CN107937161A - A kind of concentrated type antifog glass cleaning agent - Google Patents
A kind of concentrated type antifog glass cleaning agent Download PDFInfo
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- CN107937161A CN107937161A CN201711018252.7A CN201711018252A CN107937161A CN 107937161 A CN107937161 A CN 107937161A CN 201711018252 A CN201711018252 A CN 201711018252A CN 107937161 A CN107937161 A CN 107937161A
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- CN
- China
- Prior art keywords
- cleaning agent
- glass cleaning
- concentrated type
- antifog glass
- agent
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- 239000011521 glass Substances 0.000 title claims abstract description 42
- 239000012459 cleaning agent Substances 0.000 title claims abstract description 29
- RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 claims abstract description 29
- -1 polypropylene Polymers 0.000 claims abstract description 22
- 239000003795 chemical substances by application Substances 0.000 claims abstract description 14
- 239000004094 surface-active agent Substances 0.000 claims abstract description 14
- 239000003960 organic solvent Substances 0.000 claims abstract description 13
- 239000002738 chelating agent Substances 0.000 claims abstract description 11
- 239000004743 Polypropylene Substances 0.000 claims abstract description 7
- 229920001155 polypropylene Polymers 0.000 claims abstract description 7
- 229920001289 polyvinyl ether Polymers 0.000 claims abstract description 7
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Chemical compound O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 7
- 239000004372 Polyvinyl alcohol Substances 0.000 claims abstract description 5
- 125000000118 dimethyl group Chemical group [H]C([H])([H])* 0.000 claims abstract description 5
- 239000001866 hydroxypropyl methyl cellulose Substances 0.000 claims abstract description 5
- 235000010979 hydroxypropyl methyl cellulose Nutrition 0.000 claims abstract description 5
- 229920003088 hydroxypropyl methyl cellulose Polymers 0.000 claims abstract description 5
- UFVKGYZPFZQRLF-UHFFFAOYSA-N hydroxypropyl methyl cellulose Chemical compound OC1C(O)C(OC)OC(CO)C1OC1C(O)C(O)C(OC2C(C(O)C(OC3C(C(O)C(O)C(CO)O3)O)C(CO)O2)O)C(CO)O1 UFVKGYZPFZQRLF-UHFFFAOYSA-N 0.000 claims abstract description 5
- 229920001495 poly(sodium acrylate) polymer Polymers 0.000 claims abstract description 5
- 229920002451 polyvinyl alcohol Polymers 0.000 claims abstract description 5
- NNMHYFLPFNGQFZ-UHFFFAOYSA-M sodium polyacrylate Chemical compound [Na+].[O-]C(=O)C=C NNMHYFLPFNGQFZ-UHFFFAOYSA-M 0.000 claims abstract description 5
- 239000004205 dimethyl polysiloxane Substances 0.000 claims abstract description 4
- 235000013870 dimethyl polysiloxane Nutrition 0.000 claims abstract description 4
- 229920000435 poly(dimethylsiloxane) Polymers 0.000 claims abstract description 4
- 229920005573 silicon-containing polymer Polymers 0.000 claims abstract description 4
- 239000008367 deionised water Substances 0.000 claims abstract description 3
- 229910021641 deionized water Inorganic materials 0.000 claims abstract description 3
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 claims description 24
- 229940051841 polyoxyethylene ether Drugs 0.000 claims description 23
- 229920000056 polyoxyethylene ether Polymers 0.000 claims description 23
- 150000002191 fatty alcohols Chemical class 0.000 claims description 10
- 239000004519 grease Substances 0.000 claims description 10
- 150000001732 carboxylic acid derivatives Chemical class 0.000 claims description 9
- 229930182470 glycoside Natural products 0.000 claims description 9
- KFZMGEQAYNKOFK-UHFFFAOYSA-N Isopropanol Chemical compound CC(C)O KFZMGEQAYNKOFK-UHFFFAOYSA-N 0.000 claims description 8
- XFRVVPUIAFSTFO-UHFFFAOYSA-N 1-Tridecanol Chemical compound CCCCCCCCCCCCCO XFRVVPUIAFSTFO-UHFFFAOYSA-N 0.000 claims description 7
- QAOWNCQODCNURD-UHFFFAOYSA-L Sulfate Chemical compound [O-]S([O-])(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-L 0.000 claims description 7
- 229940073499 decyl glucoside Drugs 0.000 claims description 6
- 229930182478 glucoside Natural products 0.000 claims description 6
- 150000002338 glycosides Chemical class 0.000 claims description 6
- JVAZJLFFSJARQM-RMPHRYRLSA-N (2r,3r,4s,5s,6r)-2-hexoxy-6-(hydroxymethyl)oxane-3,4,5-triol Chemical compound CCCCCCO[C@@H]1O[C@H](CO)[C@@H](O)[C@H](O)[C@H]1O JVAZJLFFSJARQM-RMPHRYRLSA-N 0.000 claims description 5
- 239000000194 fatty acid Substances 0.000 claims description 5
