CN102108320A - Mouldproof liquid detergent - Google Patents
Mouldproof liquid detergent Download PDFInfo
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- CN102108320A CN102108320A CN2009102599986A CN200910259998A CN102108320A CN 102108320 A CN102108320 A CN 102108320A CN 2009102599986 A CN2009102599986 A CN 2009102599986A CN 200910259998 A CN200910259998 A CN 200910259998A CN 102108320 A CN102108320 A CN 102108320A
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- mildew
- washing liquid
- liquid according
- resistant washing
- acid
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Abstract
The invention relates to a detergent and discloses a mouldproof liquid detergent. The mouldproof liquid detergent comprises the following components in parts by weight: 0.1-1 part of triclosan DP-300, 0.1-1 part of p-chloro-m-xylenol (PCMX), 0.1-1 part of antifungal agent Plus FG, 0.1-1 part of antifungal agent LZ-25, 1-30 parts of surfactant, 0.1-1 part of chelating agent, 0.1-0.5 part of fluorescent brightener and 0.1-5 parts of thickener. As DP-300, PCMX, Plus FG and LZ-25 are used in the mouldproof liquid detergent, the liquid detergent is efficient, antibacterial, safe and harmless, has washing durability, is convenient to use, has broad-spectrum antibacterial property and can not affect the characteristics of textile and the mouldproof function can be realized. The mouldproof liquid detergent of the invention is efficient and antibacterial and has high detergency.
Description
Technical field
The present invention relates to a kind of washing composition, especially a kind of mildew-resistant washing liquid.
Background technology
Now washing liquid on the market is in washing process, only as simple clean-out system, do not have in the time of decontamination antibacterial efficiently, antibiotic, prevent the effect of going mouldy.Along with society and human consumer more and more pay attention to health, sanitation and hygiene, development both can reach the purpose that fabric cleans, and can the effective low foam laundry liquid that suppresses bacterium and mould-growth be a kind of trend in the regular hour and under the moist environment again.
Summary of the invention
The purpose of this invention is to provide a kind of mildew-resistant washing liquid, can effectively antibacterial, mildew-resistant, health environment-friendly, and the clothing degree of cleaning height after the washing.
Mildew-resistant washing liquid provided by the invention, its component and mass fraction thereof are:
(1) mould inhibitor 0.1-2 part;
(2) tensio-active agent is 1-30 part;
(3) sequestrant is 0.1-1 part;
(4) white dyes is 0.1-0.5 part;
(5) thickening material 0.1-5 part;
Also contain deionized water 61.5-98.6 part.
One or more combination below described tensio-active agent is preferred: alkylbenzene sulfonate, alkyl-sulphate, α-Xi Jihuangsuanyan, polyoxyethylenated alcohol sodium sulfate, fatty alcohol-polyoxyethylene ether, alkylphenol polyoxyethylene, alkylolamide, amine oxide.
One or both combination below described sequestrant is preferred: ethylenediamine tetraacetic acid (EDTA), disodium edta, nitrilotriacetic acid, the nitrilotriacetic acid sodium salt, ethylenediamine tetrapropionic acid(EDTP), ethylenediamine tetrapropionic acid(EDTP) sodium salt, CDTA, the CDTA sodium salt, diethylenetriamine pentaacetic acid, diethylenetriamine pentaacetic acid sodium salt.
One or both combination below described white dyes is preferred: toluylene triazine type, diphenylethyllene naphthalene triazole type, toluylene biphenyl type, stilbene disulfonic acid derivative.
Mildew-resistant washing liquid of the present invention can also add essence or spices in prescription.
Characteristics of the present invention are the composite of one or both mould inhibitors, and effectively mould fungus inhibition growth reaches mildew-proof function, has safe and harmless, easy to use, as not influence fabric self performance characteristics simultaneously.The mixture content of mould inhibitor must be lower than 0.1 part and not have mildew-proof function between 0.1 part to 2 parts, is higher than 2 parts and easily causes the product muddiness.
The present invention has powerful mildew-resistant effect, and strong detergency has same clean effect in cold water, warm water, the hot water, and foam is few during laundry, easily rinsing. and waste liquid is not phosphorous, and coenocorrelation does not pollute in can not feeding water, and pH value is less than 10, good stability.
