CN108822986A - A kind of flexible glass cleaner for increasing the agent that rubs of addition - Google Patents
A kind of flexible glass cleaner for increasing the agent that rubs of addition Download PDFInfo
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- CN108822986A CN108822986A CN201810562539.4A CN201810562539A CN108822986A CN 108822986 A CN108822986 A CN 108822986A CN 201810562539 A CN201810562539 A CN 201810562539A CN 108822986 A CN108822986 A CN 108822986A
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- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/66—Non-ionic compounds
- C11D1/83—Mixtures of non-ionic with anionic compounds
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/02—Inorganic compounds ; Elemental compounds
- C11D3/04—Water-soluble compounds
- C11D3/046—Salts
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/20—Organic compounds containing oxygen
- C11D3/2003—Alcohols; Phenols
- C11D3/2006—Monohydric alcohols
- C11D3/201—Monohydric alcohols linear
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- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/20—Organic compounds containing oxygen
- C11D3/2003—Alcohols; Phenols
- C11D3/2065—Polyhydric alcohols
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- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/20—Organic compounds containing oxygen
- C11D3/2075—Carboxylic acids-salts thereof
- C11D3/2079—Monocarboxylic acids-salts thereof
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/20—Organic compounds containing oxygen
- C11D3/2075—Carboxylic acids-salts thereof
- C11D3/2086—Hydroxy carboxylic acids-salts thereof
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/20—Organic compounds containing oxygen
- C11D3/22—Carbohydrates or derivatives thereof
- C11D3/222—Natural or synthetic polysaccharides, e.g. cellulose, starch, gum, alginic acid or cyclodextrin
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/26—Organic compounds containing nitrogen
- C11D3/30—Amines; Substituted amines ; Quaternized amines
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- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/26—Organic compounds containing nitrogen
- C11D3/32—Amides; Substituted amides
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- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/26—Organic compounds containing nitrogen
- C11D3/33—Amino carboxylic acids
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- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/34—Organic compounds containing sulfur
- C11D3/349—Organic compounds containing sulfur additionally containing nitrogen atoms, e.g. nitro, nitroso, amino, imino, nitrilo, nitrile groups containing compounds or their derivatives or thio urea
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- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/37—Polymers
- C11D3/3703—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
- C11D3/3707—Polyethers, e.g. polyalkyleneoxides
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- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/02—Anionic compounds
- C11D1/12—Sulfonic acids or sulfuric acid esters; Salts thereof
- C11D1/14—Sulfonic acids or sulfuric acid esters; Salts thereof derived from aliphatic hydrocarbons or mono-alcohols
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- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/38—Cationic compounds
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Abstract
The present invention relates to cleaning agent technical fields, and in particular to a kind of flexible glass cleaner for increasing the agent that rubs of addition.The glass cleaner includes following components：Cocoanut fatty acid diethanolamide, sodium alkyl sulfonate, isopropanol, chelating agent, flexibility increase rub agent, corrosion inhibiter, lubricant, preservative, essence and deionized water.Wherein, flexible to increase the agent that rubs as by the polyphenylene sulfide particle of surface hydrophilic modification, corrosion inhibiter is one of sodium metasilicate, sodium molybdate, morpholine and triethanolamine oleate or any a variety of mixture；Chelating agent is ethylenediamine tetra-acetic acid or citric acid；Lubricant is one of glycerol, water-soluble silicon oil and anhydrous sodium metasilicate.The type cleaning agent has the characteristics that strong detergency, water-saving easy rinsing, can also effectively be cleaned to organic viscose class spot of strong cohesive property, and will not cause to scratch to glass.
Description
Technical field
The present invention relates to cleaning agent technical fields, and in particular to a kind of flexible glass cleaner for increasing the agent that rubs of addition.
Background technique
With the continuous improvement of economic level, a large amount of office building has been built in Chinese city, these are for office
Office building is largely the office building with glass curtain wall, and the office building of glass curtain wall has the characteristics that light transmittance is good, office building
Internal illuminating effect more preferably, can reduce the lighting energy consumption in building, to have the characteristics that be more energy-saving and environmentally friendly.