- 150000004702 methyl esters Chemical class 0.000 claims description 5
- 150000003839 salts Chemical class 0.000 claims description 5
- 235000019387 fatty acid methyl ester Nutrition 0.000 claims description 3
- 239000000975 dye Substances 0.000 claims description 2
- 150000008131 glucosides Chemical class 0.000 claims description 2
- QYKIQEUNHZKYBP-UHFFFAOYSA-N Vinyl ether Chemical compound C=COC=C QYKIQEUNHZKYBP-UHFFFAOYSA-N 0.000 claims 2
- JDRSMPFHFNXQRB-IWQYDBTJSA-N (3r,4s,5s,6r)-2-decoxy-6-(hydroxymethyl)oxane-3,4,5-triol Chemical group CCCCCCCCCCOC1O[C@H](CO)[C@@H](O)[C@H](O)[C@H]1O JDRSMPFHFNXQRB-IWQYDBTJSA-N 0.000 claims 1
- 239000000796 flavoring agent Substances 0.000 claims 1
- 235000019634 flavors Nutrition 0.000 claims 1
- 125000002347 octyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 claims 1
- 238000004140 cleaning Methods 0.000 abstract description 18
- 230000000694 effects Effects 0.000 abstract description 9
- 235000019441 ethanol Nutrition 0.000 description 15
- 238000000034 method Methods 0.000 description 6
- 238000006116 polymerization reaction Methods 0.000 description 6
- 239000003595 mist Substances 0.000 description 4
- 239000006185 dispersion Substances 0.000 description 3
- 239000005357 flat glass Substances 0.000 description 3
- 239000000463 material Substances 0.000 description 3
- JDRSMPFHFNXQRB-CMTNHCDUSA-N Decyl beta-D-threo-hexopyranoside Chemical compound CCCCCCCCCCO[C@@H]1O[C@H](CO)C(O)[C@H](O)C1O JDRSMPFHFNXQRB-CMTNHCDUSA-N 0.000 description 2
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 2
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical class O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 2
- PMZURENOXWZQFD-UHFFFAOYSA-L Sodium Sulfate Chemical compound [Na+].[Na+].[O-]S([O-])(=O)=O PMZURENOXWZQFD-UHFFFAOYSA-L 0.000 description 2
- 150000001875 compounds Chemical class 0.000 description 2
- 238000005516 engineering process Methods 0.000 description 2
- 238000011156 evaluation Methods 0.000 description 2
- 238000007654 immersion Methods 0.000 description 2
- 239000000203 mixture Substances 0.000 description 2
- 238000012986 modification Methods 0.000 description 2
- 230000004048 modification Effects 0.000 description 2
- 238000004806 packaging method and process Methods 0.000 description 2
- 238000011056 performance test Methods 0.000 description 2
- 229910052708 sodium Inorganic materials 0.000 description 2
- 239000011734 sodium Substances 0.000 description 2
- 229910052938 sodium sulfate Inorganic materials 0.000 description 2
- IAYPIBMASNFSPL-UHFFFAOYSA-N Ethylene oxide Chemical compound C1CO1 IAYPIBMASNFSPL-UHFFFAOYSA-N 0.000 description 1
- WQZGKKKJIJFFOK-GASJEMHNSA-N Glucose Natural products OC[C@H]1OC(O)[C@H](O)[C@@H](O)[C@@H]1O WQZGKKKJIJFFOK-GASJEMHNSA-N 0.000 description 1
- 229920003171 Poly (ethylene oxide) Polymers 0.000 description 1
- QAOWNCQODCNURD-UHFFFAOYSA-N Sulfuric acid Chemical compound OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 description 1
- 230000032683 aging Effects 0.000 description 1
- 150000001335 aliphatic alkanes Chemical class 0.000 description 1
- 150000003863 ammonium salts Chemical class 0.000 description 1
- 238000003287 bathing Methods 0.000 description 1
- 230000003796 beauty Effects 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 238000009835 boiling Methods 0.000 description 1
- 229910052799 carbon Inorganic materials 0.000 description 1
- 230000003749 cleanliness Effects 0.000 description 1
- 239000011248 coating agent Substances 0.000 description 1
- 238000000576 coating method Methods 0.000 description 1
- 229920001577 copolymer Polymers 0.000 description 1
- 238000011161 development Methods 0.000 description 1
- 230000018109 developmental process Effects 0.000 description 1
- 238000007865 diluting Methods 0.000 description 1
- 238000010790 dilution Methods 0.000 description 1
- 239000012895 dilution Substances 0.000 description 1
- 239000000428 dust Substances 0.000 description 1
- 238000005265 energy consumption Methods 0.000 description 1
- 238000001125 extrusion Methods 0.000 description 1
- 239000008103 glucose Substances 0.000 description 1
- 239000011159 matrix material Substances 0.000 description 1
- 239000003755 preservative agent Substances 0.000 description 1
- 230000002335 preservative effect Effects 0.000 description 1
- 238000012545 processing Methods 0.000 description 1
- QQONPFPTGQHPMA-UHFFFAOYSA-N propylene Natural products CC=C QQONPFPTGQHPMA-UHFFFAOYSA-N 0.000 description 1
- 125000004805 propylene group Chemical group [H]C([H])([H])C([H])([*:1])C([H])([H])[*:2] 0.000 description 1
