CN101096619A - Ceramic cleaning fluid - Google Patents
Ceramic cleaning fluid Download PDFInfo
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- CN101096619A CN101096619A CNA2006100146032A CN200610014603A CN101096619A CN 101096619 A CN101096619 A CN 101096619A CN A2006100146032 A CNA2006100146032 A CN A2006100146032A CN 200610014603 A CN200610014603 A CN 200610014603A CN 101096619 A CN101096619 A CN 101096619A
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Abstract
The invention discloses a ceramic cleaning fluid, which comprises the following parts: 0.5%-8% solvent typed ether as component I, 3%-20% organic base as component II, 0.01%-0.5% first surface activator as component III, 1%-8% second surface activator as component IC and 63.5%-94.9% deionized water as solvent as component V. The invention is characterized by the following: 1. displaying oblivious cleaning effect for ceramics; 2. overcoming the defect of ozone layer by traditional ceramic abluent; 3. making the pH value of ceramic abluent within alkaline scale without corroding for equipment; 4. using safely; 5. saving cost obviously; 6. fitting for cleaning kinds of hard surface.
Description
(1) technical field:
The present invention relates to a kind of ceramic cleaning fluid, particularly a kind of scavenging solution that is applied to a kind of aluminum oxide, zirconium white industrial ceramics.
(2) background technology:
Aluminum oxide, zirconia ceramics are the third generation materials of high speed development after metal and engineering plastics, development of modern industry, and pottery uses not only to be used for home decoration and family.Metal and the incomparable performances of engineering plastics such as high temperature resistant, corrosion-resistant, wear-resistant, high insulation that its finished product have.Be widely used in every profession and trades such as machinery, electronics, electrical equipment, chemical industry, weaving, hot-water heating five metals, automobile.Existing high technology ceramics spare product classification mainly contains: structural ceramics, porous ceramics, electronic ceramics.
Along with the development of ceramic industry, the shape of pottery is more and more irregular, much presents different shapeies such as sky shape pipe dress.This just has higher requirement to the cleaning after ceramic polished.Traditional purging method is manual cleaning, so promptly loses time and is difficult to reach excellent cleaning effect, and be unfavorable for big industrial production.
And because fouls such as abrasive material and iron rust in surface attachment, are difficult to remove, so to adopt suitably and purging method efficiently.For a long time, use Ozone Depleting Substances such as trichloroethane, CFC-113 (being called for short the ODS material) to clean mostly, but the ozonosphere in these ODS material havoc earth high-altitudes, the serious harm environment for human survival.According to the Montreal Protocol on Substances that Deplete the Ozone Layer requirement, developed country stopped to produce and using the ODS material in 1996, and developing country to 2010 stops to produce and using the ODS material.Therefore research substitutes the novel cleaning technique of ODS cleaning, has become to be badly in need of one of key subjects that solve.
(3) summary of the invention:
The objective of the invention is to design a kind of ceramic cleaning fluid, it can effectively remove impurity, especially CeO on the pottery
2Particle reaches the environmental requirement that does not damage the ozone layer simultaneously, is a kind of good ceramic masses scavenging solution.
Technical scheme of the present invention: a kind of ceramic cleaning fluid, it is characterized in that it is to be become to be grouped into for five kinds with deionized water by solvent-borne type ethers, organic bases, first kind of tensio-active agent, second kind of tensio-active agent, its weight fraction is respectively: the solvent-borne type ethers accounts for 0.5%～8% as composition I, organic bases accounts for 3%～20% as composition II, first kind of tensio-active agent accounts for 0.01%～0.5% as composition III, second kind of tensio-active agent accounts for 1%～8% as composition IV, and deionized water accounts for 63.5%～94.9% as solvent for composition V.
Above-mentioned said solvent-borne type ethers comprises ethylene glycol monobutyl ether, propylene glycol monobutyl ether, Virahol or ethanol.
Above-mentioned said organic bases comprises monoethanolamine, quadrol, diethanolamine or trolamine.
Above-mentioned said first kind of tensio-active agent comprises anion active agent or amphoterics.
Above-mentioned said second kind of tensio-active agent comprises that polyoxyethylene is nonionogenic tenside, polyol ester class nonionogenic tenside, polymer or element organic system nonionic surfactants.
Above-mentioned said polyoxyethylene is that ionic surfactant pack is drawn together: polyoxyethylene alkylphenol, polyoxyethylene Fatty Alcohol(C12-C14 and C12-C18), polyoxyethylene fatty acid ester, polyoxyethylene amine or polyoxyethylate amide.
Principle of work of the present invention is: a kind of new thinking is adopted in this case, pottery after promptly adopting the corrosive way to polishing is handled, promptly fall very thin one deck, impurity such as greasy dirt, iron rust, fingerprint and particle are removed simultaneously, guaranteed the thoroughness of cleaning at ceramic surface corrosion.