The office building of glass curtain wall undergoes wind and weather solarization throughout the year, can by air dust or pollutant be attached to table
Face.In order to promote the overall beautiful of city, a kind of emerging industry out, high building exterior wall cleaning are bred in modern metropolitan cities.It is engaged in
The personnel of this industry are the trained high-altitude application worker of profession, utilize high-altitude application rope, safety rope, high-altitude seat plate（Or
Platform sling, hanging basket etc.）Carry out the top-down work for carrying out scrub cleaning formulation for building exposed wall material, cleaning dirt dust
Make.This work risk is very big, so safety is by selecting the same of up-to-standard operating rope and safety rope to be important
When, scientific preparation proportion is also reasonably carried out, building exposed wall could be made to clean beautiful, clean, environmentally friendly, safe, just may be used
So that the building exposed wall ornament materials service life extends.
Curtain cleaning needs to be cleaned using dedicated glass cleaner, and glass cleaner is widely used in building, dress
Decorations, automobile, electronics, optical instrument various industries.Current market sales of cleaning agent that can be used for cleaning glass is liquid
Cleaning agent after cleaning agent is coated on glass, needs to be cleaned with clear water, can be only achieved the purpose of cleaning.
Other than common coal ash, dust, pollutant, it can also be hit because of insect on cladding glass or material bonds and shape
At the sticking spots of a variety of tools, this spot is very difficult to remove, when cleaning do not require nothing more than wetting of the detergent with height,
Dissolution, dissociation, dispersion, the effect of lubrication, it is also necessary to which detergent has certain frictional resistance, by way of increasing frictional force
Spot is removed from glass curtain wall surface, but the surface of glass is caused to draw because increasing in worry detergent and rubbing into branch
Hurt, is not contained in nearly all glass detergent and increase the agent ingredient that rubs.
Patent publication No. CN102604751A discloses a kind of cleaning agent for optical glass, and length is contained in the type glass cleaner
Carbochain binary acid, inorganic base, nonionic surfactant, special surfactant, intercalating agent, has anionic surfactant
Machine alkali, deionized water；The type cleaning agent overcomes the defect that traditional cleaning agent corrosivity is big, cleaning force is poor, provides a kind of corrosion
The cleaning agent for optical glass that property is small, washing power is excellent.But detergent is for glass surface contamination viscose class organic pollutant
Cleaning effect relative deficiency.
Patent publication No. CN102586035A discloses a kind of molybdenum aluminium molybdenum coated glass cleaning agent, which overcomes biography
The molybdenum aluminium molybdenum ito coated glass dirty removal capacities of system are weak, perishable substrate, the feature of environmental protection are poor, the disadvantage more than foam, the clearing glass provided
Lotion dirt-removing power is strong, has more wide environmental suitability, has preferable stability, low bubble, easily rinses, with good
It is wetability, not damaged to glass surface, but to still remain organic adhesive contaminant cleaning effect poor for the type glass cleaner
The problem of.
Summary of the invention
Aiming at the problems existing in the prior art, the flexible glass cleaner for increasing the agent that rubs is added the present invention provides a kind of,
The type cleaning agent has the characteristics that strong detergency, water-saving easy rinsing, in addition, be added in the cleaning agent it is flexible increase the agent that rubs, can be with
Organic viscose class spot of strong cohesive property is effectively cleaned, and glass will not be caused to scratch.
A kind of flexible glass cleaner for increasing the agent that rubs of addition, according to mass fraction, glass cleaner includes following components：Coconut palm
5-10 parts of seed oil fatty diglycollic amide, 4-8 parts of sodium alkyl sulfonate, 5-8 parts of isopropanol, 4-6 parts of chelating agent, flexibility increases the agent that rubs
2-5 parts, 0.1-0.3 parts of corrosion inhibiter, 0.3-0.6 parts of lubricant, 0.2-0.4 parts of preservative, 0.2-0.6 parts of essence, deionized water
85-100 parts.
Preferably, according to mass fraction, glass cleaner includes following components：Cocoanut fatty acid diethanolamide 6-8
Part, 5-7 parts of sodium alkyl sulfonate, 6-7 parts of isopropanol, 4-5 parts of chelating agent, flexibility, which increases, rubs 3-4 parts of agent, and 0.1-0.2 parts of corrosion inhibiter, profit
0.4-0.5 parts of lubrication prescription, 0.2-0.3 parts of preservative, 0.3-0.5 parts of essence, 90-95 parts of deionized water.