- 238000010926 purge Methods 0.000 description 1
- 239000002994 raw material Substances 0.000 description 1
- 238000009991 scouring Methods 0.000 description 1
- 150000004760 silicates Chemical class 0.000 description 1
- 239000000377 silicon dioxide Substances 0.000 description 1
- 235000011152 sodium sulphate Nutrition 0.000 description 1
- 239000002904 solvent Substances 0.000 description 1
- 235000013599 spices Nutrition 0.000 description 1
- 239000007921 spray Substances 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 238000012360 testing method Methods 0.000 description 1
- 238000002604 ultrasonography Methods 0.000 description 1
- 125000000391 vinyl group Chemical group [H]C([*])=C([H])[H] 0.000 description 1
- 229920002554 vinyl polymer Polymers 0.000 description 1
- 238000005406 washing Methods 0.000 description 1
- 238000005303 weighing Methods 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/66—Non-ionic compounds
- C11D1/83—Mixtures of non-ionic with anionic compounds
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09K—MATERIALS FOR MISCELLANEOUS APPLICATIONS, NOT PROVIDED FOR ELSEWHERE
- C09K3/00—Materials not provided for elsewhere
- C09K3/18—Materials not provided for elsewhere for application to surfaces to minimize adherence of ice, mist or water thereto; Thawing or antifreeze materials for application to surfaces
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/66—Non-ionic compounds
- C11D1/825—Mixtures of compounds all of which are non-ionic
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/20—Organic compounds containing oxygen
- C11D3/2003—Alcohols; Phenols
- C11D3/2006—Monohydric alcohols
- C11D3/201—Monohydric alcohols linear
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/20—Organic compounds containing oxygen
- C11D3/2003—Alcohols; Phenols
- C11D3/2006—Monohydric alcohols
- C11D3/2017—Monohydric alcohols branched
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/20—Organic compounds containing oxygen
- C11D3/22—Carbohydrates or derivatives thereof
- C11D3/222—Natural or synthetic polysaccharides, e.g. cellulose, starch, gum, alginic acid or cyclodextrin
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/37—Polymers
- C11D3/3703—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
- C11D3/373—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds containing silicones
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/37—Polymers
- C11D3/3746—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
- C11D3/3753—Polyvinylalcohol; Ethers or esters thereof
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/02—Anionic compounds
- C11D1/12—Sulfonic acids or sulfuric acid esters; Salts thereof
- C11D1/29—Sulfates of polyoxyalkylene ethers
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/66—Non-ionic compounds
- C11D1/662—Carbohydrates or derivatives
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/66—Non-ionic compounds
- C11D1/72—Ethers of polyoxyalkylene glycols
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/66—Non-ionic compounds
- C11D1/74—Carboxylates or sulfonates esters of polyoxyalkylene glycols
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Organic Chemistry (AREA)
- Life Sciences & Earth Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Wood Science & Technology (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Health & Medical Sciences (AREA)
- Emergency Medicine (AREA)
- Molecular Biology (AREA)
- Combustion & Propulsion (AREA)
- Materials Engineering (AREA)
- Detergent Compositions (AREA)
Abstract
The invention discloses a kind of concentrated type antifog glass cleaning agent, it includes component and percetage by weight it is as follows：Surfactant 10~30%, chelation agent 0.1~2%, surface filming agent 0.1~2%, organic solvent 0~25%, and the deionized water of surplus.Wherein, the surface filming agent is at least one of the block modified dimethyl silicone polymer of polyvinylether polypropylene ether, polyvinylether modified dimethyl polysiloxane, polypropylene ether modified dimethyl polysiloxane, Sodium Polyacrylate, polyvinyl alcohol and hydroxypropyl methyl cellulose.Wherein, it is miscible that surfactant, chelation agent and surface filming agent only need a small amount of organic solvent to be cooperateed with even without addition organic solvent, not only there is preferable cleaning, surface effect and anti-fog effect, but also VOC emission amount can be substantially reduced, it is more environmentally-friendly.
