CN109337767A - A kind of Self-cleaning type outdoor glass bi-component detergent and its preparation and application - Google Patents
A kind of Self-cleaning type outdoor glass bi-component detergent and its preparation and application Download PDFInfo
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- CN109337767A CN109337767A CN201811367617.1A CN201811367617A CN109337767A CN 109337767 A CN109337767 A CN 109337767A CN 201811367617 A CN201811367617 A CN 201811367617A CN 109337767 A CN109337767 A CN 109337767A
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- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/66—Non-ionic compounds
- C11D1/83—Mixtures of non-ionic with anionic compounds
-
- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C17/00—Surface treatment of glass, not in the form of fibres or filaments, by coating
- C03C17/28—Surface treatment of glass, not in the form of fibres or filaments, by coating with organic material
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- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/20—Organic compounds containing oxygen
- C11D3/2003—Alcohols; Phenols
- C11D3/2065—Polyhydric alcohols
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- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/20—Organic compounds containing oxygen
- C11D3/22—Carbohydrates or derivatives thereof
- C11D3/222—Natural or synthetic polysaccharides, e.g. cellulose, starch, gum, alginic acid or cyclodextrin
- C11D3/225—Natural or synthetic polysaccharides, e.g. cellulose, starch, gum, alginic acid or cyclodextrin etherified, e.g. CMC
-
- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C2217/00—Coatings on glass
- C03C2217/70—Properties of coatings
- C03C2217/76—Hydrophobic and oleophobic coatings
-
- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C2218/00—Methods for coating glass
- C03C2218/10—Deposition methods
- C03C2218/11—Deposition methods from solutions or suspensions
- C03C2218/112—Deposition methods from solutions or suspensions by spraying
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/008—Polymeric surface-active agents
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/02—Anionic compounds
- C11D1/12—Sulfonic acids or sulfuric acid esters; Salts thereof
- C11D1/22—Sulfonic acids or sulfuric acid esters; Salts thereof derived from aromatic compounds
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- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/02—Anionic compounds
- C11D1/12—Sulfonic acids or sulfuric acid esters; Salts thereof
- C11D1/29—Sulfates of polyoxyalkylene ethers
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/66—Non-ionic compounds
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- Chemical Kinetics & Catalysis (AREA)
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Abstract
The invention discloses a kind of Self-cleaning type outdoor glass bi-component detergent and its preparation and application, the two-component detergent is divided into cleaning solution and at two kinds of cleansing of film liquid, percentage, the cleaning solution is composed of the following components: surfactant 10 ~ 40%, auxiliary agent 3 ~ 20%, surplus are deionized water；Described composed of the following components at film liquid: surfactant 5 ~ 40%, auxiliary agent 5 ~ 20%, film forming agent 3 ~ 6%, surplus are deionized water；The auxiliary agent is one or more mixtures of glycerine, ethyl alcohol, sodium alkyl sulfate.Cleaning of the detergent of bi-component of the invention especially suitable for glass surfaces such as photovoltaic battery panel, glass curtain wall and auto mirrors, detergent decontamination of the invention, ability of keeping a public place clean are strong, the preparation method simple process of detergent, it is wide to prepare raw material sources, preparation process equipment investment is small, is advantageously implemented industrialized production.
Description
Technical field
The present invention relates to detergent fields, and in particular to a kind of Self-cleaning type outdoor glass bi-component detergent and its preparation and
Application method.
Background technique
Currently, outdoor glass types both domestic and external are more, but since outdoor glass is there are solarization sandy soil contamination amount is larger, together
Shi Jingchang has the accumulation such as bird excrement, although the pollution without heavy oil pollution is big, the pollutant gathered is more complicated, and existing
Detergent the problems such as all to there is dirt-removing power poor, and cleaning difficulty is big, and persistence is inadequate, influence illumination and beauty, especially
The cleaning problem of photovoltaic battery panel, photovoltaic power generation are the green energy resources that current country actively advocates development, but in photovoltaic cell
While plate absorption solar energy is converted into electric energy, inevitably the invasion by dust in air, make solar panel over time
One layer of dust is coverd with, the assimilation effect of solar energy is obstructed, to influence photovoltaic power generation, this is also a great problem of photovoltaic power generation.