It is further preferred that glass cleaner includes following components according to mass fraction：Coco-nut oil fatty acid diethanol acyl
7 parts of amine, 6 parts of sodium alkyl sulfonate, 6.5 parts of isopropanol, 4.5 parts of chelating agent, flexibility, which increases, rubs 3.5 parts of agent, and 0.2 part of corrosion inhibiter, lubrication
0.5 part of agent, 0.3 part of preservative, 0.4 part of essence, 92 parts of deionized water.
In the present invention, the preparation method that flexibility increases the agent that rubs includes the following steps：
According to mass fraction, by 8 parts of polyphenylene sulfides, 0.2 part of fatty diglycollic amide, 0.7 part of alkyl trimethyl chlorination
Ammonium is added in 100 parts of n,N-Dimethylformamide solvent, and under nitrogen atmosphere protection, the solvent in heating autoclave is extremely
145-150 DEG C of promotion dissolution；Solution is cooled down rapidly with frozen water to boiling point hereinafter, resin particle precipitation, uses ice water after dissolution
Flushing extracts particle, resin particle hydrolyzate is obtained resin particle after filtration drying, which is institute
Flexibility is needed to increase the agent that rubs, the partial size that flexibility increases the agent that rubs is 30-50 μm.
Preferably, flexibility increases the agent that rubs and needs to handle by hydrophilic modifying, and the method for hydrophilic modifying processing includes the following steps：
According to mass fraction, weighs 5 parts of flexible increase and rub agent and 50 parts of dioxane are added in Scattered Kettle, in earthquake shaking table at concussion
It is filtered after reason 1.5-2h；10 parts of agaroses and 3 parts of sodium hydroxides are added in 500 parts of dimethyl sulphoxide aqueous solution, with
Then filtered flexibility is increased the agent that rubs and is added in solution by the revolving speed stirring and dissolving of 100-200r/min, heated solution to 70-
73 DEG C, insulation reaction 20-22h is filtered after reaction, is then washed with 80-85 DEG C of deionized water；Then will
10 parts of sodium hydroxides are added in dimethyl sulphoxide aqueous solution and dissolve, and the flexibility of upper step is increased the agent that rubs and is added in solution, Xiang Rong
5 parts of ethylene glycol diglycidylethers are added in liquid and are stirred to react 10-15h, are filtered after reaction, to flexibility after suction filtration
Increase the agent that rubs to be washed using deionized water, ethyl alcohol and deionization respectively, be dried extremely in 50-55 DEG C of vacuum environment after washing
Constant weight.
Wherein, the volume ratio of dimethyl sulfoxide and water is 1 in dimethyl sulphoxide aqueous solution:4.
Using the solvent of the proportional arrangement, after carrying out basic treatment, can be adapted for the type resin particle in the solution with
Hydrophilic modifier is chemically reacted, and modifying agent and resin particle can react in the control environment that the solvent provides, and is being set
Rouge microparticle surfaces form hydrophilic group, so that the type particle can be removed completely by clear water.
Preferably, corrosion inhibiter is one of sodium metasilicate, sodium molybdate, morpholine and triethanolamine oleate or any a variety of
Mixture.The effect of corrosion inhibiter is to improve the type glass cleaner corrosive nature, avoids cleaning agent in washing process, to glass
Cause chemical damage in surface.
Preferably, chelating agent is ethylenediamine tetra-acetic acid or citric acid.
The effect of chelating agent is to improve the stability and dispersibility of cleaning agent, allow it is flexible increase rub agent be scattered in
In glass cleaner, the problem of being precipitated or settling will not occur in storage process.
Preferably, lubricant is one of glycerol, water-soluble silicon oil and anhydrous sodium metasilicate.
The effect of lubricant is the lubricant effect for improving glass cleaner, reduces the damage to glass, and utilize glass
The rinsing of cleaning agent.
The preparation method of glass cleaner provided by the invention includes the following steps：
（1）Deionized water is added in Scattered Kettle, is heated to 45-50 DEG C；
（2）According to mass fraction, by cocoanut fatty acid diethanolamide, sodium alkyl sulfonate, isopropanol, chelating agent, flexible increasing
It rubs agent and lubricant is added in Scattered Kettle, with the revolving speed decentralized processing 25-30min of 550-600r/min；
（3）Corrosion inhibiter, preservative and essence are added in the Scattered Kettle walked upwards, continues to stir 20-25min, then stand naturally
2-3h, filling and sealing.