The nontoxic odorless of solvent-borne type ethers in the ceramic cleaning fluid is the solvent with high flash point and capacitive oil; Organic bases can strengthen cleaning performance, enhancing solvability, adjusting pH value and avoid equipment is caused the burn into nontoxic pollution-free; First kind of tensio-active agent can reduce the surface tension of solution, makes ceramic cleaning fluid can spread over ceramic surface all sidedly, and strong osmosis is arranged, and can accelerate mass exchange, improve cleaning rate; Second kind of tensio-active agent forms protective layer at substrate surface, prevents the pollutent second adsorption, can reduce solution surface tension, and make promoting agent can be penetrated into ceramic surface and the impurity that is cleaned between, reach and remove the purpose of polluting; Deionized water is as solvent, makes that above-mentioned various compositions can uniform dissolution, makes the pH value reach definite scope simultaneously.
The raw material that the present invention is selected, except ceramic surface is had the cleanup action, adopting the non-ODS material that does not damage the ozone layer simultaneously is main raw material, makes product satisfy environmental requirement.
Preparation process of the present invention is: the addition sequence of each composition: composition I and II add among the composition V, and composition I and II are dissolved fully, add composition III and IV then.Stir.
Application example 1: will be through grinding and unwashed pottery is put into this ceramic cleaning fluid of 3%, under 40 ℃ in ultrasonic machine ultrasonic 5min, hyperacoustic setpoint frequency is 28kHz.Pottery is taken out back blower drying, observe with colored lights, no greasy dirt, particle etc., cleaning performance is good.
Application example 2: will be through grinding and unwashed pottery is put into this glass erosion liquid of 8%, under 40 ℃ in ultrasonic machine ultrasonic 3min, hyperacoustic setpoint frequency is 28kHz.Pottery is taken out back blower drying, observe with colored lights, no greasy dirt, particle etc., cleaning performance is good.
Application example 3: will be through polishing and unwashed pottery is put into this ceramic cleaning fluid of 3%, under 60 ℃ in ultrasonic machine ultrasonic 3min, hyperacoustic setpoint frequency is 28kHz.Pottery is taken out back blower drying, observe with colored lights, no greasy dirt, particle etc., cleaning performance is good.
Superiority of the present invention and technique effect are: 1. the cleaning performance of pair pottery is obvious; 2. adopt the main component of proper organic matter, overcome the shortcoming that the traditional ceramics scavenging solution damages the ozone layer as ceramic cleaning fluid; 3. this case ceramic cleaning fluid pH value does not have corrosive nature to ceramic processing units in alkaline range, makes that large-scale application becomes possibility on industrial production; 4. this case ceramic cleaning fluid non-foam, non-stimulated smell, safe in utilization; 5. the several components of this case ceramic cleaning fluid all are the common industrial products, and wide material sources are easy to get, and the industrialization cost advantage is obvious; 6. this product is not limited to the cleaning to pottery, and other various crusts are also had excellent cleaning effect, and as steel surface is added man-hour, available scavenging solution cleans steel surface, removes surface impurity, makes steel surface light more.
(4) embodiment:
Embodiment 1: ceramic cleaning fluid preparation: propylene glycol monobutyl ether 5g in the solvent-borne type ethers and the quadrol 15g in the organic bases are added in the 69.8g deionized water, under the temperature of 35C, stir, propylene glycol monobutyl ether and quadrol are dissolved fully, add first kind of tensio-active agent Isopropylamine dodecane sulfonate 0.1g and second kind of surfactant polyoxyethylene dehydrating sorbitol monooleate (tween-80) 2g then, stir, that is, standby.
Embodiment 2: ceramic cleaning fluid preparation: ethylene glycol monobutyl ether 3g in the solvent-borne type ethers and the quadrol 12g in the organic bases are added in the 79.5g deionized water, under the temperature of 35C, stir, ethylene glycol monobutyl ether and quadrol are dissolved fully, add first kind of tensio-active agent Isopropylamine dodecane sulfonate 0.5g and second kind of surfactant polyoxyethylene amine 5g then, stir, that is, standby.
Embodiment 3: ceramic cleaning fluid preparation: propylene glycol monobutyl ether 5g in the solvent-borne type ethers and the diethanolamine 20g in the organic bases are added in the 69.7g deionized water, under the temperature of 35C, stir, propylene glycol monobutyl ether and diethanolamine are dissolved fully, add first kind of tensio-active agent Isopropylamine dodecane sulfonate 0.3g and second kind of surfactant polyoxyethylene dehydrating sorbitol monooleate (tween-80) 5g then, stir, that is, standby.
Claims (7)
1, a kind of ceramic cleaning fluid, it is characterized in that it is to be become to be grouped into for five kinds with deionized water by solvent-borne type ethers, organic bases, first kind of tensio-active agent, second kind of tensio-active agent, its weight fraction is respectively: the solvent-borne type ethers accounts for 0.5%～8% as composition I, organic bases accounts for 3%～20% as composition II, first kind of tensio-active agent accounts for 0.01%～0.5% as composition III, second kind of tensio-active agent accounts for 1%～8% as composition IV, and deionized water accounts for 63.5%～94.9% as solvent for composition V.
2,, it is characterized in that said solvent-borne type ethers comprises ethylene glycol monobutyl ether, propylene glycol monobutyl ether, Virahol or ethanol according to the said a kind of ceramic cleaning fluid of claim 1.