Description
Technical field
The present invention relates to cleaning agent technical field, and in particular to a kind of concentrated type antifog glass cleaning agent.
Background technology
Glass is a kind of silicates nonmetallic materials, is had the advantages that beautiful, applicable.It is widely used in building curtain wall,
Container etc..Glass easily adheres to the dirts such as dust, greasy dirt.Need to use intermediate medium in glassware process, processing
Removing etc. is needed into rear.
In the winter time, larger with the indoor temperature difference because outdoor temperature is relatively low, window-glass surface easily forms fog, influences to adopt
Also easily there is very thin mist film, influence driver's sight in light, windshield；Indoor washing mirror is bathed after bathing also to hold
Mist film is easily formed, can not temporarily use etc. factor, the life to people to bring inconvenience.
Glass cleaner currently on the market is most only to have a simple cleaning action, few concentrated products and with preventing
The function of mist.Furthermore the glass cleaner of in the market is mostly plain edition, more than 95% is all water in content, adds product
Packaging and cost of transportation etc., do not meet the low-carbon economy theory that country advocates.In conclusion develop a kind of concentration, have it is anti-
The glass cleaner of mist effect becomes a kind of trend.
To remove the dirt for being deposited on above-mentioned surface, the composition that crust is cleaned in this area by relatively broad is visited
Beg for and studied.Usual way is the aqueous cleaning agent used using alkaline ammonium class as matrix, but its cleaning performance is not mostly special
Not preferable, the cleaning agent using conventional surfactants as base leaves a considerable amount of striated on above-mentioned hard, glossy surface
Or the uneven residue of cloud or dispersion trace, influence beauty.This problem becomes when after being cleaned with composition without rinsing
It is more prominent.Especially in glass surface, glass surface and glassware process inside and outside purge chamber, problems are more prominent.
Shu Weiguo (a kind of new glass cleaner chemical cleaning .1993, (4):34-35) novel glass of exploitation is clear
Lotion, the system formed with nonionic surfactant agent, organic solvent and additive, using clean mode, clean effect compared with
Get well, glass surface noresidue, but have the solvent of certain toxicity using butyl glycol ether, acetone, VOC content is higher.And use
The surfactant for having teratogenesis risk that nonylphenol polyoxyethylene ether classification front glass cleaning agent national standard limits the use of.
(development of environment-friendly type glass cleaner, Aviation Engineering Institutes Of Nanchang's journal (natural science such as Zhong Jingmao, Tang Xinghua
Version), 2003,17 (4)：A kind of environment-friendly type glass cleaner 45-47) is developed, by fatty alcohol polyoxyethylene ether (AEO-9), fat
Fat acid alkanolamide (6501), sodium sulfate of polyethenoxy ether of fatty alcohol (AES), absolute ethyl alcohol and auxiliary agent etc. form, without washing,
But its ethanol usage amount relatively up to 18%, VOC emission is larger.
Tang Zhiping (CN103740494A, a kind of glass pane detergent and preparation method thereof), invention are related to a kind of glass pane
Detergent and preparation method thereof, glass surface quick-drying after cleaning, it is bright the advantages of.With ammonium in dodecyl dimethyl propane sulfonic acid
For surfactant, using propylene glycol monobutyl ether, ethylene glycol and isopropanol as solvent, auxiliary agent sodium pyrophosphate etc..It uses relatively large
Propandiol butyl ether, isopropanol etc., total amount is close to 50%.
