Continuous table 2
Can find out that from the test-results of embodiment 3 quality product satisfies Japanese industry standard JIS K2398-2001 fully---the requirement of " automobile wind shield glass clean-out system ", performance index such as rubber phase dissolubility, metal protection, detersive power are quite excellent.
Claims (4)
1. an automobile windscreen cleaning agent is made up of monohydroxy-alcohol, terepthaloyl moietie, complexing agent, cats product, nonionogenic tenside, composite corrosion inhibitor, tinting material and softening water, and the weight proportion of each component is following:
Described monohydroxy-alcohol is one or more the mixture in methyl alcohol, ethanol and the Virahol;
Described cats product is that dodecyl benzyl dimethyl ammonium chloride, lauryl trimethyl ammonium chloride and methyl diethylammonium gather at least a in the propoxy-ammonium chloride;
Described nonionogenic tenside is at least a in aliphatic alcohol polyethenoxy (9) ether, Nonyl pheno (10) ether and LAURIC ACID 99 MIN polyoxyethylene glycol (20) ester;
Described complexing agent is at least a in adjacent cyclohexanediaminetetraacetic acid sodium, EDTA Disodium and the Trisodium Citrate;
Described composite corrosion inhibitor is the mixture of TTA, SODIUMNITRATE, tsp, trolamine, Sodium orthomolybdate, Sodium Benzoate and sebacic acid sodium.
2. automobile windscreen cleaning agent according to claim 1 is characterized in that described tinting material is tetrabromo-mcresolsulfonphthalein and/or Bromothymol blue.
3. according to the preparation method of each described automobile windscreen cleaning agent of claim 1-2; It is characterized in that monohydroxy-alcohol, terepthaloyl moietie, softening water are dropped in the reaction kettle; Stirred at normal temperatures 10 minutes; And then get cats product, nonionogenic tenside, complexing agent and composite corrosion inhibitor and add successively in the reaction kettle, stir after 30 minutes, add tinting material at last and get final product until dissolving fully.
4. according to the purposes of each described automobile windscreen cleaning agent of claim 1-2, be used for the cleaning of windshield.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN 200910079367 CN101831360B (en) | 2009-03-09 | 2009-03-09 | Cleaning agent for automobile windshield |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN 200910079367 CN101831360B (en) | 2009-03-09 | 2009-03-09 | Cleaning agent for automobile windshield |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN101831360A CN101831360A (en) | 2010-09-15 |
| CN101831360B true CN101831360B (en) | 2012-05-23 |
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Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN 200910079367 Active CN101831360B (en) | 2009-03-09 | 2009-03-09 | Cleaning agent for automobile windshield |
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| CN102021590B (en) * | 2010-12-14 | 2013-03-06 | 戴锐 | Metal scale remover and using method thereof |
| CN102653708B (en) * | 2011-12-21 | 2013-08-07 | 东昊石油集团有限公司 | All-around automobile windshield washing agent |
| CN102978026B (en) * | 2012-11-27 | 2014-04-16 | 高金菊 | Water glass for car |
| CN102994262A (en) * | 2012-11-27 | 2013-03-27 | 高金菊 | Preparation method for automobile glass water |
| CN103224842A (en) * | 2012-12-28 | 2013-07-31 | 青岛润鑫伟业科贸有限公司 | Glass cleaning agent |
| CN103224843A (en) * | 2012-12-28 | 2013-07-31 | 青岛润鑫伟业科贸有限公司 | Glass cleaning agent |
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| CN103060136A (en) * | 2012-12-28 | 2013-04-24 | 青岛润鑫伟业科贸有限公司 | Glass cleaning agent |
| CN103060138A (en) * | 2013-01-07 | 2013-04-24 | 北京洛娃日化有限公司 | Automotive glass-washing fluid |
| CN103087835A (en) * | 2013-03-02 | 2013-05-08 | 王蔚 | Detergent for automobile windshields |