The present invention has following beneficial effect：
The pressure sensitive adhesive that the type glass cleaner can be infected with glass surface, or by the sticking pollution of tool that organic matter is formed
Object is effectively removed.When removing, pollutant is soaked and dissociated by substance in glass cleaner first, then by having
The flexibility for increasing effect of rubbing increases the agent that rubs and rubs to pollutant, so that pollutant is stripped down from glass surface.
Wherein, which increases the agent that rubs and is prepared by polyphenylene sulfide, and the diameter of particle that flexibility increases the agent that rubs is small, hardness
It is lower, glass surface will not be caused in use process to wipe scuffing.It rubs agent dividing in glass cleaner to improve flexible increasing
Effect is dissipated, is added to chelating agent in glass cleaner, the chelation of chelating agent can make glass cleaner in storage process
In will not occur settle and be precipitated, improve the stability and dispersion effect of glass cleaner.
In order to enhance the flexible easy-clear effect for increasing the agent that rubs, flexibility increases agent surface of rubbing and has carried out hydrophilic modifying processing, modified
Afterwards flexible increases the agent that rubs with very outstanding hydrophily, be both conducive to it is evenly dispersed in glass cleaner, can also very easily
Rinsed well with clear water, it is more environmentally-friendly to reduce glass cleaner using the water consumption in rear rinse cycle.
Specific embodiment
Below with reference to embodiment, further description of the specific embodiments of the present invention, and following embodiment is only used for more
Technical solution of the present invention is clearly demonstrated, and not intended to limit the protection scope of the present invention.
Embodiment 1
A kind of flexible glass cleaner for increasing the agent that rubs of addition, according to mass fraction, glass cleaner includes following components：Coconut oil
5 parts of fatty diglycollic amide, 4 parts of sodium alkyl sulfonate, 5 parts of isopropanol, 4 parts of chelating agent, flexibility, which increases, rubs 2 parts of agent, corrosion inhibiter 0.1
Part, 0.3 part of lubricant, 0.2 part of preservative, 0.2 part of essence, 85 parts of deionized water.
In the present embodiment, the preparation method that flexibility increases the agent that rubs includes the following steps：
According to mass fraction, by 8 parts of polyphenylene sulfides, 0.2 part of fatty diglycollic amide, 0.7 part of alkyl trimethyl chlorination
Ammonium is added in 100 parts of n,N-Dimethylformamide solvent, and under nitrogen atmosphere protection, the solvent in heating autoclave is extremely
145 DEG C of promotion dissolutions；Solution is cooled down rapidly with frozen water to boiling point hereinafter, resin particle precipitation, is rinsed using ice water after dissolution
Particle is extracted, resin particle hydrolyzate is obtained into resin particle after filtration drying, the resin particle is soft needed for being
Property increase and rub agent, the partial size that flexibility increases the agent that rubs is 30-50 μm.
Flexibility increases the agent that rubs and needs to handle by hydrophilic modifying, and the method for hydrophilic modifying processing includes the following steps：According to matter
Number is measured, 5 parts of flexible increase is weighed and rubs agent and 50 parts of dioxane are added in Scattered Kettle, concussion processing 1.5h in earthquake shaking table
After filter；10 parts of agaroses and 3 parts of sodium hydroxides are added in 500 parts of dimethyl sulphoxide aqueous solution, with 100r/min's
Revolving speed stirring and dissolving, then by it is filtered it is flexible increase the agent that rubs and be added in solution, heated solution to 70 DEG C, insulation reaction 20h,
It is filtered, is then washed with 80 DEG C of deionized water after reaction；Then 10 parts of sodium hydroxides are added to diformazan
It is dissolved in base sulfoxide aqueous solution, the flexibility of upper step is increased into the agent that rubs and is added in solution, 5 parts of ethylene glycol two are added into solution and shrink
Glycerin ether is simultaneously stirred to react 10h, is filtered after reaction, increases the agent that rubs to flexibility after suction filtration and uses deionized water, second respectively
Pure and mild deionization is washed, and is dried in 50 DEG C of vacuum environment to constant weight after washing.Wherein, in dimethyl sulphoxide aqueous solution
The volume ratio of dimethyl sulfoxide and water is 1:4.
Corrosion inhibiter is sodium metasilicate.
Chelating agent is ethylenediamine tetra-acetic acid.
Lubricant is glycerol.