Jiang Linyue, Zhou Yanlin etc. have invented concentration type antifog glass cleaning agent (CN102071115B), are related to a kind of concentration
Type antifog glass detergent, its component and its mass fraction are：0.1~1 part of ammonium hydroxide, 0.1~5 part of triethanolamine, surface-active
1~20 part of agent, 0.1~10 part of film forming agent (high polymer), 1~50 part of ethanol, 0.1~5 part of chelating agent.It is formed in glass surface
A kind of thinner and uniform moisture film, make it is dry more rapidly, surface-brightening, and do not have stain and striped, but it use and have
The triethanolamine of certain toxicity.
Above-mentioned most organic solvents (foregoing four for even having certain toxicity due to containing more organic solvent in component
Piece document), or need to carry out the effect (CN103740494A) that rinsing can be only achieved light, otherwise it is also easy to produce the residual stain shadow of striated
Ring beautiful.Both process is added, reduces work efficiency, while also increase cost.
The content of the invention
Therefore, contain more organic solvent for glass cleaner in the prior art and be also easy to produce the residual stain of striated
Technical problem, it is an object of the invention to provide a kind of concentrated type antifog glass cleaning agent, can take into account cleaning at the same time and surface is clear
Cleanliness, can effectively be cleaned, even and if after cleaning not according to the dirt weight on cleaned material surface in the form of diluted
It will not leave behind through rinsing or hardly leave obvious striped, and with certain anti-fog effect.
The component and percetage by weight that the concentrated type antifog glass cleaning agent of the present invention includes are as follows：
Surfactant：10~30%,
Chelation agent：0.1~2%,
Surface filming agent：0.1~2%,
Organic solvent：0~25%, and
Deionized water：Surplus；
Wherein, the surfactant includes fatty acid methyl ester ethoxylate, modified grease ethoxylate, isomery alcohol
At least one of polyoxyethylene ether and fatty alcohol polyoxyethylene ether sulfate, and alkyl glycosides.
The chelation agent is C6~24Fatty alcohol polyoxyethylene ether carboxylic acid and/or its salt；
The surface filming agent is the block modified dimethyl silicone polymer of polyvinylether polypropylene ether, polyvinylether is modified and gathers
Dimethyl siloxane, polypropylene ether modified dimethyl polysiloxane, Sodium Polyacrylate, polyvinyl alcohol and hydroxypropyl methyl cellulose
At least one of.
The organic solvent is ethanol and/or isopropanol.
Preferably, the surfactant includes C12~24Fatty acid methyl ester ethoxylate, C12~24Modified grease ethyoxyl
Compound, C10~16Isomeric alcohol polyethenoxy ether and C10~16At least one of fatty alcohol polyoxyethylene ether sulfate, and C6~12Alkane
Base glucosides, the surfactant total content preferably 10~25% more preferably 18~25%.
It is further preferred that the surfactant includes the C of total content 1%~10%12~14Fatty acid methyl ester ethyoxyl
Compound, C12~14Modified grease ethoxylate, isomerous tridecanol polyoxyethylene ether and C12~14Fatty alcohol polyoxyethylene ether sulfate
At least one of, and the C of total content 3%~20%6~10Alkyl glycosides.
Preferably, the degree of polymerization (ethyoxyl quantity) preferably 1~20 more preferably 4 in fatty acid methyl ester ethoxylate~
15。
Preferably, the ethyoxyl addition quality in modified grease ethoxylate account for modified grease quality 10%~
70%, C12~14Preferably 20%~60% in modified grease ethoxylate.
Preferably, the degree of polymerization (ethyoxyl quantity) of isomeric alcohol polyethenoxy ether for 1~20 preferably 3~15 more preferably 5~
8.For example the preferred isomerous tridecanol polyoxyethylene of isomerous tridecanol polyoxyethylene ether (3~15) ether, more preferably isomerous tridecanol gather
Ethylene oxide (5~8) ether.
Preferably, the degree of polymerization of fatty alcohol polyoxyethylene ether sulfate is 1~10 preferably 1~8 more preferably 2~5.Such as
C12~14The preferred C of fatty alcohol polyoxyethylene ether sulfate12~14Aliphatic alcohol polyethenoxy (2~5) ether sodium sulfate (AES).
Preferably, C6~10Alkyl glycosides is preferably octyl-decyl glucoside (APG0810, i.e. C8~10Fatty alcohol glucose
Glycosides), decyl glucoside (APG IC10), isomeric octyls glucoside (APGIC08) and hexyl glucoside (APG IC06)
At least one of.
It is further preferred that C6~10Alkyl glycosides includes the octyl-decyl glucoside of total content 5%~7%, Yi Jizong
The hexyl glucoside of content 5%~6%.