Summary of the invention
It is an object of the invention to solve the shortcomings of the prior art, it is clear to provide a kind of Self-cleaning type outdoor glass bi-component
Clean dose and its preparation and application, detergent of the invention have the advantages that cleaning capacity is strong and has self-cleaning ability.
A kind of Self-cleaning type outdoor glass bi-component detergent, it is characterised in that bi-component detergent is divided into cleaning solution and film forming
Two kinds of cleansings of liquid, percentage, the cleaning solution are composed of the following components: surfactant 10~40% helps
Agent 3~20%, surplus are deionized water；It is described composed of the following components at film liquid: surfactant 5~40%, auxiliary agent 5~
20%, film forming agent 3~6%, surplus is deionized water；The auxiliary agent be one of glycerine, ethyl alcohol, sodium alkyl sulfate or
Two or more mixtures.
A kind of Self-cleaning type outdoor glass bi-component detergent, it is characterised in that surfactant is fatty alcohol polyoxy
Ethylene ether sodium sulfate (AES), fatty alcohol polyoxyethylene ether ammonium sulfate (AESA), fatty diglycollic amide (6501), alkylbenzene
One or more mixtures of dilute base sodium sulfonate (AOS) of sulfonic acid (LAS), α-.
A kind of Self-cleaning type outdoor glass bi-component detergent, it is characterised in that film forming agent be hydroxyethyl cellulose,
One or both of hydroxypropyl methyl cellulose mixture.
The preparation method of a kind of Self-cleaning type outdoor glass bi-component detergent, it is characterised in that including following mistake
Journey:
1) preparation of cleaning solution: after the various components of cleaning solution are measured respectively, putting into reaction kettle, opens stirring,
0~40 DEG C of temperature of control is kept stirring 300~500r/min of revolving speed, after stirring 20~30min, by mixed liquor from reaction kettle
Filtering is released, filtrate packaging obtains cleaning solution；
2) at the preparation of film liquid: it after being measured respectively at the various components of film liquid, puts into reaction kettle, opens stirring,
0~40 DEG C of temperature of control is kept stirring 600~800r/min of revolving speed, after stirring 30~40min, by mixed liquor from reaction kettle
Filtering is released, filtrate packaging obtains into film liquid.
The application method of a kind of Self-cleaning type outdoor glass bi-component detergent, it is characterised in that including following step
It is rapid:
S1 cleaning process: cleaning solution tap water is first diluted 30~50 times, stirs evenly, the cleaning solution after dilution is sprayed at
The surface of glass, makes glass surface wetting a period of time, and subsequent glass surface is rinsed well with clear water；
S2 keeps a public place clean process: will spend ionized water at film liquid and dilute 20~40 times, and stir evenly, by being sprayed at after dilution at film liquid
The glass surface cleaned up, soaks glass surface, after spontaneously drying, forms the decontamination of layer of transparent in glass surface
Film, i.e. glass surface are kept a public place clean completion.
Compared with the existing technology, the beneficial effect that the present invention obtains is:
(1) detergent of bi-component of the invention is especially suitable for photovoltaic battery panel, glass curtain wall and auto mirror
The cleaning of equal glass surfaces, the present invention provides it is a kind of it is easy, cleaning effect is obvious, a kind of low-cost novel self-cleaning formula room
The preparation method of outer glass cleaner is conducive to promote and apply, and detergent decontamination of the invention, ability of keeping a public place clean are strong, detergent
Preparation method simple process, prepares that raw material sources are wide, and preparation process equipment investment is small, is advantageously implemented industrialized production.
