CN103396897A - Automobile wind window washing liquid - Google Patents

Automobile wind window washing liquid Download PDF

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Publication number
CN103396897A
CN103396897A CN2013103394119A CN201310339411A CN103396897A CN 103396897 A CN103396897 A CN 103396897A CN 2013103394119 A CN2013103394119 A CN 2013103394119A CN 201310339411 A CN201310339411 A CN 201310339411A CN 103396897 A CN103396897 A CN 103396897A
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window washing
automobile air
washing liquid
air window
automobile
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CN103396897B (en
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曹云龙
陶佃彬
单猛
童秀凤
王少华
邹密
施丽丽
李娟�
陈明娟
闵海琴
陈洁
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ZHANGJIAGANG TEEC AUTOMOTIVE CHEMICALS CO Ltd
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ZHANGJIAGANG TEEC AUTOMOTIVE CHEMICALS CO Ltd
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Abstract

The invention discloses a novel automobile wind window washing liquid for washing of automobile windshield glass and automobile window glass. The automobile wind window washing liquid comprises: by mass percentage, 15-90% of monohydric alcohol; 0.5-3% of a film-forming agent; 0.01-0.5% of benzotriazole; 0.01-0.5% of a straight chain alkyl diphenyl ether disulfonate; 0.05-0.5% of a fatty alcohol ether sulfate, 0.0005-0.003% of a pigment and the balance of deionized water. In the automobile wind window washing liquid, methanol or ethanol is used as a main solvent, a water solution of the methanol or ethanol can quickly evaporate from surfaces of automobile windows without residue; an additive formulation technique adopting the synergetic effect of fatty alcohol polyoxypropylene ether sulfate and dodecyl diphenyl ether disulfonate can thoroughly solve the problems of removing shellac, cleaning and decontamination on the surfaces of wind windows, dirt and other organic impurities on the surfaces of wind window glass can be effectively cleaned, reflection caused by oil films can be eliminated to bring good guarantees for driving safety.

