CN108580472A - Dustbin environmentally-friendly sanitary cleaning method - Google Patents
Dustbin environmentally-friendly sanitary cleaning method Download PDFInfo
- Publication number
- CN108580472A CN108580472A CN201810076820.7A CN201810076820A CN108580472A CN 108580472 A CN108580472 A CN 108580472A CN 201810076820 A CN201810076820 A CN 201810076820A CN 108580472 A CN108580472 A CN 108580472A
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- China
- Prior art keywords
- dustbin
- friendly
- environmentally
- weight
- environment
- Prior art date
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- Granted
Links
- 238000004140 cleaning Methods 0.000 title claims abstract description 43
- 238000000034 method Methods 0.000 title claims abstract description 38
- 239000012459 cleaning agent Substances 0.000 claims abstract description 41
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 claims abstract description 40
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 34
- 235000019441 ethanol Nutrition 0.000 claims abstract description 15
- GSEJCLTVZPLZKY-UHFFFAOYSA-N Triethanolamine Chemical compound OCCN(CCO)CCO GSEJCLTVZPLZKY-UHFFFAOYSA-N 0.000 claims description 35
- QTBSBXVTEAMEQO-UHFFFAOYSA-N Acetic acid Chemical compound CC(O)=O QTBSBXVTEAMEQO-UHFFFAOYSA-N 0.000 claims description 19
- 238000002360 preparation method Methods 0.000 claims description 18
- 238000003756 stirring Methods 0.000 claims description 15
- POAOYUHQDCAZBD-UHFFFAOYSA-N 2-butoxyethanol Chemical compound CCCCOCCO POAOYUHQDCAZBD-UHFFFAOYSA-N 0.000 claims description 13
- 239000004744 fabric Substances 0.000 claims description 11
- 239000012467 final product Substances 0.000 claims description 11
- 239000002994 raw material Substances 0.000 claims description 11
- 239000004094 surface-active agent Substances 0.000 claims description 10
- 125000001453 quaternary ammonium group Chemical group 0.000 claims description 9
- NIXOWILDQLNWCW-UHFFFAOYSA-N 2-Propenoic acid Natural products OC(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 claims description 8
- MRUAUOIMASANKQ-UHFFFAOYSA-N cocamidopropyl betaine Chemical group CCCCCCCCCCCC(=O)NCCC[N+](C)(C)CC([O-])=O MRUAUOIMASANKQ-UHFFFAOYSA-N 0.000 claims description 8
- SMZOUWXMTYCWNB-UHFFFAOYSA-N 2-(2-methoxy-5-methylphenyl)ethanamine Chemical compound COC1=CC=C(C)C=C1CCN SMZOUWXMTYCWNB-UHFFFAOYSA-N 0.000 claims description 7
- WRIDQFICGBMAFQ-UHFFFAOYSA-N (E)-8-Octadecenoic acid Natural products CCCCCCCCCC=CCCCCCCC(O)=O WRIDQFICGBMAFQ-UHFFFAOYSA-N 0.000 claims description 6
- LQJBNNIYVWPHFW-UHFFFAOYSA-N 20:1omega9c fatty acid Natural products CCCCCCCCCCC=CCCCCCCCC(O)=O LQJBNNIYVWPHFW-UHFFFAOYSA-N 0.000 claims description 6
- QSBYPNXLFMSGKH-UHFFFAOYSA-N 9-Heptadecensaeure Natural products CCCCCCCC=CCCCCCCCC(O)=O QSBYPNXLFMSGKH-UHFFFAOYSA-N 0.000 claims description 6
- 235000016068 Berberis vulgaris Nutrition 0.000 claims description 6
- 241000335053 Beta vulgaris Species 0.000 claims description 6
- 239000005642 Oleic acid Substances 0.000 claims description 6
- ZQPPMHVWECSIRJ-UHFFFAOYSA-N Oleic acid Natural products CCCCCCCCC=CCCCCCCCC(O)=O ZQPPMHVWECSIRJ-UHFFFAOYSA-N 0.000 claims description 6
- 239000012190 activator Substances 0.000 claims description 6
- 239000003513 alkali Substances 0.000 claims description 6
- 239000002585 base Substances 0.000 claims description 6
- QXJSBBXBKPUZAA-UHFFFAOYSA-N isooleic acid Natural products CCCCCCCC=CCCCCCCCCC(O)=O QXJSBBXBKPUZAA-UHFFFAOYSA-N 0.000 claims description 6
- ZQPPMHVWECSIRJ-KTKRTIGZSA-N oleic acid Chemical compound CCCCCCCC\C=C/CCCCCCCC(O)=O ZQPPMHVWECSIRJ-KTKRTIGZSA-N 0.000 claims description 6
- 239000003054 catalyst Substances 0.000 claims description 4
- JIAARYAFYJHUJI-UHFFFAOYSA-L zinc dichloride Chemical group [Cl-].[Cl-].[Zn+2] JIAARYAFYJHUJI-UHFFFAOYSA-L 0.000 claims description 4
- 239000000126 substance Substances 0.000 claims description 3
- QCCKPZOPTXCJPL-UHFFFAOYSA-N dodecyl(dimethyl)azanium;hydroxide Chemical compound [OH-].CCCCCCCCCCCC[NH+](C)C QCCKPZOPTXCJPL-UHFFFAOYSA-N 0.000 claims description 2