(2) when being cleaned using detergent of the invention to glass, first the dust of glass surface is cleaned with cleaning solution
After clean, in glass surface sprinkling at film liquid, after film liquid drying, the decontamination film of layer of transparent, decontamination are formed in glass surface
Film surface is smooth, and thus decontamination film surface is not easy to save bit by bit dust, can effectively extend keeping a public place clean the time limit for glass, the rain when outdoor is rained
Water is easy to rinse out the dust on decontamination film, achievees the effect that nature decontamination, and detergent through the invention carries out glass
Cleaning, primary cleaning can keep glass surface to clean 2~3 months.Decontamination film on glass after a period of use, due to going
Dirty film is stronger in the adhesion strength of glass surface, need to be scrubbed the decontamination film on glass by using hairbrush and cleaning solution of the invention
Fall.
(3) containing auxiliary agents such as glycerine in cleaning solution of the invention, the emulsification effect that wetting can be played, reinforce surfactant
The effect of fruit, when cleaning solution cleans glass surface, the auxiliary agents such as glycerine easily propagate through dirt penetration to glass surface, add
Strong glass surface clean effect；Of the invention contains these ingredients of surfactant, auxiliary agent, film forming agent and water, auxiliary agent at film liquid
Clean glass surface is easily adhered to surfactant interaction, film forming agent and auxiliary agent, surfactant combine, in glass
Glass surface forms smooth, fine and close film and (due to the wetability and permeability of auxiliary agent, further enhances the adherency of decontamination film
Power), the film surface is not easy to save bit by bit dust.
Specific embodiment
The present invention is further explained in the light of specific embodiments, but the scope of protection of the present invention is not limited thereto.
Embodiment 1:
A kind of Self-cleaning type outdoor glass bi-component detergent, including cleaning solution and at film liquid, according to parts by weight, cleaning solution
With it is as shown in table 1 at each component of film liquid；
Table 1
The preparation process of Self-cleaning type outdoor glass bi-component detergent is as follows:
1) preparation of cleaning solution: according to the parts by weight of cleaning solution each component in table 1, the various components of cleaning solution are counted respectively
It after amount, puts into reaction kettle, opens stirring, control 20~25 DEG C of temperature, be kept stirring 350~400r/min of revolving speed, stir
After 20~25min, mixed liquor is released to filtering from reaction kettle, filtrate packaging obtains cleaning solution；
2) at the preparation of film liquid: according to the parts by weight in table 1 at film liquid each component, will be counted respectively at the various components of film liquid
It after amount, puts into reaction kettle, opens stirring, control 35~40 DEG C of temperature, be kept stirring 750~800r/min of revolving speed, stir
After 30~35min, mixed liquor is released to filtering from reaction kettle, filtrate packaging obtains into film liquid.
The cleaning effect of Self-cleaning type outdoor glass bi-component detergent manufactured in the present embodiment is detected, glass to be cleaned is table
Face deposits one layer of dust, cleans process are as follows: cleaning solution tap water is first diluted 40 times, is stirred evenly, the cleaning solution after dilution is sprayed
It is sprinkled upon the surface of glass, glass surface is made to soak 10min or more, subsequent glass surface is rinsed well with clear water；Keep a public place clean process are as follows:
Ionized water will be spent at film liquid again and dilutes 25 times, will be stirred evenly, the glass table that being sprayed at after dilution at film liquid has been cleaned up
Face soaks glass surface, forms one layer of decontamination film after spontaneously drying, and in glass surface, i.e. glass surface is kept a public place clean completion.
The decontamination film thickness of the glass surface for completion of keeping a public place clean is tested by thickness gauge, result is to form 8~10 μ in glass surface
The decontamination film of m.
The glass that above-mentioned cleaning is completed, through national glass quality Supervision Test Center, Chinese building material examines certification group
The detection of Qinhuangdao Co., Ltd, detection data are shown in Table 2 (examining report number is WT-QT2017-139-0797)；
Table 2
| Sample ID | Apply decontamination film glass |
| Detection project | Visible transmission ratio |
| Examination criteria | GB/T2680-94 |
| Testing result | 90.51% |
From 2 testing result of table, it may be said that bright detergent cleaning effect manufactured in the present embodiment is good, secondly detects translucency
By force, illustrate that the transparency of the film of the invention formed at film liquid in glass surface is good.