Description

Automobile air window washing liquid
Technical field
The present invention relates to a kind of washings, relate in particular to a kind of new automobile air window washing liquid.
Background technology
Automobile air window washing liquid, be used for the cleaning of windshield and glass for vehicle window.The vehicle window scavenging solution of selling on domestic market now is mainly that methanol type, ethanol-type or ethanol-type are main vehicle window scavenging solution, and the quality product of most of market sales is not high, comprises that liquid detergent adds water and blends, and adds water without any methyl alcohol, the ethanol of additive and blends.General liquid detergent is blent product and is difficult to use at the lower environment of temperature, easily forms to freeze to cause and can't clean vehicle window, and especially northerly Cold Winter is all the more so.
After on domestic market, the vehicle window scavenging solution uses; easily cause pull-away, variable color; the detrimentally affect such as detergent line obstruction, cleaning system ageing of plastics are too fast; domestic existing patent about glass cleaning and documents and materials; main function focuses on cleans and the functions such as decontamination dirt, shellac, and does not consider that air window washing liquid is to the consistency of car paint, plastics, rubber and to the provide protection of the metallic element of cleaning system.
Summary of the invention
Technical problem to be solved by this invention is: a kind of automobile air window washing liquid that the automobile air window cleaning system is had the all-round protection performance is provided.
In order to solve the problems of the technologies described above, technical scheme of the present invention is: automobile air window washing liquid, and by mass percentage, it consists of:
Figure BDA00003628796900011
Figure BDA00003628796900021
Described automobile air window washing liquid, by mass percentage, its preferred group becomes:
Figure BDA00003628796900022
Described automobile air window washing liquid, by mass percentage, its preferred group becomes:
Figure BDA00003628796900023
Described monohydroxy-alcohol can be methyl alcohol and/or ethanol, preferentially selects ethanol.
Described linear alkyl diphenyl ether stilbene-4,4'-bis-(1-azo-3, 4-dihydroxy-benzene)-2,2'-disulfonate is C 8~C 16The linear alkyl diphenyl ether stilbene-4,4'-bis-(1-azo-3, 4-dihydroxy-benzene)-2,2'-disulfonate, molecular formula is [C N+12H 2n+8O 7S 2] M 2Its structural formula is:
Figure BDA00003628796900031
Wherein ,-C nH 2n+1For straight chained alkyl, n=8~16, and n is integer, M is basic metal.
M=Na or K in described linear alkyl diphenyl ether stilbene-4,4'-bis-(1-azo-3, 4-dihydroxy-benzene)-2,2'-disulfonate, preferred disodium 4-dodecyl-2,4 '-oxydibenzenesulfonate.
Described fatty alcohol ether sulphate is fatty alcohol polyoxypropylene ether sodium sulfate.
What the sodium sulfate of described fatty alcohol-ether was selected is dodecyl polyoxypropylene ether sodium sulfate.
Described membrane-forming agent is selected one or more of glycol ether, glycerine, ethylene glycol, preferably glycerine.
Described pigment is: one or more in green system, yellow system, red colour system, blue series.
Described pigment optimization is water-soluble indigo.
Beneficial effect of the present invention:
Therefore although the linear alkyl diphenyl ether sodium disulfonate has extremely outstanding detergency ability, its froth stability is high, is unfavorable for the quick volatilization of vehicle window scavenging solution, can not use in a large number, and if add-on is very few can have a negative impact to large-area cleaning.The compound of the tensio-active agent of AES and linear alkyl diphenyl ether sodium disulfonate can effectively avoid this shortcoming, improve the whole detergency ability of vehicle window scavenging solution with relatively large AES, simultaneously a small amount of linear alkyl diphenyl ether sodium disulfonate the debug glue ability that can provide the vehicle window scavenging solution good is provided, have splendid cleaning and solvency action for the extremely strong protein of contaminative, effectively made up AES deficiency in this respect.
This automobile air window washing liquid adopts methyl alcohol or ethanol as primary solvent, and its aqueous solution can be in the evaporation rapidly of vehicle window surface, noresidue.
Can solve thoroughly debug glue and the cleaning decontamination problem on air regulator surface by the synergistic additive formulations technology of using fatty alcohol polyoxypropylene ether vitriol and disodium 4-dodecyl-2,4 '-oxydibenzenesulfonate salt.
the application of novel non-stimulated green surfactant disodium 4-dodecyl-2,4 '-oxydibenzenesulfonate salt has possessed the air window washing liquid product and excellent prevents that the cleaning system metal is oxidized and by acid-etched function, effectively eliminated the detrimentally affect of using other tensio-active agent to bring, the various metal partss of protection cleaning system pipeline, and and the plastics that use of automobile cleaning system, the component such as rubber have excellent consistency, has the not available extremely low surface tension of general air window washing liquid, can effectively clean dirt and other organic impurity on windscreen surface, eliminate reflective that oil film causes, bring good assurance to traffic safety.
Embodiment
Describe in detail particular content of the present invention below in conjunction with specific embodiment.
Embodiment 1
Preparation 1000Kg is adapted to a kind of automobile air window washing liquid that uses at the northern China severe cold area.
Squeeze into 420Kg ethanol in reactor, add the 1Kg benzotriazole that dissolves in advance, stir after 1 hour, squeeze into the 200Kg deionized water, the glycerine of 15Kg, stir after 30 minutes and add again the 0.3Kg disodium 4-dodecyl-2,4 '-oxydibenzenesulfonate, 1Kg lauryl alcohol polyoxypropylene ether sodium sulfate and the 0.01Kg that use in advance a small amount of deionized water dissolving water-soluble indigo, and squeeze into remaining deionized water and fully stirred 1 hour, the 1000Kg automobile air window washing liquid that obtains after dissolving can filter packing by the 0.1-0.5um strainer.
Effect is very excellent after measuring on-board, and its leading indicator is as follows:
Figure BDA00003628796900041
Figure BDA00003628796900051
Embodiment 2
Preparation 1000Kg is adapted to a kind of automobile air window washing liquid that uses at China's most areas.
Squeeze into 270Kg ethanol in reactor, add the 0.7Kg benzotriazole that dissolves in advance, stir after 1 hour, squeeze into the 200Kg deionized water, the glycerine of 10Kg, stir after 30 minutes and add again lauryl alcohol polyoxypropylene ether sodium sulfate and the 0.008Kg of the 0.15Kg disodium 4-dodecyl-2,4 '-oxydibenzenesulfonate of using in advance a small amount of deionized water dissolving and 0.8Kg water-soluble indigo, and squeeze into remaining deionized water and fully stirred 1 hour, the 1000Kg automobile air window washing liquid that obtains after dissolving can filter packing by the 0.1-0.5um strainer.
Effect is very excellent after measuring on-board, and its leading indicator is as follows:

