CN102492582A - Long-acting environment-friendly automobile air window glass washing liquid - Google Patents
Long-acting environment-friendly automobile air window glass washing liquid Download PDFInfo
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- CN102492582A CN102492582A CN2011103879197A CN201110387919A CN102492582A CN 102492582 A CN102492582 A CN 102492582A CN 2011103879197 A CN2011103879197 A CN 2011103879197A CN 201110387919 A CN201110387919 A CN 201110387919A CN 102492582 A CN102492582 A CN 102492582A
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Abstract
The invention relates to a long-acting environment-friendly automobile air window glass washing liquid which is a non-toxic environment-friendly automobile air window glass washing liquid which can prevent freezing, prevent fog and remove ice and snow. The washing liquid is formed by stirring and reacting the following components by mass weight: ethanol, ethylene glycol monobutyl ether, alkylphenol polyoxyethylene ether, dodecyl benzyl ammonium chlorine, glycol, glycerol, polyoxyethylene alkyl phenyl ether, sodium benzoate, methyl benzotriazole, sodium molybdate, disodium ethylene diamine tetraacetate, sodium chloride, sunlight-resisting blue, triethanolamine, a defoaming agent and industrial pure water. By using the washing liquid, industrial methanol is prevented from being used as a solvent in the traditional formula; and simultaneously, the washing liquid and ethylene glycol monobutyl ether are matched and used, thereby greatly improving the dissolution effect of a single solvent on blots. The washing liquid disclosed by the invention is prepared by using non-toxic and easily biodegradable raw materials and is environment-friendly, can not pollute environment if being used for a long term, and prevents toxic gases from volatilization to harm a driver in the use process. The washing liquid has the characteristics of preventing fog, removing ice and snow, maintaining no icing on the surface of the glass for a long term, is not burnt and does not corrode.
Description
One, technical field
The present invention relates to a kind of long effective environmental protection type automobile air window glass cleaning solution, is a kind of antifreeze, antifog, non-toxic, environmental friendly automobile air window glass cleaning solution that can deicing.
Two, background technology
In recent years, China's automobile demand amount and recoverable amount present a rapidly rising trend.Chinese annual sale of automobile total amount was 1,806 ten thousand in 2010, and it is very general that automobile enters into ordinary family, and people environmentally safe gradually, personal health, have safe in utilizationly had a higher requirement when using automobile.Life-time service glass cleaning solution inferior also can make windshield, metal parts corrosion, the rain brush swelling, and lacquer painting is stained, causes traffic hazard when serious because of pilot's line of vision is bad.
At present, China's automobile air window glass cleaning solution exists the serious phenomenon of manufacturing in a rough and slipshod way, and objectionable impuritiess such as most use methyl alcohol cause serious pollution as the main raw material of glass cleaning solution to environment, and officer and passenger are caused certain injury.After glass cleaning solution has cleaned glass; Can flow near the Air Conditioning blast inlet; Glass cleaning solution evaporable smell can enter into along the ventilation duct of automative air conditioning in the wheel house; Glass cleaning solution evaporable obnoxious flavour inferior can become the healthy stealthy killer of officer, so the automobile air window glass cleaning solution of inventing a kind of asepsis environment-protecting seems particularly important.
Three, summary of the invention
The objective of the invention is for a kind of long effective environmental protection type automobile air window glass cleaning solution is provided, this scavenging solution adopts the component compounded technology, optimizes consumption, reaches best washing effect with minimum composite amount.Particularly use winter, can antifog, deicing, and can form one deck organic membrane at glass surface, stop frost formation once more when driving, for the officer provides a kind of driving environment that gets a clear view.Simultaneously, nontoxic, pollution-free solvent and easy biodegradable cats product are selected in this invention for use, and be environmentally friendly, can not cause environmental pollution, also can in use not produce obnoxious flavour and pollute cab environment.This scavenging solution adopts solvent complex technology, more good dissolving glass surface dirt; The employing surfactant compound is technological, has improved the cleaning and the emulsifying effectiveness of scavenging solution; Adopt antifreeze membrane-forming agent compounded technology, reduced the consumption of single membrane-forming agent, reduced product cost; Adopt the inhibiter compounded technology, can effectively delay the aging of rain brush rubber, automobile finish is not had influence, metal parts does not produce corrosion, effectively prolongs the work-ing life of windscreen and rain brush.