Detect the metal protection of the cleaning solution in the detergent of the present embodiment, detection method are as follows: surface is smooth, bright
Copper, iron and aluminium immerse in cleaning solution respectively, impregnate 48h after take out, range estimation copper, iron and aluminium surface it is still smooth, bright, will
Copper, iron and aluminium surface wash with water clean rear drying respectively, weigh, and copper, iron and aluminium impregnate front and back quality and is basically unchanged,
Testing result is: cleaning solution does not generate corrosion to three kinds of copper, iron and aluminium metals.
Detect the metal protection at film liquid in the detergent of the present embodiment, detection method are as follows: surface is smooth, bright
Copper, iron and aluminium immerse respectively film forming liquid in, impregnate 48h after take out, range estimation copper, iron and aluminium surface it is still smooth, bright, will
Copper, iron and aluminium surface wash with water clean rear drying respectively, weigh, and copper, iron and aluminium impregnate front and back quality and is basically unchanged,
Testing result is: not generating corrosion to three kinds of copper, iron and aluminium metals at film liquid.
Embodiment 2:
A kind of Self-cleaning type outdoor glass bi-component detergent, including cleaning solution and at film liquid, according to parts by weight, cleaning solution
With it is as shown in table 3 at each component of film liquid；
Table 3
The preparation process of Self-cleaning type outdoor glass bi-component detergent is as follows:
1) preparation of cleaning solution: according to the parts by weight of cleaning solution each component in table 3, the various components of cleaning solution are counted respectively
It after amount, puts into reaction kettle, opens stirring, control 5~10 DEG C of temperature, be kept stirring 450~500r/min of revolving speed, stirring 20
After~25min, mixed liquor is released to filtering from reaction kettle, filtrate packaging obtains cleaning solution；
2) at the preparation of film liquid: according to the parts by weight in table 3 at film liquid each component, will be counted respectively at the various components of film liquid
It after amount, puts into reaction kettle, opens stirring, control 15~20 DEG C of temperature, be kept stirring 650~700r/min of revolving speed, stir
After 30~35min, mixed liquor is released to filtering from reaction kettle, filtrate packaging obtains into film liquid.
The cleaning effect of Self-cleaning type outdoor glass bi-component detergent manufactured in the present embodiment is detected, glass to be cleaned is table
Face deposits one layer of dust, cleans process are as follows: cleaning solution tap water is first diluted 50 times, is stirred evenly, the cleaning solution after dilution is sprayed
It is sprinkled upon the surface of glass, glass surface is made to soak 10min or more, subsequent glass surface is rinsed well with clear water；Keep a public place clean process are as follows:
Ionized water will be spent at film liquid again and dilutes 35 times, will be stirred evenly, the glass table that being sprayed at after dilution at film liquid has been cleaned up
Face soaks glass surface, forms one layer of decontamination film after spontaneously drying, and in glass surface, i.e. glass surface is kept a public place clean completion.
The decontamination film thickness of the glass surface for completion of keeping a public place clean is tested by thickness gauge, result is to form 8~10 μ in glass surface
The decontamination film of m.
The glass that above-mentioned cleaning is completed, through national glass quality Supervision Test Center, Chinese building material examines certification group
The detection of Qinhuangdao Co., Ltd, detection data are shown in Table 4 (examining report number is WT-QT2017-139-0797)；
Table 4
| Sample ID | Apply decontamination film glass |
| Detection project | Visible transmission ratio |
| Examination criteria | GB/T2680-94 |
| Testing result | 90.37% |
From 4 testing result of table, it may be said that bright detergent cleaning effect manufactured in the present embodiment is good, secondly detects translucency
By force, illustrate that the transparency of the film of the invention formed at film liquid in glass surface is good.