The preferred C of chelation agent10~16More preferably C12~14Fatty alcohol polyoxyethylene ether carboxylic acid and/or its salt.
The chelation agent total content is preferably 0.1~0.5%.
Preferably, the degree of polymerization of fatty alcohol polyoxyethylene ether carboxylic acid and/or its salt (ethyoxyl quantity) is 5~10 preferably 7
~9.
Preferably, the surface filming agent total content is 0.1~1%.
The surface filming agent for polyvinylether polypropylene ether block modified dimethyl silicone polymer when, wherein vinyl polymerization
Degree preferably 5~25 more preferably 10~20, the degree of polymerization of propylene is 10~30 more preferably 15~25.
Preferably, according to actual needs, concentrated type antifog glass cleaning agent of the invention can also add suitable water solubility
Spices, dyestuff etc., assign its apparent uniqueness, impression, preservative feature.
The total content of above-mentioned each component refers both to content of each component in concentrated type antifog glass cleaning agent.
The beneficial effects of the present invention are：
1. in the concentrated type antifog glass cleaning agent of the present invention, surfactant, chelation agent and surface filming agent association
Same-action, with preferable cleaning and surface effect, residue is few after glass cleaning, does not form dispersion streak marks；It is wherein outstanding
It is the Siloxane-Oxyalkylene Copolymers as surface filming agent, Sodium Polyacrylate, polyvinyl alcohol and hydroxypropyl methyl cellulose
Use, can not only slow down the function that glass surface washes rear trace and recontamination, but also with preferable anti-fog effect.
2. in the concentrated type antifog glass cleaning agent of the present invention, surfactant, chelation agent and surface filming agent are only
Need a small amount of organic solvent to be cooperateed with even without addition organic solvent miscible, contain a large amount of organic solvents compared to existing
Glass cleaner, concentrated type antifog glass cleaning agent of the invention can substantially reduce VOC emission amount, more environmentally-friendly.
3. the present invention is concentrated type antifog glass cleaning agent, energy consumption, packaging, cost of transportation etc. can be reduced.The cleaning agent
More than 10 times ratios use as needed during use, can need not rinse and reach bright such as new, still have when diluting more than 50 times
Preferable cleaning and surface effect.
In addition, concentrated type antifog glass cleaning agent of the invention can use the modes such as immersion, ultrasound, spray, scouring to remove
Spot on glass surface.
Embodiment
Below in conjunction with specific embodiment, the invention will be further described.It is to be understood that following embodiments are merely to illustrate this
Invention is not for restriction the scope of the present invention.
Embodiment 1~15
According to the component formula shown in table 1, the concentrated type antifog glass cleaning agent of the configuration embodiment of the present invention 1~15.
The component and percetage by weight of 1 embodiment 1~15 of table
On connect table 1
On connect table 1
Each raw material is purchased from above：
Shanghai Fakai Chemical Co., Ltd.：C8~10Fatty alcohol glucoside (APG0810), isomeric octyls glucoside
(APGIC08), decyl glucoside (APG IC10), hexyl glucoside (APG IC06), C12~14Fatty alcohol polyoxyethylene ether
Carboxylic acid (AEC7H), C12~14AEO carboxylic acid sodium (AEC9Na), C12~14Fatty alcohol polyoxyethylene ether carboxylic acid
(AEC9H)、C12~14AEO carboxylic acid sodium (AEC7Na)；
Zhong Qing daily use chemicals Science and Technology Ltd.：C12~14Fatty alcohol polyoxyethylene ether, C12~14Fatty acid methyl ester ethoxylate
(FMEE), modified grease ethoxylate (SOE-N-60)；
Sinolight Chemical Co., Ltd.：C12~14Sodium sulfate of polyethenoxy ether of fatty alcohol (AES)；
BASF：Isomerous tridecanol polyoxyethylene ether (EO8), isomerous tridecanol polyoxyethylene ether (EO5)；
The U.S. fluosilicic new material limited company of Guangdong mark：The modified poly- silica of polyoxyethylene ether (10) polyethenoxy ether (15)
Alkane；Polyoxyethylene ether (20) polyethenoxy ether (25) modified polyorganosiloxane；
Jiangmen city Zhong Sheng bio tech ltd：Sodium Polyacrylate；
Jiangsu Yonghua Fine Chemical Co., Ltd.：Polyvinyl alcohol；
Ke Naiou trade Co., Ltds：Hydroxypropyl methyl cellulose；
Shanghai Ling Feng chemical reagent Co., Ltd：Ethanol, isopropanol.
