CN103666830A - Freezing point adjustable glass cleaning agent, as well as preparation and application thereof - Google Patents

Freezing point adjustable glass cleaning agent, as well as preparation and application thereof Download PDF

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Publication number
CN103666830A
CN103666830A CN201310599745.XA CN201310599745A CN103666830A CN 103666830 A CN103666830 A CN 103666830A CN 201310599745 A CN201310599745 A CN 201310599745A CN 103666830 A CN103666830 A CN 103666830A
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China
Prior art keywords
freezing point
glass cleaner
cleaning agent
glass cleaning
sodium
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Pending
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CN201310599745.XA
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Chinese (zh)
Inventor
刘震
张琪
初黎坤
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QINGDAO COPTON TECHNOLOGY Co Ltd
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QINGDAO COPTON TECHNOLOGY Co Ltd
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Priority to CN201310599745.XA priority Critical patent/CN103666830A/en
Publication of CN103666830A publication Critical patent/CN103666830A/en
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Abstract

The invention relates to a glass cleaning agent, in particular to a freezing point adjustable glass cleaning agent, as well as preparation and application thereof. The glass cleaning agent comprises the following components: 1-70% of alcohol, 20-40% of water, 0.012-10.5% of non-ionic surface active agent, 0.11-3% of anionic surface active agent, 0.01-2% of alcohol ether sodium sulfate, 0.1-1% of sodium dodecyl benzene sulfonate, 0.5-5% of glycol ether, 0.01-0.1% of triethanolamine, 0.05-2% of amino poly-dimethyl siloxane, 0.01-0.5% of sodium benzoate, 0.1-2% of sodium EDTA, 0.1-1% of sodium metasilicate, 0.1-3% of glycerol boric aliphatic ester, 0.01-2% of dodecyl dimethyl ammonium chloride, 0.0005-3% of sunset red, and 0.1-0.3% of essence. According to the invention, the glass cleaning agent can efficiently remove stains, prevent static electricity and dust for a long time and keep glass transparent and bright. On the basis of keeping and enhancing the properties of basic cleaning, secondary pollution resisting, quick drying, fog preventing, hydrophile and no track after washing, the freezing point of the glass cleaning agent can be adjustable, so that the application range of the glass cleaning agent is enlarged.

