CN104629964B - Capsule-type liquid detergent - Google Patents

Capsule-type liquid detergent Download PDF

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Publication number
CN104629964B
CN104629964B CN201510094973.0A CN201510094973A CN104629964B CN 104629964 B CN104629964 B CN 104629964B CN 201510094973 A CN201510094973 A CN 201510094973A CN 104629964 B CN104629964 B CN 104629964B
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Prior art keywords
capsule
liquid detergent
type liquid
detergent
ether
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CN104629964A (en
Inventor
刘世超
刘伟毅
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Shanghai Soap Factory Co ltd
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SHANGHAI SOAPMAKING CO Ltd
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Abstract

The invention discloses a kind of capsule-type liquid detergent, it is made up of liquid detergent and capsule, the capsule wraps up the liquid detergent, it is characterised in that the liquid detergent includes following materials in percentage by mass:Sodium sulfate of polyethenoxy ether of fatty alcohol 15 25%, AEO or isomerous tridecanol polyoxyethylene ether 30 40%, cocinic acid potash soap 5 15%, surplus are organic solvent.The capsule-type liquid detergent of the present invention, design of machine-washing is aimed at, simple to operate, convenient not dirty hand, quality is smooth thick moderate, and property does not hinder clothing gently, is more easy to rinse, moreover it is possible to which effectively quick removal stain is clean as new by clothing.