- 150000003839 salts Chemical class 0.000 claims description 2
- 235000005074 zinc chloride Nutrition 0.000 claims description 2
- 239000011592 zinc chloride Substances 0.000 claims description 2
- LBLYYCQCTBFVLH-UHFFFAOYSA-N 2-Methylbenzenesulfonic acid Chemical compound CC1=CC=CC=C1S(O)(=O)=O LBLYYCQCTBFVLH-UHFFFAOYSA-N 0.000 claims 1
- 238000009991 scouring Methods 0.000 claims 1
- 239000012752 auxiliary agent Substances 0.000 abstract description 3
- IOVCWXUNBOPUCH-UHFFFAOYSA-M Nitrite anion Chemical compound [O-]N=O IOVCWXUNBOPUCH-UHFFFAOYSA-M 0.000 abstract description 2
- CBENFWSGALASAD-UHFFFAOYSA-N Ozone Chemical compound [O-][O+]=O CBENFWSGALASAD-UHFFFAOYSA-N 0.000 abstract description 2
- 229910019142 PO4 Inorganic materials 0.000 abstract description 2
- 239000003183 carcinogenic agent Substances 0.000 abstract description 2
- NBIIXXVUZAFLBC-UHFFFAOYSA-K phosphate Chemical compound [O-]P([O-])([O-])=O NBIIXXVUZAFLBC-UHFFFAOYSA-K 0.000 abstract description 2
- 239000010452 phosphate Substances 0.000 abstract description 2
- 239000010813 municipal solid waste Substances 0.000 description 19
- 241000894006 Bacteria Species 0.000 description 12
- JOXIMZWYDAKGHI-UHFFFAOYSA-N toluene-4-sulfonic acid Chemical compound CC1=CC=C(S(O)(=O)=O)C=C1 JOXIMZWYDAKGHI-UHFFFAOYSA-N 0.000 description 7
- 238000012360 testing method Methods 0.000 description 6
- 239000003599 detergent Substances 0.000 description 5
- 239000000725 suspension Substances 0.000 description 5
- 239000002699 waste material Substances 0.000 description 4
- 241000737241 Cocos Species 0.000 description 3
- 235000013162 Cocos nucifera Nutrition 0.000 description 3
- 230000000694 effects Effects 0.000 description 3
- HLERILKGMXJNBU-UHFFFAOYSA-N norvaline betaine Chemical compound CCCC(C([O-])=O)[N+](C)(C)C HLERILKGMXJNBU-UHFFFAOYSA-N 0.000 description 3
- FATBGEAMYMYZAF-KTKRTIGZSA-N oleamide Chemical compound CCCCCCCC\C=C/CCCCCCCC(N)=O FATBGEAMYMYZAF-KTKRTIGZSA-N 0.000 description 3
- FATBGEAMYMYZAF-UHFFFAOYSA-N oleicacidamide-heptaglycolether Natural products CCCCCCCCC=CCCCCCCCC(N)=O FATBGEAMYMYZAF-UHFFFAOYSA-N 0.000 description 3
- 238000005406 washing Methods 0.000 description 3
- 229920001817 Agar Polymers 0.000 description 2
- 241000222122 Candida albicans Species 0.000 description 2
- 239000001888 Peptone Substances 0.000 description 2
- FAPWRFPIFSIZLT-UHFFFAOYSA-M Sodium chloride Chemical compound [Na+].[Cl-] FAPWRFPIFSIZLT-UHFFFAOYSA-M 0.000 description 2
- 239000008272 agar Substances 0.000 description 2
- 235000015278 beef Nutrition 0.000 description 2
- 239000004568 cement Substances 0.000 description 2
- 239000003795 chemical substances by application Substances 0.000 description 2
- 238000011156 evaluation Methods 0.000 description 2
- 239000006260 foam Substances 0.000 description 2
- 239000001963 growth medium Substances 0.000 description 2
- 238000012376 hot air sterilization Methods 0.000 description 2
- 238000005259 measurement Methods 0.000 description 2
- 238000011056 performance test Methods 0.000 description 2
- 238000012545 processing Methods 0.000 description 2
- 239000011780 sodium chloride Substances 0.000 description 2
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 1
- 108010080698 Peptones Proteins 0.000 description 1
- 229920001131 Pulp (paper) Polymers 0.000 description 1
- 229910000831 Steel Inorganic materials 0.000 description 1
- 230000003213 activating effect Effects 0.000 description 1
- 230000000844 anti-bacterial effect Effects 0.000 description 1
- 230000001580 bacterial effect Effects 0.000 description 1
- 210000004666 bacterial spore Anatomy 0.000 description 1
- 241000385540 bacterium 10 Species 0.000 description 1
- 239000011324 bead Substances 0.000 description 1
- 229940095731 candida albicans Drugs 0.000 description 1
- 229910052799 carbon Inorganic materials 0.000 description 1
- 239000006229 carbon black Substances 0.000 description 1