The performance test results：
So far, glass cleaner has professional standard QB/T 4086-2010, but cleaning force method is not explained,
The present invention is with reference to method (development of environment-friendly type glass cleaner, the Nanchang aircraft industry in the documents such as foregoing Zhong Jingmao, Tang Xinghua
Institute's journal (natural science edition), 2003,17 (4)：45-47), dirt extrusion rate is determined using weighing method.
Dirt removal rate：Using glass slide (size 25.4mm × 76.2mm × (1~1.2mm)) as evaluation test piece,
Using the method for coating artificial dirt through 70 DEG C of aging 4h, after ultrasonic 5min cleanings, naturally dry, with the transparent modeling of equal size
Flitch, length and width distinguish 20 deciles and 5 deciles, form 100 spaces, overlap control, are accounted for according to the residual of the dirt on slide two sides
Evaluated than definite dirt removal rate, and to glass-board surface situation.Embodiment 1~15 dilutes 50 times and is evaluated.
Surface condition and anti-fog performance after cleaning：With above-mentioned sheet glass and diluted cleaning agent, to be done naturally after immersion
Range estimation surface condition after dry, and it is anti-fog properties with the transparent situation evaluation in surface that dried sheet glass contacts on boiling water with fog
Energy.
2 embodiment of table, 1~15 cleaning performance and anti-fog performance test result
As shown in Table 2, still there is preferable cleaning and table during 50 times of of the invention concentrated type antifog glass cleaning dilution agent
Face effect, cleans easily and dirt removal rate is up to more than 70%, wherein the dirt removal rate of especially embodiment 1,4 and 12 can
Up to 90%.And in terms of striped residual, the various embodiments described above cleaning after the bright and clean residue of glass surface it is few, only embodiment 2,3,
7th, there is micro striped after 11,14 cleanings, remaining does not form dispersion streak marks, and glass surface can be made to keep very high transparent
Degree.And in terms of anti-fog performance, and embodiment 1~15 is respectively provided with preferable anti-fog effect.
In addition, as shown in Table 1, organic solvent content in concentrated type antifog glass cleaning agent of the invention is less (to be less than
30%) discharge capacity of VOC, is greatly reduced.Especially embodiment 1,4,5,9,10,12,15 is not added with organic solvent ethanol
Or isopropanol, it is more environmentally-friendly, and its cleaning performance and unaffected, in addition embodiment 1,4 and 12 than other added with organic
The cleaning performance of the embodiment of solvent will also be got well.
The preferred embodiment to the invention is illustrated above, but the invention be not limited to it is described
Embodiment, those skilled in the art can also make a variety of equivalent on the premise of without prejudice to the invention spirit
Modification or replacement, these equivalent modifications or replacement are all contained in the application claim limited range.
Claims (9)
- A kind of 1. concentrated type antifog glass cleaning agent, it is characterised in that percentage, it includes：Surfactant：10~30%,Chelation agent：0.1~2%,Surface filming agent：0.1~2%,Organic solvent：0~25%, andDeionized water：Surplus；Wherein, the surfactant includes fatty acid methyl ester ethoxylate, modified grease ethoxylate, isomery alcohol polyoxy At least one of vinethene and fatty alcohol polyoxyethylene ether sulfate, and alkyl glycosides；The chelation agent is C6~24Fatty alcohol polyoxyethylene ether carboxylic acid and/or its salt；The surface filming agent is the block modified dimethyl silicone polymer of polyvinylether polypropylene ether, polyvinylether is modified poly- diformazan In radical siloxane, polypropylene ether modified dimethyl polysiloxane, Sodium Polyacrylate, polyvinyl alcohol and hydroxypropyl methyl cellulose It is at least one.
- 2. concentrated type antifog glass cleaning agent according to claim 1, it is characterised in that the organic solvent is ethanol And/or isopropanol.
- 3. concentrated type antifog glass cleaning agent according to claim 1, it is characterised in that the surfactant includes C12~24Fatty acid methyl ester ethoxylate, C12~24Modified grease ethoxylate, C10~16Isomeric alcohol polyethenoxy ether and C10~16 At least one of fatty alcohol polyoxyethylene ether sulfate, and C6~12Alkyl glycosides.