Description

Capsule-type liquid detergent
Technical field
The present invention relates to a kind of liquid detergent, more particularly to a kind of capsule-type liquid detergent.
Background technology
The laundry liquid market of China increase it is especially fast, according to the data of prospect of Chinese washing products research report in 2012, The amplitude that increases by a year-on-year basis of liquid detergent is 15.05%, up to 4,600,000 tons.The same of association's 1-6 month liquid detergents in 2013 is washed by China Exceed synthetic detergent powder and soap for 12% than increasing degree, be the most fast detergent species of increasing degree.
The year per capita consuming level of China's articles for washing is relatively low at present, only 5.9 kilograms, 12 kilograms of Europe, and the U.S. about 15 is public Jin.China's articles for washing kind accounts for the 85% of articles for washing total output based on synthetic detergent, and liquid detergent is accounted for entirely into washing Wash the 26% of agent total amount." prediction in 12, five " planning to domestic articles for washing dosage claims for light industry:With people's life matter The raising of amount, for people in the consumption of articles for washing, the consumption ratio of synthetic detergent and liquid detergent focuses on continuous increase. It it is 6,800,000 tons or so to articles for washing consumption figure in 2009, the ratio of synthetic detergent total quantity consumed is up to 90%, consumption figure For 6,120,000 tons or so.Laundry liquid accounts for the 20% of consumption figure, is 1,200,000 tons or so.
Capsule-type liquid detergent be it is a kind of detergent is fitted into small-sized hydrolyzable packaging bag from the appearance shape like capsule A kind of liquid detergent.Its is easy to use, and the metering of detergent, each capsule are adapted to wash a collection of clothing when being easy to wash clothing, together When be avoided that the phenomenon of leakage occurs when toppling over liquid detergent, reduces the trouble of user.At present foreign countries have Surf, Persil, Bold, The brands such as Fairy, the country have green wave on sale.
The content of the invention
The technical problems to be solved by the invention are to provide a kind of capsule-type liquid detergent.
In order to solve the above technical problems, the present invention is achieved through the following technical solutions:
A kind of capsule-type liquid detergent, is made up of liquid detergent and capsule, and the capsule wraps up the liquid detergent.
The liquid detergent, including following materials in percentage by mass:Sodium sulfate of polyethenoxy ether of fatty alcohol 15-25%, AEO or isomerous tridecanol polyoxyethylene ether 30-40%, cocinic acid potash soap 5-15%, surplus are organic molten Agent.
The organic solvent is butyl, triethylene glycol butyl ether and one kind in dipropylene or its mixing Thing.
Preferably, the organic solvent is made up of following components in parts by weight:5-15 parts butyl, 5-15 parts three Butyl glycol ether and 10-20 part dipropylenes.
Sodium sulfate of polyethenoxy ether of fatty alcohol, Sodium Alcohol Ether Sulphate, abbreviation AES, No. CAS: 9004-82-4。
AEO, Primary Alcobol Ethoxylate, it is that natural fatty alcohol adds with oxirane Into thing, No. CAS:68131-39-5, No. EINECS:500-195-7.
Isomerous tridecanol polyoxyethylene ether, molecular formula:RO(CH2CH2O)5H R are isomerous tridecanol, Chinese name:Isomery ten Triol APEO, Isomeric alcohol ethoxylates, CAS:9043-30-5, water is easily dispersed or dissolved in, had Excellent wetability, permeability and emulsibility.
The cocinic acid potash soap, abbreviation potash soap, also known as cocinic acid sylvite or coconut oil potash soap, No. CAS:91032- 02-9.Cocinic acid potash soap is to be formed by coconut oil or coconut oil with potassium hydroxide reaction.
Butyl, No. CAS:112-34-5;Triethylene glycol butyl ether, No. CAS:143-22-6;Dipropylene, No. CAS:29911-28-2.
The material of the capsule is water-soluble film, preferably PVA film, PVOH film or PVP films, and optimal is PVA Film.
The capsule thickness is 0.10-0.30mm.
PVA film has water soluble nature, cold water solubles.The mechanical property of PVA film:Epistasis modulus 2500-400kg/ cm2, tensile strength 400-200kg/cm2, tear edge 200-50kg/cm2, elongation percentage 150-220%.
In the present invention, according to being actually needed, the brightening agent, preservative, color of liquid detergent routine addition can also be added Element and essence, to meet corresponding demand.
The capsule-type liquid detergent of the present invention, machine washing design is aimed at, simple to operate, conveniently not dirty hand, quality are smooth thick suitable In, property does not hinder clothing gently, is more easy to rinse, moreover it is possible to which effectively quick removal stain is clean as new by clothing.
Embodiment
Raw material introduction:AEO (3) sodium sulphate, Cognis companies, SLES N70, active matter content 70 ± 2%;C7 branched fatty alcohol APEOs, German BASF BASF,TO 7, active matter content 100%.;Coconut palm Seed oil acid potash soap, the cocinic acid potash soap of Shanghai Soap Making Co., Ltd.'s production, active matter content 25%.
Embodiment 1
A kind of capsule-type liquid detergent, is made up of liquid detergent and capsule, capsule parcel liquid detergent.Capsule wall thickness is 0.20mm, liquid detergent weight are 25 grams.
The capsule material PVA film.
Liquid detergent formula:AEO (3) sodium sulphate 20wt%, C7 branched fatty alcohol APEOs 35wt%, cocinic acid potash soap 10wt%, butyl 20wt%, dipropylene 15wt%.
Using industry universal method, by capsule sealed envelope liquid detergent, capsule-type liquid detergent of the invention is formed.
Embodiment 2
A kind of capsule-type liquid detergent, is made up of liquid detergent and capsule, capsule parcel liquid detergent.Capsule wall thickness is 0.20mm, liquid detergent weight are 25 grams.
The capsule material PVA film.
Liquid detergent formula:AEO (3) sodium sulphate 20wt%, C7 branched fatty alcohol APEOs 35wt%, cocinic acid potash soap 10wt%, triethylene glycol butyl ether 20wt%, dipropylene 15wt%.
Using industry universal method, by capsule sealed envelope liquid detergent, capsule-type liquid detergent of the invention is formed.
Embodiment 3
A kind of capsule-type liquid detergent, is made up of liquid detergent and capsule, capsule parcel liquid detergent.Capsule wall thickness is 0.20mm, liquid detergent weight are 25 grams.
The capsule material PVA film.
Liquid detergent formula:AEO (3) sodium sulphate 20wt%, C7 branched fatty alcohol APEOs 35wt%, cocinic acid potash soap 10wt%, butyl 10wt%, triethylene glycol butyl ether 25wt%.
Using industry universal method, by capsule sealed envelope liquid detergent, capsule-type liquid detergent of the invention is formed.
Embodiment 4
A kind of capsule-type liquid detergent, is made up of liquid detergent and capsule, capsule parcel liquid detergent.Capsule wall thickness is 0.20mm, liquid detergent weight are 25 grams.
The capsule material PVA film.
Liquid detergent formula:AEO (3) sodium sulphate 20wt%, C7 branched fatty alcohol APEOs 35wt%, cocinic acid potash soap 10wt%, butyl 10wt%, triethylene glycol butyl ether 10wt%, dipropylene 15wt%.
Using industry universal method, by capsule sealed envelope liquid detergent, capsule-type liquid detergent of the invention is formed.
The capsule-type liquid detergent of the present invention includes high concentration concentration liquid detergent elite, potent stain removal, a pouch, side Just use, without outer layer plastic is torn, be directly placed into washing machine, the outer capsule of capsule-type liquid detergent is molten after 1-3 minutes Solution, you can effectively wash clothing.
Test case
Detergency test:According to method as defined in QB/T 1224-2007, the liquid scrubbing in capsule-type liquid detergent is extracted Agent, detect the detergency of the liquid detergent (0.2wt%).
Specific detection data, refer to table 1.
Table 3:Soap lye detergency test table
Embodiment 1 Embodiment 2 Embodiment 3 Embodiment 4
Decontamination ratio, (carbon black soiled cotton), P 1.02 1.03 1.01 1.06
Decontamination ratio, (albumen soiled cotton), P 1.05 1.04 1.01 1.12
Decontamination ratio, (sebum soiled cotton), P 1.09 1.06 1.04 1.28
Certainly, it is of the invention, can also have a variety of conversion and remodeling, however it is not limited to the specific reality of above-mentioned embodiment Apply example.In a word, protection scope of the present invention should include those obvious conversion to those skilled in the art Or substitute and retrofit.