The preparation method of glass cleaner provided in this embodiment includes the following steps：
（1）Deionized water is added in Scattered Kettle, is heated to 45 DEG C；
（2）According to mass fraction, by cocoanut fatty acid diethanolamide, sodium alkyl sulfonate, isopropanol, chelating agent, flexible increasing
It rubs agent and lubricant is added in Scattered Kettle, with the revolving speed decentralized processing 25min of 550r/min；
（3）Corrosion inhibiter, preservative and essence are added in the Scattered Kettle walked upwards, continues to stir 20min, then stands 2h naturally,
Filling and sealing.
Embodiment 2
A kind of flexible glass cleaner for increasing the agent that rubs of addition, according to mass fraction, glass cleaner includes following components：Coconut oil
10 parts of fatty diglycollic amide, 8 parts of sodium alkyl sulfonate, 8 parts of isopropanol, 6 parts of chelating agent, flexibility, which increases, rubs 5 parts of agent, corrosion inhibiter
0.3 part, 0.6 part of lubricant, 0.4 part of preservative, 0.6 part of essence, 100 parts of deionized water.
In the present embodiment, the preparation method that flexibility increases the agent that rubs includes the following steps：
According to mass fraction, by 8 parts of polyphenylene sulfides, 0.2 part of fatty diglycollic amide, 0.7 part of alkyl trimethyl chlorination
Ammonium is added in 100 parts of n,N-Dimethylformamide solvent, and under nitrogen atmosphere protection, the solvent in heating autoclave is extremely
150 DEG C of promotion dissolutions；Solution is cooled down rapidly with frozen water to boiling point hereinafter, resin particle precipitation, is rinsed using ice water after dissolution
Particle is extracted, resin particle hydrolyzate is obtained into resin particle after filtration drying, the resin particle is soft needed for being
Property increase and rub agent, the partial size that flexibility increases the agent that rubs is 30-50 μm.
Flexibility increases the agent that rubs and needs to handle by hydrophilic modifying, and the method for hydrophilic modifying processing includes the following steps：According to matter
Number is measured, 5 parts of flexible increase is weighed and rubs agent and 50 parts of dioxane are added in Scattered Kettle, in earthquake shaking table after concussion processing 2h
It filters；10 parts of agaroses and 3 parts of sodium hydroxides are added in 500 parts of dimethyl sulphoxide aqueous solution, with turning for 200r/min
Then filtered flexibility is increased the agent that rubs and is added in solution by fast stirring and dissolving, heated solution is to 73 DEG C, insulation reaction 22h, instead
It is filtered after answering, is then washed with 85 DEG C of deionized water；Then 10 parts of sodium hydroxides are added to dimethyl
It is dissolved in sulfoxide aqueous solution, the flexibility of upper step is increased into the agent that rubs and is added in solution, 5 parts of ethylene glycol two of addition shrink sweet into solution
Oily ether is simultaneously stirred to react 15h, is filtered after reaction, increases the agent that rubs to flexibility after suction filtration and uses deionized water, ethyl alcohol respectively
It is washed with deionization, is dried in 55 DEG C of vacuum environment to constant weight after washing.Wherein, two in dimethyl sulphoxide aqueous solution
The volume ratio of methyl sulfoxide and water is 1:4.
Corrosion inhibiter is sodium molybdate.
Chelating agent is citric acid.
Lubricant is water-soluble silicon oil.
The preparation method of glass cleaner provided in this embodiment includes the following steps：
（1）Deionized water is added in Scattered Kettle, is heated to 50 DEG C；
（2）According to mass fraction, by cocoanut fatty acid diethanolamide, sodium alkyl sulfonate, isopropanol, chelating agent, flexible increasing
It rubs agent and lubricant is added in Scattered Kettle, with the revolving speed decentralized processing 30min of 600r/min；
（3）Corrosion inhibiter, preservative and essence are added in the Scattered Kettle walked upwards, continues to stir 25min, then stands 3h naturally,
Filling and sealing.
Embodiment 3
A kind of flexible glass cleaner for increasing the agent that rubs of addition, according to mass fraction, glass cleaner includes following components：Coconut oil
7 parts of fatty diglycollic amide, 6 parts of sodium alkyl sulfonate, 6.5 parts of isopropanol, 4.5 parts of chelating agent, flexibility, which increases, rubs 3.5 parts of agent, delays
0.2 part of agent, 0.5 part of lubricant, 0.3 part of preservative, 0.4 part of essence, 92 parts of deionized water of erosion.