This glass cleaning solution has that cleaning effect is obvious, nontoxic, environmental protection, antifog, deicing, and burn into characteristics such as do not burn not.
Another object of the present invention is a preparation method of the present invention.
In order to realize the object of the invention, the present invention by mass percentage, following component forms through stirring reaction:
A kind of long effective environmental protection type automobile air window glass cleaning solution of the present invention by mass percentage, forms through stirring reaction with following component, and it is applicable to the area of minimum temperature-25 ℃:
A kind of long effective environmental protection type automobile air window glass cleaning solution of the present invention by mass percentage, forms through stirring reaction with following component, and it is applicable to the area of minimum temperature-40 ℃;
Preparation method of the present invention:
(1), under agitation successively ethanol, ethylene glycol monobutyl ether, TX10, dodecylbenzyl ammonium chloride are added industrial pure water, start and stir, make it abundant dissolving;
(2), under agitation methyl phenylpropyl alcohol triazole is added terepthaloyl moietie, it is subsequent use to make it fully dissolving;
(3), under agitation successively Sodium Benzoate, Sodium orthomolybdate, EDTA Disodium and sodium-chlor are added, make it abundant dissolving;
(4), under agitation terepthaloyl moietie dissolved methyl phenylpropyl alcohol triazole is added;
(5), transfer to products obtained therefrom pH value to 6.5～10.0 with trolamine;
(6), add skimmer and sun-proof is blue, mend to 100% with industrial pure water;
(7), fully stirred 30 minutes, left standstill 4 hours, warp filters packing with the strainer of 1 μ m after the assay was approved.
Mainly explain as follows to component of the present invention and characteristic:
1, ethanol and ethylene glycol monobutyl ether.It is to reduce freezing point that alcoholic acid mainly acts on; Ethylene glycol monobutyl ether is a kind of organic solvent of brilliance, and spots such as oil stain, natural gum, shellac are had good solvency action, and synergy is arranged when using with ethanol; Can well dissolve the glass surface spot, improve cleaning performance.
2, TX10.Characteristics are not form striped vestige, non-residual solids after the washing; Major function is wetting and emulsification, and nonionogenic tenside can form one deck unit molecule protective membrane at glass surface under the environment that organic solvents such as alcohol, terepthaloyl moietie exist; This layer protective membrane can prevent to form droplet; The assurance windshield glass is as clear as crystal, and the visual field is bright, has anti-fog function.
3, dodecylbenzyl ammonium chloride.Its major function is to eliminate the static of windshield glass and air friction generation, has antistatic property, plays the sterilization and anticorrosion effect simultaneously, and the cats product readily biodegradable, and life-time service can not pollute environment, environmental protection.
4, terepthaloyl moietie and USP Kosher.It mainly acts on is to cooperate with ethanol to reduce freezing point on the one hand, has frost prevention, antifreeze effect; On the other hand, its viscosity is big than ethanol, and volatility is little, forms a skim at glass surface, prevents the generation once more of ice and snow in the winter driving process, simultaneously can lubricate, reduce the friction between rain brush and the glass, and prevent to scratch glass.
5, polyoxyethylene alkyl phenyl ether.It mainly acts on is to cooperate terepthaloyl moietie and USP Kosher to use, and has improved compsn in the residence time on glass, makes frost protection, anti-ice-snow effect more lasting, and drive safety has been improved in the visual field of becoming clear when guaranteeing winter ice and snow weather driving effectively.Polyoxyethylene alkyl phenyl ether have adhere to, wetting action, can make terepthaloyl moietie and USP Kosher at longtime drying on glass, can get rid of ice and snow and frosting material, make terepthaloyl moietie and USP Kosher more be prone to film forming.