- 210000004027 cell Anatomy 0.000 description 1
- 239000000919 ceramic Substances 0.000 description 1
- 238000005660 chlorination reaction Methods 0.000 description 1
- 238000010411 cooking Methods 0.000 description 1
- 230000007812 deficiency Effects 0.000 description 1
- 230000007613 environmental effect Effects 0.000 description 1
- 238000002474 experimental method Methods 0.000 description 1
- 238000000605 extraction Methods 0.000 description 1
- 238000013213 extrapolation Methods 0.000 description 1
- 238000005187 foaming Methods 0.000 description 1
- 239000011521 glass Substances 0.000 description 1
- 238000010438 heat treatment Methods 0.000 description 1
- 238000011534 incubation Methods 0.000 description 1
- 230000006698 induction Effects 0.000 description 1
- 239000000463 material Substances 0.000 description 1
- 239000002609 medium Substances 0.000 description 1
- 238000002844 melting Methods 0.000 description 1
- 230000008018 melting Effects 0.000 description 1
- 229910052751 metal Inorganic materials 0.000 description 1
- 239000002184 metal Substances 0.000 description 1
- 239000000203 mixture Substances 0.000 description 1
- 239000013642 negative control Substances 0.000 description 1
- 238000012856 packing Methods 0.000 description 1
- 235000019319 peptone Nutrition 0.000 description 1
- 239000000843 powder Substances 0.000 description 1
- 238000004064 recycling Methods 0.000 description 1
- 229910052708 sodium Inorganic materials 0.000 description 1
- 239000011734 sodium Substances 0.000 description 1
- 239000002904 solvent Substances 0.000 description 1
- 239000010959 steel Substances 0.000 description 1
- 230000001954 sterilising effect Effects 0.000 description 1
- 238000004659 sterilization and disinfection Methods 0.000 description 1
- 238000010998 test method Methods 0.000 description 1
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B08—CLEANING
- B08B—CLEANING IN GENERAL; PREVENTION OF FOULING IN GENERAL
- B08B9/00—Cleaning hollow articles by methods or apparatus specially adapted thereto
- B08B9/08—Cleaning containers, e.g. tanks
- B08B9/093—Cleaning containers, e.g. tanks by the force of jets or sprays
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/88—Ampholytes; Electroneutral compounds
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/88—Ampholytes; Electroneutral compounds
- C11D1/886—Ampholytes containing P
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/88—Ampholytes; Electroneutral compounds
- C11D1/94—Mixtures with anionic, cationic or non-ionic compounds
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/20—Organic compounds containing oxygen
- C11D3/2003—Alcohols; Phenols
- C11D3/2006—Monohydric alcohols
- C11D3/201—Monohydric alcohols linear
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/20—Organic compounds containing oxygen
- C11D3/2068—Ethers
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/26—Organic compounds containing nitrogen
- C11D3/30—Amines; Substituted amines ; Quaternized amines
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/38—Cationic compounds
- C11D1/62—Quaternary ammonium compounds
-
- C11D2111/14—
Abstract
The invention discloses a kind of dustbin environmentally-friendly sanitary cleaning methods, and dustbin is contacted with environment-friendly cleaning agent.Dustbin environmentally-friendly sanitary cleaning method of the present invention, it is of low cost, method is simple, the cleaning agent being prepared using water, ethyl alcohol, a variety of auxiliary agents, strong detergency, quickly, efficiently, noresidue, not phosphate-containing and carcinogenic substance nitrite and the nuisance for endangering atmospheric ozone layer are dedicated to greasy dirt, foul, weathering dirt and the scale spot etc. on cleaning dustbin surface, and cleaning performance is good, washable surface is good, effectively save water resource and the energy improve working efficiency and cleaning quality, reduce the cleaning cost of dustbin.