In the present embodiment, the preparation method that flexibility increases the agent that rubs includes the following steps：
According to mass fraction, by 8 parts of polyphenylene sulfides, 0.2 part of fatty diglycollic amide, 0.7 part of alkyl trimethyl chlorination
Ammonium is added in 100 parts of n,N-Dimethylformamide solvent, and under nitrogen atmosphere protection, the solvent in heating autoclave is extremely
148 DEG C of promotion dissolutions；Solution is cooled down rapidly with frozen water to boiling point hereinafter, resin particle precipitation, is rinsed using ice water after dissolution
Particle is extracted, resin particle hydrolyzate is obtained into resin particle after filtration drying, the resin particle is soft needed for being
Property increase and rub agent, the partial size that flexibility increases the agent that rubs is 30-50 μm.
Flexibility increases the agent that rubs and needs to handle by hydrophilic modifying, and the method for hydrophilic modifying processing includes the following steps：According to matter
Number is measured, 5 parts of flexible increase is weighed and rubs agent and 50 parts of dioxane are added in Scattered Kettle, concussion processing 1.7h in earthquake shaking table
After filter；10 parts of agaroses and 3 parts of sodium hydroxides are added in 500 parts of dimethyl sulphoxide aqueous solution, with 150r/min's
Revolving speed stirring and dissolving, then by it is filtered it is flexible increase the agent that rubs and be added in solution, heated solution to 72 DEG C, insulation reaction 21h,
It is filtered, is then washed with 83 DEG C of deionized water after reaction；Then 10 parts of sodium hydroxides are added to diformazan
It is dissolved in base sulfoxide aqueous solution, the flexibility of upper step is increased into the agent that rubs and is added in solution, 5 parts of ethylene glycol two are added into solution and shrink
Glycerin ether is simultaneously stirred to react 13h, is filtered after reaction, increases the agent that rubs to flexibility after suction filtration and uses deionized water, second respectively
Pure and mild deionization is washed, and is dried in 53 DEG C of vacuum environment to constant weight after washing.Wherein, in dimethyl sulphoxide aqueous solution
The volume ratio of dimethyl sulfoxide and water is 1:4.
Corrosion inhibiter is the mixture of sodium metasilicate and triethanolamine oleate.
Chelating agent is ethylenediamine tetra-acetic acid.
Lubricant is anhydrous sodium metasilicate.
The preparation method of glass cleaner provided in this embodiment includes the following steps：
（1）Deionized water is added in Scattered Kettle, is heated to 48 DEG C；
（2）According to mass fraction, by cocoanut fatty acid diethanolamide, sodium alkyl sulfonate, isopropanol, chelating agent, flexible increasing
It rubs agent and lubricant is added in Scattered Kettle, with the revolving speed decentralized processing 27min of 580r/min；
（3）Corrosion inhibiter, preservative and essence are added in the Scattered Kettle walked upwards, continues to stir 22min, then stand naturally
2.5h, filling and sealing.
Performance test
1, according to QB/T 4086-2010《Glass cleaner standard》Specified in test method to the glass cleaning of the present embodiment
Stability, surface tension, pH value of agent etc. are tested to obtain following test result：
Table 1：The performance test results of the present embodiment glass cleaner
The above experimental data discovery is analyzed, glass cleaner property provided by the invention is stablized, the good dispersion of material, surface
The compound requirements of the national standard of power, for the pH value of glass cleaner at neutrality, use process will not cause corruption to human body or other materials
Erosion, to the comparatively safe environmental protection of environment.
2, respectively using the detergent in the present embodiment, white dish washing liquid and the washing of " Lan Shuai " glass are found with what is bought in the market
Agent is tested for the property test, and founding white dish washing liquid group is comparative example 1, and blue general's glass detergent group is comparative example 2, every group of experiment
Sample size be 5 groups, detect the cleaning effect of the spot that different detergent cleaning pressure sensitive adhesives leave on glass and average
Cleaning time, and detect whether cleaning process causes glass surface to scratch；Obtain descended test result：
Table 2：The cleaning effect of glass cleaner and comparative example in the present embodiment
| Test item | Comparative example 1 | Comparative example 2 | Embodiment 1 | Embodiment 2 | Embodiment 3 |
| Cleaning effect | Fail clean | It is completely clean | It is completely clean | It is completely clean | It is completely clean |
| Average cleaning time/s | \ | 25s | 11s | 13s | 10s |
| Surface scratching | Nothing | Nothing | Nothing | Nothing | Nothing |
The above test data discovery is analyzed, glass cleaner of the invention has the sticky spot that pressure sensitive adhesive generates on glass
There is good cleaning effect, and the clean used time is shorter, relative to quotient's common glass detergent in the market, contracts when Clean-
Short 12-15s, cleaning efficiency obtain larger promotion.In addition, glass cleaner use process will not cause glass surface significantly
It wipes and scratches.