6, Sodium Benzoate, methyl phenylpropyl alcohol triazole, Sodium orthomolybdate.The Sodium Benzoate effect is a sanitas, and the effect that extends the shelf life is arranged, and Sodium Benzoate, methyl phenylpropyl alcohol triazole, the composite use of Sodium orthomolybdate have good preservative effect to the various metals of windshield cleaning system contact;
7, trolamine be the pH value that is used for regulating scavenging solution between 6.5～10.0, can play shock absorption, it is stable that the scavenging solution pH value is kept in 6.5～10.0 scopes, increases the emulsifying capacity and the emulsifying stability of scavenging solution, prevents that dirt from forming once more.
8, EDTA Disodium.Here selecting EDTA Disodium for use, is a kind of sequestrant, can with calcium, magnesium, the iron plasma generation chelating in the water; Be attracted to the incrustation scale crystal surface; No longer continued growth and lattice distortion takes place, thus the generation of glass surface hard scale stoped, effectively prolonged the work-ing life of automobile air window glass; Can reduce the generation of incrustation scale simultaneously with calcium, magnesium, the iron plasma generation chelating in the system water, prevent that automotive system from stopping up.
9, sodium-chlor.Sodium-chlor plays solublization, and the adding of sodium-chlor has improved speed and the effect of removing frost greatly.
10, direct fast blue.It mainly acts on the one hand is and other product differentiations to be easy on the other hand hunt leak in use.
11, the present invention has avoided conventional formulation to use industrial methanol as solvent; Be used with ethylene glycol monobutyl ether simultaneously; Improved the solute effect of single solvent to spot greatly, the present invention uses, and nontoxic, the biological degraded preparation of raw material that is prone to forms, and is environmentally friendly; Life-time service can not pollute environment, the toxic gas that in use yet can not volatilize harm officer.This invention can be antifog, deicing, snow removing and can keep characteristics such as glass surface does not freeze the long period, do not burn, do not corrode, and is environmentally friendly.
Embodiment
Through concrete example the present invention is further specified below:
Embodiment 1: the area that is applicable to minimum temperature-25 ℃:
The 300kg industrial pure water is added reaction kettle, open and stir, the ethanol, 15kg ethylene glycol monobutyl ether, 1.5kg TX10, the 0.5kg dodecylbenzyl ammonium chloride that under whipped state, add 400kg make it abundant dissolving.Under whipped state, add 8kg USP Kosher, 5kg polyoxyethylene alkyl phenyl ether, 5kg Sodium Benzoate, 2kg Sodium orthomolybdate, 0.5kg EDTA Disodium, 2kg sodium-chlor then successively; Again 0.5kg methyl phenylpropyl alcohol triazole is dissolved in 10kg terepthaloyl moietie; Treat that methyl phenylpropyl alcohol triazole fully dissolves in terepthaloyl moietie after; Add in the reaction kettle and stirred 10 minutes; In 6.5～10.0 scopes, together add reaction kettle with industrial pure water the mixings skimmer and the sun-proof indigo plant of surplus with 2.5kg trolamine adjustment pH value, warp passes through the strainer packing of 1 μ m after the assay was approved.
This routine leading indicator is following:
Embodiment 2: the area that is applicable to minimum temperature-40 ℃.
The 200kg industrial pure water is added reaction kettle, open and stir, the edible ethanol, 20kg ethylene glycol monobutyl ether, 2kg TX10, the 1kg dodecylbenzyl ammonium chloride that under whipped state, add 580kg make it abundant dissolving.Under whipped state, add 10kg USP Kosher, 8kg polyoxyethylene alkyl phenyl ether, 5kg Sodium Benzoate, 3kg Sodium orthomolybdate, 0.5kg EDTA Disodium, 3kg sodium-chlor then successively; Again 0.5kg methyl phenylpropyl alcohol triazole is dissolved in 15kg terepthaloyl moietie; Treat that methyl phenylpropyl alcohol triazole fully dissolves in terepthaloyl moietie after; Add in the reaction kettle and stirred 10 minutes; In 6.5～10.0 scopes, together add reaction kettle with industrial pure water the mixings skimmer and the sun-proof indigo plant of surplus with 3kg trolamine adjustment pH value, warp passes through the strainer packing of 1 μ m after the assay was approved.
