CN102181326A - Glass cleaner and application thereof - Google Patents
Glass cleaner and application thereof Download PDFInfo
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- CN102181326A CN102181326A CN 201110082165 CN201110082165A CN102181326A CN 102181326 A CN102181326 A CN 102181326A CN 201110082165 CN201110082165 CN 201110082165 CN 201110082165 A CN201110082165 A CN 201110082165A CN 102181326 A CN102181326 A CN 102181326A
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Abstract
The invention provides a glass cleaner. The cleaner comprises a nonionic surfactant, an anionic surfactant, a corrosion inhibitor, an antifreezing film-forming agent, a lubricant and a solvent. The invention also provides application of the glass cleaner to the cleaning of front windshields of trains, in particular application of the glass cleaner to the cleaning of front windshields of motor trains. The cleaner has extremely strong decontamination capacity, and can quickly and effectively remove pollutants which appear on windshields of trains running at a high speed; the cleaner has higher ambient temperature adaptability, and can be used at the temperature of between minus 40 and 60 DEG C; the pH value is 6.8 to 7.2, and the cleaner has lower corrosivity; the cleaner has high lubricity and can prevent the windshields from being bruised; an antifreezing film-forming component is added and can achieve the effects of anti-icing and demisting; and the cleaner does not contain components which are toxic or irritant to human bodies such as methanol, ammonia water and the like.
Description
Technical field
The present invention relates to a kind of glass cleaner and application thereof, particularly relate to a kind of EMUs front windshield clean-out system and application thereof.
Background technology
Along with the development of high-speed railway, EMUs are by a large amount of coming into operation.EMUs are (generally more than 250km/h) when high-speed motion, front windshield through regular meeting by pollutions such as the corpse of shellac, birds droppings, animalcule, lubricating oil, petrol and diesel oils; In the sleet sky, also have rainwater and ice and snow, the sight line that these will influence the officer causes very big traffic safety hidden danger.In addition, the EMUs range ability is longer, and the part EMUs need drive to warm southern area from the area, northeast of cold.At present also do not have a kind of EMUs effectively both to have good cleaning capacity, have the effect of low temperature resistant (below 40 ℃) again with the front windshield clean-out system.
Domestic EMUs front windshield clean-out system mainly contains following several:
(1) common pure water;
(2) general-utility car front windshield clean-out system;
(3) after EMUs arrive at a station, clear up with washing composition.
Pure water is difficult to wash shellac as windscreen cleaning liquid, pollutents such as animalcule corpse and oil stain, and winter because ice formation issues, can not use.The general-utility car windscreen cleaning liquid, general shellac and oil stain there is certain cleanup action, the EMUs speed per hour is generally more than 250km/h, so down high-speed, the animalcule corpse that is collided to death is difficult to clean up with windscreen cleaning liquid with general-utility car, while area, northeast in the winter time, and temperature generally is lower than-30 ℃, even reaching-40 ℃, general-utility car generally all can freeze and can not use with windscreen cleaning liquid.After EMUs arrive at a station, with clean-out system cleaning front windshield and vehicle body is the most effective way at present, but this way can not fundamentally solve the problem that the EMUs front windshield cleans, and dispatch a car once more in a short period of time after motor-car generally arrives at a station now, increasing to the pressure that cleaning is brought.
In a word, existing glass cleaner has following shortcoming:
(1) dirty removal capacities a little less than, be difficult to once with shellac, the animalcule corpse, pollutant removals such as bloodstain and oil stain are clean, and repeatedly hydro-peening has a strong impact on EMUs officer's sight line, and traffic safety is produced hidden danger;
(2) resistance to low temperature is limited, and is general minimum to-25 ℃, and generally can not use because of viscosity is excessive to time below-20 ℃, is difficult to satisfy EMUs and runs through operation in China north and south;
(3) to contain methyl alcohol, ammoniacal liquor etc. poisonous or the pungency composition is arranged more, and human and environment is had certain detrimentally affect;
(4) manyly do not contain lubricated composition, and pH be alkaline, windshield glass is had corrosive nature, life-time service, windshield glass becomes fragile, and abrades windshield glass because of rain brush and windshield glass friction easily.
Summary of the invention
The objective of the invention is to overcome in the prior art that EMUs front windshield clean-out system dirty removal capacities is weak, resistance to low temperature is poor, contain poisonous more or pungency composition, unlubricated composition are arranged, windshield glass is had shortcoming such as corrosive nature, a kind of glass cleaner and application thereof are provided.This clean-out system not only has extremely strong cleaning and clean effect, and stronger environmental adaptability is arranged, and still keeps liquid and viscosity good at-40 ℃, does not hinder use.In addition, this clean-out system also has good lubricating effect, can reduce the friction of rubber rain brush to windshield glass, prevents to abrade windshield glass, has lower corrodibility and good anti-fog performance simultaneously.