Description
Technical field
The invention belongs to clean environment firendly technical field more particularly to a kind of dustbin environmentally-friendly sanitary cleaning methods.
Background technology
With successful warp of the continuous improvement and some developed countries of people's environmental consciousness in garbage classification processing
It tests, and the attention of country in this respect, all promotes the appearance of classification garbage can.In October, 2003, country puts into effect《It gives birth in city
Garbage classification mark living》.The unified mark formulated according to country, house refuse are divided into four classes, they are recyclable respectively
Object, rubbish from cooking, Harmful Waste and Other Waste.
Dustbin also known as litter-bin or dustbin refer to the place for putting rubbish.Majority is with metal or plastic cement system, used time
It is put into polybag, is lost when rubbish more than one can tie up bag.Dustbin is the container " sheltered evil people and countenance evil practices " in people's life and society
A kind of refraction of meeting culture.
Dustbin can be divided into public garbage bin and household garbage bin with regard to use occasion.Independence can be divided by just holding rubbish form
Dustbin and classification garbage can.It can be divided into plastic garbage bin, tainless steel dustbin, ceramic dustbin, wooden rubbish with regard to rapidoprint
Rubbish bucket, cement waste bucket and paper pulp dustbin etc..The mode of being switched on have opened type, covering type, trample uncap, induction type it is (red
Outside line) etc..
In being investigated in each city, people are relatively low to sanitary conditions evaluation around the dustbin of living area, and satisfied accounts for
33.2%, it is unsatisfied, have 66.8%.Since flow of the people is big in urban cells, rubbish quantity is accordingly more, and type is also therewith
Increase, thus the frequency for causing dustbin dirty and dirty degree are also higher.
Conventional garbage bucket cleaning efficiency is low, and there are cleaning loopholes：Certain places are not because dustbin cleans in time, rubbish
There are the problems such as dirty, smelly, therefore people are not desired to, close to dustbin, only be thrown into around dustbin rubbish, vicious circle occur bucket.
And existing rubbish manner of cleaning up, simple high-pressure washing is mainly used, but such cleaning performance is undesirable, and be easy
The waste of water resource is caused, this just needs a kind of completely new dustbin cleaning method to solve the above problems.
Invention content
For the deficiencies in the prior art, the present invention provides a kind of dustbin environmentally-friendly sanitary cleaning methods.
Technical solution：
A kind of dustbin environmentally-friendly sanitary cleaning method contacts dustbin with environment-friendly cleaning agent.
The preparation method of the environment-friendly cleaning agent, includes the following steps：
(1) weigh ethylene glycol monobutyl ether, ethyl alcohol, triethanolamine, beet alkali surface activator, Gemini surface active,
Water；
(2) each raw material is uniformly mixed to obtain the final product.
Preferably, the preparation method of the environment-friendly cleaning agent, includes the following steps：
(1) 2-5 parts by weight ethylene glycol monobutyl ether, 3-9 parts by weight of ethanol, the part by weight modified triethanolamines of 2-5,1-3 are weighed
Parts by weight beet alkali surface activator, 2-5 parts by weight Gemini surface active, 95-105 parts by weight water；
(2) it is that 200-500r/min stirrings 20-40min is uniformly mixed with rotating speed by each raw material to obtain the final product.