The foregoing is only a preferred embodiment of the present invention, is not intended to restrict the invention, although referring to aforementioned reality
Applying example, invention is explained in detail, for those skilled in the art, still can be to aforementioned each implementation
Technical solution documented by example is modified or equivalent replacement of some of the technical features.It is all in essence of the invention
Within mind and principle, any modification, equivalent replacement, improvement and so on be should all be included in the protection scope of the present invention.
Claims (10)
1. a kind of flexible glass cleaner for increasing the agent that rubs of addition, it is characterised in that：According to mass fraction, the glass cleaner packet
Include following components：5-10 parts of cocoanut fatty acid diethanolamide, 4-8 parts of sodium alkyl sulfonate, 5-8 parts of isopropanol, chelating agent 4-6
Part, flexibility, which increases, rubs 2-5 parts of agent, and 0.1-0.3 parts of corrosion inhibiter, 0.3-0.6 parts of lubricant, 0.2-0.4 parts of preservative, essence 0.2-
0.6 part, 85-100 parts of deionized water.
2. the flexible glass cleaner for increasing the agent that rubs of a kind of addition according to claim 1, it is characterised in that：According to mass parts
Number, the glass cleaner includes following components：It is 6-8 parts of cocoanut fatty acid diethanolamide, 5-7 parts of sodium alkyl sulfonate, different
6-7 parts of propyl alcohol, 4-5 parts of chelating agent, flexibility, which increases, rubs 3-4 parts of agent, and 0.1-0.2 parts of corrosion inhibiter, 0.4-0.5 parts of lubricant, preservative
0.2-0.3 parts, 0.3-0.5 parts of essence, 90-95 parts of deionized water.
3. the flexible glass cleaner for increasing the agent that rubs of a kind of addition according to claim 2, it is characterised in that：According to mass parts
Number, the glass cleaner includes following components：7 parts of cocoanut fatty acid diethanolamide, 6 parts of sodium alkyl sulfonate, isopropanol
6.5 parts, 4.5 parts of chelating agent, flexibility, which increases, rubs 3.5 parts of agent, and 0.2 part of corrosion inhibiter, 0.5 part of lubricant, 0.3 part of preservative, essence 0.4
Part, 92 parts of deionized water.
4. the flexible glass cleaner for increasing the agent that rubs of a kind of addition according to claim 1, it is characterised in that：The flexible increasing
The preparation method of agent of rubbing includes the following steps：
According to mass fraction, by 8 parts of polyphenylene sulfides, 0.2 part of fatty diglycollic amide, 0.7 part of alkyl trimethyl chlorination
Ammonium is added in 100 parts of n,N-Dimethylformamide solvent, and under nitrogen atmosphere protection, the solvent in heating autoclave is extremely
145-150 DEG C of promotion dissolution；Solution is cooled down rapidly with frozen water to boiling point hereinafter, resin particle precipitation, uses ice water after dissolution
Flushing extracts particle, resin particle hydrolyzate is obtained resin particle after filtration drying, which is institute
Flexibility is needed to increase the agent that rubs, the partial size that flexibility increases the agent that rubs is 30-50 μm.