| CN104178368A (en) * | 2013-05-21 | 2014-12-03 | 江苏天恒纳米科技有限公司 | High-molecular nanometer glass cleanser |
| CN103396897B (en) * | 2013-08-06 | 2014-12-31 | 张家港迪克汽车化学品有限公司 | Automobile wind window washing liquid |
| CN103600080B (en) * | 2013-11-12 | 2015-09-02 | 东莞市安美润滑科技有限公司 | Degumming cleaning liquid is used in neodymium-iron-boron magnetic material processing |
| CN103773638B (en) * | 2014-01-20 | 2016-04-06 | 武汉卓成光伏新能源有限公司 | Solar cell board cleaning agent |
| CN104152279A (en) * | 2014-07-16 | 2014-11-19 | 湖南城市学院 | Water-based cleanser for glass of smart phone and preparation method thereof |
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| CN104263535A (en) * | 2014-09-19 | 2015-01-07 | 山东华亚环保科技有限公司 | Glass cleaning agent with sterilization and oil removal effects |
| CN104357252A (en) * | 2014-11-19 | 2015-02-18 | 柳州市二和汽车零部件有限公司 | Automobile window cleaning solution |
| CN104327960A (en) * | 2014-11-19 | 2015-02-04 | 柳州市二和汽车零部件有限公司 | Automotive glass cleaning agent |
| CN104450234A (en) * | 2014-12-01 | 2015-03-25 | 张山 | Environment-friendly automobile glass cleaning fluid |
| CN104403825A (en) * | 2014-12-18 | 2015-03-11 | 无锡伊诺永利文化创意有限公司 | Glass cleaning agent and preparation method thereof |
| CN106085618A (en) * | 2016-06-08 | 2016-11-09 | 山东源根石油化工有限公司 | A kind of glass for vehicle window cleaning agent and preparation method thereof |
| CN106497518A (en) * | 2016-11-01 | 2017-03-15 | 重庆返璞科技有限公司 | A kind of nano-glass antifoggant and preparation method thereof |
| CN107603791A (en) * | 2017-10-08 | 2018-01-19 | 六安市九十里山水画廊有限公司 | Table glass turnplate greasy dirt flushing-free cleaning rubber |
| CN107760482A (en) * | 2017-12-01 | 2018-03-06 | 钱理 | A kind of environment protection type automobile wind screen efficient cleaner and its preparation technology |
| CN108467801A (en) * | 2018-02-13 | 2018-08-31 | 平南县亿翔环保能源有限公司 | A kind of detergent containing wood vinegar |
| CN111662782A (en) * | 2020-07-07 | 2020-09-15 | 台州职业技术学院 | Automobile front windshield cleaning fluid |
| CN113430057A (en) * | 2021-07-09 | 2021-09-24 | 桂林理工大学 | Automobile windshield cleaning fluid and preparation method thereof |
| CN115820346B (en) * | 2022-10-31 | 2024-02-02 | 铁科金化检测中心有限公司 | Cleaning agent for cleaning surface of railway vehicle and preparation method and application thereof |
| CN115975737A (en) * | 2022-12-13 | 2023-04-18 | 新疆金雪驰科技股份有限公司 | Multifunctional environment-friendly aromatic glass water composition and preparation method thereof |
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| CN101831360A (en) | 2010-09-15 |
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Free format text: FORMER OWNER: BLUE STAR ENVIRONMENTAL ENGINEERING CO., LTD. Effective date: 20130417 Owner name: BEIJING BLUESTAR TECHNOLOGY CO., LTD. Free format text: FORMER OWNER: CHINA BLUE STAR (GROUP) CO., LTD. Effective date: 20130417 |
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Effective date of registration: 20130417 Address after: 101318 Beijing City, Shunyi District Airport Industrial Zone B Anxiang Road No. 5 Patentee after: Beijing Bluestar Technology Co., Ltd. Address before: 100176, No. 19 East Third Ring Road, Chaoyang District, Beijing Patentee before: China National Bluestar (Group) Co., Ltd. Patentee before: Blue Star Environmental Engineering Co., Ltd. |
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Owner name: BEIJING BLUESTAR WASHING CO., LTD. Free format text: FORMER NAME: BEIJING BLUESTAR TECHNOLOGY CO., LTD. |
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Address after: 101318 Beijing City, Shunyi District Airport Industrial Zone B Anxiang Road No. 5 Patentee after: BEIJING BLUESTAR CLEANING CO., LTD. Address before: 101318 Beijing City, Shunyi District Airport Industrial Zone B Anxiang Road No. 5 Patentee before: Beijing Bluestar Technology Co., Ltd. |