Embodiment
Embodiment 1: a kind of mildew-resistant washing liquid, and its component and mass fraction thereof are:
300 0.2 parts of triclosan DP;
0.2 part of parachlormetaxylenol;
Sodium laurate (CH
3(CH
2)
10COONa) 6 parts;
Polyoxyethylene carboxylate (RCOO (CH
2CH
2O) nH) 3 parts;
14 parts of linear alkyl benzene sulphonates;
0.2 part in γ crystal formation toluylene trisulfonic acid derivative (BLF);
0.1 part of disodium ethylene diamine tetraacetate (EDTA-2Na);
0.1 part in essence;
2 parts of alkylolamides;
1 part in sodium-chlor;
73.2 parts of deionized waters.
Linear alkyl benzene sulphonate, sodium laurate (CH
3(CH
2)
10COONa), polyoxyethylene carboxylate (RCOO (CH
2CH
2O) nH) and alkylolamide be tensio-active agent, triclosan DP 300, parachlormetaxylenol (PCMX) are antibacterial mildew inhibitor, γ crystal formation toluylene trisulfonic acid derivative is a white dyes, closes Li Ya Fine Chemical Co., Ltd available from Shanghai, model:
BLF, sodium-chlor are thickening material, and disodium ethylene diamine tetraacetate is a sequestrant.
Embodiment 2: the preparation method of embodiment 1 described mildew-resistant washing liquid:
1. add 3000.2 parts of 73.2 parts of deionized waters, triclosan DP, 0.2 part of parachlormetaxylenol (PCMX), 6 parts of the sodium laurates that measures successively, stirring also is warming up to 60 ℃-70 ℃, add EDTA-2Na0.1 part, 3 parts of polyoxyethylene carboxylates, 14 parts of linear alkyl benzene sulphonates, 2 parts of alkylolamides again, 1 part in sodium-chlor stirs and makes it dissolving.
2. be cooled to below 30 ℃, add 0.2 part of whitening agent BLF, 0.1 part in essence, stir and make it dissolving.
3. filtering the back with 300 mesh filter screens packs.
3. 1 kinds of mildew-resistant washing liquids of embodiment, its component and mass fraction thereof are:
0.2 part of mould inhibitor Plus FG;
8 parts of polyoxyethylene carboxylates;
12 parts of polyoxyethylenated alcohol sodium sulfate;
10 parts in aliphatic alcohol polyethenoxy (9) ether;
0.1 part in toluylene biphenyl type whitening agent (CBS-X);
0.2 part of nitrilotriacetic acid;
0.1 part in essence;
2 parts of amine oxides;
67.4 parts of deionized waters.
Polyoxyethylenated alcohol sodium sulfate, polyoxyethylene carboxylate, fatty alcohol-polyoxyethylene ether and amine oxide are tensio-active agent.Toluylene biphenyl type whitening agent (CBS-X) is a white dyes, and available from green hill, Shanxi chemical inc, name of product is the Tinopal CBS-X (Tinopal CbsX CBS-X) that fluorescent brightener CBS-X or Ciba company produce; Nitrilotriacetic acid is a sequestrant, and Plus FG is a mould inhibitor, available from Ciba company.。
4. 1 kinds of washing liquids of embodiment, its component and mass fraction thereof are:
1 part of mould inhibitor LZ-25;
8 parts of sodium laurates;
5 parts of polyoxyethylene carboxylates;
10 parts of α-Xi Jihuangsuanyans;
3 parts in aliphatic alcohol polyethenoxy (7) ether;
1 part in aliphatic alcohol polyethenoxy (3) ether;
2 parts of Trisodium Citrates;
0.1 part in toluylene biphenyl type whitening agent (CBS-X)
0.1 part in essence;
1.5 parts of amine oxides;
1.5 parts in sodium-chlor;
66.8 parts of deionized waters.
α-Xi Jihuangsuanyan, sodium laurate, polyoxyethylene carboxylate, aliphatic alcohol polyethenoxy (7) ether, aliphatic alcohol polyethenoxy (3) ether and amine oxide are tensio-active agent.Toluylene biphenyl type whitening agent (CBS-X) is a white dyes, and Trisodium Citrate is a sequestrant, and sodium-chlor is thickening material.LZ-25 is available from Qingdao green bamboo Science and Technology Ltd..