Detect the metal protection of the cleaning solution in the detergent of the present embodiment, detection method are as follows: surface is smooth, bright
Copper, iron and aluminium immerse in cleaning solution respectively, impregnate 48h after take out, range estimation copper, iron and aluminium surface it is still smooth, bright, will
Copper, iron and aluminium surface wash with water clean rear drying respectively, weigh, and copper, iron and aluminium impregnate front and back quality and is basically unchanged,
Testing result is: cleaning solution does not generate corrosion to three kinds of copper, iron and aluminium metals.
Detect the metal protection at film liquid in the detergent of the present embodiment, detection method are as follows: surface is smooth, bright
Copper, iron and aluminium immerse respectively film forming liquid in, impregnate 48h after take out, range estimation copper, iron and aluminium surface it is still smooth, bright, will
Copper, iron and aluminium surface wash with water clean rear drying respectively, weigh, and copper, iron and aluminium impregnate front and back quality and is basically unchanged,
Testing result is: not generating corrosion to three kinds of copper, iron and aluminium metals at film liquid.
Embodiment 3:
A kind of Self-cleaning type outdoor glass bi-component detergent, including cleaning solution and at film liquid, according to parts by weight, cleaning solution
With it is as shown in table 5 at each component of film liquid；
Table 5
The preparation process of Self-cleaning type outdoor glass bi-component detergent is as follows:
1) preparation of cleaning solution: according to the parts by weight of cleaning solution each component in table 5, the various components of cleaning solution are counted respectively
It after amount, puts into reaction kettle, opens stirring, control 35~40 DEG C of temperature, be kept stirring 450~500r/min of revolving speed, stir
After 20~22min, mixed liquor is released to filtering from reaction kettle, filtrate packaging obtains cleaning solution；
2) at the preparation of film liquid: according to the parts by weight in table 5 at film liquid each component, will be counted respectively at the various components of film liquid
It after amount, puts into reaction kettle, opens stirring, control 5~10 DEG C of temperature, be kept stirring 750~800r/min of revolving speed, stirring 30
After~35min, mixed liquor is released to filtering from reaction kettle, filtrate packaging obtains into film liquid.
The cleaning effect of Self-cleaning type outdoor glass bi-component detergent manufactured in the present embodiment is detected, glass to be cleaned is table
Face deposits one layer of dust, cleans process are as follows: cleaning solution tap water is first diluted 30 times, is stirred evenly, the cleaning solution after dilution is sprayed
It is sprinkled upon the surface of glass, glass surface is made to soak 10min or more, subsequent glass surface is rinsed well with clear water；Keep a public place clean process are as follows:
Ionized water will be spent at film liquid again and dilutes 30 times, will be stirred evenly, the glass table that being sprayed at after dilution at film liquid has been cleaned up
Face soaks glass surface, forms one layer of decontamination film after spontaneously drying, and in glass surface, i.e. glass surface is kept a public place clean completion.
The decontamination film thickness of the glass surface for completion of keeping a public place clean is tested by thickness gauge, result is to form 6~8 μm in glass surface
Decontamination film.
The glass that above-mentioned cleaning is completed, through national glass quality Supervision Test Center, Chinese building material examines certification group
The detection of Qinhuangdao Co., Ltd, detection data are shown in Table 6 (examining report number is WT-QT2017-139-0797)；
Table 6
| Sample ID | Apply decontamination film glass |
| Detection project | Visible transmission ratio |
| Examination criteria | GB/T2680-94 |
| Testing result | 90.53% |
From 6 testing result of table, it may be said that bright detergent cleaning effect manufactured in the present embodiment is good, secondly detects translucency
By force, illustrate that the transparency of the film of the invention formed at film liquid in glass surface is good.
Detect the metal protection of the cleaning solution in the detergent of the present embodiment, detection method are as follows: surface is smooth, bright
Copper, iron and aluminium immerse in cleaning solution respectively, impregnate 48h after take out, range estimation copper, iron and aluminium surface it is still smooth, bright, will
Copper, iron and aluminium surface wash with water clean rear drying respectively, weigh, and copper, iron and aluminium impregnate front and back quality and is basically unchanged,
Testing result is: cleaning solution does not generate corrosion to three kinds of copper, iron and aluminium metals.