This routine leading indicator is following:
Claims (4)
1. a kind of long effective environmental protection type automobile air window glass cleaning solution, it is characterized in that: by mass percentage, following component forms through stirring reaction:
2. a kind of according to claim 1 long effective environmental protection type automobile air window glass cleaning solution is characterized in that: by mass percentage, following component forms through stirring reaction, and it is applicable to the area of minimum temperature-25 ℃:
3. a kind of according to claim 1 long effective environmental protection type automobile air window glass cleaning solution is characterized in that: by mass percentage, following component forms through stirring reaction, and it is applicable to the area of minimum temperature-40 ℃:
4. like claim 1 or 2 or 3 said a kind of long effective environmental protection type automobile air window glass cleaning solutions, its compound method is following:
(1), under agitation successively ethanol, ethylene glycol monobutyl ether, TX10, dodecylbenzyl ammonium chloride are added industrial pure water, start and stir, make it abundant dissolving;
(2), under agitation methyl phenylpropyl alcohol triazole is added terepthaloyl moietie, it is subsequent use to make it fully dissolving;
(3), under agitation successively Sodium Benzoate, Sodium orthomolybdate, EDTA Disodium and sodium-chlor are added, make it abundant dissolving;
(4), under agitation terepthaloyl moietie dissolved methyl phenylpropyl alcohol triazole is added;
(5), transfer to products obtained therefrom pH value to 6.5～10.0 with trolamine;
(6), add skimmer and sun-proof is blue, mend to 100% with industrial pure water;
(7), fully stirred 30 minutes, left standstill 4 hours, warp filters packing with the strainer of 1 μ m after the assay was approved.
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| Application Number | Priority Date | Filing Date | Title |
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| CN201110387919.7A CN102492582B (en) | 2011-11-29 | 2011-11-29 | Automobile air window glass washing liquid |
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| CN201110387919.7A CN102492582B (en) | 2011-11-29 | 2011-11-29 | Automobile air window glass washing liquid |
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| CN102492582A true CN102492582A (en) | 2012-06-13 |
| CN102492582B CN102492582B (en) | 2014-12-17 |
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Cited By (16)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN103396897A (en) * | 2013-08-06 | 2013-11-20 | 张家港迪克汽车化学品有限公司 | Automobile wind window washing liquid |
| CN103773638A (en) * | 2014-01-20 | 2014-05-07 | 武汉卓成电子材料中心 | Cleaning agent for solar panel |
| CN103849508A (en) * | 2012-12-06 | 2014-06-11 | 厦门加岩高分子材料有限公司 | Glass cleaning agent and preparation method thereof |
| CN104277924A (en) * | 2013-07-12 | 2015-01-14 | 中国石油天然气股份有限公司 | Automobile windshield cleaning fluid |
| CN104357252A (en) * | 2014-11-19 | 2015-02-18 | 柳州市二和汽车零部件有限公司 | Automobile window cleaning solution |
| CN105199870A (en) * | 2015-09-30 | 2015-12-30 | 江苏耀兴安全玻璃有限公司 | Preparation method of glass detergent for automobiles |
| CN105838511A (en) * | 2016-04-11 | 2016-08-10 | 河南工程学院 | A novel environmental-friendly automobile windshield washing concentrated liquid |
| CN106085618A (en) * | 2016-06-08 | 2016-11-09 | 山东源根石油化工有限公司 | A kind of glass for vehicle window cleaning agent and preparation method thereof |
| CN106609193A (en) * | 2015-10-21 | 2017-05-03 | 中国石油化工股份有限公司 | Vehicle headlamp cleaning agent |
| CN106675798A (en) * | 2016-12-16 | 2017-05-17 | 安徽长庚光学科技有限公司 | Cleaning fluid for optical lens and preparation method thereof |