Description

Freezing point adjustable type glass cleaner and preparation thereof and application
Technical field
The present invention relates to glass cleaner, particularly a kind of freezing point adjustable type glass cleaner and preparation and application.
Background technology
Glass, because it is smooth transparent, has good transparence and decorative effect and be widely used on the door and windows such as buildings and automobile, but glass is easily dirty, after being infected with dust or oil stain, not only affect sight line and attractive in appearance, also likely cause serious accident, therefore will clean in time.
Windshield water of the prior art is mainly comprised of alcohol, a small amount of tensio-active agent and water, this windshield glass water can be removed greasy dirt and the shellac on windshield glass, low temperature that can resistance to subzero 5~8 degrees Celsius, the characteristic also with quick-drying, can meet the general requirement of windshield glass substantially.Enter after winter, glass cleaner must have anti-freezing property, but different areas have the larger temperature difference, therefore develops freezing point adjustable, and the anti-freezing type glass cleaning technology that is applicable to wide geographic area has very great meaning.
Denomination of invention
The present invention is directed to deficiency of the prior art, a kind of novel glass cleaner, keep and improve substantially clean, anti-pollution again, quick-drying, antifog, hydrophilic and wash after leave no trace etc. on the basis of performance, there is the adjustable characteristic of freezing point, applicable to vast region.
Technical scheme of the present invention is:
A kind of freezing point adjustable type glass cleaner, in described glass cleaner, each component is composed as follows by mass percentage: ethanol 1~70%, water 20~40%, nonionogenic tenside 0.012~10.5%, anion surfactant 0.11~3%, alcohol ether sodium sulfate 0.01~2%, Sodium dodecylbenzene sulfonate 0.1~1%, glycol ether 0.5~5%, trolamine 0.01%~0.1%, amino polydimethylsiloxane 0.05~2%, Sodium Benzoate 0.01~0.5%, sodium ethylene diamine tetracetate 0.1~2%, Starso 0.1~1%, glycerol boric acid fatty acid ester 0.1~3%, dodecyl dimethyl ammonium chloride 0.01~2%, sunset red 0.0005~3%, essence 0.1~0.3%.
Preferably, described nonionogenic tenside is fatty alcohol-polyoxyethylene ether 0.001~1.5%, Oleum Cocois alkylolamide 0.001~3%, alkyl glycoside 0.001~5%, tween 80 0.01~1%.
Preferably, described anion surfactant is alcohol ether sodium sulfate 0.01~2%, Sodium dodecylbenzene sulfonate 0.1~1%.
In described clean-out system, anion surfactant and nonionogenic tenside are composite, and each component is more easily mixed, and improve simultaneously and hold agent cleaning performance, not stratified after guaranteeing to place for a long time, do not produce precipitation.
Described sodium ethylene diamine tetracetate can with water in metal ion form inner complex, there is the function of anti-hard water.Described alkyl glycoside and amino polydimethylsiloxane can effectively be reduced in the resistance of scraping water while cleaning glass.Described glycerol boric acid fatty acid ester is that the glass surface being cleaned has anti-fog performance.
The preparation method who the invention also discloses a kind of described freezing point adjustable type glass cleaner, first adds water and ethanol, then adds tensio-active agent, finally remaining ingredient is mixed one by one, is stirred to homogeneous transparent.
The invention also discloses a kind of application of freezing point adjustable type glass cleaner, when described glass cleaner and water Dilution ratio are 2:1, freezing point is-30 ℃; When the Dilution ratio of described glass cleaner and water is 1:1, freezing point is-20 ℃; When the Dilution ratio of described glass cleaner and water is 1:2, freezing point is-10 ℃.
The invention has the beneficial effects as follows: freezing point adjustable type glass cleaner of the present invention cleans glass can form hydrophobic film at glass surface later, effectively remove dirt long-acting anti-electrostatic, dustproof, keep glass transparent light.Keep and improve substantially clean, anti-pollution again, quick-drying, antifog, hydrophilic and wash after leave no trace etc. on the basis of performance, there is the adjustable characteristic of freezing point, applicable to vast region, use.
Embodiment
Below by embodiment, the present invention will be further described, but not as limitation of the present invention.
Embodiment mono-: described in this example, cleaning agent formula is:
Figure DEST_PATH_GDA0000458857620000021
Preparation method: first add water and ethanol, other components are mixed one by one, are stirred to homogeneous transparent.
Embodiment bis-: described in this example, cleaning agent formula is:
Figure DEST_PATH_GDA0000458857620000022
Figure DEST_PATH_GDA0000458857620000031
Preparation method: first add water and ethanol, other components are mixed one by one, are stirred to homogeneous transparent.
Embodiment tri-: described in this example, cleaning agent formula is:
Figure DEST_PATH_GDA0000458857620000032
Preparation method: first add water and ethanol, other components are mixed one by one, are stirred to homogeneous transparent.
Apply after above-mentioned three embodiment, the transparent anhydrous line of glass surface, can give the anti-pollution again of glass surface, quick-drying, antifog, hydrophilic and wash after the performance such as leave no trace, and possess the features such as nontoxic, environmental protection, protection against corrosion, the glass cleaner after dilution all can reach predetermined freezing point in proportion.
The freezing point of sanitising agent stoste prepared by above embodiment is-40 ℃; While being 2:1 with the Dilution ratio of water, freezing point is-30 ℃; While being 1:1 with the Dilution ratio of water, freezing point is-20 ℃; While being 1:2 with the Dilution ratio of water, freezing point is-10 ℃.

Claims (5)

1. a freezing point adjustable type glass cleaner, is characterized in that in described glass cleaner, each component is composed as follows by mass percentage:
Ethanol 1~70%, water 20 ~ 40%, nonionogenic tenside 0.012%~10.5%, anion surfactant 0.11%~3%, alcohol ether sodium sulfate 0.01~2%, Sodium dodecylbenzene sulfonate 0.1~1%, glycol ether 0.5~5%, trolamine 0.01~0.1%, amino polydimethylsiloxane 0.05~2%, Sodium Benzoate 0.01~0.5%, sodium ethylene diamine tetracetate 0.1~2%, Starso 0.1~1%, glycerol boric acid fatty acid ester 0.1~3%, dodecyl dimethyl ammonium chloride 0.01~2%, sunset red 0.0005~3%, essence 0.1~0.3%.
2. freezing point adjustable type glass cleaner according to claim 1, is characterized in that described nonionogenic tenside is fatty alcohol-polyoxyethylene ether 0.001~1.5%, Oleum Cocois alkylolamide 0.001~3%, alkyl glycoside 0.001~5%, tween 80 0.01~1%.
3. freezing point adjustable type glass cleaner according to claim 1 and 2, is characterized in that described anion surfactant is alcohol ether sodium sulfate 0.01~2%, Sodium dodecylbenzene sulfonate 0.1~1%.
4. according to a preparation method for right freezing point adjustable type claimed in claim 1 glass cleaner, it is characterized in that, first add water and ethanol, then add tensio-active agent, finally remaining ingredient is mixed one by one, be stirred to homogeneous transparent.
5. according to an application for described right freezing point adjustable type claimed in claim 1 glass cleaner, it is characterized in that, when described glass cleaner and water Dilution ratio are 2:1, freezing point is-30 ℃; When the Dilution ratio of described glass cleaner and water is 1:1, freezing point is-20 ℃; When the Dilution ratio of described glass cleaner and water is 1:2, freezing point is-10 ℃.
CN201310599745.XA 2013-11-25 2013-11-25 Freezing point adjustable glass cleaning agent, as well as preparation and application thereof Pending CN103666830A (en)