Detect the metal protection at film liquid in the detergent of the present embodiment, detection method are as follows: surface is smooth, bright
Copper, iron and aluminium immerse respectively film forming liquid in, impregnate 48h after take out, range estimation copper, iron and aluminium surface it is still smooth, bright, will
Copper, iron and aluminium surface wash with water clean rear drying respectively, weigh, and copper, iron and aluminium impregnate front and back quality and is basically unchanged,
Testing result is: not generating corrosion to three kinds of copper, iron and aluminium metals at film liquid.
Application Example 1:
Test the timeliness of keeping a public place clean of detergent of the invention, test method are as follows: the detergent prepared using embodiment 1, according to
The application method of the detergent cleaning glass of embodiment 1, obtains the glass that surface forms one layer of decontamination film, surface is formed decontamination
The glass of film is divided into two groups of a, b, two groups of glass of a, b is placed in outdoor, a covering is taken in top, prevents from drenching with rain.Outdoor temperature model
Enclosing is 10~30 DEG C, and humidity range is 75~81%, observes the performance of keeping a public place clean of two groups of glass with decontamination film of a, b, wherein b group band
The glass of decontamination film, which was sprayed every 10 days with proper amount of clear water, rinses 2min, makes glass surface wetting and clear water is dripped along glass surface
Under, spraying clear water every time can observe: having dust to flow down with water droplet, illustrate that dust is not easy to be adhered on decontamination film.Test 50
After it, range estimation has a thin layer of dust to a group glass surface, needs replacing decontamination film, b group glass surface dust is seldom, can
To continue to use；After test 90 days, range estimation has a thin layer of dust to b group glass surface, needs replacing decontamination film (due to going
Dirty film is stronger in the adhesion strength of glass surface, when carrying out the replacement of decontamination film, need to use hairbrush and combine cleaning solution of the invention will
Decontamination film on glass scrubs off, and then obtains surface according to the application method of detergent of the present invention cleaning glass again and is formed
The glass of one layer of decontamination film, again keeps a public place clean to glass).
After glass surface forms one layer of decontamination film, when being timed clear water sprinkling, timeliness of keeping a public place clean is longer and significant effect, by
This illustrates that dust is low in decontamination film surface adhesiveness, i.e. decontamination film surface is relatively smooth.Detergent of the invention is in reality as a result,
In use process, it is contemplated that the influence of outdoor weather rainy day, due to rainwash effect, the glass for completion of keeping a public place clean is actually used
In the process, timeliness of keeping a public place clean can keep a public place clean than a group glass, and timeliness is long, and thus outdoor can keep glass surface to clean 2~3 months.
Content described in this specification is only to enumerate to inventive concept way of realization, and protection scope of the present invention is not answered
When the concrete form for being seen as limited by embodiment and being stated, protection scope of the present invention is also only in those skilled in the art's root
According to present inventive concept it is conceivable that equivalent technologies mean.
Claims (5)
1. a kind of Self-cleaning type outdoor glass bi-component detergent, it is characterised in that two-component detergent is divided into cleaning solution and at film liquid
Two kinds of cleansings, percentage, the cleaning solution are composed of the following components: surfactant 10 ~ 40%, and auxiliary agent 3 ~
20%, surplus is deionized water；It is described composed of the following components at film liquid: surfactant 5 ~ 40%, auxiliary agent 5 ~ 20%, film forming agent 3
~ 6%, surplus is deionized water；The auxiliary agent is the mixing of one or more of glycerine, ethyl alcohol, sodium alkyl sulfate
Object.
2. a kind of Self-cleaning type outdoor glass bi-component detergent according to claim 1, it is characterised in that surfactant
For sodium sulfate of polyethenoxy ether of fatty alcohol, fatty alcohol polyoxyethylene ether ammonium sulfate, fatty diglycollic amide, alkyl benzene sulphonate,
One or more mixtures of dilute base sodium sulfonate of α-.