The preparation method of the modified triethanolamine is：It is 1 in mass ratio by triethanolamine, acrylic acid, catalyst：
(0.1-0.3)：(0.02-0.05) is that 200-500r/min stirrings 5-15min is uniformly mixed with rotating speed, is heated to 120-140 DEG C,
It is that 50-150r/min is stirred to react 30-90min with rotating speed, adds triethanolamine quality 10-30wt% acetic acid, continue in temperature
It with rotating speed is that 50-150r/min is stirred to react 1.5-3.5h that degree, which is at 120-140 DEG C, be cooled to room temperature to get.
The catalyst is zinc chloride or p-methyl benzenesulfonic acid.
The beet alkali surface activator is Cocoamidopropyl betaine or dodecyldimethylammonium hydroxide inner salt.
The Gemini surface active is that Quaternary Ammonium Gemini Surfactants and/or the surfaces oleic acid base Gemini are lived
Property agent.In one embodiment of the present invention, the Gemini surface active is by the surfaces 65-75wt% quaternary Gemini
Activating agent and 25-35wt% oleic acid base Gemini surface actives composition.
Preferably, the mode of the contact is that the environment-friendly cleaning agent is diluted with water 1-10 times, then
It is sprayed directly on dustbin surface, is directly cleaned with cloth or other hydroscopic substances.
As another preferred embodiment, the mode of the contact is that 1-10 is diluted with water in the environment-friendly cleaning agent
Times, dustbin is then impregnated into 20-40min wherein, then dried with cloth or other hydroscopic substances.
As another preferred embodiment, the mode of the contact is that 1-10 is diluted with water in the environment-friendly cleaning agent
Times, then it is rinsed against dustbin.
Dustbin environmentally-friendly sanitary cleaning method of the present invention, of low cost, method is simple, using water, ethyl alcohol, a variety of auxiliary agent systems
Cleaning agent made of standby, strong detergency, quickly, efficiently, noresidue phosphate-containing and carcinogenic substance nitrite and does not endanger air
The nuisance of ozone layer is dedicated to greasy dirt, foul, weathering dirt and the scale spot etc. on cleaning dustbin surface, cleaning performance
Well, washable surface is good, effectively save water resource and the energy, improves working efficiency and cleaning quality, reduce the cleaning of dustbin at
This.
Specific implementation mode
Foam performance is tested：
According to the measurement (Ross-Miles methods) of GB/T13173.6-91 detergent foaming powers.
Detergency ability is tested：
With reference to GB/T13174-2008《Dress material detergent detergency and the measurement for recycling scourability》Method test is each
The washing effect of environment-protection detergent powder prepared by embodiment.
Test method：Using B values (whiteness holding ratio) as the evaluation index of washing effect, as B >=1.0, detergent
Detergency is qualified；When B ＜ 1.0, detergent detergency is unqualified.
Test sample includes JB-01 (carbon black greasy dirt cloth).
Wash conditions：A concentration of 0.2wt% of environment-friendly cleaning agent in cleaning solution, 20 DEG C of wash temperature, wash time
20min, water hardness 270mg/kg.
Bacteriostasis property is tested：
Bacteria Culture is with beef extract-peptone agar medium specific formula：Beef extract 3.0g, peptone 10g, chlorination
Sodium 5.0g, agar 20g, water 1000mL heating and meltings, it is 7.5 to adjust pH value.Packing, high pressure moist heat sterilization (121 DEG C, 20min) are standby
With.
Strain：Candida albicans (ATCC10231).
It will enter on corresponding test tube slant culture medium for examination strain transposing, strain connects branched repetition.Bacterium is placed in 37 DEG C
Biochemical cultivation case culture is for 24 hours.
Picking colony is inoculated with plate, and Bacteria Culture for 24 hours, is eluted with sterile saline, is respectively prepared containing bacterium 107CFU/mL
Bacteria suspension.Specific preparation method：It is washed out in a small amount of bacterial spore to sterile saline of picking respectively, bead is broken up, made
At bacteria suspension, bacteria suspension concentration is adjusted to be 107CFU/mL, it is spare.