| CN107254366A (en) * | 2017-05-31 | 2017-10-17 | 江苏精盾节能科技有限公司 | A kind of glass cleaner and preparation method thereof |
| CN107557172A (en) * | 2017-09-29 | 2018-01-09 | 洛娃日化(江苏)股份有限公司 | A kind of antifreeze glass cleaner and preparation method |
| CN108624416A (en) * | 2018-05-11 | 2018-10-09 | 肥西县碧涛建材有限公司 | A kind of preparation method of door glass efficient cleaner |
| CN108753496A (en) * | 2018-07-06 | 2018-11-06 | 天津津龙汽车用品有限公司 | A kind of automobile window glass cleaning agent and preparation method |
| CN109280539A (en) * | 2017-07-21 | 2019-01-29 | 法雷奥系统公司 | Automotive windows deicing fluid, de-icing method and the method for conveying deicing fluid |
| CN115491264A (en) * | 2022-09-28 | 2022-12-20 | 抚顺润益化工有限公司 | Environment-friendly multifunctional glass cleaning fluid |
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| CN1673325A (en) * | 2004-03-24 | 2005-09-28 | 张金辉 | Automobile wind screen detergent |
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2011
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Patent Citations (1)
| Publication number | Priority date | Publication date | Assignee | Title |
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| CN1673325A (en) * | 2004-03-24 | 2005-09-28 | 张金辉 | Automobile wind screen detergent |
Cited By (19)
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| CN103849508A (en) * | 2012-12-06 | 2014-06-11 | 厦门加岩高分子材料有限公司 | Glass cleaning agent and preparation method thereof |
| CN104277924A (en) * | 2013-07-12 | 2015-01-14 | 中国石油天然气股份有限公司 | Automobile windshield cleaning fluid |
| CN103396897A (en) * | 2013-08-06 | 2013-11-20 | 张家港迪克汽车化学品有限公司 | Automobile wind window washing liquid |
| CN103773638A (en) * | 2014-01-20 | 2014-05-07 | 武汉卓成电子材料中心 | Cleaning agent for solar panel |
| CN103773638B (en) * | 2014-01-20 | 2016-04-06 | 武汉卓成光伏新能源有限公司 | Solar cell board cleaning agent |
| CN104357252A (en) * | 2014-11-19 | 2015-02-18 | 柳州市二和汽车零部件有限公司 | Automobile window cleaning solution |
| CN105199870A (en) * | 2015-09-30 | 2015-12-30 | 江苏耀兴安全玻璃有限公司 | Preparation method of glass detergent for automobiles |
| CN106609193A (en) * | 2015-10-21 | 2017-05-03 | 中国石油化工股份有限公司 | Vehicle headlamp cleaning agent |
| CN105838511A (en) * | 2016-04-11 | 2016-08-10 | 河南工程学院 | A novel environmental-friendly automobile windshield washing concentrated liquid |
| CN106085618A (en) * | 2016-06-08 | 2016-11-09 | 山东源根石油化工有限公司 | A kind of glass for vehicle window cleaning agent and preparation method thereof |
| CN106675798A (en) * | 2016-12-16 | 2017-05-17 | 安徽长庚光学科技有限公司 | Cleaning fluid for optical lens and preparation method thereof |
| CN107254366A (en) * | 2017-05-31 | 2017-10-17 | 江苏精盾节能科技有限公司 | A kind of glass cleaner and preparation method thereof |
| CN109280539A (en) * | 2017-07-21 | 2019-01-29 | 法雷奥系统公司 | Automotive windows deicing fluid, de-icing method and the method for conveying deicing fluid |
| JP2019023289A (en) * | 2017-07-21 | 2019-02-14 | ヴァレオ システム デシュヤージュＶａｌｅｏ Ｓｙｓｔｅｍｅｓ Ｄ’Ｅｓｓｕｙａｇｅ | Motor vehicle window deicing fluid, deicing process, and process for conveying deicing fluid |
| JP7091179B2 (en) | 2017-07-21 | 2022-06-27 | ヴァレオ システム デシュヤージュ | Deicing liquid for automobile windows, deicing method and deicing liquid transportation method |
| CN107557172A (en) * | 2017-09-29 | 2018-01-09 | 洛娃日化(江苏)股份有限公司 | A kind of antifreeze glass cleaner and preparation method |
| CN108624416A (en) * | 2018-05-11 | 2018-10-09 | 肥西县碧涛建材有限公司 | A kind of preparation method of door glass efficient cleaner |
| CN108753496A (en) * | 2018-07-06 | 2018-11-06 | 天津津龙汽车用品有限公司 | A kind of automobile window glass cleaning agent and preparation method |
| CN115491264A (en) * | 2022-09-28 | 2022-12-20 | 抚顺润益化工有限公司 | Environment-friendly multifunctional glass cleaning fluid |
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