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Cited By (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN104194964A (en) * 2014-07-30 2014-12-10 南昌印仁贸易有限公司 Automobile glass cleaner and preparation method thereof
CN105400616A (en) * 2015-12-15 2016-03-16 广东环凯微生物科技有限公司 CIP alkaline cleaning agent with anti-freezing effect and preparation method therefor
CN105586168A (en) * 2015-12-30 2016-05-18 北京蓝星清洗有限公司 Water-based shellac-removing cleaning agent and preparation method thereof
CN105838511A (en) * 2016-04-11 2016-08-10 河南工程学院 A novel environmental-friendly automobile windshield washing concentrated liquid
CN105982630A (en) * 2015-01-29 2016-10-05 上海佳森科技有限公司 Cleaning dishcloth easy to remove oil and making method thereof
CN106676544A (en) * 2016-07-03 2017-05-17 丁玉琴 Preparation method for efficient environmental-friendly rustproof water-based metal cleaning agent
CN107488374A (en) * 2017-08-11 2017-12-19 航天凯天环保科技股份有限公司 It is a kind of for dust-proof modified dose of glass baking varnish material, modified glass baking varnish coating and its application
CN109704554A (en) * 2019-01-28 2019-05-03 深圳市普盛旺科技有限公司 A kind of removing surface layer of glass stress aqueous dose

Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
GB1603047A (en) * 1977-07-05 1981-11-18 Dotolo V Cleaners containing d-limonene
CN101798550A (en) * 2009-09-23 2010-08-11 河北农业大学 Antistatic automobile glass cleaning agent
CN102653708A (en) * 2011-12-21 2012-09-05 上海东昊油品有限公司 All-around automobile windshield washing agent

Patent Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
GB1603047A (en) * 1977-07-05 1981-11-18 Dotolo V Cleaners containing d-limonene
CN101798550A (en) * 2009-09-23 2010-08-11 河北农业大学 Antistatic automobile glass cleaning agent
CN102653708A (en) * 2011-12-21 2012-09-05 上海东昊油品有限公司 All-around automobile windshield washing agent

Cited By (10)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN104194964A (en) * 2014-07-30 2014-12-10 南昌印仁贸易有限公司 Automobile glass cleaner and preparation method thereof
CN104194964B (en) * 2014-07-30 2017-06-20 南昌印仁贸易有限公司 A kind of automobile glass cleaning agent and preparation method thereof
CN105982630A (en) * 2015-01-29 2016-10-05 上海佳森科技有限公司 Cleaning dishcloth easy to remove oil and making method thereof
CN105400616A (en) * 2015-12-15 2016-03-16 广东环凯微生物科技有限公司 CIP alkaline cleaning agent with anti-freezing effect and preparation method therefor
CN105586168A (en) * 2015-12-30 2016-05-18 北京蓝星清洗有限公司 Water-based shellac-removing cleaning agent and preparation method thereof
CN105838511A (en) * 2016-04-11 2016-08-10 河南工程学院 A novel environmental-friendly automobile windshield washing concentrated liquid
CN106676544A (en) * 2016-07-03 2017-05-17 丁玉琴 Preparation method for efficient environmental-friendly rustproof water-based metal cleaning agent
CN107488374A (en) * 2017-08-11 2017-12-19 航天凯天环保科技股份有限公司 It is a kind of for dust-proof modified dose of glass baking varnish material, modified glass baking varnish coating and its application
CN107488374B (en) * 2017-08-11 2020-02-14 航天凯天环保科技股份有限公司 Dustproof modifier for glass baking varnish material, modified glass baking varnish coating and application thereof
CN109704554A (en) * 2019-01-28 2019-05-03 深圳市普盛旺科技有限公司 A kind of removing surface layer of glass stress aqueous dose

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Application publication date: 20140326