Embodiment 5. clean effects relatively
Measure check embodiment 1, embodiment 3, embodiment 4 described mildew-resistant washing liquid detersive poweies of the present invention by the method for QB/T1224-2007 regulation: the standard flour strength of solution is 0.2 part, washing liquid sample solution concentration to be measured is 0.3 part, respectively with the preparation of 250mg/kg hard water, the commercial like product is numbered washing liquid 1# to washing liquid 6#, method and soiled cotton with GB/T 13174 regulations, measure the detersive power of washing liquid sample and standard flour with machine, and compare with the detersive power of standard flour.
Assay: the detersive power of standard flour is considered as 1, press the QB/T1224-2007 regulation, the washing liquid product specification is divided into three grades of A, B, C: soiled cotton JB-01, JB-02, the JB-03 by regulation is the A level simultaneously, by JB-02, JB-03 one of (both) and JB-01 is the B level, is the C level by JB-01 only.
Table 1. product of the present invention and commercial like product clean effect are relatively
Product washing effect of the present invention can reach the A level product of QB/T1224-2007 regulation
Embodiment 6. anti-mold effects compare:
Prepare the fabric of 9 parts of equivalent, respectively wash a fabric with commercial like product washing liquid 1# to 6# and embodiment 1, embodiment 3, embodiment 4 described mildew-resistant washing liquids of the present invention, the fabric that washes is not directly being put in the airtight plastics bag under the air dried situation, do sun test then, and by the big or small of artificial nasil musty and then its anti-mold effect of comparison.
Table 2. product of the present invention and commercial like product anti-mold effect are relatively
Product of the present invention is after the Exposure to Sunlight regular hour under the situation of humidity, and musty is starkly lower than commercially available other products, and as seen, the anti-mold effect of product of the present invention is better than the commercially available prod.
The above is preferred embodiment of the present invention only, is not to be used to limit protection scope of the present invention.
Claims (11)
1. a mildew-resistant washing liquid is characterized in that, component that comprises and mass fraction thereof are:
Triclosan DP-300 0.1-1 part,
Parachlormetaxylenol (PCMX) 0.1-1 part,
Plus FG 0.1-1 part,
LZ-25 0.1-1 part,
Tensio-active agent 1-30 part,
Sequestrant 0.1-1 part,
White dyes 0.1-0.5 part,
Thickening material 0.1-5 part.
2. mildew-resistant washing liquid according to claim 1 is characterized in that, also contains deionized water 59.5-98.3 part.
3. mildew-resistant washing liquid according to claim 1 is characterized in that, described mould inhibitor is selected from following one or more combination: triclosan DP-300, parachlormetaxylenol (PCMX), mould inhibitor PlusFG, mould inhibitor LZ-25.
4. mildew-resistant washing liquid according to claim 1 and 2, it is characterized in that described tensio-active agent is selected from following one or more combination: sodium laurate, alkylbenzene sulfonate, alkyl-sulphate, α-Xi Jihuangsuanyan, polyoxyethylenated alcohol sodium sulfate, fatty alcohol-polyoxyethylene ether, polyoxyethylene carboxylate, alkylphenol polyoxyethylene, alkylolamide, amine oxide.
5. mildew-resistant washing liquid according to claim 1 and 2, it is characterized in that sequestrant is selected from following one or more combination: ethylenediamine tetraacetic acid (EDTA), disodium edta, nitrilotriacetic acid, the nitrilotriacetic acid sodium salt, ethylenediamine tetrapropionic acid(EDTP), ethylenediamine tetrapropionic acid(EDTP) sodium salt, CDTA, the CDTA sodium salt, diethylenetriamine pentaacetic acid, diethylenetriamine pentaacetic acid sodium salt.
6. mildew-resistant washing liquid according to claim 1 and 2 is characterized in that, white dyes is selected from following one or more combination: toluylene triazine type, diphenylethyllene naphthalene triazole type, toluylene biphenyl type, stilbene disulfonic acid derivative.
7. mildew-resistant washing liquid according to claim 3 is characterized in that, white dyes is selected from following one or more combination: toluylene triazine type, diphenylethyllene naphthalene triazole type, toluylene biphenyl type, stilbene disulfonic acid derivative.