By the round blank filter paper piece of a diameter of 3cm after 160 DEG C of hot air sterilizations, saved backup under aseptic condition.With nothing
Bacterium pipettor draws the culture that experiment bacteria suspension 0.1mL that is activated and adjusting bacterial concentration is added to good culture medium
In ware, bacteria suspension is coated with uniformly with glass spreader of the self-control through hot air sterilization.Each filter paper is picked up with aseptic nipper again to put
Enter on different culture dishes containing bacterium, is drawn on 10 μ L environment-friendly cleaning agents to each filter paper with sterile pipette, each bacterium is parallel
Make two wares.Then make negative control with corresponding Extraction solvent.Bacterium in biochemical cultivation case 37 DEG C of constant temperature incubations for 24 hours, ten
Word interior extrapolation method measures antibacterial circle diameter, is averaged.
Oleic acid base Gemini surface active is according in the Chinese patent application No. is 201310509555.4 in embodiment
It is prepared by method shown in embodiment 2.
Ethylene glycol monobutyl ether in embodiment, No. CAS：111-76-2.
Ethyl alcohol in embodiment, No. CAS：64-17-5.
Cocoamidopropyl betaine in embodiment, No. CAS：86438-79-1.
Quaternary Ammonium Gemini Surfactants are according to application No. is 201210042527.1 Chinese patents in embodiment
It is prepared by method shown in middle embodiment 1.
Triethanolamine in embodiment, No. CAS：102-71-6.
Acrylic acid in embodiment, No. CAS：79-10-7.
P-methyl benzenesulfonic acid in embodiment, No. CAS：104-15-4.
Acetic acid in embodiment, No. CAS：64-19-7.
Embodiment 1
Environment-friendly cleaning agent is diluted with water 5 times, is then sprayed directly on rubbish by dustbin environmentally-friendly sanitary cleaning method
Bucket surface, is directly cleaned with cloth.
The preparation method of the environment-friendly cleaning agent, includes the following steps：
(1) 3.5 parts by weight ethylene glycol monobutyl ethers, 6 parts by weight of ethanol, 3.5 parts by weight triethanolamines, 2 parts by weight coconut palms are weighed
Oleamide propyl betaine, 3 parts by weight Quaternary Ammonium Gemini Surfactants, 100 parts by weight water；
(2) it is that 300r/min stirs the uniformly mixed environment-friendly cleaning agents to obtain the final product of 30min with rotating speed by each raw material.
Embodiment 2
Environment-friendly cleaning agent is diluted with water 5 times by dustbin environmentally-friendly sanitary cleaning method, then carries out it against dustbin
It rinses.
The preparation method of the environment-friendly cleaning agent, includes the following steps：
(1) 3.5 parts by weight ethylene glycol monobutyl ethers, 6 parts by weight of ethanol, 3.5 parts by weight triethanolamines, 2 parts by weight coconut palms are weighed
Oleamide propyl betaine, 3 parts by weight Quaternary Ammonium Gemini Surfactants, 100 parts by weight water；
(2) it is that 300r/min stirs the uniformly mixed environment-friendly cleaning agents to obtain the final product of 30min with rotating speed by each raw material.
Embodiment 3
Environment-friendly cleaning agent is diluted with water 5 times, then impregnates dustbin wherein by dustbin environmentally-friendly sanitary cleaning method
30min, then dry with a cloth.
The preparation method of the environment-friendly cleaning agent, includes the following steps：
(1) 3.5 parts by weight ethylene glycol monobutyl ethers, 6 parts by weight of ethanol, 3.5 parts by weight triethanolamines, 2 parts by weight coconut palms are weighed
Oleamide propyl betaine, 3 parts by weight Quaternary Ammonium Gemini Surfactants, 100 parts by weight water；
(2) it is that 300r/min stirs the uniformly mixed environment-friendly cleaning agents to obtain the final product of 30min with rotating speed by each raw material.
Embodiment 4
Environment-friendly cleaning agent is diluted with water 5 times, then impregnates dustbin wherein by dustbin environmentally-friendly sanitary cleaning method
30min, then dry with a cloth.