Therefore, the invention provides a kind of glass cleaner, this clean-out system comprises nonionogenic tenside, anion surfactant, inhibiter, antifreeze membrane-forming agent, lubricant and solvent.
According to glass cleaner provided by the invention, wherein, the nonionogenic tenside that can comprise 0.1～0.2 weight part in the clean-out system of 100 weight parts, 0.01 the anion surfactant of～0.1 weight part, 0.1 the inhibiter of～1.0 weight parts, the antifreeze membrane-forming agent of 5～25 weight parts, the lubricant of 1～5 weight part, all the other are solvent.For fear of the problem that anion surfactant under cold condition is separated out, the content of described anion surfactant can be preferably 0.01～0.05 weight part.
Under the preferable case, the weight ratio of described nonionogenic tenside and anion surfactant can be 1-3: 1, most preferably be 1.5～2.5: 1.
According to glass cleaner of the present invention, wherein, described nonionogenic tenside can be fatty alcohol-polyoxyethylene ether and/or alkylphenol polyoxyethylene.
According to glass cleaner provided by the invention, wherein, described anion surfactant can be selected from one or more in secondary alkyl sulfonate, dodecane sulfonate, dodecylbenzene sulfonate, aliphatic acid polyethenoxy ether vitriol, the alkyl succinic acid sulfonated ester, and wherein said salt all is preferably sylvite and/or sodium salt.Preferably, described anion surfactant can be in Sodium dodecylbenzene sulfonate, sodium laurylsulfonate, alkyl succinic acid sulfonated ester and the fatty acid polyether Vinyl Ether vitriol one or more.
Tensio-active agent adopts anion surfactant to mix with nonionogenic tenside and uses mode, and composite rear surface promoting agent has the good penetration performance, to shellac, birds droppings, the corpse of animalcule and bloodstain carry out dispersion and emulsion, make it equal solvent soluble in water, thereby reach cleaning action.After adding tensio-active agent, greatly reducing the tension force of each phase interface, improved the cleaning and the emulsifying effectiveness of clean-out system, is a kind of low foaming cleaning.
According to glass cleaner of the present invention, wherein, described inhibiter can be selected from one or more in Sodium Nitrite, borax, trolamine, Starso, the Sodium orthomolybdate, is preferably Sodium Nitrite and/or Sodium orthomolybdate.Inhibiter is mainly used in the pH value of regulating scavenging solution maintains between 6.8～7.2 it, when preventing that its PH is too high to non-metallic material, the particularly corrosion of windshield glass, perhaps its pH value is crossed when hanging down the metallic substance in the pipeline is corroded, and can also increase the emulsifying capacity and the emulsifying stability of clean-out system simultaneously.
According to glass cleaner provided by the invention, wherein, described antifreeze membrane-forming agent can be selected from ethylene glycol, 1, the 2-propylene glycol, and 1, one or more in ammediol and the ethylene glycol monobutyl ether are to play the effect of " antifog ".
According to glass cleaner of the present invention, wherein, described lubricant can be selected from propyl carbinol, glycerol, 1,3 butylene glycol and 1, and one or more in the 4-butyleneglycol are preferably glycerol and/or 1, the 4-butyleneglycol.Lubricant mainly is the friction that reduces rubber rain brush and windshield glass, prevents that the rubber rain brush from scratching glass, prolongs rain brush work-ing life.
According to glass cleaner provided by the invention, wherein, described solvent is preferably the mixture of deionized water and organic solvent, and described organic solvent can be ethanol and/or Virahol.Deionized water is used for the dissolved dilution tensio-active agent, and the matching surface promoting agent performs to optimum regime; The adding of organic solvent can reduce the freezing point of water greatly, the freezing point of clean-out system is reached below-40 ℃, can accelerate to spray the evaporation rate of the clean-out system on windshield glass.Simultaneously the part organic solvent can also be on windshield glass film forming, play the effect of " antifog ".Ethanol and/or Virahol have good solvability to tensio-active agent and antifreeze membrane-forming agent, can reach good composite effect, and nontoxic pollution-free.
According to glass cleaner of the present invention, wherein, be benchmark with the described solvent of 100 weight parts, the weight of described organic solvent can be 20～50 weight parts, is preferably 30～50 weight parts, all the other are deionized water.