- 4. concentrated type antifog glass cleaning agent as stated in claim 3, it is characterised in that the surfactant includes always containing The C of amount 1%~10%12~14Fatty acid methyl ester ethoxylate, C12~14Modified grease ethoxylate, isomerous tridecanol polyoxy Vinethene and C12~14At least one of fatty alcohol polyoxyethylene ether sulfate, and the C of total content 3%~20%6~10Alkyl Glucosides.
- 5. concentrated type antifog glass cleaning agent according to claim 4, it is characterised in that C6~10Alkyl glycosides is the octyl group last of the ten Heavenly stems At least one of base glucoside, decyl glucoside, isomeric octyls glucoside and hexyl glucoside.
- 6. concentrated type antifog glass cleaning agent according to claim 5, it is characterised in that C6~10Alkyl glycosides includes always containing The octyl-decyl glucoside of amount 5%~7%, and the hexyl glucoside of total content 5%~6%.
- 7. concentrated type antifog glass cleaning agent according to claim 1, it is characterised in that the chelation agent is C10~16 Fatty alcohol polyoxyethylene ether carboxylic acid and/or its salt, total content are 0.1~0.5%.
- 8. concentrated type antifog glass cleaning agent according to claim 1, it is characterised in that the surface filming agent total content For 0.1~1%.
- 9. concentrated type antifog glass cleaning agent according to claim 1, it is characterised in that it also includes water soluble flavours And/or dyestuff.
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| CN201711018252.7A CN107937161A (en) | 2017-10-26 | 2017-10-26 | A kind of concentrated type antifog glass cleaning agent |
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| CN109135673A (en) * | 2018-08-24 | 2019-01-04 | 广州番禺职业技术学院 | A kind of formula and its application method of lens antifogging spray |
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| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102071115A (en) * | 2011-01-24 | 2011-05-25 | 北京洛娃日化有限公司 | Concentration type antifog glass cleaning agent |
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2017
- 2017-10-26 CN CN201711018252.7A patent/CN107937161A/en active Pending
- 2017-10-26 CN CN202311699889.2A patent/CN117925329A/en active Pending
Patent Citations (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102071115A (en) * | 2011-01-24 | 2011-05-25 | 北京洛娃日化有限公司 | Concentration type antifog glass cleaning agent |
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| CN109135673A (en) * | 2018-08-24 | 2019-01-04 | 广州番禺职业技术学院 | A kind of formula and its application method of lens antifogging spray |
| CN109337767A (en) * | 2018-11-16 | 2019-02-15 | 杭州米土新材料科技有限公司 | A kind of Self-cleaning type outdoor glass bi-component detergent and its preparation and application |
| CN109337767B (en) * | 2018-11-16 | 2021-08-10 | 杭州米土新材料科技有限公司 | Self-cleaning type outdoor glass dual-component cleaning agent and preparation and use methods thereof |
| CN109762672A (en) * | 2019-01-15 | 2019-05-17 | 佛山德联汽车用品有限公司 | A kind of automobile windscreen cleaning agent |
| CN109810672A (en) * | 2019-03-06 | 2019-05-28 | 深圳永合高分子材料有限公司 | A kind of antifog combination agent, biaxial tension sheet material and molded product |
| CN110066639A (en) * | 2019-04-17 | 2019-07-30 | 上海和黄白猫有限公司 | A kind of anti-scratch type glass antidimmer and preparation method thereof |
| CN111019767A (en) * | 2019-10-21 | 2020-04-17 | 广东莱雅新化工科技有限公司 | Aerosol with deoiling and antifogging functions |
| CN113046196A (en) * | 2019-12-27 | 2021-06-29 | 张家港迪克汽车化学品有限公司 | Solid cleaning liquid concentrating agent and preparation method and application thereof |
| CN113046196B (en) * | 2019-12-27 | 2024-06-21 | 张家港迪克汽车化学品有限公司 | Solid cleaning liquid concentrate and preparation method and application thereof |
| CN111154560A (en) * | 2020-01-08 | 2020-05-15 | 维达力实业(深圳)有限公司 | Glass cleaning agent, and preparation method and application thereof |
| CN111574960A (en) * | 2020-05-12 | 2020-08-25 | 浙江优亿医疗器械有限公司 | Formula and preparation method of antifogging liquid |
| CN112403140A (en) * | 2020-10-19 | 2021-02-26 | 傅光明 | Smoke-eliminating and dust-removing agent and preparation method thereof |
| CN113214917A (en) * | 2021-02-07 | 2021-08-06 | 广东莱雅新化工科技有限公司 | Anti-freezing automobile glass cleaning agent and preparation method thereof |
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Application publication date: 20180420 |