The preparation method of the environment-friendly cleaning agent, includes the following steps：
(1) 3.5 parts by weight ethylene glycol monobutyl ethers, 6 parts by weight of ethanol, 3.5 part by weight modified triethanolamines, 2 weight are weighed
Part Cocoamidopropyl betaine, 3 parts by weight Quaternary Ammonium Gemini Surfactants, 100 parts by weight water；
(2) it is that 300r/min stirs the uniformly mixed environment-friendly cleaning agents to obtain the final product of 30min with rotating speed by each raw material.
The preparation method of the modified triethanolamine is：It is 1 in mass ratio by triethanolamine, acrylic acid, p-methyl benzenesulfonic acid：
0.2：0.03 stirs 10min with rotating speed for 300r/min is uniformly mixed, and is heated to 130 DEG C, is stirred to react for 60r/min with rotating speed
60min, adds triethanolamine quality 20wt% acetic acid, continuation be 130 DEG C in temperature at rotating speed be that 60r/min is stirred to react
2.5h is cooled to room temperature to get modified triethanolamine.
Embodiment 5
Environment-friendly cleaning agent is diluted with water 5 times, then impregnates dustbin wherein by dustbin environmentally-friendly sanitary cleaning method
30min, then dry with a cloth.
The preparation method of the environment-friendly cleaning agent, includes the following steps：
(1) 3.5 parts by weight ethylene glycol monobutyl ethers, 6 parts by weight of ethanol, 3.5 part by weight modified triethanolamines, 2 weight are weighed
Part Cocoamidopropyl betaine, 3 parts by weight Quaternary Ammonium Gemini Surfactants, 100 parts by weight water；
(2) it is that 300r/min stirs the uniformly mixed environment-friendly cleaning agents to obtain the final product of 30min with rotating speed by each raw material.
The preparation method of the modified triethanolamine is：It is 1 in mass ratio by triethanolamine, acrylic acid, p-methyl benzenesulfonic acid：
0.2：0.03 stirs 10min with rotating speed for 300r/min is uniformly mixed, and is heated to 130 DEG C, is stirred to react for 60r/min with rotating speed
3.5h is cooled to room temperature to get modified triethanolamine.
Embodiment 6
Environment-friendly cleaning agent is diluted with water 5 times, then impregnates dustbin wherein by dustbin environmentally-friendly sanitary cleaning method
30min, then dry with a cloth.
The preparation method of the environment-friendly cleaning agent, includes the following steps：
(1) 3.5 parts by weight ethylene glycol monobutyl ethers, 6 parts by weight of ethanol, 3.5 part by weight modified triethanolamines, 2 weight are weighed
Part Cocoamidopropyl betaine, 3 parts by weight oleic acid base Gemini surface actives, 100 parts by weight water；
(2) it is that 300r/min stirs the uniformly mixed environment-friendly cleaning agents to obtain the final product of 30min with rotating speed by each raw material.
The preparation method of the modified triethanolamine is：It is 1 in mass ratio by triethanolamine, acrylic acid, p-methyl benzenesulfonic acid：
0.2：0.03 stirs 10min with rotating speed for 300r/min is uniformly mixed, and is heated to 130 DEG C, is stirred to react for 60r/min with rotating speed
60min, adds triethanolamine quality 20wt% acetic acid, continuation be 130 DEG C in temperature at rotating speed be that 60r/min is stirred to react
2.5h is cooled to room temperature to get modified triethanolamine.
Embodiment 7
Environment-friendly cleaning agent is diluted with water 5 times, then impregnates dustbin wherein by dustbin environmentally-friendly sanitary cleaning method
30min, then dry with a cloth.
The preparation method of the environment-friendly cleaning agent, includes the following steps：
(1) 3.5 parts by weight ethylene glycol monobutyl ethers, 6 parts by weight of ethanol, 3.5 part by weight modified triethanolamines, 2 weight are weighed
Part Cocoamidopropyl betaine, 2.1 parts by weight Quaternary Ammonium Gemini Surfactants, 0.9 parts by weight oleic acid base Gemini
Surfactant, 100 parts by weight water；
(2) it is that 300r/min stirs the uniformly mixed environment-friendly cleaning agents to obtain the final product of 30min with rotating speed by each raw material.Environment-friendly cleaning agent
The performance test results：Candida albicans Candida albicans is 18.9mm, and B values (JB-01) are 1.50, foam height 213mm.