The preparation method of glass cleaner provided by the invention is: each component is mixed, be stirred to homogeneous transparent.
According to a further aspect in the invention, the application of glass cleaner of the present invention in the train front windshield cleans, the particularly application in the motor-car front windshield cleans are also provided.
The invention has the advantages that clean-out system provided by the invention:
1. have extremely strong soil removability, can fast and effeciently dispose the shellac on the train windshield glass that appears at high-speed cruising, birds droppings, the corpse of animalcule and pollutents such as bloodstain and oil stain;
2. have stronger environmental adaptability, can in-40～60 ℃ temperature, use, do not influence cleaning performance;
3. have lower corrodibility, the pH value approaches water between 6.8～7.2, to metal and nonmetally do not have corrosion substantially;
4. have good lubricity, reduce of the friction of rubber rain brush, prevent to abrade windshield glass windshield glass;
5. add antifreeze film forming component, can play anti-icing demist effect;
6. do not contain methyl alcohol and ammoniacal liquor etc. to the people poisonous or pungency composition.
Embodiment
Below in conjunction with embodiment the present invention is further described in detail, the embodiment that provides is only in order to illustrate the present invention, rather than in order to limit the scope of the invention.
Embodiment 1
Present embodiment is used for illustrating the preparation method of glass cleaner provided by the invention.
With alkylphenol polyoxyethylene 1 gram, sodium laurylsulfonate 0.5 gram, Starso 3.5 grams, ethylene glycol 100 grams, ethylene glycol monobutyl ether 50 grams, glycerol 20 grams, Virahol 350 grams, water 475 grams mix, and are stirred to homogeneous transparent, and recording its pH is 6.9.
Embodiment 2
Present embodiment is used for illustrating the preparation method of glass cleaner provided by the invention.
With fatty alcohol-polyoxyethylene ether 1.5 grams, Sodium dodecylbenzene sulfonate 0.7 gram, Starso 1.8 grams, 1,2-propylene glycol 80 grams, ethylene glycol monobutyl ether 150 grams, 1,4-butyleneglycol 10 grams, Virahol 300 grams, water 456 grams mix, and are stirred to homogeneous transparent, and recording its pH is 7.0.
Embodiment 3
Present embodiment is used for illustrating the preparation method of glass cleaner provided by the invention.
With fatty alcohol-polyoxyethylene ether 1 gram, aliphatic acid polyethenoxy ether sodium sulfate 0.8 gram, Sodium Nitrite 5 grams, ethylene glycol 50 grams, ethylene glycol monobutyl ether 150 grams, glycerol 10 grams, ethanol 300 grams, water 483 grams mix, and are stirred to homogeneous transparent, and recording its pH is 7.1.
The cleaning performance test
One, glass cleaner, pure water and the general-utility car front windshield clean-out system that uses embodiment 1-3 to make respectively cleans front windshield in the motor-car driving process, detailed process is: 500 kilometers of strokes, temperature variation is-30～25 ℃, every 1 hour front windshield is once cleaned, cleaning performance is as follows:
1, the glass cleaner that uses embodiment of the invention 1-3 to make cleans front windshield in the motor-car driving process, cleaning performance is: once spray can be disposed birds droppings, the corpse of animalcule and bloodstain and oil stain etc., sight line is good, and spray back front windshield does not haze.
2, use pure water in the motor-car driving process front windshield to be cleaned, cleaning performance is: repeatedly spray can't be removed birds droppings, the corpse of animalcule and bloodstain and oil stain etc., and rain brush is scraped afterwards, and front windshield hazes.
3, use general-utility car front windshield clean-out system (commercially available) in the motor-car driving process, front windshield to be cleaned, cleaning performance is: dispose birds droppings behind the spray several times, the corpse of animalcule and bloodstain and oil stain etc., after external temperature was lower than-15 ℃, along with the continuation reduction of temperature, glass cleaning solution viscosity increased, spray flux reduces, cleaning effect reduces greatly, illustrates that clean-out system begins icing sign is arranged, and spray back front windshield hazes once in a while.
Two, front windshield is not cleaned in the process of moving, after EMUs arrived at a station, with washing composition (commercially available) cleaning motor-car front windshield, cleaning performance was: dispose birds droppings, the corpse of animalcule and bloodstain and oil stain etc., windshield glass cleaning.
By above test as can be seen, the effect that to clean in the motor-car driving process compares, the cleaning performance of glass cleaner of the present invention is far superior to pure water and general-utility car front windshield clean-out system, and is suitable with the effect after the specially washing agent cleaning behind its cleaning performance and the train arrival.