5. the flexible glass cleaner for increasing the agent that rubs of a kind of addition according to claim 4, it is characterised in that：The flexible increasing
The agent that rubs needs to handle by hydrophilic modifying, and the method for hydrophilic modifying processing includes the following steps：According to mass fraction, 5 parts are weighed
Flexibility, which increases, rubs agent and 50 parts of dioxane are added in Scattered Kettle, filters after concussion processing 1.5-2h in earthquake shaking table；By 10
Part agarose and 3 parts of sodium hydroxides are added in 500 parts of dimethyl sulphoxide aqueous solution, are stirred with the revolving speed of 100-200r/min
Then filtered flexibility is increased the agent that rubs and is added in solution by dissolution, heated solution is to 70-73 DEG C, insulation reaction 20-22h, instead
It is filtered after answering, is then washed with 80-85 DEG C of deionized water；Then 10 parts of sodium hydroxides are added to diformazan
It is dissolved in base sulfoxide aqueous solution, the flexibility of upper step is increased into the agent that rubs and is added in solution, 5 parts of ethylene glycol two are added into solution and shrink
Glycerin ether is simultaneously stirred to react 10-15h, is filtered after reaction, after suction filtration to flexibility increasing rub agent use respectively deionized water,
Ethyl alcohol and deionization are washed, and are dried in 50-55 DEG C of vacuum environment to constant weight after washing.
6. the flexible glass cleaner for increasing the agent that rubs of a kind of addition according to claim 5, it is characterised in that：The dimethyl
The volume ratio of dimethyl sulfoxide and water is 1 in sulfoxide aqueous solution:4.
7. the flexible glass cleaner for increasing the agent that rubs of a kind of addition according to claim 1, it is characterised in that：The corrosion inhibiter
For one of sodium metasilicate, sodium molybdate, morpholine and triethanolamine oleate or any a variety of mixture.
8. the flexible glass cleaner for increasing the agent that rubs of a kind of addition according to claim 1, it is characterised in that：The chelating agent
For ethylenediamine tetra-acetic acid or citric acid.
9. the flexible glass cleaner for increasing the agent that rubs of a kind of addition according to claim 1, it is characterised in that：The lubricant
For one of glycerol, water-soluble silicon oil and anhydrous sodium metasilicate.
10. the flexible glass cleaner for increasing the agent that rubs of a kind of addition according to claim 9, it is characterised in that：The glass
The preparation method of cleaning agent includes the following steps：
（1）Deionized water is added in Scattered Kettle, is heated to 45-50 DEG C；
（2）According to mass fraction, by cocoanut fatty acid diethanolamide, sodium alkyl sulfonate, isopropanol, chelating agent, flexible increasing
It rubs agent and lubricant is added in Scattered Kettle, with the revolving speed decentralized processing 25-30min of 550-600r/min；
（3）Corrosion inhibiter, preservative and essence are added in the Scattered Kettle walked upwards, continues to stir 20-25min, then stand naturally
2-3h, filling and sealing.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201810562539.4A CN108822986A (en) | 2018-06-04 | 2018-06-04 | A kind of flexible glass cleaner for increasing the agent that rubs of addition |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201810562539.4A CN108822986A (en) | 2018-06-04 | 2018-06-04 | A kind of flexible glass cleaner for increasing the agent that rubs of addition |
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| Publication Number | Publication Date |
|---|---|
| CN108822986A true CN108822986A (en) | 2018-11-16 |
Family
ID=64143505
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| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201810562539.4A Withdrawn CN108822986A (en) | 2018-06-04 | 2018-06-04 | A kind of flexible glass cleaner for increasing the agent that rubs of addition |
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Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN110982637A (en) * | 2019-08-14 | 2020-04-10 | 朱洵 | Glass cleaning agent |
Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPH07310091A (en) * | 1994-05-17 | 1995-11-28 | Ajinomoto Co Inc | Liquid detergent composition |
| CN102181326A (en) * | 2011-04-01 | 2011-09-14 | 中国铁道科学研究院金属及化学研究所 | Glass cleaner and application thereof |
| CN107474967A (en) * | 2017-07-29 | 2017-12-15 | 安徽艺云玻璃有限公司 | A kind of glass cleaner and preparation method thereof |
-
2018
- 2018-06-04 CN CN201810562539.4A patent/CN108822986A/en not_active Withdrawn
Patent Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPH07310091A (en) * | 1994-05-17 | 1995-11-28 | Ajinomoto Co Inc | Liquid detergent composition |
| CN102181326A (en) * | 2011-04-01 | 2011-09-14 | 中国铁道科学研究院金属及化学研究所 | Glass cleaner and application thereof |
| CN107474967A (en) * | 2017-07-29 | 2017-12-15 | 安徽艺云玻璃有限公司 | A kind of glass cleaner and preparation method thereof |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN110982637A (en) * | 2019-08-14 | 2020-04-10 | 朱洵 | Glass cleaning agent |
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