8. mildew-resistant washing liquid according to claim 1 and 2 is characterized in that, alternative essence or the spices of adding.
9. mildew-resistant washing liquid according to claim 3 is characterized in that, alternative essence or the spices of adding.
10. mildew-resistant washing liquid according to claim 4 is characterized in that, alternative essence or the spices of adding.
11. mildew-resistant washing liquid according to claim 5 is characterized in that, alternative essence or the spices of adding.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN2009102599986A CN102108320A (en) | 2009-12-24 | 2009-12-24 | Mouldproof liquid detergent |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN2009102599986A CN102108320A (en) | 2009-12-24 | 2009-12-24 | Mouldproof liquid detergent |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN102108320A true CN102108320A (en) | 2011-06-29 |
Family
ID=44172604
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN2009102599986A Pending CN102108320A (en) | 2009-12-24 | 2009-12-24 | Mouldproof liquid detergent |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN102108320A (en) |
Cited By (9)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN103264609A (en) * | 2013-05-09 | 2013-08-28 | 广州大学 | Chemical composition and drawing method |
| CN103540417A (en) * | 2013-10-18 | 2014-01-29 | 桂林雪芙莲日化有限公司 | Anti-mold liquid laundry detergent |
| CN104736687A (en) * | 2012-09-07 | 2015-06-24 | 荷兰联合利华有限公司 | Soap composition |
| CN105779156A (en) * | 2014-12-24 | 2016-07-20 | 阎珊珊 | Preparation of foam-free liquid laundry detergent |
| CN106434033A (en) * | 2016-09-27 | 2017-02-22 | 枣阳市华威硅氟材料有限公司 | Wool cleaning agent containing amino silicon oil |
| CN107287038A (en) * | 2017-05-24 | 2017-10-24 | 钱小平 | A kind of aerobic laundry care agent |
| CN111088124A (en) * | 2019-12-30 | 2020-05-01 | 山西晋光化工有限公司 | Special stilbene bistriazine fluorescent whitening agent for detergent and preparation method thereof |
| CN111548361A (en) * | 2020-05-29 | 2020-08-18 | 广东迪美生物技术有限公司 | Novel high-stability transparent silver ion complex and preparation method and application thereof |
| CN114903039A (en) * | 2021-02-09 | 2022-08-16 | 宝洁公司 | Antimicrobial compositions |
-
2009
- 2009-12-24 CN CN2009102599986A patent/CN102108320A/en active Pending
Cited By (11)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN104736687A (en) * | 2012-09-07 | 2015-06-24 | 荷兰联合利华有限公司 | Soap composition |
| CN104736687B (en) * | 2012-09-07 | 2018-03-02 | 荷兰联合利华有限公司 | Soap composition |
| CN103264609A (en) * | 2013-05-09 | 2013-08-28 | 广州大学 | Chemical composition and drawing method |
| CN103540417A (en) * | 2013-10-18 | 2014-01-29 | 桂林雪芙莲日化有限公司 | Anti-mold liquid laundry detergent |
| CN105779156A (en) * | 2014-12-24 | 2016-07-20 | 阎珊珊 | Preparation of foam-free liquid laundry detergent |
| CN106434033A (en) * | 2016-09-27 | 2017-02-22 | 枣阳市华威硅氟材料有限公司 | Wool cleaning agent containing amino silicon oil |
| CN107287038A (en) * | 2017-05-24 | 2017-10-24 | 钱小平 | A kind of aerobic laundry care agent |
| CN111088124A (en) * | 2019-12-30 | 2020-05-01 | 山西晋光化工有限公司 | Special stilbene bistriazine fluorescent whitening agent for detergent and preparation method thereof |
| CN111548361A (en) * | 2020-05-29 | 2020-08-18 | 广东迪美生物技术有限公司 | Novel high-stability transparent silver ion complex and preparation method and application thereof |
| CN114903039A (en) * | 2021-02-09 | 2022-08-16 | 宝洁公司 | Antimicrobial compositions |
| WO2022170454A1 (en) * | 2021-02-09 | 2022-08-18 | The Procter & Gamble Company | Anti-microbial composition |
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Addressee: Beijing Luowa Daily Chemical Co., Ltd. Sun Hong Document name: Notification that Application Deemed to be Withdrawn |
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Application publication date: 20110629 |