Claims (5)

1. a kind of capsule-type liquid detergent, is made up of liquid detergent and capsule, the capsule wraps up the liquid detergent, and it is special Sign is that the liquid detergent includes following materials in percentage by mass:Sodium sulfate of polyethenoxy ether of fatty alcohol 15-25%, fat Fat alcohol APEO 30-40%, cocinic acid potash soap 5-15%, surplus are organic solvent;
The organic solvent is made up of following components in parts by weight:5-15 parts butyl, 5-15 part triethylene glycol butyl ether With 10-20 part dipropylenes.
2. capsule-type liquid detergent as claimed in claim 1, it is characterised in that the material of the capsule is water-soluble film.
3. capsule-type liquid detergent as claimed in claim 2, it is characterised in that the water-soluble film is PVA film, PVOH is thin Film or PVP films.
4. capsule-type liquid detergent as claimed in claim 3, it is characterised in that the water-soluble film is PVA film.
5. the capsule-type liquid detergent as any one of claim 1-4, it is characterised in that the capsule thickness is 0.10- 0.30mm。
CN201510094973.0A 2015-03-03 2015-03-03 Capsule-type liquid detergent Active CN104629964B (en)

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Families Citing this family (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN106833996B (en) * 2017-01-05 2020-04-21 广东优凯科技有限公司 Single-cavity or multi-cavity packaged liquid detergent with stable cavity film
CN107384615A (en) * 2017-07-12 2017-11-24 江苏卓尔美物联科技股份有限公司 Pearl liquid and its preparation technology are coagulated in a kind of ecological, environmental protective health type concentration laundry
CN108192767A (en) * 2018-01-09 2018-06-22 广州市加茜亚化妆品有限公司 A kind of hyperconcetration dishwashing liquid and preparation method thereof
CN108795606A (en) * 2018-07-11 2018-11-13 泉州市倍斯豪日用品有限公司 A kind of detergent capsule and its manufacturing method

Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1096442A (en) * 1993-06-18 1994-12-21 佛山友联医药发展有限公司 A kind of water-proof insoluble capsule
CN1935970A (en) * 2006-09-22 2007-03-28 王涛 Independant washing matter disintegrating agent and its use
CN101002720A (en) * 2000-03-01 2007-07-25 Pvaxx研究和开发有限公司 Method and apparatus for blowmolding capsules of polyvinylalcohol and blowmolded polyvinylalcohol capsules
CN203199403U (en) * 2012-12-19 2013-09-18 梁晓军 Laundry capsule
CN103820239A (en) * 2014-02-28 2014-05-28 刘菊 Mild safe laundry detergent

Patent Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1096442A (en) * 1993-06-18 1994-12-21 佛山友联医药发展有限公司 A kind of water-proof insoluble capsule
CN101002720A (en) * 2000-03-01 2007-07-25 Pvaxx研究和开发有限公司 Method and apparatus for blowmolding capsules of polyvinylalcohol and blowmolded polyvinylalcohol capsules
CN1935970A (en) * 2006-09-22 2007-03-28 王涛 Independant washing matter disintegrating agent and its use
CN203199403U (en) * 2012-12-19 2013-09-18 梁晓军 Laundry capsule
CN103820239A (en) * 2014-02-28 2014-05-28 刘菊 Mild safe laundry detergent

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Address after: 7th Floor, Building 143, No. 2310, Yangshupu Road, Yangpu District, Shanghai 200090

Patentee after: Shanghai Soap Factory Co.,Ltd.

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Patentee before: Shanghai Soap Co.,Ltd.

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