3. a kind of Self-cleaning type outdoor glass bi-component detergent according to claim 1, it is characterised in that film forming agent is hydroxyl
One or both of ethyl cellulose, hydroxypropyl methyl cellulose mixture.
4. a kind of preparation method of Self-cleaning type outdoor glass bi-component detergent according to claim 1, it is characterised in that
Including following procedure:
1) preparation of cleaning solution: after the various components of cleaning solution are measured respectively, putting into reaction kettle, opens stirring, control
0 ~ 40 DEG C of temperature, it is kept stirring 300 ~ 500r/min of revolving speed, after stirring 20 ~ 30min, mixed liquor was released from reaction kettle
Filter, filtrate packaging obtain cleaning solution；
2) at the preparation of film liquid: after being measured respectively at the various components of film liquid, putting into reaction kettle, open stirring, control
0 ~ 40 DEG C of temperature, it is kept stirring 600 ~ 800r/min of revolving speed, after stirring 30 ~ 40min, mixed liquor was released from reaction kettle
Filter, filtrate packaging obtain into film liquid.
5. a kind of application method of Self-cleaning type outdoor glass bi-component detergent according to claim 1, it is characterised in that
The following steps are included:
S1 cleaning process: cleaning solution tap water is first diluted 30 ~ 50 times, stirs evenly, the cleaning solution after dilution is sprayed at glass
Surface, make glass surface wetting a period of time, subsequent glass surface rinsed well with clear water；
S2 keeps a public place clean process: will spend ionized water at film liquid and dilute 20 ~ 40 times, and stir evenly, by being sprayed at clearly after dilution at film liquid
The glass surface of wash clean, soaks glass surface, after spontaneously drying, forms the decontamination film of layer of transparent in glass surface,
That is glass surface is kept a public place clean completion.
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| CN201811367617.1A CN109337767B (en) | 2018-11-16 | 2018-11-16 | Self-cleaning type outdoor glass dual-component cleaning agent and preparation and use methods thereof |
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| CN201811367617.1A CN109337767B (en) | 2018-11-16 | 2018-11-16 | Self-cleaning type outdoor glass dual-component cleaning agent and preparation and use methods thereof |
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| CN109337767B CN109337767B (en) | 2021-08-10 |
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Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN112094702A (en) * | 2019-06-18 | 2020-12-18 | 东莞市华研环保科技有限公司 | Glass cleaning liquid with hydrophobic function and preparation process of glass cleaning liquid |
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| CN103103043A (en) * | 2012-12-19 | 2013-05-15 | 隋丽梅 | Outer wall cleaning powder composition of green building with self-cleaning function |
| CN103396897A (en) * | 2013-08-06 | 2013-11-20 | 张家港迪克汽车化学品有限公司 | Automobile wind window washing liquid |
| CN103555439A (en) * | 2013-10-25 | 2014-02-05 | 江苏雪豹日化有限公司 | Concentrated cleaning agent for outdoor glass |
| CN107937161A (en) * | 2017-10-26 | 2018-04-20 | 上海发凯化工有限公司 | A kind of concentrated type antifog glass cleaning agent |
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Patent Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN103103043A (en) * | 2012-12-19 | 2013-05-15 | 隋丽梅 | Outer wall cleaning powder composition of green building with self-cleaning function |
| CN103396897A (en) * | 2013-08-06 | 2013-11-20 | 张家港迪克汽车化学品有限公司 | Automobile wind window washing liquid |
| CN103555439A (en) * | 2013-10-25 | 2014-02-05 | 江苏雪豹日化有限公司 | Concentrated cleaning agent for outdoor glass |
| CN107937161A (en) * | 2017-10-26 | 2018-04-20 | 上海发凯化工有限公司 | A kind of concentrated type antifog glass cleaning agent |
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| Publication number | Priority date | Publication date | Assignee | Title |
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| CN112094702A (en) * | 2019-06-18 | 2020-12-18 | 东莞市华研环保科技有限公司 | Glass cleaning liquid with hydrophobic function and preparation process of glass cleaning liquid |
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| CN109337767B (en) | 2021-08-10 |
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