The preparation method of the modified triethanolamine is：It is 1 in mass ratio by triethanolamine, acrylic acid, p-methyl benzenesulfonic acid：
0.2：0.03 stirs 10min with rotating speed for 300r/min is uniformly mixed, and is heated to 130 DEG C, is stirred to react for 60r/min with rotating speed
60min, adds triethanolamine quality 20wt% acetic acid, continuation be 130 DEG C in temperature at rotating speed be that 60r/min is stirred to react
2.5h is cooled to room temperature to get modified triethanolamine.
Test case 1
The environment-friendly cleaning agent performance prepared in embodiment 3-6 is tested, specific test result is shown in Table 1.
Table 1：Performance test data table
Dustbin environmentally-friendly sanitary cleaning method of the present invention, of low cost, method is simple, using water, ethyl alcohol, a variety of auxiliary agent systems
Cleaning agent made of standby, strong detergency, quickly, efficiently, noresidue is modified triethanolamine and improves it after processing and wash
It washs, bacteriostasis property, cleaning performance is good, and washable surface is good, effectively save water resource and the energy, improves working efficiency and cleaning matter
Amount, reduces the cleaning cost of dustbin.
Claims (10)
1. a kind of dustbin environmentally-friendly sanitary cleaning method, which is characterized in that contact dustbin with environment-friendly cleaning agent.
2. dustbin environmentally-friendly sanitary cleaning method as described in claim 1, which is characterized in that the preparation side of the environment-friendly cleaning agent
Method includes the following steps：
(1) ethylene glycol monobutyl ether, ethyl alcohol, triethanolamine, beet alkali surface activator, Gemini surface active, water are weighed；
(2) each raw material is uniformly mixed to obtain the final product.
3. dustbin environmentally-friendly sanitary cleaning method as described in claim 1, which is characterized in that the preparation side of the environment-friendly cleaning agent
Method includes the following steps：
(1) 2-5 parts by weight ethylene glycol monobutyl ether, 3-9 parts by weight of ethanol, the part by weight modified triethanolamines of 2-5,1-3 weight are weighed
Part beet alkali surface activator, 2-5 parts by weight Gemini surface active, 95-105 parts by weight water；
(2) it is that 200-500r/min stirrings 20-40min is uniformly mixed with rotating speed by each raw material to obtain the final product.
4. dustbin environmentally-friendly sanitary cleaning method as claimed in claim 3, which is characterized in that the preparation of the modified triethanolamine
Method is：It is 1 in mass ratio by triethanolamine, acrylic acid, catalyst：(0.1-0.3)：(0.02-0.05) is 200- with rotating speed
500r/min stirs 5-15min and is uniformly mixed, and is heated to 120-140 DEG C, is that 50-150r/min is stirred to react 30- with rotating speed
90min, adds triethanolamine quality 10-30wt% acetic acid, continuation be 120-140 DEG C in temperature at rotating speed for 50-150r/
Min is stirred to react 1.5-3.5h, be cooled to room temperature to get.
5. dustbin environmentally-friendly sanitary cleaning method as claimed in claim 4, which is characterized in that the catalyst is zinc chloride or right
Toluenesulfonic acid.
6. dustbin environmentally-friendly sanitary cleaning method as claimed in claim 3, which is characterized in that the beet alkali surface activator is
Cocoamidopropyl betaine or dodecyldimethylammonium hydroxide inner salt.
7. dustbin environmentally-friendly sanitary cleaning method as claimed in claim 3, which is characterized in that the Gemini surface active is
Quaternary Ammonium Gemini Surfactants and/or oleic acid base Gemini surface active.
8. dustbin environmentally-friendly sanitary cleaning method as described in claim 3 or 4, which is characterized in that the mode of the contact is will
The environment-friendly cleaning agent is diluted with water 1-10 times, is then sprayed directly on dustbin surface, straight with cloth or other hydroscopic substances
Connect scouring.
9. dustbin environmentally-friendly sanitary cleaning method as described in claim 3 or 4, which is characterized in that the mode of the contact is will
The environment-friendly cleaning agent is diluted with water 1-10 times, and dustbin is then impregnated 20-40min wherein, then with cloth or other water suctions
Object is dried.
10. dustbin environmentally-friendly sanitary cleaning method as described in claim 3 or 4, which is characterized in that the mode of the contact is will
The environment-friendly cleaning agent is diluted with water 1-10 times, is then rinsed it against dustbin.
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