2,, it is characterized in that said organic bases comprises monoethanolamine, quadrol, diethanolamine or trolamine according to the said a kind of ceramic cleaning fluid of claim 1.
3, according to the said a kind of ceramic cleaning fluid of claim 1, it is characterized in that said
First kind of tensio-active agent comprises anion active agent or amphoterics.
4,, it is characterized in that said second kind of tensio-active agent comprises that polyoxyethylene is nonionogenic tenside, polyol ester class nonionogenic tenside, polymer or element organic system nonionic surfactants according to the said a kind of ceramic cleaning fluid of claim 1.
5,, it is characterized in that said polyoxyethylene is that ionic surfactant pack is drawn together: polyoxyethylene alkylphenol, polyoxyethylene Fatty Alcohol(C12-C14 and C12-C18), polyoxyethylene fatty acid ester, polyoxyethylene amine or polyoxyethylate amide according to the said a kind of ceramic cleaning fluid of claim 4.
6, a kind of preparation method of ceramic cleaning fluid is characterized in that each composition adds in the following order: composition I and II add among the composition V, and composition I and II are dissolved fully, add composition III and IV then; Stir, promptly.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CNA2006100146032A CN101096619A (en) | 2006-06-30 | 2006-06-30 | Ceramic cleaning fluid |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CNA2006100146032A CN101096619A (en) | 2006-06-30 | 2006-06-30 | Ceramic cleaning fluid |
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| Publication Number | Publication Date |
|---|---|
| CN101096619A true CN101096619A (en) | 2008-01-02 |
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| Application Number | Title | Priority Date | Filing Date |
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| CNA2006100146032A Pending CN101096619A (en) | 2006-06-30 | 2006-06-30 | Ceramic cleaning fluid |
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| CN (1) | CN101096619A (en) |
Cited By (9)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102443494A (en) * | 2010-10-11 | 2012-05-09 | 郑州大学 | Washing agent specially used for female underpants and its preparation method |
| CN103865698A (en) * | 2012-12-11 | 2014-06-18 | 董方民 | Multi-surface cleaning agent |
| CN105567455A (en) * | 2016-01-22 | 2016-05-11 | 柳州博泽科技有限公司 | High-performance mild cleaning agent for ceramic tile cleaning |
| CN107365637A (en) * | 2017-06-15 | 2017-11-21 | 清华大学 | Cleaning agent and preparation method thereof, and application method |
| CN107520171A (en) * | 2017-10-15 | 2017-12-29 | 孙源泽 | A kind of method for cleaning glazed ceramic surface oxidation iron spot |
| CN108580472A (en) * | 2018-01-26 | 2018-09-28 | 广西洁邦环保科技有限公司 | Dustbin environmentally-friendly sanitary cleaning method |
| CN109694782A (en) * | 2017-10-24 | 2019-04-30 | 蓝思科技（长沙）有限公司 | A kind of ceramics cleaning agent and preparation method thereof |
| CN111909794A (en) * | 2020-08-11 | 2020-11-10 | 广州洛德化工科贸有限公司 | Low-temperature cleaning agent suitable for fluorine-free refrigeration industry and preparation method and application thereof |
| CN114621082A (en) * | 2022-03-31 | 2022-06-14 | 合肥微睿光电科技有限公司 | Ceramic plate cleaning fluid and preparation method and application thereof |
-
2006
- 2006-06-30 CN CNA2006100146032A patent/CN101096619A/en active Pending
Cited By (10)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102443494A (en) * | 2010-10-11 | 2012-05-09 | 郑州大学 | Washing agent specially used for female underpants and its preparation method |
| CN103865698A (en) * | 2012-12-11 | 2014-06-18 | 董方民 | Multi-surface cleaning agent |
| CN105567455A (en) * | 2016-01-22 | 2016-05-11 | 柳州博泽科技有限公司 | High-performance mild cleaning agent for ceramic tile cleaning |
| CN107365637A (en) * | 2017-06-15 | 2017-11-21 | 清华大学 | Cleaning agent and preparation method thereof, and application method |
| CN107365637B (en) * | 2017-06-15 | 2019-08-02 | 清华大学 | Cleaning agent and preparation method thereof and application method |
| CN107520171A (en) * | 2017-10-15 | 2017-12-29 | 孙源泽 | A kind of method for cleaning glazed ceramic surface oxidation iron spot |
| CN109694782A (en) * | 2017-10-24 | 2019-04-30 | 蓝思科技（长沙）有限公司 | A kind of ceramics cleaning agent and preparation method thereof |
| CN108580472A (en) * | 2018-01-26 | 2018-09-28 | 广西洁邦环保科技有限公司 | Dustbin environmentally-friendly sanitary cleaning method |
| CN111909794A (en) * | 2020-08-11 | 2020-11-10 | 广州洛德化工科贸有限公司 | Low-temperature cleaning agent suitable for fluorine-free refrigeration industry and preparation method and application thereof |
| CN114621082A (en) * | 2022-03-31 | 2022-06-14 | 合肥微睿光电科技有限公司 | Ceramic plate cleaning fluid and preparation method and application thereof |
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