Claims (10)
1. a glass cleaner is characterized in that, this clean-out system comprises nonionogenic tenside, anion surfactant, inhibiter, antifreeze membrane-forming agent, lubricant and solvent.
2. glass cleaner according to claim 1, wherein, the nonionogenic tenside that comprises 0.1～0.2 weight part in the clean-out system of 100 weight parts, 0.01 the anion surfactant of～0.1 weight part, 0.1 the inhibiter of～1.0 weight parts, the antifreeze membrane-forming agent of 5～25 weight parts, the lubricant of 1～5 weight part, all the other are solvent.
3. glass cleaner according to claim 1 and 2, wherein, the content of described anion surfactant is 0.01～0.05 weight part, preferably, the weight ratio of described nonionogenic tenside and anion surfactant is 1-3: 1, most preferably be 1.5～2.5: 1.
4. according to each described glass cleaner in the claim 1 to 3, wherein, described nonionogenic tenside is fatty alcohol-polyoxyethylene ether and/or alkylphenol polyoxyethylene; Described anion surfactant is selected from one or more in secondary alkyl sulfonate, dodecane sulfonate, dodecylbenzene sulfonate, aliphatic acid polyethenoxy ether vitriol, the alkyl succinic acid sulfonated ester, is preferably Sodium dodecylbenzene sulfonate, sodium laurylsulfonate, alkyl succinic acid ester sodium sulfonate and fatty acid polyether Vinyl Ether sodium sulfate.
5. according to each described glass cleaner in the claim 1 to 4, wherein, described inhibiter is selected from one or more in Sodium Nitrite, borax, trolamine, Starso, the Sodium orthomolybdate, is preferably Sodium Nitrite and Sodium orthomolybdate.
6. according to each described glass cleaner in the claim 1 to 5, wherein, described antifreeze membrane-forming agent is selected from ethylene glycol, 1, the 2-propylene glycol, 1, ammediol, with in the ethylene glycol monobutyl ether one or more, be preferably ethylene glycol, 1,2-propylene glycol and ethylene glycol monobutyl ether.
7. according to each described glass cleaner in the claim 1 to 6, wherein, described lubricant is selected from propyl carbinol, glycerol, 1,3 butylene glycol and 1, and the 4-butyleneglycol is preferably glycerol and 1, the 4-butyleneglycol.
8. according to each described glass cleaner in the claim 1 to 7, wherein, described solvent is the mixture of deionized water and organic solvent, and described organic solvent is ethanol and/or Virahol.
9. according to each described glass cleaner in the claim 1 to 8, wherein, be benchmark with the described solvent of 100 weight parts, the weight of described organic solvent is the 20-50 weight part, is preferably the 30-50 weight part, all the other are deionized water.
10. the application of each described glass cleaner in the train front windshield cleans, the particularly application in the motor-car front windshield cleans in the claim 1 to 9.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN 201110082165 CN102181326A (en) | 2011-04-01 | 2011-04-01 | Glass cleaner and application thereof |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN 201110082165 CN102181326A (en) | 2011-04-01 | 2011-04-01 | Glass cleaner and application thereof |
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| CN102181326A true CN102181326A (en) | 2011-09-14 |
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| CN 201110082165 Pending CN102181326A (en) | 2011-04-01 | 2011-04-01 | Glass cleaner and application thereof |
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| CN102660416A (en) * | 2012-05-02 | 2012-09-12 | 浙江东南橡胶机带有限公司 | Solid detergent for automotive windshield and preparation method for solid detergent |
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| CN102876292A (en) * | 2012-10-12 | 2013-01-16 | 苏州谷力生物科技有限公司 | Antifogging agent for glasses surface |
| CN102899155A (en) * | 2012-11-08 | 2013-01-30 | 戴新育 | Working solution special for machining of machine tool |
| CN102978026A (en) * | 2012-11-27 | 2013-03-20 | 高金菊 | Water glass for car |
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| CN103031111A (en) * | 2011-10-08 | 2013-04-10 | 天津博克尼科技发展有限公司 | Automotive glass deicer |
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| CN103087835A (en) * | 2013-03-02 | 2013-05-08 | 王蔚 | Detergent for automobile windshields |
| CN103740331A (en) * | 2013-11-27 | 2014-04-23 | 南通晶鑫光学玻璃有限公司 | Vehicle glass frost-prevention anti-freezing agent and preparation method thereof |
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Application publication date: 20110914 |