Claims (10)

1. automobile air window washing liquid, by mass percentage, it consists of:
Figure FDA00003628796800011
2. automobile air window washing liquid according to claim 1, it is characterized in that: by mass percentage, it consists of:
Figure FDA00003628796800012
3. automobile air window washing liquid according to claim 1, it is characterized in that: by mass percentage, it consists of:
Figure FDA00003628796800013
Figure FDA00003628796800021
4. according to claim 1,2 or 3 described automobile air window washing liquids, it is characterized in that: described monohydroxy-alcohol is methyl alcohol and/or ethanol.
5. according to claim 1,2 or 3 described automobile air window washing liquids, it is characterized in that: described linear alkyl diphenyl ether stilbene-4,4'-bis-(1-azo-3, 4-dihydroxy-benzene)-2,2'-disulfonate is C 8~C 16The linear alkyl diphenyl ether stilbene-4,4'-bis-(1-azo-3, 4-dihydroxy-benzene)-2,2'-disulfonate, molecular formula is [C N+12H 2n+8O 7S 2] M 2Its structural formula is:
Figure FDA00003628796800022
Wherein ,-C nH 2n+1For straight chained alkyl, n=8~16, and n is integer, M is basic metal.
6. automobile air window washing liquid according to claim 5 is characterized in that: in described linear alkyl diphenyl ether stilbene-4,4'-bis-(1-azo-3, 4-dihydroxy-benzene)-2,2'-disulfonate, and the preferred Na of M or K.
7. according to claim 1,2 or 3 described automobile air window washing liquids, it is characterized in that: described fatty alcohol ether sulphate is fatty alcohol polyoxypropylene ether sodium sulfate.
8. automobile air window washing liquid according to claim 7, it is characterized in that: described fatty alcohol-ether sodium sulfate is dodecyl polyoxypropylene ether sodium sulfate.
9. according to claim 1,2 or 3 described automobile air window washing liquids, it is characterized in that: described membrane-forming agent is selected from one or more in following substances: glycol ether, glycerine, ethylene glycol.
10. according to claim 1,2 or 3 described automobile air window washing liquids, it is characterized in that: described pigment is: one or more in green system, yellow system, red colour system, blue series pigment.
CN201310339411.9A 2013-08-06 2013-08-06 Automobile wind window washing liquid Active CN103396897B (en)

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Cited By (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN105296169A (en) * 2015-12-02 2016-02-03 苏州龙腾万里化工科技有限公司 Efficient decontamination glass cleaner
CN105586168A (en) * 2015-12-30 2016-05-18 北京蓝星清洗有限公司 Water-based shellac-removing cleaning agent and preparation method thereof
CN106867709A (en) * 2017-01-23 2017-06-20 青岛农业大学 A kind of efficient, preparation of the automobile glass cleaning agent of easily biological-degradable
CN108192759A (en) * 2017-12-29 2018-06-22 张艳雪 A kind of eco-friendly car glass cleaning solution and its preparing process
CN108658455A (en) * 2018-05-03 2018-10-16 安徽智胜光学科技有限公司 A kind of production method of high intensity mobile phone screen glass
CN109337767A (en) * 2018-11-16 2019-02-15 杭州米土新材料科技有限公司 A kind of Self-cleaning type outdoor glass bi-component detergent and its preparation and application
GB2577111A (en) * 2018-09-14 2020-03-18 Tetrosyl I Tec Ltd Screen wash
CN113430057A (en) * 2021-07-09 2021-09-24 桂林理工大学 Automobile windshield cleaning fluid and preparation method thereof

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* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101041793A (en) * 2007-04-23 2007-09-26 北京交通大学 Automobile windscreen cleaning agent
CN101550383A (en) * 2009-05-13 2009-10-07 张家港迪克汽车化学品有限公司 Automobile air window washing liquid
CN101831360A (en) * 2009-03-09 2010-09-15 中国蓝星(集团)股份有限公司 Cleaning agent for automobile windshield
CN102071115A (en) * 2011-01-24 2011-05-25 北京洛娃日化有限公司 Concentration type antifog glass cleaning agent
CN102443492A (en) * 2010-10-08 2012-05-09 蔡全喜 Automobile glass water
CN102492582A (en) * 2011-11-29 2012-06-13 陕西中核大地实业有限公司 Long-acting environment-friendly automobile air window glass washing liquid
CN102653708A (en) * 2011-12-21 2012-09-05 上海东昊油品有限公司 All-around automobile windshield washing agent
CN103087835A (en) * 2013-03-02 2013-05-08 王蔚 Detergent for automobile windshields

Patent Citations (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101041793A (en) * 2007-04-23 2007-09-26 北京交通大学 Automobile windscreen cleaning agent
CN101831360A (en) * 2009-03-09 2010-09-15 中国蓝星(集团)股份有限公司 Cleaning agent for automobile windshield
CN101550383A (en) * 2009-05-13 2009-10-07 张家港迪克汽车化学品有限公司 Automobile air window washing liquid
CN102443492A (en) * 2010-10-08 2012-05-09 蔡全喜 Automobile glass water
CN102071115A (en) * 2011-01-24 2011-05-25 北京洛娃日化有限公司 Concentration type antifog glass cleaning agent
CN102492582A (en) * 2011-11-29 2012-06-13 陕西中核大地实业有限公司 Long-acting environment-friendly automobile air window glass washing liquid
CN102653708A (en) * 2011-12-21 2012-09-05 上海东昊油品有限公司 All-around automobile windshield washing agent
CN103087835A (en) * 2013-03-02 2013-05-08 王蔚 Detergent for automobile windshields

Cited By (10)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN105296169A (en) * 2015-12-02 2016-02-03 苏州龙腾万里化工科技有限公司 Efficient decontamination glass cleaner
CN105586168A (en) * 2015-12-30 2016-05-18 北京蓝星清洗有限公司 Water-based shellac-removing cleaning agent and preparation method thereof
CN106867709A (en) * 2017-01-23 2017-06-20 青岛农业大学 A kind of efficient, preparation of the automobile glass cleaning agent of easily biological-degradable
CN108192759A (en) * 2017-12-29 2018-06-22 张艳雪 A kind of eco-friendly car glass cleaning solution and its preparing process
CN108658455A (en) * 2018-05-03 2018-10-16 安徽智胜光学科技有限公司 A kind of production method of high intensity mobile phone screen glass
GB2577111A (en) * 2018-09-14 2020-03-18 Tetrosyl I Tec Ltd Screen wash
GB2577111B (en) * 2018-09-14 2022-07-13 Tetrosyl I Tec Ltd Screen wash
CN109337767A (en) * 2018-11-16 2019-02-15 杭州米土新材料科技有限公司 A kind of Self-cleaning type outdoor glass bi-component detergent and its preparation and application
CN109337767B (en) * 2018-11-16 2021-08-10 杭州米土新材料科技有限公司 Self-cleaning type outdoor glass dual-component cleaning agent and preparation and use methods thereof
CN113430057A (en) * 2021-07-09 2021-09-24 桂林理工大学 Automobile windshield cleaning fluid and preparation method thereof

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